Fabrication and building energy-saving performance evaluation of polyethylene glycol/polymethyl methacrylate/expanded graphite thermal enhanced shape-stable phase change material

Abstract

Integrating Phase Change Material (PCM) with building envelope is a promising way to reduce building energy consumption. However, leakage and insufficient PCM loading rate for existing encapsulation strategies limit its further application. In this work, a safer and easier way to fabricate Shape-Stable Phase Change Material (SSPCM) is proposed, whose products combine the outstanding leakage-proof property and high PCM loading rate. With the method of in-situ polymerization, not only the Polyethylene Glycol (PEG) is packaged by Polymethyl Methacrylate (PMMA), but the Expanded Graphite (EG) also has a chance to be added as the property regulator. The prepared SSPCMs are proved to be shape-stable over melting temperature with a leakage rate under 1 %. The characterization test reveals that with EG mass fraction increase from 0 to 2.5 %, the thermal conductivity augments from 0.23 to 1.73 W/(m·K) while the phase change latent enthalpy changes from 85.11 kJ/kg to 116.10 kJ/kg. Notably, the EG is more than a thermal conductivity enhancer, it also plays an important role in the modification of comprehensive properties. To optimize the building energy-saving performance of SSPCMs, the factors affecting building cooling electricity consumption like deployment position and thermal properties are evaluated in detail. The simulation results show that the optimum strategy is employing SSPCM with 2.0 wt% EG in the middle of the envelope, the cooling electricity consumption can be reduced by 8.64 % compared with the benchmark. The physical mechanism of energy-saving is also discussed from multiple angles. From a statistical view, sensitivity and uncertainty analysis of the simulation results is completed, to identify the influence of input parameters and validate the reliability of the simulation results. Finally, an economic analysis is carried out, proving the economic feasibility for further application. This research provides valuable insights for SSPCM’s application and design of energy-efficient buildings.