The contribution of a solid phase to the low-shear viscosity of a solid–liquid dispersion, i.e., the specific viscosity, ηSP, is investigated theoretically by applying a variational procedure. The Fuchs stability ratio has been interpreted as a general steady-state equilibrium constant for aggregation and has been extended to a functional form which describes the motion of two Brownian units in a dispersion. Application of the Euler–Lagrange equation under the validity of an adiabatic-like approximation for the Hamiltonian (approximately Brownian kinetic energy and inertial potential field) yields a constraint that involves specific viscosity, solid volume fraction, φ, interparticle energy and correlation functions of the dispersed phase. The Einstein formula is found as the limit of the Saito equation when an infinitely dilute hard-sphere suspension is considered, while a general closed form expression, ηSP=ηSP(φ), is proposed for a concentrated suspension. It depends on the particle coordination number and affinity, returns the low density expansion predicted by effective-medium-type theories for the viscosity, and can be represented as the sum of two dominant contributions, associated respectively with the first peak of the radial distribution function and the second peak of the total correlation function. Application to experimental data, concerning latex particles in cis-decalin and interacting silica–water systems, is presented and discussed.
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