ABSTRACT Global expansion of the EV market has led to widespread DC charging infrastructure. Consumers prefer DC charging over AC to reduce charging time per kilometer. However, grid-connected DC chargers can cause issues such as grid instability, power quality problems, demand imbalance, and conversion losses. This paper proposes an off-grid photovoltaic (PV) fed DC charger for EVs along with a battery energy storage system (BESS) to mitigate these challenges. The work aims to increase the use of clean energy for EV charging, to ensure uninterrupted EV charging with minimum power conversion stages, and to improve PV utilization. BESS serves as a backup power source that charges or discharges based on PV availability. Additionally, the system powers the non-critical adjustable loads of domestic/industrial sites with the available PV power when both EV and BESS are fully charged. The system can be reconfigured to operate in six distinct modes using two DC-DC converters and five relays. Among six modes, four modes operate in single-stage power conversion. A buck converter is used to extract power from PV. A bidirectional buck-boost converter is used to charge and discharge the BESS. The proposed system is validated through hardware prototype for both steady-state and transient conditions.