The structural features of the domain walls of the BaFe12O19 hexaferrite near the Curie temperature TC = 724 K were studied. The studies were performed on single-crystal samples in an alternating magnetic field with a frequency of 73 MHz and 71 MHz with a constant magnetic field in the range 0–0.25 kOe. In BaFe12O19 at a temperature of T1 = 716 K, the magnetic structure of the domain walls changes – the Bloch walls transform into linear walls with increasing temperature. The value ΔТ = Tc – T1≈8 K. The physical mechanism considered in the work, which determines the difference between the temperature range of the existence of the magnetically ordered state and the temperature range of the existence of the Bloch domain walls, is consistent with experimental results. The estimated calculation of the criterion for the transition of the Bloch domain wall to a linear wall at T1 = 716 K corresponds to the obtained experimental data.