Reduced-order modeling (ROM) techniques involving physics are gaining importance due to their ability to generate physically meaningful results swiftly and accurately. They are finding applications in design and optimization and in digital twins where real-time results are required. The proper orthogonal decomposition (POD)-Galerkin ROM based on finite volume discretization methodology is utilized here for solving a high-dimensional system in a reduced dimensional space in which the reduced basis is spanned by the POD modes. The reduced-order equations are obtained by projecting the discretized form of the full-order model (FOM) equations onto the reduced basis which eliminates the need for boundary control techniques. The proposed methodology is demonstrated for transient conjugate heat transfer (CHT) in an electric vehicle battery. The POD modes are computed using simulation data for three Reynolds numbers and the ROM is evaluated for transient analysis of temperature from initial state to steady state for seven Reynolds numbers. The ROM predictions are fairly accurate both in the interpolated and the extrapolated regions with significant computational speed-up. Five modes are sufficient for constructing the fluid and battery temperature ROM solution. The ROM computational speed-up obtained with 5 modes is approximately 4–7.4 times compared to the FOM. The proposed methodology is generic and can be readily applied for any engineering system involving CHT.