The present study investigates the potential of latent heat storage using phase change materials (PCMs) to reduce building energy consumption, addressing the common challenges of PCM leakage and compatibility with construction materials. We introduce a novel phase change hydrogel, created by encapsulating polyethylene glycol (PEG) within a superabsorbent polymer (SAP) network through osmotic pressure. The structural and thermal characteristics of the PEG/SAP composite were analyzed using differential scanning calorimetry (DSC), thermal gravimetric analysis (TG), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and polarizing optical microscopy (POM). Results demonstrated that PEG effectively filled the SAP network, forming a stable composite structure, with PEG as the core and SAP as the supporting matrix. The composite achieved a remarkable PEG mass fraction of 80 %, yielding a melting enthalpy of 129.7 J/g and a peak melting temperature of 51.89 °C. Additionally, PEG/SAP exhibited robust thermal stability up to 300 °C. Notably, when incorporated into cement, surface temperatures of phase change cement decreased by 12 °C compared to conventional Portland cement under constant heating. This approach highlights high latent heat capacity, low production costs, and straightforward fabrication, positioning PEG/SAP as a promising solution for large-scale applications in building energy conservation.
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