The manganese mineralization occurred in three ages in Hokkaido. The older one is of Palaeozoic or Mesozoic ages, and the younger two of Miocene and Quaternary. Late Tertiary, especially the Miocene age is characterized by the most intensive and extensive volcanic activities. The mostly ore deposits are found this age and the only south-western Hokkaido.The writer investigated the various modification of manganese dioxide and hydroxide minerals mainly from the mineralogical stand point and clarified of geological occurrence in late Tertiary. Some geologists suppose that the deposits are syngenetic ore beds precipitated from marine water, the manganese of which were supplied from manganese-bearing hot springs. But others postulate the hydrothermal replacement origin.Manganese dioxide or hydroxide is one of the most familiar and common minerals found in various manganese deposits, but is mineralogical study is very equivocal owing to the variability and overlapping of physical properties and chemical composition. It is obvious, in Hokkaido, that they always occur in a fine grained massive state, and comparises several modification. Some members well crystallized but other a very poorly crystallized.The writer found pyrolusite, manganite, cryptomelane, ramsdellite, birnessite and ranceite in Hokkaido. Ramsdellite has not been found in Japan, but it was found in fissure of Palaeozoic red chert from the Tanno mine, Kitami District in Hokkaido. Birnessite and ranceite are found in manganese wads from the Komagadake mine.The manganese dioxide deposits in Hokkaido are found concordantly or slightly obliquely to the stratification in Miocene green tuff, tuff breccia, and shale. The modes of occurrence of many manganese dioxide deposits are controlled by geological structure : the deposits are distributed at special portion as small basin. A somewhat sedimentary cycle was given to explain the distribution of manganite → pyrolusite to upper bed from lower bed. These phenomena are applicable for the prospecting of the so-called Pirika type manganese dioxide deposits.Some manganese oxide mineral specimens show under a rate heating, a characteristic type of differential thermal analysis curve. Natural manganese dioxide and hydroxide ores were aggregates of some manganese·minerals. The application of differential thermal analysis to this group of mineral provides valuable information invaluable by other standard method of technique.In this paper, the results of mineralogical and geological distribution researches on these deposits are summarised.
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