Broad Peak Research Articles

Green synthesis of silver nanoparticles using Acroptilon repens aqueous extract and their antibacterial efficacy against multidrug-resistant Acinetobacter baumannii.

Acinetobacter baumannii is a critical pathogen associated with hospital-acquired infections, particularly in burn and intensive care unit (ICU) patients, and is notorious for its high level of antibiotic resistance. This study aims to evaluate the antibacterial potential of silver nanoparticles (AgNPs) synthesized using Acroptilon repens extract as a promising alternative treatment for combating multidrug-resistant A. baumannii. Twelve clinical isolates of A. baumannii were identified through biochemical testing. Antibiotic susceptibility testing using the Kirby-Bauer disk diffusion method revealed universal resistance to ceftazidime, amikacin, imipenem, gentamicin, ciprofloxacin, and piperacillin-tazobactam, while all isolates remained sensitive to colistin (p ≤ 0.05). AgNPs were synthesized using A. repens extract and characterized through transmission electron microscopy (TEM), scanning electron microscopy (SEM), particle size analysis (PSA), UV-Vis spectroscopy, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FT-IR). TEM analysis showed that the AgNPs had a spherical morphology with an average particle size of approximately 30nm, while SEM confirmed their spherical shape and size distribution, ranging from 10 to 130nm, with a mean size of 38.89nm. UV-Vis spectroscopy confirmed the successful formation of AgNPs, indicated by a distinct broad absorption peak between 400 and 480nm. XRD analysis validated the crystalline nature of the nanoparticles, with characteristic peaks at 2θ values of 38.21°, 46.28°, 64.57°, and 77.49°, corresponding to the (111), (200), (220), and (311) planes of face-centered cubic (fcc) silver. Antibacterial activity was evaluated by determining the minimum inhibitory concentration (MIC), which ranged from 50 to 400µg/mL. The highest inhibitory activity was observed at 400µg/mL. Gene expression analysis using quantitative real-time PCR (qRT-PCR) demonstrated downregulation of the oprD and carO porin genes following AgNP treatment. However, these reductions were not statistically significant (p = 0.302 and p = 0.198, respectively). AgNPs synthesized from A. repens demonstrated strong antibacterial activity against multidrug-resistant A. baumannii. While downregulation of porin genes was observed, further investigation is required to elucidate the underlying mechanisms of action and assess their potential clinical applications. These findings support the potential of AgNPs as an alternative therapeutic strategy for addressing A. baumannii infections resistant to conventional antibiotics.

Spin glass behavior of single-crystalline ErFe2O4−δ

Abstract We investigated magnetic properties of ErFe2O4-δ single crystal containing oxygen vacancies with value of δ being estimated to be 0.066. The temperature dependence of dc magnetization in zero field cooling (ZFC) process reveals that ErFe2O4-δ undergoes a ferrimagnetic transition at 234 K followed by a broad peak at 224.3 K. The latter is attributable to the spin glass transition as indicated by the strong frequency dependence of temperature-dependent ac susceptibility. The frequency variation of transition temperature is described well by the dynamic scaling law and the critical exponent is similar to those reported for typical spin glasses. Additionally, the spin glass transition at 224.3 K is confirmed by the fact that the magnetic field dependence of irreversible transition temperature is coincident with the de Almeida-Thouless line and that the aging memory and rejuvenation effect is observed. Noticeably, ErFe2O4-δ single crystal exhibits the field-cooled hysteresis loop shift and training effect below 200 K, suggesting the occurrence of exchange bias effect originating from the spin glass phase.

Temperature and Ge fraction dependence of broad peaks observed in Ge-rich SiGe Raman spectra by oil-immersion Raman spectroscopy

Abstract We present the temperature and Ge fraction dependence of the broad peaks at the lower wavenumber side of the Ge-Ge vibration mode in Raman spectra from Ge-rich Si1−xGex thin films (x = 0.750, 0.852, and 0.918) investigated by oil-immersion Raman spectroscopy. The sample temperature was elevated by increasing laser power and estimated using the relation between Raman shift ω and temperature T (dω/dT) of Ge-Ge vibration mode. The broad peaks observed from all the Ge-rich SiGe thin films shifted toward the lower wavenumber side with increasing laser power. We confirmed that dω/dT of the broad peak differs from the Ge-Ge vibration mode and changes with increasing Ge fraction. In addition, we found that the correlation between Ge fraction and the peak intensity ratio of the broad peak and the Ge-Ge vibration mode is almost the same at various laser power conditions.

Study of Some Structural and Optical Properties for Synthesized Graphene/Polyaniline/Zns Nanocomposite

Hybrid graphene (GR)/ polyaniline (PANI) based composites incorporating zinc sulfide (ZnS) nanoparticles were synthesized using the drop-casting method. The weight percentage of ZnS was varied from 0.01 to 0.05%. The optical, structural, and morphological characteristics of the nanocomposite were examined utilizing X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopic (AFM), and UV-Vis spectroscopy. The qualities and dimensions of the GR, PANI, and ZnS NPs and nanoparticle morphology resulting from the nanocomposite process were examined. Utilizing energy dispersive energy X-ray dispersive (EDX), the weight percentage of each element can be verified. The widening sharp peaks in the XRD patterns suggested the creation of a nanocrystalline phase of ZnS with a crystallite size of less than 50 nm. SEM demonstrated the interaction between ZnS nanoparticles and graphene/polyaniline. Surface topography examination using AFM shows that ZnS NPs may be effectively dispersed on top of GR/PANI structures. The ultraviolet-visible absorption spectrum (UV-Vis) showed a small absorption peak at the wavelength of 459.34nm and a broad absorption peak at 652nm.

Study the Structural and Optical Properties (Energy Gap) of Polythiophene/MWCNT/SnO2 Nanocomposite as an NO2 Gas Sensor

The polythiophene (PTh) is of great interest in various applications due to its unique electrical, mechanical and structural. In this work, PTh was synthesized using the oxidation method by employing ferric chloride (FeCl3) as an oxidizing agent, Then the nanocomposite polythiophene: Multi walled carbon nanotubes: Tin (IV) oxide (PTh/MWCNT/SnO2) was prepared by adding constant weight ratio of MWCNT(0.7g) and different weight ratios of SnO2 (0.1, and 0.5g) using the oxidation method. The FE-SEM images of the pure PTh and the nanocomposite showed an apparent change in the morphological composition of the surface. The X-ray diffraction (XRD) pattern of PTh/ MWCNT/SnO2 nanocomposites show the appearance of clear peaks for SnO2, while there are broad peaks for MWCNT. As for the polymer, its behavior is random. The morphology of these nanocomposites shows that the nanotubes were not well aligned and were randomly entangled. The Fourier transformer infrared (FT-IR) spectra of the pure and nanocomposite samples prepared by chemical method in the range of 450-4000 cm-1 wave number are recognized the chemical pledges (bonds) as well as functional groups in the compound. The band gap energy decreased from 3.53 into 2.78 and 2.97 when SnO2 was added. The sensitivity of the two nanocomposites shows a good enhancement 14.6% and 62% at temperature 150oC as gas sensor.

Electro-optical and thermal characterization of copper tartrate crystals grown in silica gel

Copper Tartrate crystals were grown by Gel Growth technique by single diffusion method. Silica gel of Optimum specific gravity was set with tartaric acid at optimum pH and aging period. Band gap of copper tartrate crystal is determined using to be 5.24 eV. In PL spectra broad peak is observed at nearly 367.44186 nm in the range 287 nm to 458 nm along with the sharp, intense transmission maxima peak at wavelength nearly 505.03876 nm which is characteristic of a material composition and electronic band structure. This shows the transparency of it in UV-Visible region and it as a filter in this range TGA analysis concludes that Copper tartrate has loss of one-half water molecule as crystalline water and is stable up to 85.02 ℃DSC analysis assigns the temperature value 314.5 ℃ as melting point and apparent enthalpy of fusion determined is 10.18 mW.

Validation of quantum espresso software in estimating the optical parameters of CaAlSiN3 crystal

This communication presents a theoretical analysis of certain optical properties of the CaAlSiN3 (CASN) crystal through first principles calculation. For the first time, this work validates the optical properties of the crystal performed using Quantum ESPRESSO (Acronym for opEn-Source Package for Research in Electronic Structure, Simulation, and Optimization) Plane Wave Self Consistent Field (PWscf). The calculated optical joint density of states show that the absorption begins at 4.8 eV and exhibits two sharp peaks and one broad peak at 48 nm, 64 nm, and 170 nm. The absorption range is in good agreement with our experimental observations. The dielectric function shows electric polarization between the 2p state of nitrogen and 3d state of calcium. The crystal’s static refractive index is 1.87 with a maximum value of 6.4 in the visible region, which is optimal for optical devices. The absorption coefficient confirms experimentally comparable optical states with no notable anisotropy.

Exploring Rashba spin-splitting and optoelectronic properties in lead-free 2D chiral hybrid perovskite (R-/S-/racemic-NEA)2SnI4 materials

Two-dimensional (2D) chiral metal-halide perovskites have recently emerged as significant candidates for spintronic and optoelectronic applications. This is attributed to their spin polarization induced by chiral organic components and the robust spin-orbit coupling of lead. However, there is a considerable demand for nontoxic lead-free chiral perovskites in the realm of spintronic devices. Unveiling the intrinsic relationships between structure and property is crucial for designing materials with optimal performance. Herein, we report systematic study of structure, electronic structures, Rashba-type spin-splitting and optical features of tin based 2D chiral hybrid organic inorganic perovskites, namely (R, S-naphthylethylamine (NEA))2SnI4 and racemic phase (racemic-NEA)2SnI4 semiconductors. According to the computed electronic structure and optical characteristics, all structures exhibit a broad intense peak in the energy region of 400 nm. Our results revealed a significant Rashba effect, supported by an energy splitting of 32.9 meV, and a Rashba parameter of 0.707 eV·Å for the (R\\S-NEA)2SnI4. Furthermore, we demonstrate that spin-polarized can be controlled and manipulated depending on the enantiomeric form of perovskites without any external magnetic field. These results pave the way for innovative structural engineering, offering a platform to finely tune the splitting in lead-free perovskites. This holds significant potential for the advancement of cutting-edge spintronic devices.

Ultra-highly conductive optoelectronic modulated single-molecule nickel bis(dithiolene) junctions with strong molecule-electrode coupling

Strong molecule-electrode coupling originating from orbit hybridization between gold and the delocalized molecular wires in single-molecule junctions facilitates facile transport towards smart molecular devices. In this paper, we report ultra-highly conductive single-molecule circuits based on highly delocalized nickel bis(dithiolene) (NiS4) molecular junctions using scanning tunneling microscope break junction technique. Single-molecule charge transport measurement of both NiS4 reveals they exhibits high conductance of 10−1.49G0 and 10−1.51G0, respectively. Moreover, under intervention of high bias voltage the molecular conductance could be further improved to approximately 10−1.00G0, the highest value reported to date with similar molecular lengths. Theoretical calculations suggest that the strong hybridization of the π-channels and the gold electrodes in both junctions exists and it further extends from molecule-electrode interfaces to metal electrodes as visualized by the isosurface plots of the transmitting eigenstate, which lead to not only a distinct energy shift of the dominated LUMO peaks toward Fermi level, but also broad peaks in the LUMO resonance in the transmission functions. In addition, the both molecular junctions show remarkable photoconductance of approximately 10−1.00G0 under resonant light excitation, due to possible exciton binding in these junctions. Interestingly, the conductance switching of both molecular junctions under optoelectronic modulation is highly reversible, forming a multi-stimulus responsive molecular switch. This work not only provides a building block for fabricating highly conducting molecular wires with strong molecule-electrode coupling, but also lays a foundation for designing optoelectronic modulated functional molecule-scale devices.

Tips versus Holes: ×10 Higher Scattering in FIB-made Plasmonic Nanoscale Arrays for Spectral Imaging.

Plasmonic nanostructure arrays, designed for performance as pixels in an advanced SERS imaging device, were fabricated by gallium focused ion beam (FIB). Though the FIB is best suited for etching holes and negative structures, our previously reported simulations favor protrusions. Herein, we report on the FIB methodology to "sculpt" positive structures by "ion-blasting" away the surrounding material. Nanoprotrusions and nanoholes with different aspect ratios are compared experimentally with depth and height controlled by the dwell time. The amplitude and spectra of optical absorption and scattering from the two species are compared as a function of structure height. Measurements were performed using ASI's model Rainbow hyperspectral camera, demonstrating the utility of hyperspectral microscopy for plasmonic imaging applications. Both the scattered and absorbed radiation display the broad peak qualitatively similar to the localized surface plasmon (LSP) scattering spectrum of gold nanospheroids. The intensity of the scattered light from the protrusions-measured in dark-field-was observed to be an order of magnitude higher than that from the nanoholes, consistent with simulation predictions. Poor contrast against bright background specular reflection is inherent in bright-field reflection mode; image-processing succeeded in detecting patterns indiscernible to the eye. To extract the absorption the full hyperspectral image field was exploited, allowing the sample to serve as its own reference. The resulting spectra display a plasmonic resonance which grows stronger and increasingly red-shifted at increasing heights, corroborating visual observations of changes in sample hue.

Structural, magnetic and dielectric properties in double perovskite La2-xScxCoMnO6 (x = 0.0, 0.1, and 0.2)

The effect of Sc doping on structural, magnetic, and dielectric properties of double perovskite La2CoMnO6 synthesized by solid-state method was investigated. Crystal structure of La2-xScxCoMnO6 (x = 0.0, 0.1, and 0.2) compounds confirmed through X-ray diffraction patterns (XRD). Rietveld refinement of the XRD revealed the monoclinic phase with P21/n space group and the structural properties such as lattice parameter, bond lengths, and bond angles were obtained. Field emission scanning electron microscopy images revealed a uniform grain distribution, and the grain size was increased with increasing Sc content. The elemental mapping confirms the stoichiometry of the compounds. The room temperature Raman spectra confirm the monoclinic crystal structure and reveal two broad peaks viz., Ag, and Bg which were attributed to specific vibrational modes within the (Co/Mn)O6 octahedra. Magnetic measurements show that Curie temperature (Tc1) decreases with Sc substitution of 206 K for x = 0.0–193 for x = 0.2 due to the Co2+-Mn4+ FM coupling and it follows Curie–Weiss law in the paramagnetic region. Impedance spectroscopy studies show that the conductivity in these materials is predominantly due to the intrinsic bulk grains.

Structural, morphological and Magnetic studies of Soft magnetic Fe-Si-B Metallic Glass ribbons

Abstract A comparative study of two metallic glass ribbons produced by two different industries namely M/s Honeywell corporation, U.S.A., and M/s Vijay electricals. The potential of different experimental techniques like XRD, SEM and EDAX and VSM has been carried out for two soft metallic glass ribbons. XRD studies reveal that for sample A has two broad peaks and sample B shows the absence of any sharp peaks indicating crystalline secondary phases are <5%. Morphological studies show that sample A has homogeneous matrix whereas sample B has crystallites of varied shapes and sizes distributed in the range of 5-40 μm. EDAX for both the samples A and B was done to investigate the compositional elements. VSM measurements reveals sample B to exhibit a relatively larger anisotropy compared to sample A.

Fe incorporation and modulation of oxygen vacancies in ZnO nanoparticles for photocatalytic degradation of Rhodamine B

In this study, self-assembled ultrafine nanoclusters of Fe2O3 supported with defective Fe-doped ZnO nanoparticles (NPs) prepared via calcination of a Fe/Zn precursor in the presence of deep eutectic solvents (DES) complex. During the calcination process, surface defects are generated through the decomposition of Fe/Zn precursor with DES complex, simultaneously crystallinity of catalysts improved. The hexagonal wurtzite structure of ZnO NPs is retained after the incorporation of Fe atoms into the ZnO crystal lattice. Notably, the particle size is reduced from 32 to 22 nm after Fe incorporation due to alterations in the nucleation center in the ionic solvent. Electron paramagnetic resonance analysis reveals a broad peak at a g value of 2.0, attributed to Fe3+ atoms doped into ZnO matrix. These doped Fe3+ atoms create additional active sites on the surface of NPs, leading to an extended photoluminescence lifetime of the Fe2O3/ZnO nanocomposite. Consequently, the optimized Vo-Fe/ZnO nanocomposite achieves a 95 % removal efficiency for Rhodamine B (RhB) degradation with a rate constant (k) of 0.0755 min−1. Additionally, nanocomposite shows visible light photo-Fenton activity for RhB degradation with k of 0.0069 min−1.

Variations in the optical and thermoelectric behavior of ZnCo2O4 nanostructures as a function of synthesis temperature

Zinc cobalt oxide nanostructures were synthesized by electrochemical deposition of zinccobalt alloy at various bath temperatures (15, 30, 45 and 60 ˚C) and its hydrothermal oxidation at 100 ˚C. X-ray diffraction pattern and Raman spectroscopy data reveals the formation of spinal structure of ZnCo2O4. Photoluminescence spectra of the samples exhibit broad peaks with a red shift in the emission energy. Diffused reflectance spectroscopy measured the band gap of the synthesized materials; band gap is 3.06, 3.03, 3.02 and 2.99 eV, for samples electrodeposited at 15, 30, 45 and 60 ˚C, respectively. Optical conductivity of synthesized materials decreases with increasing deposition layers while reflectance shows opposite trend. Thermoelectric set up measures the change in potential difference through synthesized materials when different temperatures are applied and an increment in potential were observed. Seebeck co-efficient and power factor are also studied as function of bath temperature.

Production, Optimization, and Characterization of Bio-cellulose Produced from Komagataeibacter (Acetobacter aceti MTCC 3347) Usage of Food Sources as Media.

Bio-cellulose is a type of cellulose that is produced by some particular group of bacteria, for example, Komagataeibacter (previously known as Acetobacter), due to their natural ability to synthesize exopolysaccharide as a byproduct. Gluconacetobacter xylinus is mostly employed for the production of bio-cellulose throughout the world. Therefore, exploring other commonly available strains, such as Komagataeibacter aceti (Acetobacter aceti), is needed for cellulose production. Bio-cellulose is one of the most reliable biomaterials in the limelight because it is highly pure, crystalline, and biocompatible. Hence, it is necessary to enhance the industrial manufacturing of bio-cellulose with low costs. Different media such as fruit waste, milk whey, coconut water, sugarcane juice, mannitol broth, and H&S (Hestrin and Schramm's) broth were utilized as a medium for culture growth. Other factors like temperature, pH, and time were also optimized to achieve the highest yield of bio-cellulose. Moreover, after the synthesis of biocellulose, its physicochemical and structural properties were evaluated. The results depicted that the highest yield of bio-cellulose (45.735 mg/mL) was found at 30 °C, pH 5, and on the 7th day of incubation. Though every culture media experimented with synthesized bio-cellulose, the maximum production (90.25 mg/mL) was reported in fruit waste media. The results also indicated that bio-cellulose has high water-holding capacity and moisture content. XRD results showed that bio-cellulose is highly crystalline in nature (54.825% crystallinity). SEM micrograph demonstrated that bio-cellulose exhibited rod-shaped, highly porous fibers. The FTIR results demonstrated characteristic and broad peaks for O-H at 3336.25 cm-1, which indicated strong O-H bonding. The thermal tests, such as DSC and TGA, indicated that bio-cellulose is a thermally stable material that can withstand temperatures even beyond 500 °C. The findings demonstrated that the peel of fruits could be utilized as a substrate for synthesizing bio-cellulose by a rather cheap and easily available strain, Komagataeibacter (Acetobacter aceti MTCC 3347). This alternative culture media reduces environmental pollution, promotes economic advantages, and initiates research on sustainable science.

A Broadband X-Ray Investigation of Fast-spinning Intermediate Polar CTCV J2056–3014

We report on XMM-Newton, NuSTAR, and NICER X-ray observations of CTCV J2056–3014, a cataclysmic variable (CV) with one of the fastest-spinning white dwarfs (WDs) at P = 29.6 s. While previously classified as an intermediate polar, CJ2056 also exhibits the properties of WZ Sge–type CVs, such as dwarf novae and superoutbursts. With XMM-Newton and NICER, we detected the spin period up to ∼2 keV with 7σ significance. We constrained its derivative to |Ṗ|<1.8×10−12 s s−1 after correcting for binary orbital motion. The pulse profile is characterized by a single broad peak with ∼25% modulation. NuSTAR detected a fourfold increase in unabsorbed X-ray flux coincident with an optical flare, in 2022 November. The XMM-Newton and NICER X-ray spectra at 0.310 keV are best characterized by an absorbed, optically thin three-temperature thermal plasma model (kT = 0.3, 1.0, and 4.9 keV), while the NuSTAR spectra at 3–30 keV are best fit by a single-temperature thermal plasma model (kT = 8.4 keV), both with Fe abundance Z Fe/Z ⊙ = 0.3. CJ2056 exhibits similarities to other fast-spinning CVs, such as low plasma temperatures and no significant X-ray absorption at low energies. As the WD’s magnetic field strength is unknown, we applied both nonmagnetic and magnetic CV spectral models (MKCFLOW and MCVSPEC) to determine the WD mass. The derived WD mass range (M = 0.7–1.0 M ⊙) is above the centrifugal breakup mass limit of 0.56 M ⊙ and consistent with the mean WD mass of local CVs (M ≈ 0.8–0.9 M ⊙).

Synthesis and Characterization of ZnO/Cu&lt;sub&gt;2&lt;/sub&gt;O and Co co-doped Ag-ZnO/Cu&lt;sub&gt;2&lt;/sub&gt;O Nanoparticles with Possible Photovoltaic Applications

The Photovoltaics phenomenon is one of the major turning points in the battle against the depletion of fossil fuels. Sunlight is the main resource in photovoltaics, but there remains a quest to harvest it efficiently to generate electricity. This study is focused on designing basic, cost-effective prototype solar cells using ZnO/Cu2O nanoparticles (NPs) and Co(cobalt) co-doped Ag-ZnO/Cu2O NPs under normal university laboratory conditions. ITO-coated glass was used as the substrate of the solar cell and a modified low-temperature chemical bath deposition method was used for fabrication. Both ZnO and Cu2O NPs were synthesized by aqueous precipitation methods and the fabrication was performed successfully using ZnO and Cu2O NPs. However, the fabrication with Co co-doped Ag-ZnO and Cu2O NPs requires more research since the Co co-doped Ag-ZnO NPs were synthesized by solvothermal method, and it appeared as a fine powder which was not thick enough to hold onto the Cu2O layer. The UV-spectroscopic analysis confirmed the characteristic band of ZnO NPs at 367.5 nm, Cu2O NPs at 360 nm, and Co co-doped Ag-ZnO NPs at 378 nm. The FTIR spectrum showed sharp peaks at 460 cm-1 and 606 cm-1 for the corresponding Zn-O bond and Cu-O bond, respectively with a broad peak at 1329 cm-1 for Cu2O FTIR, due to the chemisorbed and/or physiosorbed H2O and CO2 molecules on the surface of the nanostructure. The EDX analysis showed the presence of slight carbon impurity in ZnO NPs which resulted in a deviated XRD pattern while Cu2O NPs showed the characteristic XRD pattern. The solar cell illuminated under three different lux conditions, had the characteristic J-V plot when measured through Gamry Potentiostat.

Processing of Reduced Graphene Oxide Reinforced Ultra High Molecular Weight Polyethylene for Orthopedic Implants

Ultra-high molecular weight polyethylene (UHMWPE) has been used as a bearing material in total joint replacements due to its excellent mechanical properties and biocompatibility. The acetabular cup in total hip replacement and the tibial component in total knee replacement is widely fabricated from UHMWPE. The use of UHMWPE in total joint replacements is well established, and the goal is to improve its mechanical properties, wear resistance, and oxidation resistance. The quality and life span of the artificial joints can be further increased by enhancing the relevant mechanical properties of UHMWPE. The addition of filler material to UHMWPE is an effective way to enhance its relevant properties. In this study, relevant properties of UHMWPE were enhanced by incorporating an appropriate filler. Reduced Graphene Oxide (rGO) was selected as a filler material as it improves mechanical properties, wear resistance, toughness, and thermal stability. Graphene oxide (GO) was synthesized by Modified Hummer’s Method (MHM), and it was thermally reduced to obtain rGO. The synthesized GO was characterized by Fourier Transform Infrared spectroscopy (FTIR) and X-Ray Diffraction (XRD) which confirmed the accurate synthesis. The reduction of GO was validated by the disappearance of (OH) broad peak in the FTIR analysis. The rGO/UHMWPE nanocomposite was prepared by adding 0.7 wt.% of rGO employing the solvent mixing method. The morphology of the composite was validated by Scanning Electron Microscopy (SEM). Tensile and Izod Impact tests were performed on the samples which showed an increase in tensile strength of 33.2% and the impact strength increased by 140.5%. The rGO/UHMWPE nanocomposite with greater tensile and impact strength is an excellent candidate to produce orthopedic implants with superior properties.

Electro-optical and thermal characterization of copper tartrate crystals grown in silica gel

Copper Tartrate crystals were grown by Gel Growth technique by single diffusion. Silica gel of Optimum specific gravity was set with tartaric acid at optimum pH and aging period. Band gap of copper tartrate crystal is determined using UV-Visible spectroscopy to be 5.24 eV. In PL spectra broad peak is observed at nearly 367.44186 nm in the range 287 nm to 458 nm along with the sharp, intense transmission maxima peak at wavelength nearly 505.03876 nm which is characteristic of a material composition and electronic band structure. This shows the transparency in UV-visible region and material is a filter in this range .TGA analysis concluded that Copper tartrate has one half water molecule as crystalline water and is stable up to 85.02 0 C.DSC analysis assigns the temperature value 314.5 0C as melting point and apparent enthalpy of fusion determined is 10.18 mW.

THE ANTIBACTERIAL ACTIVITY OF GUM ARABIC-COATED Mn-DOPED CuS NANOPRISMS

Novel nanoprism-shaped manganese-doped copper sulfide (Mn–CuS) was fabricated by two-phase colloidal method (Mn percentages = 0%, 1%, 3%, and 5%). The Mn–CuS was analyzed by XRD, FTIR, UV–Vis spectrometer, and TEM. The XRD shows that the hexagonal covellite copper sulfide peaks appeared at 2[Formula: see text], and [Formula: see text] for 0%, 1%, 3%, and 5% respectively, and orthorhombic chalcocite copper sulfide appeared at the peaks that are corresponding the planes (412), (275), (029) and (106). According to UV–Vis analysis, the optical absorption of manganese-doped copper sulfide 0%, 1%, 3%, and 5% clearly appeared in the UV–Vis region at 518, 440, 478, and 477[Formula: see text]nm respectively, and there are broad peaks for localized surface plasmon resonances (LSPR) of CuS located at 970, 1061, 1002, and 1006[Formula: see text]nm for Mn–CuS 0%, 1%, 3%, and 5%, respectively. The favored nanoprism-shaped sample (manganese-doped copper sulfide 1%) was coated with gum Arabic (GA) in order to decrease the cytotoxicity and enhance the biocompatibility. The antibacterial activity of manganese-doped copper sulfide and GA@Mn–CuS 1% nanostructure toward Staphylococcus aureus and Escherichia coli bacteria was determined by inhibition zone. It was found that the fabrecated Mn–CuS 1% nanoprisms were more active toward both E. coli and S. aureus bacteria and the doping enhanced the antibacterial activity.