Broken Time-reversal Symmetry Research Articles

Observation of flat bands and Dirac cones in a pyrochlore lattice superconductor

Emergent phases often appear when the electronic kinetic energy is comparable to the Coulomb interactions. One approach to seek material systems as hosts of such emergent phases is to realize localization of electronic wavefunctions due to the geometric frustration inherent in the crystal structure, resulting in flat electronic bands. Recently, such efforts have found a wide range of exotic phases in the two-dimensional kagome lattice, including magnetic order, time-reversal symmetry breaking charge order, nematicity, and superconductivity. However, the interlayer coupling of the kagome layers disrupts the destructive interference needed to completely quench the kinetic energy. Here we demonstrate that an interwoven kagome network—a pyrochlore lattice—can host a three dimensional (3D) localization of electron wavefunctions. Meanwhile, the nonsymmorphic symmetry of the pyrochlore lattice guarantees all band crossings at the Brillouin zone X point to be 3D gapless Dirac points, which was predicted theoretically but never yet observed experimentally. Through a combination of angle-resolved photoemission spectroscopy, fundamental lattice model and density functional theory calculations, we investigate the novel electronic structure of a Laves phase superconductor with a pyrochlore sublattice, CeRu2. We observe evidence of flat bands originating from the Ce 4f orbitals as well as flat bands from the 3D destructive interference of the Ru 4d orbitals. We further observe the nonsymmorphic symmetry-protected 3D gapless Dirac cone at the X point. Our work establishes the pyrochlore structure as a promising lattice platform to realize and tune novel emergent phases intertwining topology and many-body interactions.

Noise-Induced Phase Separation and Time Reversal Symmetry Breaking in Active Field Theories Driven by Persistent Noise.

Within the Landau-Ginzburg picture of phase transitions, scalar field theories develop phase separation because of a spontaneous symmetry-breaking mechanism. This picture works in thermodynamics but also in the dynamics of phase separation. Here we show that scalar nonequilibrium field theories undergo phase separation just because of nonequilibrium fluctuations driven by a persistent noise. The mechanism is similar to what happens in motility-induced phase separation where persistent motion introduces an effective attractive force. We observe that noise-induced phase separation occurs in a region of the phase diagram where disordered field configurations would otherwise be stable at equilibrium. Measuring the local entropy production rate to quantify the time-reversal symmetry breaking, we find that such breaking is concentrated on the boundary between the two phases.

Ultrafast Polarization-Resolved Phonon Dynamics in Monolayer Semiconductors.

Monolayer transition metal dichalcogenide semiconductors exhibit unique valleytronic properties interacting strongly with chiral phonons that break time-reversal symmetry. Here, we observed the ultrafast dynamics of linearly and circularly polarized E'(Γ) phonons at the Brillouin zone center in single-crystalline monolayer WS2, excited by intense, resonant, and polarization-tunable terahertz pulses and probed by time-resolved anti-Stokes Raman spectroscopy. We separated the coherent phonons producing directional sum-frequency generation from the incoherent phonon population emitting scattered photons. The longer incoherent population lifetime than what was expected from coherence lifetime indicates that inhomogeneous broadening and momentum scattering play important roles in phonon decoherence at room temperature. Meanwhile, the faster depolarization rate in circular bases than in linear bases suggests that the eigenstates are linearly polarized due to lattice anisotropy. Our results provide crucial information for improving the lifetime of chiral phonons in two-dimensional materials and potentially facilitate dynamic control of spin-orbital polarizations in quantum materials.

Evidence for time-reversal symmetry-breaking kagome superconductivity.

Superconductivity and magnetism are often antagonistic in quantum matter, although their intertwining has long been considered in frustrated-lattice systems. Here we utilize scanning tunnelling microscopy and muon spin resonance to demonstrate time-reversal symmetry-breaking superconductivity in kagome metal Cs(V, Ta)3Sb5, where the Cooper pairing exhibits magnetism and is modulated by it. In the magnetic channel, we observe spontaneous internal magnetism in a fully gapped superconducting state. Under the perturbation of inverse magnetic fields, we detect a time-reversal asymmetrical interference of Bogoliubov quasi-particles at a circular vector. At this vector, the pairing gap spontaneously modulates, which is distinct from pair density waves occurring at a point vector and consistent with the theoretical proposal of an unusual interference effect under time-reversal symmetry breaking. The correlation between internal magnetism, Bogoliubov quasi-particles and pairing modulation provides a chain of experimental indications for time-reversal symmetry-breaking kagome superconductivity.

Loss-compensated non-reciprocal scattering based on synchronization

Breaking the reciprocity of wave propagation is a problem of fundamental interest, and a much-sought functionality in practical applications, both in photonics and phononics. Although it has been achieved using resonant linear scattering from cavities with broken time-reversal symmetry, such realizations have remained inescapably plagued by inherent passivity constraints, which make absorption losses unavoidable, leading to stringent limitations in transmitted power. In this work, we solve this problem by converting the cavity resonance into a limit cycle, exploiting the uncharted interplay between non-linearity, gain, and non-reciprocity. Remarkably, strong enough incident waves can synchronize with these self-sustained oscillations and use their energy for amplification. We theoretically and experimentally demonstrate that this mechanism can simultaneously enhance non-reciprocity and compensate absorption. Real-world acoustic scattering experiments allow us to observe non-reciprocal transmission of audible sound in a synchronization-based three-port circulator with full immunity against losses.

Characterization of ferromagnetic semiconductors and valley polarization in janus VBXS2(X = N, P) monolayers

The manipulation of the valley degree of freedom has attracted increasing attention in both fundamental scientific research and emerging applications. Here, we employ first-principles calculations to investigate the structural stability and electronic properties of Janus monolayers of VBXS2 (X=N, P). These materials exhibit characteristics of ferromagnetic semiconductors, with their valence band maximum located at the K/K′ point. Due to the combined effects of inversion symmetry breaking and time reversal symmetry breaking, VBNS2 and VBPS2 exhibit exotic spontaneous valley polarization in their top valence bands, measured at magnitudes of 48.6 meV and 47.6 meV, respectively. Consequently, this phenomenon potentially enables the observation of the anomalous valley Hall effect (AVHE). The unique electronic and valleytronic properties exhibited by Janus VBXS2 suggest a feasible experimental avenue for exploring ferrovalley (FV) and valley-related Hall effects within a two dimensional lattice.

Anomalous relaxation and hyperuniform fluctuations in center-of-mass conserving systems with broken time-reversal symmetry.

We study the Oslo model, a paradigm for absorbing-phase transition, on a one-dimensional ring of L sites with a fixed global density ρ[over ¯]; we consider the system strictly above critical density ρ_{c}. Notably, microscopic dynamics conserve both mass and center of mass (CoM), but lack time-reversal symmetry. We show that, despite having highly constrained dynamics due to CoM conservation, the system exhibits diffusive relaxation away from criticality and superdiffusive relaxation near criticality. Furthermore, the CoM conservation severely restricts particle movement, causing the mobility-a transport coefficient analogous to the conductivity for charged particles-to vanish exactly. Indeed, the steady-state temporal growth of current fluctuation is qualitatively different from that observed in diffusive systems with a single conservation law. Remarkably, far from criticality where the relative density Δ=ρ[over ¯]-ρ_{c}≫ρ_{c}, the second cumulant, or the variance, 〈Q_{i}^{2}(T,Δ)〉_{c}, of current Q_{i} across the ith bond up to time T in the steady-state saturates as 〈Q_{i}^{2}〉_{c}≃Σ_{Q}^{2}(Δ)-constT^{-1/2}; near criticality, it grows subdiffusively as 〈Q_{i}^{2}〉_{c}∼T^{α}, with 0<α<1/2, and eventually saturates to Σ_{Q}^{2}(Δ). Interestingly, the asymptotic current fluctuation Σ_{Q}^{2}(Δ) is a nonmonotonic function of Δ: It diverges as Σ_{Q}^{2}(Δ)∼Δ^{2} for Δ≫ρ_{c} and Σ_{Q}^{2}(Δ)∼Δ^{-δ}, with δ>0, for Δ→0^{+}. Using a mass-conservation principle, we exactly determine the exponents δ=2(1-1/ν_{⊥})/ν_{⊥} and α=δ/zν_{⊥} via the correlation-length and dynamic exponents, ν_{⊥} and z, respectively. Finally, we show that in the steady state the self-diffusion coefficient D_{s}(ρ[over ¯]) of tagged particles is connected to activity through the relation D_{s}(ρ[over ¯])=a(ρ[over ¯])/ρ[over ¯].

Unraveling the evolution of multigap superconductivity in layered Na–B–C films: An additional energy gap induced by the internal B–C layer

Multigap superconductors provide a platform to confirm rich new physics such as time-reversal symmetry breaking, giant paramagnetic response, and hidden criticality. However, an obstacle hindering the experimental validation of these phenomena lies in the lack of superconductors with three or more gaps and critical temperatures higher than the liquid nitrogen temperature. In this work, we predicted NaB2C2 and Na2B3C3 films with high-temperature superconductivity (beyond 90 K) using the fully anisotropic Migdal-Eliashberg theory. The multigap behaviors of Na–B–C films with three and five atomic layers were analyzed in detail, revealing two typical configurations: three-gap (NaB2C2) and four-gap (Na2B3C3) superconductors. Compared with the NaB2C2 film, the additional gap observed in the Na2B3C3 film originates from the in-plane covalent state of the internal B–C layer. This research offers valuable insights into the evolution of multigap superconductivity in layered B–C films.

Minimal model for chirally induced spin selectivity: spin-orbit coupling, tunneling and decoherence

Here we review a universal model for chirally induced spin-selectivity (CISS) as a standalone effect occurring in chiral molecules. We tie together the results of forward scattering in the gas phase to the results for photoelectrons in chiral self-assembled monolayers, and the more contemporary results in two terminal transport setups. We discuss the ingredients that are necessarily present in all experiments to date, which we identify as: (i) chirality, be it point, helical or configurational, (ii) the spin–orbit coupling as the spin active coupling of atomic origin, (iii) decoherence as a time-reversal symmetry breaking mechanism that avoids reciprocity relations in the linear regime and finally (iv) tunneling that accounts for the magnitude of the spin polarization effect. This proposal does not discard other mechanisms that can yield comparable spin effects related to interactions of the molecule to contacts or substrates that have been proposed but are less universal or apply to specific situations. Finally, we discuss recent results suggesting CISS as a molecular phenomenon in the realms of enantiomer selectivity, coherent electron transfer, and spin effects in chiroptical activity.

Measurement and Feed Forward Induced Entanglement Negativity Transition.

We study the interplay between measurement-induced dynamics and conditional unitary evolution in quantum systems. We numerically and analytically investigate commuting random measurement and feed forward (MFF) processes and find a sharp transition in their ability to generate entanglement negativity as the number of MFF channels varies. We also establish a direct connection between these findings and transitions induced by random dephasing from an environment with broken time-reversal symmetry. In one variant of the problem, we employ free probability theory to rigorously prove the transition's existence. Furthermore, these MFF processes have dynamic circuit representations that can be experimentally explored on current quantum computing platforms.

Information-theoretical limit on the estimates of dissipation by molecular machines using single-molecule fluorescence resonance energy transfer experiments.

Single-molecule fluorescence resonance energy transfer (FRET) experiments are commonly used to study the dynamics of molecular machines. While in vivo molecular processes often break time-reversal symmetry, the temporal directionality of cyclically operating molecular machines is often not evident from single-molecule FRET trajectories, especially in the most common two-color FRET studies. Solving a more quantitative problem of estimating the energy dissipation/entropy production by a molecular machine from single-molecule data is even more challenging. Here, we present a critical assessment of several practical methods of doing so, including Markov-model-based methods and a model-free approach based on an information-theoretical measure of entropy production that quantifies how (statistically) dissimilar observed photon sequences are from their time reverses. The Markov model approach is computationally feasible and may outperform model free approaches, but its performance strongly depends on how well the assumed model approximates the true microscopic dynamics. Markov models are also not guaranteed to give a lower bound on dissipation. Meanwhile, model-free, information-theoretical methods systematically underestimate entropy production at low photoemission rates, and long memory effects in the photon sequences make these methods demanding computationally. There is no clear winner among the approaches studied here, and all methods deserve to belong to a comprehensive data analysis toolkit.

Irreversibility in belief dynamics: Unraveling the link to cognitive effort.

The relationship between time irreversibility in neuronal dynamics and cognitive effort is a subject of growing interest in the scientific literature. Although correlations between proxies of both concepts have been experimentally observed, the underlying precise linkage between them remains elusive. Here we investigate the case of learning in decision-making tasks; we do so by introducing a thermodynamically grounded metric-inspired by Landauer's principle-which connects time-irreversible information processing to energy consumption. Equipped with this metric, we investigate the role of macroscopic time-reversal symmetry breaking in belief dynamics for the case of an agent with finite sensitivity while performing a static two-armed bandit task-a standard setup in cognitive neuroscience. To gain insights into the belief dynamics, we analogize it to the dynamics of an active particle subject to state-dependent noise and living in a two-dimensional space. This mapping allows an analytical description of learning-induced biases. We deeply explore the case of Q-learning with forgetting the nonchosen option. In this case, learning-induced risk aversion is formally equivalent to standard thermophoresis, i.e., the net motion towards low-temperature regions. Finally, we quantify the irreversibility of belief dynamics in the steady state for different bandit configurations, sensitivity levels, and exploitative behavior. We found a strong correlation in high-sensitivity learning between heightened irreversibility in belief dynamics and improved decision-making outcomes. Notably, as the task's difficulty increases, a greater degree of irreversibility in belief dynamics becomes necessary for having superior performances; this explicitly unravels a plausible connection between time irreversibility and cognitive effort. In conclusion, our investigation reveals that irreversibility in belief dynamics bridges out-of-equilibrium statistical physics concepts and cognitive neuroscience. In decision-making contexts, this perspective offers insights into the notion of cognitive effort, suggesting a potential mechanism driving the evolution of living systems toward out-of-equilibrium structures.

Spin-Orbit-Locking Chiral Bound States in the Continuum.

Bound states in the continuum (BICs), which are confined optical modes exhibiting infinite quality factors and carrying topological polarization configurations in momentum space, have recently sparked significant interest across both fundamental and applied physics. Here, we show that breaking time-reversal symmetry by an external magnetic field enables a new form of chiral BICs with spin-orbit locking. Applying a magnetic field to a magneto-optical photonic crystal slab lifts doubly degenerate BICs into a pair of chiral BICs carrying opposite pseudospins and orbital angular momenta. Multipole analysis verifies the nonzero angular momenta and reveals the spin-orbital-locking behaviors. In momentum space, we observe ultrahigh quality factors and near-circular polarization surrounding chiral BICs, enabling potential applications in spin-selective nanophotonics. Compared to conventional BICs, the magnetically induced chiral BICs revealed here exhibit distinct properties and origins, significantly advancing the topological photonics of BICs by incorporating broken time-reversal symmetry.

Superconducting diode effect in two-dimensional topological insulator edges and Josephson junctions

The superconducting diode effect—the dependence of critical current on its direction—can arise from the simultaneous breaking of inversion and time-reversal symmetry in a superconductor and has gained interest for its potential applications in superconducting electronics. In this Letter, we study the effect in a two-dimensional topological insulator (2D TI) in both a uniform geometry as well as in a long Josephson junction. We show that in the presence of Zeeman fields, a circulating edge current enables a large non-reciprocity of the critical current. We find a maximum diode efficiency of 1 for the uniform 2D TI and (2−1)2≈0.17 for the long Josephson junction.

Hydrodynamics of Borromean Counterfluids.

Counterflow superfluidity in a system with N≥3 components is distinctively different from the N=2 case. The key feature is the difference between the number (N) of elementary vortex excitations and the number (N-1) of independent branches of phonon modes, that is, the number of superfluid modes is larger than the number of ordered phase variables. We formulate a hydrodynamic theory of this state. We show how all the dynamical and statistical aspects of this ("Borromean") type of ordering are naturally described by effective N-component theory featuring compact-gauge invariance. We also discuss how off diagonal intercomponent couplings convert the Borromean supercounterfluid into a Borromean insulator, with an emphasis on the properties of a nontrivial state with broken time-reversal symmetry.

Tunable hybrid-order Weyl semimetal via staggered magnetic flux

We investigate a hybrid-order Weyl semimetal (HOWS) constructed by stacking the two-dimensional kagome lattice with staggered magnetic flux. By adjusting the magnitude of flux, higher-order topological phases are tunably intertwined with the first-order topological Chern insulators, which is governed by the evolution of Weyl points. Meanwhile the surface Fermi arcs undergo topological Lifshitz transition. Notably, due to the breaking of time-reversal symmetry (TRS), a novel split of a quadratic double Weyl point occurs, giving rise to additional three type-II Weyl points hybridizing with one type-I node. This phenomenon plays a crucial role in realizing high-Chern-number phases with C=±2 and reveals a new mechanism for the emergence of type-II Weyl fermions in topological kagome semimetals. We anticipate that this study will stimulate further investigation into the unique physics of kagome materials and Weyl semimetals.

Unconventional superconductivity in chiral molecule-TaS2 hybrid superlattices.

Chiral superconductors, a unique class of unconventional superconductors in which the complex superconducting order parameter winds clockwise or anticlockwise in the momentum space1, represent a topologically non-trivial system with intrinsic time-reversal symmetry breaking (TRSB) and direct implications for topological quantum computing2,3. Intrinsic chiral superconductors are extremely rare, with only a few arguable examples, including UTe2, UPt3 and Sr2RuO4 (refs. 4-7). It has been suggested that chiral superconductivity may exist in non-centrosymmetric superconductors8,9, although such non-centrosymmetry is uncommon in typical solid-state superconductors. Alternatively, chiral molecules with neither mirror nor inversion symmetry have been widely investigated. We suggest that an incorporation of chiral molecules into conventional superconductor lattices could introduce non-centrosymmetry and help realize chiral superconductivity10. Here we explore unconventional superconductivity in chiral molecule intercalated TaS2 hybrid superlattices. Our studies reveal an exceptionally large in-plane upper critical field Bc2,|| well beyond the Pauli paramagnetic limit, a robust π-phase shift in Little-Parks measurements and a field-free superconducting diode effect (SDE). These experimental signatures of unconventional superconductivity suggest that the intriguing interplay between crystalline atomic layers and the self-assembled chiral molecular layers may lead to exotic topological materials. Our study highlights that the hybrid superlattices could lay a versatile path to artificial quantum materials by combining a vast library of layered crystals of rich physical properties with the nearly infinite variations of molecules of designable structural motifs and functional groups11.

Tunable quasi-bound states in the continuum in magneto-optical metasurfaces

The enhancement of electromagnetic field with high Q factor in metasurfaces has attracted extensive attention of researchers. Magneto-optical metasurfaces (MOMS) provide approaches with controllable magnetic fields to modulate the optical response, which contributes towards the magneto-optical Kerr effect in nanophotonic devices. However, it is challenging for MOMS to obtain narrow spectra peak with high Q factors. Here, we propose MOMS-supported quasi-bound states in the continuum (quasi-BIC) and theoretically investigate the evolution process from BIC to quasi-BIC. By applying an external magnetic field, the BIC in our proposed metasurface can be transformed into a quasi-BIC with finite Q factor up to 33 620. Meanwhile, the quasi-BIC shows magnetization-related circular dichroism with a vortex point in the polarization graph, based on time-reversal symmetry breaking in the magneto-optical material under the condition of external magnetic field. The quasi-BIC also maintains nearly unity reflection and almost zero absorption, showing a promising future in sensing. Our results enrich the light control mechanisms of MOMS and provide a unique opportunity for applications requiring flexible tunability and high Q factors, such as sensors, laser sources, filters and chiral-related elements.

Thermal conductivity of nonunitary triplet superconductors: application to UTe2

Considerable evidence shows that the heavy fermion material UTe2 is a spin-triplet superconductor, possibly manifesting time-reversal symmetry breaking, as measured by Kerr effect below the critical temperature, in some samples. Such signals can arise due to a chiral orbital state or possible nonunitary pairing. Although experiments at low temperatures appear to be consistent with point nodes in the spectral gap, the detailed form of the order parameter and even the nodal positions are not yet determined. Thermal conductivity measurements can extend to quite low temperatures, and varying the heat current direction should be able to provide information on the order parameter structure. Here, we derive a general expression for the thermal conductivity of a spin-triplet superconductor and use it to compare the low-temperature behavior of various states proposed for UTe2.

Optical manipulation of the charge-density-wave state in RbV3Sb5.

Broken time-reversal symmetry in the absence of spin order indicates the presence of unusual phases such as orbital magnetism and loop currents1-4. The recently discovered kagome superconductors AV3Sb5 (where A is K, Rb or Cs)5,6 display an exotic charge-density-wave (CDW) state andhave emerged as astrong candidate for materialshosting a loop currentphase. The idea that the CDW breaks time-reversal symmetry7-14 is, however, being intensely debated due to conflicting experimental data15-17. Here we use laser-coupled scanning tunnelling microscopy to study RbV3Sb5. By applying linearly polarized light along high-symmetry directions, we show that the relative intensities of the CDW peaks can be reversibly switched, implying a substantial electro-striction response, indicative of strong nonlinear electron-phonon coupling. A similar CDW intensity switching is observed with perpendicular magnetic fields, which implies an unusual piezo-magnetic response that, in turn, requires time-reversal symmetry breaking. We show that the simplest CDW that satisfies these constraints is an out-of-phase combination of bond charge order and loop currents that we dub a congruent CDW flux phase. Our laser scanning tunnelling microscopy data open the door to the possibility of dynamic optical control of complex quantum phenomenon in correlated materials.