Shale Research Articles

Porosity and pore structure evolution during the weathering of black shale

Pore type and pore structure evolves systematically across continuous black shale weathering profile. However, the extend and process of pore structure change is still an enigma. In this study, we try to unveil the pore structure evolution during weathering process through studying Cambrian Hetang shales in southern China. Fourteen shale samples, from protolith zone (PZ), fractured and weathered shale zone (FWZ), and saprolite zone (SZ), were collected to elucidate how porosity and pore structure develop during black shale weathering under subtropical condition. Through low pressure argon (Ar) gas adsorption (LP-ArGA), high pressure mercury intrusion (HPMI), nuclear magnetic resonance(NMR) and field emission scanning electron microscope (FESEM) observation, the results reveal significant differences in physical properties and pore structures among the PZ, FWZ, and SZ samples. Specifically, compared to PZ, FWZ and SZ samples are characterized by higher clay mineral content, lower organic matter (OM), and the absence of carbonates and pyrite. Total porosity, determined through HPMI and NMR, exhibits a gradual increase from PZ (6.70 % and 6.41 %) to FWZ (20.47 % and 13.45 %) and SZ (23.22 % and 12.48 %). Ar adsorption isotherms indicate a change in pore type from predominantly ink-bottle and slit-shaped in the PZ to mainly slit-shaped in FWZ and SZ. Integrated analysis of LP-ArGA, HPMI, NMR and SEM observation suggests a substantial decrease in the contribution of micropores to total pore volume (PV) and a concurrent increase in larger pores (meso-macropores) with the increase of weathering intensity. This results in smoother surfaces of micro-transition pores but rougher surfaces of macropores. Changes in mineralogy composition during weathering play a crucial role in influencing pore structure of shales and further accelerating the release and migration of toxic elements in black shale. Our study provides the essential theoretical foundation for the remediation of soil and water environmental pollution caused by black shale weathering.

Geochemical Characteristic of the Carbonaceous Sediments of the Upper Paleozoic Kuantan Group, Malaysia

The geochemical parameters discussed in this paper are based on the analysis of twelve outcrop carbonaceous samples, mainly black shales, using X-Ray Fluorescence (XRF) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) techniques. These samples are representative of the Charu, Sagor, and Permian formations. The aim of this study is to define and discuss their characteristics, the distribution abundance of major and minor elements, investigate the dominant mineralogical composition, and reconstruct the depositional environment for these sediments. The bulk chemical results showed that the average values of the major elements are 65.83%, 64.82%, and 71.4% SiO?; 18.27%, 22.2%, and 15.66% Al?O?; 1.53%, 0.99%, and 2.49% Fe?O?; and 4.06%, 6.25%, and 3.66% K?O for the Charu, Sagor, and Permian formations, respectively. The minor elements recorded values of 524.4 ppm, 758.8 ppm, and 446.3 ppm Ba; 366 ppm, 399.3 ppm, and 257.3 ppm Rb; 88 ppm, 67.3 ppm, and 47.3 ppm Sr; and 308 ppm, 288.8 ppm, and 327 ppm Zr for the Charu, Sagor, and Permian formations, respectively. The major oxides reflect the dominant mineralogical composition of quartz and other silicate minerals (e.g., illite, kaolinite, smectite) and a deficiency in carbonates. The high Rb/K ratio suggests a brackish marine environment or rapid deposition that prevented equilibrium between Rb and K in these shales. The high Rb/Sr ratios of 4.16, 5.89, and 5.44 for the Charu, Sagor, and Permian formations, respectively, are possibly attributed to the low Sr content due to reducing conditions prevailing during the deposition of these sediments.

Carbon-isotope stratigraphy of the Lower Cambrian (Cambrian explosion) in northwestern Yangtze Platform, China: Implications for global correlation

The Archaeocyathid Extinction Carbon Isotope Excursion (AECE) and Mingxinsi Carbon Isotope Excursion (MICE) are major events in the Early Cambrian sedimentary records but controversially heterogeneous in their magnitudes, as well as local and global correlations. This paper presents a high-resolution δ13Ccarb profile from the Shiliu section in the western Yangtze Platform (China) that spans the lower part of the Lower Cambrian. The investigated Lower Tianheban interval (∼110 m) is dominated by marine carbonates (lime mudstones) alternating occasionally with thinly-bedded black shale and mudstone interbeds. The investigated micritic carbonates were examined through a multi-technique protocol, combining petrographic and geochemical assessments, to evaluate the degree of sample preservation. The δ13Ccarb values (−2.4‰–1.8‰) show an insignificant correlation with the δ18Ocarb values (−12.6‰ to −8.7‰, R2 = 0.012), the Mn/Sr ratios (R2 = 0.001), and Al concentrations (R2 = 0.041). This supports the preservation of predominantly at least near-primary δ13Ccarb signatures, which can be utilized to reconstruct a reliable, high-resolution δ13Ccarb profile for chemostratigraphic correlations in the area and beyond. The profile displays a lower positive excursion of ∼3‰ overlain immediately by a negative excursion of ∼2.3‰. The archaeocyath zonation scheme suggests that the lower excursion is correlated with the global MICE event and the upper excursion with the AECE event. The results provide an alternative option for interpreting the carbon isotope excursions in the Lower Cambrian within the Yangtze Platform as well as other equivalent sections at a global scale.

The relationship between total organic carbon and bottom water redox state in North American black shales

It is clear from modern analogue studies that O2-deficient conditions favor preservation of organic matter (OM) in fine-grained sedimentary rocks (black shales). It is also clear that appreciable productivity and OM flux to the sediment are required to establish and maintain these conditions. However, debates regarding redox controls on OM accumulation in black shales have mainly focused on oxic versus anoxic conditions, and the implications of different anoxic redox states remain unexplored. Here, we present detailed multi-proxy sedimentary geochemical studies of major Paleozoic and Mesozoic North American black shale units to elucidate their depositional redox conditions. This is the first broad-scale study to use a consistent geochemical methodology and to incorporate data from Fe-speciation – presently the only redox proxy able to clearly distinguish anoxic depositional conditions as ferruginous (H2S-limited) or euxinic (H2S-replete, Fe-limited). These data are coupled with total organic carbon (TOC), programmed pyrolysis, and redox-sensitive trace element proxies, with almost all measurements analyzed using the same geochemical methodology. Consistent with expectations based on previous geochemical and paleontological/ichnological studies, these analyses demonstrate that the study units were almost exclusively deposited under anoxic bottom waters. These analyses also demonstrate that there is wide variance in the prevalence of euxinic versus ferruginous conditions, with many North American black shale units deposited under predominantly ferruginous or oscillatory conditions. TOC is significantly higher under euxinic bottom waters in analyses of both preserved (present day) TOC and reconstructed initial TOC values, although sediments deposited under both redox states do have economically viable TOC content. While this correlation does not reveal the mechanism behind higher organic enrichment in euxinic environments, which may be different in different basins, it does open new research avenues regarding resource exploration and the biogeochemistry of ancient reducing environments.

Helium‐isotope constraints on palaeoceanographic change and sedimentation rates during precession cycles (Cenomanian Scaglia Bianca Formation, central Italy)

AbstractFor much of the pelagic sedimentary record, time control is limited to the resolution of precession cycles (ca 20 kyr): the Milankovitch parameter that forms the most detailed metronome for the Cenozoic and Mesozoic Eras. The influence of precession is often detected in lithological alternations, where the duration represented by individual lithologies is not well constrained. Here the novel technique of extraterrestrial helium abundance (3HeET) is used to investigate the sedimentation dynamics and palaeoceanography within individual precessional cycles. High‐resolution 3HeET timescales were produced for four precession cycles from the rhythmically bedded Scaglia Bianca Formation, a sequence of Upper Cretaceous (Cenomanian) deep‐marine pelagic limestones from central Italy that are well characterized by cyclostratigraphy. Using 3HeET concentrations as a proxy for sedimentation rate allows instantaneous sedimentation rates and organic‐carbon mass accumulation rates to be calculated for each bed within a precession cycle. Eccentricity is known to modulate the amplitude of precession forcing, and precession cycles deposited under eccentricity maxima and minima were selected for comparison. Lithological changes through these chert–(black shale)–limestone cycles are explained using the concept of ‘palaeoenvironmental thresholds’; these timescale calculations indicate that when the amplitude of precessional insolation forcing was greatest (at eccentricity maxima) the palaeoenvironmental system spent longer in the more nutrient‐rich environment under which siliceous and organic‐rich sediments were deposited, reflecting increased time spent above a ‘threshold’ insolation level. Estimates of primary productivity are relatively elevated for organic‐rich beds. An increase in the flux of terrestrial helium (4Heterr) during the deposition of cherts may have been coincident with an increase in terrestrially derived nutrients. The presented results indicate great potential for the use of 3HeET to understand past oceanographic, climatic and sedimentological processes at high temporal resolution.

Pore Fractal Characteristics between Marine and Marine–Continental Transitional Black Shales: A Case Study of Niutitang Formation and Longtan Formation

Marine shales from the Niutitang Formation and marine–continental transitional shales from the Longtan Formation are two sets of extremely important hydrocarbon source rocks in South China. In order to quantitatively compare the pore complexity characteristics between marine and marine–continental transitional shales, the shale and kerogen of the Niutitang Formation and the Longtan Formation are taken as our research subjects. Based on organic petrology, geochemistry, and low-temperature gas adsorption analyses, the fractal dimension of their pores is calculated by the Frenkel–Halsey–Hill (FHH) and Sierpinski models, and the influences of total organic carbon (TOC), vitrinite reflectance (Ro), and mineral composition on the pore fractals of the shale and kerogen are discussed. Our results show the following: (1) Marine shale predominantly has wedge-shaped and slit pores, while marine–continental transitional shale has inkpot-shaped and slit pores. (2) Cylindrical pores are common in organic matter of both shale types, with marine shale having a greater gas storage space (CRV) from organic matter pores, while marine–continental transitional shale relies more on inorganic pores, especially interlayer clay mineral pores, for gas storage due to their large specific surface area and high adsorption capacity (CRA). (3) The fractal characteristics of marine and marine–continental transitional shale pores are influenced differently. In marine shale, TOC positively correlates with fractal dimensions, while in marine–continental shale, Ro and clay minerals have a stronger influence. Ro is the primary factor affecting organic matter pore complexity. (4) Our two pore fractal models show that the complexity of the shale in the Longtan Formation surpasses that of the shale in the Niutitang Formation, and type I kerogen has more complex organic matter pores than type III, aiding in evaluating pore connectivity and flow effectiveness in shale reservoirs.

Publisher Correction to: Sedimentary and metamorphic processes priming black shale for magmatic assimilation of sulfur: an example from the Virginia Formation, Minnesota, United States

Publisher Correction to: Sedimentary and metamorphic processes priming black shale for magmatic assimilation of sulfur: an example from the Virginia Formation, Minnesota, United States

An intelligent lithology recognition system for continental shale by using digital coring images and convolutional neural networks

Lithology identification is a critical component of reservoir evaluation and hydrocarbon development. However, the continental shale rocks, characterized by complex lithologies and developed laminations, present new challenges to traditional lithology identification techniques. In this study, we develop a centimeter-level intelligent identification system for continental shale lithology, leveraging digital image preprocessing and deep learning methods. Specifically, we construct a dataset from 400 m of drilling cores, encompassing 24 types of lithology and 152 lithological transitions. The downsampling and oversampling methods are employed to balance the dataset. The digital image denoising and restoration techniques are then utilized to enhance rock image features. Different neural network models are examined to obtain the optimum predictive results. The results indicate that data balancing improves the TOP1 and TOP5 accuracies by 10% and 5%, respectively. Gaussian low-pass filter denoising, in comparison to other methods, increases the TOP1 and TOP5 accuracies by 2%, establishing it as the superior denoising technique for lithology recognition. Considering both computational efficiency and prediction accuracy, EfficientNet emerges as the most effective model for continental shale image recognition. The optimized model attains up to 60% TOP1 and 95% TOP5 across 22 categories in drilling core samples. This study delves into the intelligent identification of macroscopic drilling core images of continental shale, and the findings can offer technical support for the interpretation and evaluation of continental shale reservoirs.

Climate cyclicity-controlled recurrent bottom-water ventilation events in the aftermath of the Toarcian Oceanic Anoxic Event: the Jenkyns Event

AbstractEnvironmental perturbations of the Toarcian Anoxic Event and its associated carbon isotope excursion (CIE) occurred in a cyclic fashion indicating an orbital control mechanism. Sedimentary strata of the E. elegantulum ammonite subzone in the Lorraine Sub-basin, Luxembourg, exhibit eight sedimentary cycles, most of which postdate the CIE, implying that its termination did not coincide with a full recovery from environmental stress. Sea-level and temperature fluctuations of the Toarcian crisis were linked to a cryosphere demise in the Northern Hemisphere, which modulated stadial versus interstadial phases on the orbital 100 ka eccentricity frequency band. Upon stadial phases, enhanced wind strength in combination with lowered sea level disrupted stratified shelf waters and shifted the storm wave base close to the sea floor. Ventilation of bottom waters interrupted accumulation of laminated and organic-rich black shales, but formed organic-lean and non-laminated gray claystones enriched in terrigenous wax lipids and spores provided via aeolian transport from the hinterland due to the enhanced wind strength. Wind systems are assumed to have been driven by high pressure differences between the cryosphere in the North of the Tethyan shelf and the warmer costal lowland. This distinguishes the atmospheric turbulences after the CIE from the postulated intensification of the cyclones that accompanied the rapid warming at the beginning of the CIE. The deep-water ventilation event following the CIE in the Lorraine Sub-basin was accompanied by a parallel evolution in the SW German Basin, indicating a supraregional driving mechanism in paleobathymetric sub-basins susceptible to lowering of storm wave base. In sub-basins with greater water depth on the NW-Tethyan shelf, post-CIE orbitally driven atmospheric turbulences had a minor or no effect on water column stratification and deposition of organic-rich laminated black shales persisted. Graphical abstract

Formation integrity evaluation for geosequestration of CO2 in depleted petroleum reservoirs under cyclic stress conditions

The geological storage of carbon dioxide (CO2), also referred to as CO2 geosequestration, represents one of the most promising options for reducing greenhouse gases in the atmosphere. However, most of the time, CO2 is captured with small amounts of other industrial gases such as sulphur dioxide (SO2) and hydrogen sulphide (H2S), which might be compressed together and stored in depleted petroleum reservoirs or aquifers. Moreover, during CO2 geosequestration in reservoirs, pressure variations during injection could force some amount of CO2 (with or without other acid gas impurities) into the caprock; thereby, altering the petrophysical, geochemical, and geomechanical properties of the caprock. Thus, the brittleness index of the reservoir and caprock might be impacted during CO2 geosequestration due to the chemical reactions between the rock minerals and the formation fluid. Furthermore, to meet the world net-zero carbon target, the promotion of CO2 utilization is paramount. This could be possible by developing an effective technology for cyclic CO2 geosequestration (with or without gas impurities). Therefore, studies on the co-injection of CO2 with other acid gases from industrial emissions, their withdrawal from the porous medium, and their impact on reservoir and caprock integrity are paramount. In this study, a dual-tubing string well completion technology was designed for cyclic injection and withdrawal of CO2 (with or without another acid gas), and numerical simulations were performed using TOUGHREACT codes, to model the cyclic process and investigate the co-injection of SO2 and H2S (separately) with CO2 in sandstone formations overlain by shale caprock. A novel technique of converting the volume fraction of minerals to their weight fraction was developed in this study, to evaluate the brittleness index of the sandstone reservoir and shale caprock during CO2 geosequestration. The findings of the study indicate that the porosity and permeability increase for the CO2 only and CO2–H2S injection cases, in the shale caprock; while for the CO2–SO2 injection case, porosity and permeability only decreased in the layers of the shale caprock contacted by SO2 and due to anhydrite precipitation. In all the injection cases, the porosity and permeability of the sandstone reservoir decreased in a few layers directly below the perforation interval of the production zone. However, in other regions in the sandstone reservoir, the porosity and permeability increased for the CO2 only and CO2–H2S injection cases. In contrast, for the CO2–SO2 co-injection case, porosity and permeability decreased in the layers of the sandstone rock contacted by SO2. In all the CO2 geosequestration cases, the brittleness of the shale and sandstone rocks investigated decreased slightly, except in the CO2–SO2 co-injection case where the brittleness of the sandstone rock decreased significantly. Based on the mineralogical composition of the formations in this study, co-injection of SO2 gas with CO2 gas, only decreased the brittleness index of the shale caprock slightly, but significantly decreased the brittleness of the sandstone reservoir.

Optimization design of plugging agent dosage and application of deep shale gas inner-diversion fracturing

China boasts abundant deep shale gas resources with considerable development potential. However, the weak brittleness and large horizontal stress contrast of deep shale rock may restrain the complex fractures network extension during hydraulic fracturing. To address this challenge, the inner-diversion fracturing technique is widely employed, facilitating the formation of a complex fractures network. Numerous theoretical studies emphasize the pivotal role of plugging pressure exerted by temporary plugging agents within fractures in enhancing deep shale stimulation performance. However, various types of temporary plugging agents with different plugging performances make it difficult to determine the optimal dosage of temporary plugging agents before fracturing operation. This study considered the dynamic propagation of fractures affected by the coupling of the induced stress from clustered fractures and the fluid pressure within the fractures into the mathematical model, based on rock mechanics theory. Subsequently, the inner-diversion capability testing instrument was utilized to evaluate the critical plugging pressure of several common temporary plugging materials. By integrating on-site data from temporary plugging and inner-diversion fracturing operations in the Southern Sichuan deep shale gas reservoir with this approach, the optimal dosage of temporary plugging agents in the operational scheme was refined. The fracturing operation curves demonstrate that the temporary plugging and inner-diversion pressure significantly increased after pumping the temporary plugging agent, indicating the hydraulic fractures successful plugging and a large-scale complex fractures network extension. This underscores the potential effectiveness of the temporary plugging dosage optimization method for inner-diversion fracturing. Furthermore, this study not only provides important guidance for optimal design but also mitigates the operational risks of inner-diversion fracturing in deep shale gas horizontal wells.

Mechanism of organo-nickel co-enrichment in marine black shale

Mechanism of organo-nickel co-enrichment in marine black shale

Evolution of black shale sedimentary environment and its impact on organic matter content and mineral composition: a case study from Wufeng-Longmaxi Formation in Southern and Eastern Sichuan Basin

Due to global geological events and differences in regional sedimentary environments, marine shale reservoirs of Wufeng-Longmaxi Formation in Eastern and Southern Sichuan Basin exhibit significant heterogeneity in organic matter content and mineral composition. In order to reveal the influence of paleoenvironment evolution on reservoir heterogeneity, key geochemical indicators of elements were used to reconstruct the sedimentary environment of marine shale in Eastern and Southern Sichuan Basin. The influence mechanism of paleoenvironment on organic matter content and mineral components was also explored. The results indicate that the Wufeng-Longmaxi Formation in the Southern and Eastern Sichuan Basin can be divided into two third-order sequences (Sq 1 and Sq 2). Each third-order sequence is divided into a transgressive system tract (TST) and a highstand system tract (HST). The average TOC content in the Eastern Sichuan Basin is the highest during the TST1 period with reaching 4.2%, while reached its maximum at 3.9% during the TST2 period in the Southern Sichuan Basin. Due to the influence of high paleo-productivity, the organic matter accumulation and quartz content in the eastern Sichuan region were higher than those in the southern Sichuan region from the TST1 to the middle TST2 period. However, the organic matter accumulation and quartz content in the late TST2 period were lower than those in the southern Sichuan region due to the dilution of terrestrial debris. During the HST2 period, due to the influence of higher paleo-productivity, clay adsorption and preservation condition, the TOC content in the eastern Sichuan region slightly increased in the early stage. At the same time, the marine shale in the southern Sichuan region has a high content of quartz minerals and a low content of clay minerals due to strong weathering intensity and input of coarse-grained debris (silt-size quartz).

Effects of water temperature on soil aggregate stability between soils developed from different parent materials in the subtropical hilly area of China

Water temperature has an important effect on soil aggregate stability. In this study, six soils derived from different parent materials in the hilly region of southern China were selected, and the mean weight diameter (MWD), geometric mean diameter (GMD), and soil erodibility (K value) were measured under different water temperature conditions. The aim of this study was to investigate the influence of water temperature on soil aggregate stability and erodibility. As the water temperature increased from 5 °C to 40 °C, the average content of >5 mm water-stable aggregates decreased by 57.13 %, while the average content of <0.25 mm water-stable aggregates increased by 214.41 %. The MWD and GMD of the six different parent soil types exhibited a decreasing trend with increasing water temperature. The trend of the K value was opposite to that of these values. The influence of water temperature on soil aggregate stability is mainly attributed to the thermal effect on the viscosity of soil water and the expansion of clay minerals. As the water temperature increases, the water viscosity coefficient, water density and water surface tension gradually decrease. Moreover, the response of soil aggregate stability and erosion resistance to water temperature varies with soil depth and parent material type. The topsoil exhibits greater sensitivity to water temperature than does the subsoil. Shale (SH) soils and quartz sandstone (QS) soils exhibited higher sensitivities, and Quaternary red clay (QRC) soils exhibited the lowest sensitivity to water temperature among the six soils. This difference is mainly attributed to differences in the contents of expansive clay minerals and organic matter. These results indicate that soil aggregate stability and erosion resistance decrease with increasing water temperature, which may be one reason for severe soil erosion under extremely high temperature and rainfall conditions in the southern red soil hilly region during summer.

New approach for predicting time-dependent deformation of shale rock: a modified fractional-order creep constitutive model

New approach for predicting time-dependent deformation of shale rock: a modified fractional-order creep constitutive model

Analyzing thermal maturity effect on shale organic matter via PeakForce quantitative nanomechanical mapping

Organic-rich shales have gained significant attention in recent years due to their pivotal role in unconventional hydrocarbon production. These shale rocks undergo thermal maturation processes that alter their mechanical properties, making their study essential for subsurface operations. However, characterizing the mechanical properties of organic-rich shale is often challenging due to its multiscale nature and complex composition. This work aims to bridge that knowledge gap to fully understand the nanomechanical properties of Shale organic matter at various thermal maturation stages. This study employs PeakForce Quantitative Nanomechanical Mapping (PF-QNM) using Atomic Force Microscopy (AFM) to investigate how changes at the immature, early mature, and peak mature stages impact the mechanical properties of the Bakken Shale organic matter. PF-QNM provides reliable mechanical measurements, allowing for the quantification and qualification of shale constituents' elastic modulus (E). We also accounted for the effect of probe type and further analyzed the impact of probe wear on the nanomechanical properties of shale organic matter. In immature shale, the average elastic modulus of organic matter is approximately 6 ​GPa, whereas in early mature and peak mature shale, it decreases to 5.5 ​GPa and 3.8 ​GPa, respectively. Results reveal a mechanical degradation with increasing thermal maturation, as evidenced by a reduction in Young's modulus (E). Specifically, the immature shale exhibits an 8% reduction in E, while the early mature and peak mature shales experience more substantial reductions of 31% and 37%, respectively. This phenomenon could be attributed to the surface probing of low-modulus materials like bitumen generated during heating. The findings underscore the potential of AFM PF-QNM for assessing the nanomechanical characteristics of complex and heterogeneous rocks like shales. However, it also highlights the need for standardized measurement practices, considering the diverse components in these rocks and their different elastic moduli.

The history of palaeontological research and excavations at Monte San Giorgio

There is a long history of palaeontological excavations at Monte San Giorgio (Switzerland) and the adjoining Monte Pravello—Monte Orsa (Italy), aimed at finding well-preserved skeletons of Middle Triassic vertebrates. The first fossils were discovered in the mid-Nineteenth Century during mining of black shales (scisti bituminosi) near Besano, Italy, with further finds in the early Twentieth Century through industrial-scale mining. Studies of the material generated international interest and prompted formal palaeontological excavations on both sides of the border. The earliest excavations took place in 1863 and 1878, with the most extensive between 1924 and 1968. Systematic excavations have continued up to the present day, focusing on six distinct fossiliferous horizons: the Besano Formation and the overlying Meride Limestone with the Cava inferiore, Cava superiore, Cassina, Sceltrich and Kalkschieferzone beds. All these have provided material for study and display, with Monte San Giorgio itself recently designated a UNESCO World Heritage Site. The workers and organisations involved, locations excavated and material recovered are described herein.

Rock physics-based anisotropy parameters estimation of Marcellus Shale using log data acquired in a vertical well

The elastic properties of shale rock exhibit anisotropy due to the presence of highly anisotropic clay minerals and their alignment. This anisotropy has a significant impact on geophysical and geomechanical responses. However, the elastic anisotropy of shale is often overlooked due to the difficulty in measuring sufficient parameters in the field, resulting in a gap between theoretical understanding and practical implementation. To address this issue, a rock physics-based approach was tested on log data obtained from a vertical well in the Marcellus Shale to estimate anisotropy parameters. The approach utilized a rock physics model based on the Sayers-den Boer method with model parameters optimized using measured stiffness parameters C33, C55, and C66. Anisotropy parameters δ and ε were then calculated using these optimized model parameters. The optimized model parameters and estimated anisotropy parameters are consistent with existing studies, indicating the correctness of the model. Additionally, the rock physics model was used to investigate the impact of gas saturation on the vertical VP/VS ratio and ε/γ ratio. It was found that gas saturation has a significant impact on these ratios. This carries important implications for acoustic log data interpretation and seismic characterization of shales.

A new rock physics model for fractured oil shale reservoirs in Mahu oil field

The exploration of unconventional reservoirs such as oil shale has become a focus of research in the oil/gas industry, but due to the diversity of lithology and structural complexity of shale reservoirs, the study of their rock physics laws is a challenge. By analyzing the physical, lithologic, and fluid characteristics of oil shale reservoirs in the Mahu area of Xinjiang, China, we adopted a variety of effective-medium theories to carry out rock physics modeling. We analyzed the differences in the calculation results of various theoretical models, and finally constructed a set of rock physics modeling processes suitable for oil shale reservoirs. The analysis shows that the calculation results of Voigt-Reuss-Hill (VRH) and Hashin-Shtrikman (HS) average for mixed mineral matrix are very similar, but there are certain differences between the upper and lower bounds calculated by them. The upper and lower bounds of HS average are closer than VRH average. We used the Kuster-Toksoz effective-medium, differential effective-medium (DEM), and self-consistent approximation models to construct the rock skeleton and analyzed the differences of the models. The results of the three models are almost identical, but their assumptions and limitations differ. We used DEM in the final shale model, considering the large porosity and the order of inclusion filling. According to the fracture distribution characteristics of oil shale reservoirs, we used an inclined fracture model to describe the fractures with different structural characteristics. Finally, the established shale rock physics model was used to calculate the actual logging data, and the results of elastic parameters are consistent with the measured data. Through the inversion of the fracture parameters, the inversion results are consistent with the measured results as a whole, indicating that the model has certain applicability to the simulation of oil shale reservoirs.

Platinoids in gold sulphide deposits in black shales in the east of the Orenburg Region

Platinoids in gold sulphide deposits in black shales in the east of the Orenburg Region