Blueschist Unit Research Articles

Evidence for and significance of the Late Cretaceous Asteroussia event in the Gondwanan Ios basement terranes

Abstract. The Late Cretaceous Asteroussia event as recorded in the Cyclades is a potential key to the tectonic evolution of Western Tethys. Microstructural analysis and 40Ar/39Ar geochronology on garnet–mica schists and the underlying granitoid basement terrane on the island of Ios demonstrates evidence of a Late Cretaceous high-pressure, medium-temperature (HP–MT) metamorphic event. This suggests that the Asteroussia crystalline nappe on Crete extended northward to include these Gondwanan tectonic slices. In this case, the northern part of the Asteroussia nappe (on Ios) is overlain by the terrane stack defined by the individual slices of the Cycladic Eclogite–Blueschist Unit, whereas in the south (in Crete) the Asteroussia slices are near the top of a nappe stack defined by the individual tectonic units of the external Hellenides. This geometry implies that accretion of the Ios basement terrane involved a significant leap of the subduction megathrust (250–300 km) southward. Accretion needs to have commenced at or about ∼38 Ma, when the already partially exhumed slices of the Cycladic Eclogite–Blueschist Unit began to thrust over the Ios basement. By ∼35–34 Ma, the subduction jump had been accomplished, and renewed rollback began the extreme extension that led to the exhumation of the Ios metamorphic core complex.

Insight Into the Early Exhumation of the Cycladic Blueschist Unit, Syros, Greece: Combined Application of Zoned Garnet Geochronology, Thermodynamic Modeling, and Quartz Elastic Barometry

AbstractConstraining conditions and mechanisms of the early stages of exhumation from within subduction zones is challenging. Although pressure, temperature, and age can be inferred from the exhumed rock record, it is generally difficult to derive each of these parameters from any single rock, thus demanding assumptions that diverse data from multiple samples can be safely combined into a single pressure‐temperature‐time (P‐T‐t) path that might then be used to infer tectonic context and mechanisms of exhumation. Here, we present new thermobarometric and geochronologic information preserved in a single sample from Syros, Greece, to deduce the conditions and rates of the earliest phase of exhumation as a part of the well‐preserved high‐pressure metamorphic rocks of the Cycladic Blueschist Unit (CBU). The sample studied here is a garnet‐bearing, quartz‐mica schist that records two distinct metamorphic events. Results from thermodynamic models and quartz‐in‐garnet elastic geobarometry show that metamorphic garnet cores formed as P‐T conditions evolved from ∼485°C and 2.2 GPa to 530°C and 2.0 GPa, and that garnet rims formed as conditions evolved from ∼560°C and 2.1 GPa to ∼550°C and 1.6 GPa. Sm‐Nd geochronology on garnet cores and rims yields ages of 45.3 ± 1.0 and 40.5 ± 1.9 Ma, respectively, thus indicating a 4.8 ± 2.1 Myr growth span. Given the decompression path calculated based on garnet core and rim P‐T estimates, we conclude that the distinct phases of garnet growth preserve evidence of the initial exhumation of portions of the CBU.

Zircon U-Pb and geochemical signatures in high-pressure, low-temperature metamorphic rocks as recorders of subduction zone processes, Sikinos and Ios islands, Greece

Zircon U-Pb dating is a powerful and widely used geochronologic technique to constrain the timing and rates of magmatic and high and lower-grade metamorphic processes, as well as sediment provenance. Zircon trace element (TE) compositions also record magmatic and metamorphic processes during zircon growth. In this study, zircon laser ablation split-stream (LA-SS)-ICP-MS U-Pb and TE depth-profiling and novel two-dimensional zircon mapping techniques are used in combination with oxygen isotope analyses (secondary ion mass spectrometry, SIMS) to reconstruct the timing and metamorphic conditions recorded by recrystallization and growth of zircon rims, which provide valuable insight into the petro-tectonic evolution of high-pressure/low-temperature (HP/LT) metamorphic rocks formed in subduction zones. These techniques are applied to zircon grains from HP/LT metamorphic rocks of the Cycladic Blueschist Unit (CBU) and Cycladic Basement (CB) on Sikinos and Ios islands, Greece, which experienced metamorphism and deformation associated with subduction and subsequent back-arc exhumation. Zircon records multiple episodes of non-magmatic zircon rim growth at ~50 Ma and ~ 26 Ma. Eocene metamorphic rims are associated with HP/LT metamorphism and are observed in both units, suggesting likely juxtaposition prior to or during subduction and associated HP metamorphism. The similarity between TE concentrations and δ18O values of the Eocene rims and their corresponding cores is an indicator for re-crystallization and precipitation as a mechanism of zircon growth. In contrast, Oligocene zircon rims appear to be restricted to a < 0.5 km thick zone along the CB-CBU contact, characterized by garnet break-down, and show HREE enrichment and higher ẟ18O values in the rims compared to the cores, consistent with a model suggesting metasomatic infiltration of fluids derived from dehydrating sedimentary rocks during progressive subduction and underplating prior to back-arc extension. This metamorphism appears to be static in nature and does not support major late Cenozoic reactivation of the contact as an extensional shear zone during back-arc extension.

Insights from elastic thermobarometry into exhumation of high-pressure metamorphic rocks from Syros, Greece

Abstract. Retrograde metamorphic rocks provide key insights into the pressure–temperature (P–T) evolution of exhumed material, and resultant P–T constraints have direct implications for the mechanical and thermal conditions of subduction interfaces. However, constraining P–T conditions of retrograde metamorphic rocks has historically been challenging and has resulted in debate about the conditions experienced by these rocks. In this work, we combine elastic thermobarometry with oxygen isotope thermometry to quantify the P–T evolution of retrograde metamorphic rocks of the Cycladic Blueschist Unit (CBU), an exhumed subduction complex exposed on Syros, Greece. We employ quartz-in-garnet and quartz-in-epidote barometry to constrain pressures of garnet and epidote growth near peak subduction conditions and during exhumation, respectively. Oxygen isotope thermometry of quartz and calcite within boudin necks was used to estimate temperatures during exhumation and to refine pressure estimates. Three distinct pressure groups are related to different metamorphic events and fabrics: high-pressure garnet growth at ∼1.4–1.7 GPa between 500–550 ∘C, retrograde epidote growth at ∼1.3–1.5 GPa between 400–500 ∘C, and a second stage of retrograde epidote growth at ∼1.0 GPa and 400 ∘C. These results are consistent with different stages of deformation inferred from field and microstructural observations, recording prograde subduction to blueschist–eclogite facies and subsequent retrogression under blueschist–greenschist facies conditions. Our new results indicate that the CBU experienced cooling during decompression after reaching maximum high-pressure–low-temperature conditions. These P–T conditions and structural observations are consistent with exhumation and cooling within the subduction channel in proximity to the refrigerating subducting plate, prior to Miocene core-complex formation. This study also illustrates the potential of using elastic thermobarometry in combination with structural and microstructural constraints, to better understand the P–T-deformation conditions of retrograde mineral growth in high-pressure–low-temperature (HP/LT) metamorphic terranes.

Geometry and Kinematics of Bivergent Extension in the Southern Cycladic Archipelago: Constraining an Extensional Hinge Zone on Sikinos Island, Aegean Sea, Greece

AbstractWe report the results of a field study on Sikinos Island in the Aegean extensional province of Greece and propose a hinge zone controlling incipient bivergent extension in the southern Cyclades. A first deformation event led to top‐S thrusting of the Cycladic Blueschist Unit (CBU) onto the Cycladic basement in the Oligocene. The mean kinematic vorticity number (Wm) during this event is between 0.56 and 0.63 in the CBU, and 0.72 to 0.84 in the basement, indicating general‐shear deformation with about equal components of pure and simple shear. The strain geometry was close to plane strain. Subsequent lower‐greenschist‐facies extensional shearing was also by general‐shear deformation; however, the pure‐shear component was distinctly greater (Wm = 0.3–0.41). The degree of subvertical pure‐shear flattening increases structurally upward and explains alternating top‐N and top‐S shear senses over large parts of the island. Along with an increased coaxial deformation component, the strain geometry became oblate. Published quantitative data from nearby Ios Island are similar and both data sets define an extensional hinge zone between top‐N extensional deformation across large parts of the central and northern Cyclades and top‐S extensional deformation at the southern and western fringe of the archipelago. This extensional hinge zone is an important large‐scale structure forming early in the history of lithospheric extension due to southward retreat of the Hellenic slab.

Quo vadis Zeus : is there a Zas shear zone on Naxos Island, Aegean Sea, Greece? A review of metamorphic history and new kinematic data

Detecting zones of considerable early-orogenic displacement in rather monotonous rock sequences which have undergone a late and pervasive tectonometamorphic overprint is challenging. It has been proposed that the alleged Zas shear zone in the passive margin sequence of the Cycladic Blueschist Unit on Naxos Island, Greece, separates amphibolite facies, non-high-pressure rocks (Koronos Unit) below the shear zone from Eocene high-pressure rocks (Zas Unit) above the shear zone. We review existing pressure–temperature data from the Koronos Unit and present new kinematic data from the anticipated Zas shear zone to evaluate the tectonic significance of this recently proposed structure. This has implications for unravelling the subduction history of rock units from tectonometamorphic datasets. Common to all pressure–temperature data from the Koronos Unit is a well-defined amphibolite facies equilibration stage at 8–11 kbar and 600–700°C, followed by initial near-isothermal to slightly prograde decompression and subsequent pronounced cooling. This segment of the high-temperature pressure–temperature loop is associated with top-to-the-NNE extensional deformation in the footwall of the Miocene Naxos–Paros detachment. Little is known about the metamorphism preceding the amphibolite facies overprint in the Koronos Unit. Our review shows that it is likely that the rocks experienced a prior high-pressure metamorphic overprint that is typical of rocks of the Cycladic Blueschist Unit. Our kinematic data show that the Zas shear zone contains variably deformed rocks with dominantly top-to-the-NNE shear sense indicators that developed under greenschist facies metamorphism in the footwall of the Naxos–Paros detachment. No significant offset can be detected across the Zas shear zone and the geology on either side of it does not support large-scale movement across the shear zone. We discuss a model in which the Zas shear zone is considered to be a minor zone of deformed schist near the biotite-in isograd of Miocene high-temperature metamorphism. We conclude that there is no need to tectonically subdivide the passive margin sequence of the Cycladic Blueschist Unit on Naxos.

The Late Cretaceous magmatic arc of the south Aegean: Geodynamic implications from petrological and geochemical studies of granitoids from Anafi island (Cyclades – Greece)

ABSTRACT In the Aegean region (Cyclades – Greece), a large part of the Island of Anafi consists of exhumed high-grade metamorphic sequences (amphibolites, serpentinites and metasediments) that have been intruded by Late Cretaceous intermediate and felsic granitoids. These correspond to I-type arc-related rocks, displaying calc-alkaline geochemical affinities. Variability in their petrographic features, mineral composition and geochemistry is assigned to differentiation processes that mostly involved plagioclase and/or K-feldspar, and to a lesser extent amphibole and biotite. Mineral chemistry and geochemical results suggest that the Anafi granitoids are highly comparable with the Late Cretaceous granitoid intrusive rocks from East Crete and Donousa island. The amphibole and zircon saturation thermometry yields relatively moderate temperature crystallization conditions (~790°C) for the intermediate granitoids and lower for the felsic granitoids (~630°C). Geobarometric calculations based upon the chemistry of magnesiohornblende, as well as the normative (Qz), (Ab) and (Or) contents clearly point to shallow intrusion conditions (~2.0–6.5 kbar), corresponding to an estimated depth of crystallization of ~12 ± 4 km. The thrust sheets that overly the Palaeogene flysch in Anafi (metasediments with serpentinized peridotites, amphibolites and metabasites), constitute a subducted and metamorphosed oceanic sequence. These metamorphic units likely represent a part of the Pindos – Cycladic Blueschist Unit domain that was subducted at an earlier pre-Campanian stage. In the hydrated mantle wedge, incorporation of shallow level granitoids within metamorphic units was likely facilitated via corner flow intrusion mechanisms. Following the intrusion, the granitoid rocks were exhumed in a syn-convergent setting, along with the metamorphic thrust sheets, by continuous underplating of more external units, thus, escaping penetrative ductile deformation.

Differences in decompression of a high-pressure unit: A case study from the Cycladic Blueschist Unit on Naxos Island, Greece

Determining the tectonic evolution and thermal structure of a tectonic unit that experiences a subduction-related pressure temperature (P-T) loop is challenging. Within a single unit, P-T conditions can vary from top to bottom which can only be revealed by detailed petrological work. We present micropetrological data from the middle section of the Cycladic Blueschist Unit (CBU) in Naxos, Greece, which indicates a different P-T loop than that for the top of the sequence. Using Zr-in-rutile and Ti-in-biotite thermometry coupled with quartz-in-garnet elastic barometry and phase equilibrium thermodynamic modeling, we identify a prograde path from 15.4 ± 0.8 kbar to 19.9 ± 0.6 kbar and from 496 ± 16 °C to 572 ± 7 °C (2σ uncertainty), equilibration during decompression at 8.3 ± 1.5 kbar and 519 ± 12 °C followed by near-isobaric heating to 9.2 ± 0.8 kbar and 550 ± 10 °C (or even 584 ± 19 °C), and a final greenschist-facies equilibration stage at 3.8 ± 0.3 kbar and 520 ± 4 °C. We compare these P-T estimates with published data from the top and also the bottom of the CBU section and find that the bottom half of the CBU on Naxos records higher peak high-pressure (HP) of about 4 kbar than the top of the unit, defining the thickness of the CBU section on Naxos to about 15 km in the Eocene. We determine that crustal thickening of up to ~15% occurs in the upper half of the CBU section during exhumation of the HP rocks in an extrusion wedge in a convergence setting. At about 30 Ma, the bottom half of the CBU was finally thrust onto the radiogenic Cycladic basement. Subsequently this bottom half of the CBU section underwent isobaric heating of 9–96 °C between c. 32–28 and 23–21 Ma. Isobaric heating occurred below the upper CBU section that thickened during decompression and commenced when HP metamorphism in the Cyclades ended. This suggests that thermal relaxation following tectonic accretion in the Cyclades controlled heating of the evolving Cycladic orogen during a tectonically quiescent period before lithospheric extension commenced by 23–20.5 Ma.

Lateral Termination of a Cycladic‐Style Detachment System (Hymittos, Greece)

AbstractThe bedrock of Hymittos, Attic peninsula, Greece, exposes a pair of low‐angle crustal‐scale ductile‐then‐brittle detachment faults. The uppermost detachment fault separates sub‐greenschist facies phyllite and marble of a Pelagonian Zone hanging wall, from greenschist facies metasedimentary schist, calc‐schist, and marble correlated to the Cycladic Blueschist Unit. A second, structurally lower detachment fault subdivides the metamorphic rocks of the Cycladic blueschist unit footwall into middle and lower units. There is a marked step in metamorphic grade between the sub‐greenschist facies uppermost package, and the middle‐to‐upper greenschist facies middle and lower packages. A suite of new white mica40Ar/39Ar and zircon (U‐Th)/He dates indicates accommodation of deformation along these faults occurred from the late Oligocene to the late Miocene with both faults active during the middle Miocene. The structures have clear top‐S/SSW kinematics determined from flanking folds, sigmoids, shear bands, stair‐stepping of strain shadows on porphyroclasts, and SCC' fabrics. The ductile‐to‐brittle deformation of the structures, morphology of the massif, and the increase in metamorphic grade suggest these low‐angle structures are part of a major, crustal‐scale extensional complex, located at the northwest end of the West Cycladic Detachment System, that accommodated Miocene bivergent exhumation of Attic‐Cycladic metamorphic core complexes in the central Aegean. Taken together, the above data suggest that multiple coeval detachment branches may form in areas with high strain gradients to accommodate the mechanically necessary termination of Cycladic‐style detachment systems.

The Cycladic Blueschist Unit on Tinos, Greece: Cold NE Subduction and SW Directed Extrusion of the Cycladic Continental Margin Under the Tsiknias Ophiolite

AbstractHigh pressure‐low temperature (HP‐LT) metamorphic rocks structurally beneath the Tsiknias Ophiolite make up the interior of Tinos Island, Greece, but their relationship with the overlying ophiolite is poorly understood. Here, new field observations are integrated with petrological modeling of eclogite and blueschists to provide new insight into their tectonothermal evolution. Pseudomorphed lawsonite‐, garnet‐, and glaucophane‐bearing schists exposed at the highest structural levels of Tinos (Kionnia and Pyrgos Subunits) reached ~22–26 kbar and 490–520°C under water‐saturated conditions, whereas pseudomorphed lawsonite‐ and aegirine‐omphacite bearing eclogite reached ~20–23 kbar and 530–570°C. These rocks are separated from rocks at deeper structural levels (Sostis Subunit) by a top‐to‐SW thrust. The Sostis Subunit records P‐T conditions of ~18.5 kbar and 480–510°C and is overprinted by pervasive top‐to‐NE shearing that developed during exhumation from (M1) blueschist to (M2) greenschist facies conditions of ~7.3 ± 0.7 kbar and 536 ± 16°C. These P‐T‐D relationships suggest that the Cycladic Blueschist Unit represents a discrete series of tectonometamorphic subunits that each experienced different tectonic and thermal histories. These subunits were buried to variable depths and sequentially extruded toward the SW from a NE dipping subduction zone. The difference in age and P‐T conditions between the HP‐LT rocks and the overlying metamorphic sole of the Tsiknias Ophiolite suggests that this NE dipping subduction zone was active between circa 74 and 46 Ma and cooled at a minimum rate of ~1.2–1.5°C/km/Myr prior to continent‐continent collision between Eurasia and Adria/Cyclades.

The Kallianos Au-Ag-Te mineralization, Evia Island, Greece: a detachment-related distal hydrothermal deposit of the Attico-Cycladic Metallogenetic Massif

The Kallianos Au-Ag-Te deposit in Evia Island (Greece) comprises sixteen syntaxial veins that intersect the schists and marbles of the Cycladic Blueschist Unit. The veins are filled with quartz-I and quartz-II, contain two hypogene ore stages (stages I and II), and are surrounded by infrequent muscovite-chlorite alteration zones. A magmatic origin is deduced for the Kallianos Au-Ag-Te mineralization, based on stable (S, C, Si, O, and H) and radiogenic (Pb, Sr, and Rb) isotopes, and fluid chemistry. The veins were deposited under pressures of ~ 220 to ~ 145 bars and temperatures of ~ 260 to 120 °C, from almost neutral H2Te-bearing hydrothermal fluids with a salinity of 2.2 to 15.8 wt.% NaCl equivalent. The telluride mineralization related to stage II was deposited at ~ 180 °C and evolved from Au- through Bi- to Ag-bearing tellurides. The vein minerals precipitated by simple cooling of almost non-reactive fluids that retained their initial magmatic signature. Taking into account the magmatic origin of the Kallianos deposit, we examine two proximal areas with granodioritic and leucogranitic intrusions similar to those associated with base and precious metal mineralization at Lavrion (~ 8.3 to ~ 7.1 Ma) and Tinos Island (~ 15 to ~ 13 Ma), as potential sources for the Kallianos fluids. Rb-Sr geochronology dating of the distal Kallianos Au-Ag-Te veins gave an age range of 8.1 to 7.6 Ma, implying that an overlapping and channelized hydrothermal system was active at the northern part of the Attico-Cycladic Metallogenetic Massif, utilizing the CBU detachment zones as fluid pathways.

P–T–tevolution of the Cycladic Blueschist Unit in Western Anatolia/Turkey: Geodynamic implications for the Aegean region

AbstractEclogite and blueschist facies rocks occurring as a tectonic unit between the underlying Menderes Massif (MM) and the overlying Afyon Zone/Lycian Nappes and the Bornova Flysch Zone in western Anatolia represent the eastward continuation of the Cycladic Blueschist Unit (CBU) in Turkey. This high‐Punit is attributed to the closure of the Pindos Ocean and consists of (a) a Triassic to Upper Cretaceous coherent series derived from passive continental margin sediments and (b) the tectonically overlying Upper Cretaceous Selçuk mélange with eclogite blocks embedded in a pelitic epidote‐blueschist matrix. The coherent series has experienced epidote‐blueschist facies metamorphism (490 ± 25°C/11.5 ± 1.5 kbar; 38 km depth).40Ar/39Ar white mica and206Pb/238U monazite dating of quartz metaconglomerate from coherent series yielded middle Eocene ages of 44 ± 0.3 and 40.1 ± 3.1 Ma for epidote‐blueschist facies metamorphism, respectively. The epidote‐blueschist facies metamorphism of the matrix of the Selçuk mélange culminates at 520 ± 15°C/13 ± 1.5 kbar, 43 km depth, and is dated at 57.5 ± 0.3–54.5 ± 0.1 Ma (40Ar/39Ar phengite). Eclogite facies metamorphism of the blocks (570 ± 30°C/18 ± 2 kbar, 60 km depth) is early Eocene and dated at 56.2 ± 1.5 Ma by206Pb/238U zircon. Eclogites experienced a nearly isothermal retrogression (490 ± 40°C/~6 to 7 kbar) during their incorporation into the Selçuk mélange. The retrograde overprints of the coherent series (410 ± 15°C/7 ± 1.5 kbar from Dilek Peninsula and 485 ± 33°C/~6 to 7 kbar from Selçuk–Tire area) and the Selçuk mélange (510 ± 15°C/6 ± 1 kbar) are dated at 35.8 ± 0.5–34.3 ± 0.1 Ma by40Ar/39Ar white mica and 31.6 ± 6.6 Ma by206Pb/238U allanite dating methods, respectively. Regional geological constrains reveal that the contact between the MM and the CBU originally formed a lithosphere‐scale transform fault zone.40Ar/39Ar white mica age from the contact indicates that the CBU and the MM were tectonically juxtaposed under greenschist facies conditions during late Eocene, 35.1 ± 0.3 Ma.

Forced Return Flow Deep in the Subduction Channel, Syros, Greece

AbstractWe present the results of a detailed structural study in the Cycladic Blueschist Unit at Fabrika on Syros Island, Greece, and discuss their significance for tectonic processes at the subduction interface. Some samples record top‐to‐the‐west shear reflecting prograde (burial), peak high‐pressure (HP) and initial decompression (exhumation) conditions. Other nearby samples record top‐to‐the‐east shear during HP metamorphism and exhumation. Some rocks re‐equilibrated at greenschist‐facies conditions and record top‐to‐the‐west shear. Greenschist‐facies top‐to‐the‐west shear is also found at the base of non‐HP upper units above the Fabrika HP sequence. We interpret the HP structures to reflect forced return flow and incipient formation of an extrusion wedge in the subduction channel. The HP top‐to‐the‐west structures resulted from thrusting along the base of the wedge and started to form during burial before the rocks reached their deepest point. The HP top‐to‐the‐east structures reflect deformation near the top of the developing extrusion wedge. After considerable exhumation during ongoing subduction, out‐of‐sequence, top‐to‐the‐west thrusts emplaced the non‐HP upper units above the exhuming extrusion wedge ~10 Myr after the wedge initially formed. Our work suggests that the HP rocks were considerably exhumed during sustained lithospheric shortening in the subduction channel by forced return flow. Because return flow is controlled by the velocity of the subducting slab, it may explain why HP rocks can be exhumed at subduction rates. On the regional scale we find that four distinct HP belts were sequentially accreted and exhumed between ~50 and 20 Ma suggesting continuous subduction‐channel return flow in the Hellenic subduction zone.

Zircon U‐Pb Chronostratigraphy and Provenance of the Cycladic Blueschist Unit and the Nature of the Contact With the Cycladic Basement on Sikinos and Ios Islands, Greece

AbstractSikinos and Ios Islands, located in the Southern Cyclades, represent part of a Cenozoic metamorphic core complex system that exposes subduction‐related metamorphic rocks in the highly extended back‐arc region of the Hellenic subduction zone. These exhumed HP‐LT metamorphic units are composed of Mesozoic metasedimentary rocks of the Cycladic Blueschist Unit (CBU) and the Paleozoic Cycladic Basement (CB). The magmatic and stratigraphic evolution of these units, as well as the nature of the contact between the CBU and CB, have remained poorly understood. We used zircon U‐Pb dating to determine crystallization ages of the CB on Sikinos and the maximum deposition ages and detrital provenance of the metasedimentary units to reconstruct the Mesozoic to early Cenozoic stratigraphic and tectonic evolution of the CBU on both islands. The results reveal that the CB in Sikinos is composed of Cambrian‐Silurian metasedimentary rocks intruded by Carboniferous granites and is overlain by metasedimentary rocks of the CBU with depositional ages spanning from Permo‐Triassic to Late Cretaceous. The provenance data from the CBU records a long‐lived tectonic evolution from Paleo‐Tethys subduction and rifting, to passive margin formation, and to subduction of the Neo‐Tethyan Pindos basin. The continuous stratigraphic record and provenance evolution from the CB into the CBU imply a para‐autochthonous relationship. On NE Sikinos and Ios, stratigraphic constraints suggest older‐over‐younger relationships along cryptic‐thrusts, supporting premetamorphic or synmetamorphic structural repetition of the CBU by imbrication, likely during subduction underplating.

Tectono‐magmatic and Stratigraphic Evolution of the Cycladic Basement, Ios Island, Greece

AbstractThe Cycladic Basement (CB) and the overlying Cycladic Blueschist Unit (CBU) are part of the Paleogene Cycladic subduction complex exposed in Miocene metamorphic core complexes in the distended back‐arc of the retreating Hellenic subduction zone of the southern Aegean. While the Cenozoic tectono‐metamorphic evolutions of the CB and the CBU have been the foci of numerous studies, this study presents new laser ablation inductively coupled plasma mass spectrometry bedrock and detrital zircon (DZ) U‐Pb ages that place robust constraints on the presubduction tectonic, magmatic, and paleogeographic evolution of the CB. Zircon U‐Pb ages of crystalline CB are ~306‐330 Ma, demonstrating local plutonism associated with regional voluminous, protracted Carboniferous magmatism related to Paleo‐Tethys subduction. The plutons intruded the CB metasedimentary host‐rock sequence, characterized by distinct Gondwanan DZ U‐Pb provenance, Neoproterozoic to early Paleozoic maximum depositional ages, and synmagmatic, contact metamorphic zircon rims (~300‐330 Ma). DZ U‐Pb dating revealed postmagmatic Permian metasedimentary rocks (~270‐295 Ma) that unconformably overlie the CB and have unimodal DZ spectra that indicate exhumation of the CB prior to Permian deposition within extensional basins, as well as mark the onset of CBU deposition prior to formation of the Pindos rift domain. These U‐Pb results clarify the late Paleozoic‐early Mesozoic evolution of the CB as a peri‐Gondwanan terrane composed of Neoproterozoic and early Paleozoic metasedimentary rocks, intruded by voluminous Carboniferous arc magmatism, and exhumed in the Permian, prior to Triassic rifting and CBU deposition. Additionally, these data provide a chronostratigraphic framework and illuminate subduction‐related juxtaposition within the CB metasedimentary sequence.

40 Ar/ 39 Ar thermochronology in the Ios basement terrane resolves the tectonic significance of the South Cyclades Shear Zone

Abstract We conducted 39 Ar diffusion experiments using potassium feldspar from the South Cyclades Shear Zone on Ios, in the Cyclades, Aegean Sea, Greece. Irradiated samples were step-heated in an ultra-high-vacuum resistance furnace attached to a mass spectrometer, thus also allowing 40 Ar/ 39 Ar geochronology. Conjoint inversion of these datasets allowed estimation of the relevant diffusion parameters, which were then used to forward model the effect of arbitrary temperature–time histories. Simulations used Monte Carlo methods to improve approximations to the observed age spectra. Two periods of rapid cooling could be inferred. The South Cyclades Shear Zone commenced operation during or shortly after the Eocene–Oligocene transition. Episodes of south-directed movement continued into Early Miocene time, however, with the footwall still hot enough to cause biotite ± garnet metamorphic mineral growth at the base of the overlying, already substantially exhumed, eclogite–blueschist unit. Since its footwall continued to cool, the South Cyclades Shear Zone was an extensional shear zone during both episodes of its operation.

Along‐strike consistency of an extensional detachment system, West Cyclades, Greece

AbstractThe Lavrion district of the Attica Peninsula, Greece, exposes the West Cycladic Detachment System (WCDS), a low‐angle crustal‐scale extensional fault system separating tectonostratigraphic units of the Cycladic Blueschist Unit. New multiple single‐grain fusion and step‐heated white mica 40Ar/39Ar ages integrated with existing (U–Th)/He ages and independent paleothermometry resolves a syn‐ to post‐orogenic deformation history. A structurally higher unit records Oligocene greenschist facies deformation that evolved into brittle conditions by the middle Miocene, and shares a similar history to Serifos at the southern end of the detachment system. The structurally lowest unit remained ductile until the late Miocene, preserving pervasive post‐orogenic structures, similar to along‐strike structures at the centre, deepest part of the fault. The similarities of structural styles and the timing of deformation across &gt; 150 km of strike length of the detachment system indicates tens of kilometers of offset and extraordinary potential for correlating observations along Cycladic‐style detachment systems.

Fluid capture during exhumation of subducted lithologies: A fluid inclusion study from Sifnos, Greece

We present phase equilibria modeling, combined with fluid inclusion microthermometry and textural observations, to constrain the composition and relative timing of subduction zone fluid-rock interaction during exhumation of two garnet-bearing blueschists from the northern part of the island of Sifnos, Greece. Water (H2O) from seawater was incorporated into the mafic lithologies by low-temperature water-rock interaction to produce hydrous phases, and was subsequently released during the subduction and exhumation cycle. Coupled phase equilibria modeling and textural observations suggest that fluid release resulted from the breakdown of the hydrous phases epidote and glaucophane, and some of the fluid was trapped as fluid inclusions in quartz. Homogenization temperatures and isochores of fluid inclusions are consistent with petrographic observations that suggest fluid inclusions were trapped during exhumation. Constructed isochores cross the inferred P-T path for Sifnos exhumation at pressures of ~0.3–1.0 GPa (~10–30 km depth) and temperatures of ~440–540 °C, suggesting fluid entrapment during the late stages of exhumation and cooling from peak subduction depths of ~70 km. The fluid inclusions have salinities of ~30–35 wt% NaCl equivalent, likely resulting from a multi-stage process that involves an increase in salinity during formation of hydrous minerals during subduction, leaving high salinity fluids and/or halide salts sequestered in pores. This is followed by the partial release of H2O during subsequent breakdown of high-pressure metamorphic phases, with later incorporation of H2O into newly forming retrograde phases. Portions of this fluid that interacted with earlier-formed saline fluids are now preserved as inclusions trapped in quartz. This interpretation suggests that fluid-rock interaction in the northern part of Sifnos occurred in a closed system, with a low water to rock mass ratio (~0.03 to ~0.05) and little to no infiltration of externally-derived lower salinity fluids. The closed system behavior is consistent with the observation that the blueschist unit is bounded by impermeable marble layers that limited exchange with external fluids during burial and/or exhumation.

Deformation within the Cycladic subduction–exhumation channel: new insights from the enigmatic Makrotantalo nappe (Andros, Aegean)

New detailed geological/structural mapping coupled with microstructural investigations and amphibole chemistry analyses are used to elucidate the enigmatic tectonic evolution of the Makrotantalo nappe on northern Andros (Aegean region). On the basis of the new geological map, we re-evaluate the structural position of samples with previously published metamorphic ages to show that the Makrotantalo nappe has been affected by the early Eocene high-pressure (HP) metamorphism. Therefore, the Makrotantalo nappe is an integral part of the Cycladic Blueschist Unit (CBU). The early, main ductile deformation phase recognized in the mapped area, is associated with the emplacement of the Makrotantalo nappe over the North Cyclades nappe at deep subduction levels during early Eocene. The subsequent deformation phase occurred at the middle Eocene–Oligocene synchronous with the decompression of blueschist rocks from the stability field of glaucophane to that of actinolite. During this phase, the nappe pile was folded by map-scale folds, which were locally transposed by ductile shear zones. These shear zones were related with NE-directed oblique thrusting and, locally, either restacked the nappe pile or reworked the early nappe contact. Our results in combination with previous studies in the northern Cyclades show that the top-to-the-NE shearing was dominant at a large part of the CBU during exhumation. Opposite, SW-directed shearing was restricted at the upper structural levels of the CBU. We suggest that the observed spatial variation in shear sense is compatible with NE- rather than SW-directed ductile extrusion of the CBU.

Preservation of high‐P rocks coupled to rock composition and the absence of metamorphic fluids

AbstractEclogites, blueschists and greenschists are found in close proximity to one another along a 1‐km coastal section where the Cyclades Blueschist Unit (CBU) is exposed on SE Syros, Greece. Here, we show that the eclogites and blueschists experienced the same metamorphic history: prograde lawsonite blueschist facies metamorphism at 1.2–1.9 GPa and 410–530°C followed, at 43–38 Ma, by peak blueschist/eclogite facies metamorphism at 1.5–2.1 GPa and 520–580°C. We explain co‐existence of eclogites and blueschists by compositional variation probably reflecting original compositional layering. It is also shown that the greenschists record retrogression at 0.34 ± 0.21 GPa and T = 456 ± 68°C. This was spatially associated with a shear zone on a scales of 10–100‐m and veins on a scale of 1–10‐cm. Greenschist facies metamorphism ended at (or shortly after) 27 Ma. We thus infer a period of metamorphic quiescence after eclogite/blueschist facies metamorphism and before greenschist facies retrogression which lasted up to 11–16 million years. We suggest that this reflects an absence of metamorphic fluid flow at that time and conclude that greenschist facies retrogression only occurred when and where metamorphic fluids were present. From a tectonic perspective, our findings are consistent with studies showing that the CBU is (a) a high‐P nappe stack consisting of belts in which high‐P metamorphism and exhumation occurred at different times and (b) affected by greenschist facies metamorphism during the Oligocene, prior to the onset of regional tectonic extension.