The influence of pressure on the light scattering properties of low-energy acoustical phonons in cubic Indium Antimonide (InSb) has been investigated by Raman spectroscopy. By implementing optical Bragg filters, the overtone scattering from transverse acoustical phonons near the X point of Brillouin zone (2TA(X)) could be measured in an explicit manner allowing for analysis of its lineshape. Accordingly, a significant line broadening was detected for this phonon mode corroborating our previous suggestion of considerable anharmonicity of the transverse lattice vibration upon compression at room temperature. Herein reported new results of density functional theory (DFT) calculations indicated similar pressure dependence for overtones of acoustical phonons near the X and the K critical points that plausibly accounted for the lack of energy discrimination between 2TA(X) and 2TA(K) modes in spectroscopic measurements under pressure.
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