Bent Crystals Research Articles

Development of a Broadband high-resolution X-ray spectrometer with new toroidally bent crystal

X-ray diagnosis technology based on crystal diffraction is an important method to obtain key parameters in the research fields of X-ray spectroscopy diagnosis, material analysis and structural characterization on high-energy laser devices and synchrotron radiation devices. A Broadband high-resolution X-ray crystal spectrometer is proposed and built based on the principle of Rowland-Circle. This spectrometer is designed for measuring X-ray spectra across a wide spectral range(7.6keV–8.5 keV). The structure includes incorporating a curved quartz crystal as the diffraction and focusing element, along with an CMOS photon detector for spectrum detection from a Cu target X-ray tube. Experimental findings indicate that the X-ray crystal spectrometer can achieve spectral energy detection of 8027.8 eV(Kα2) and 8047.8eV (Kα1), the spectrometer's actual spectral resolution can exceed 2718@ Cu Kα1.

Mechanical Tuning of Fluorescence Lifetime and Bandgap in an Elastically Flexible Molecular Semiconductor Crystal.

Despite having superior transport properties, lack of mechanical flexibility is a major drawback of crystalline molecular semiconductors as compared to their polymer analogues. Here single crystals of an organic semiconductor are reported that are not only flexible but exhibit systematic tuning of bandgaps, fluorescence lifetime, and emission wavelengths upon elastically bending. Spatially resolved fluorescence lifetime imaging and confocal fluorescence microscopy reveals systematic trends in the lifetime decay across the bent crystal region along with shifts in the emission wavelength. From the outer arc to the inner arc of the bent crystal, a significant decrease in the lifetime of ≈1.9ns is observed, with a gradual bathochromic shift of ≈10nm in the emission wavelength. For the crystal having a bandgap of 2.73eV, the directional stress arising from bending leads to molecular reorientation effects and variations in the extent of intermolecular interactions- which are correlated to the lowering of bandgap and the evolution of the projected density of states. The systematic changes in the interactions quantified using electron density topological analysis in the compressed inner arc and elongated outer arc region are correlated to the non-radiative decay processes, thus rationalizing the tuning of fluorescence lifetime.

Ultra-Wide Modulation and Reversible Reconfiguration of a Flexible Organic Crystalline Optical Waveguide Between 645 and 731 nm.

Flexible organic crystalline optical waveguides, which deliver input or self-emit light through various dynamic organic crystals, have attracted increasing attention in the past decade. However, the modulation of the waveguide output relies on chemical design and substituent modification, being time-consuming and laborious. Here we report an elastic organic crystal that displays long-distance light transduction up to 2.0 cm and an ultra-wide modulation of crystalline optical waveguides between red (645 nm) and near infrared (731 nm) in both the pristine and the elastically bent states based on a pre-designed self-absorption effect. The flexible organic crystalline optical waveguides can be precisely and reversibly reconfigured by controlling the irradiation point. In addition, deep-red amplified spontaneous emission (ASE) that is able to transduce through a 5.0 mm bent crystal with an ultra-low optical loss coefficient of 0.093 dB/mm has been attained. To the best of our knowledge, this is the first report of flexible organic ASE waveguides. The present study not only provides a simple yet effective strategy to remarkably modulate flexible organic crystalline optical waveguides but also demonstrates the superiority of lasing over normal emission as flexible optical communication elements.

Ultra‐Wide Modulation and Reversible Reconfiguration of a Flexible Organic Crystalline Optical Waveguide Between 645 and 731 nm

AbstractFlexible organic crystalline optical waveguides, which deliver input or self‐emit light through various dynamic organic crystals, have attracted increasing attention in the past decade. However, the modulation of the waveguide output relies on chemical design and substituent modification, being time‐consuming and laborious. Here we report an elastic organic crystal that displays long‐distance light transduction up to 2.0 cm and an ultra‐wide modulation of crystalline optical waveguides between red (645 nm) and near infrared (731 nm) in both the pristine and the elastically bent states based on a pre‐designed self‐absorption effect. The flexible organic crystalline optical waveguides can be precisely and reversibly reconfigured by controlling the irradiation point. In addition, deep‐red amplified spontaneous emission (ASE) that is able to transduce through a 5.0 mm bent crystal with an ultra‐low optical loss coefficient of 0.093 dB/mm has been attained. To the best of our knowledge, this is the first report of flexible organic ASE waveguides. The present study not only provides a simple yet effective strategy to remarkably modulate flexible organic crystalline optical waveguides but also demonstrates the superiority of lasing over normal emission as flexible optical communication elements.

ON THE POSSIBILITY OF USING STRAIGHT AND BENT CRYSTALS FOR CHARGED PARTICLE BEAM STEERING AT THE FUTURE MULTIFUNCTIONAL ACCELERATOR COMPLEX OF NSC KIPT

The scattering of electrons and positrons with energy of 500 MeV on straight and bent silicon crystals has been considered using numerical simulations. The selected particle energy corresponds to parameters that can be achieved at the future multifunctional accelerator complex of the NSC “Kharkiv Institute of Physics and Technology”. It is shown that bent crystals, at certain orientations, allow deflecting charged particles at angles significantly exceeding the critical angle of axial channeling. It is also shown that experimental investigation of the effect of reducing inco- herent scattering of high-energy positrons when orienting the crystal relative to the direction of particle incidence near one of the main crystal axes is of interest.

Exploring the potential of resonance islands and bent crystals for a slow extraction from circular hadron accelerators

New developments in accelerator physics have broadened the set of available techniques for manipulating charged-particle beams. Adiabatic trapping and transport of a beam in resonance islands has been studied and successfully implemented at the CERN Proton Synchrotron to perform multiturn extraction. Bent crystals have been successfully installed in the CERN Large Hadron Collider, improving the cleaning performance of the collimation system, and at the CERN Super Proton Synchrotron for reducing losses at the extraction septum in the case of slow extraction. In this Letter, we discuss the potential of the combined use of resonance islands and bent crystals to devise a technique to perform slow extraction in circular hadron accelerators. The proposed approach is promising, particularly for applications with high-intensity beams, as it could dramatically reduce the losses on the extraction devices. Published by the American Physical Society 2024

X-ray imaging crystal spectrometer (XICS) diagnostic on the HL-3 tokamak

The construction of an X-ray imaging crystal spectrometer (XICS) diagnostic system on the HL-3 tokamak plays a crucial role in measuring core plasma parameter profiles, including ion temperature, electron temperature, rotational velocity, and impurity radiation profiles. This diagnostic system has been specifically designed to provide detailed and accurate data essential for understanding the behavior and characteristics of tokamak plasma. The resonance spectral line (w line of Ar XVII at 3.9494 Å) and its satellites of helium-like argon ions were chosen on the basis of the HL-3 parameter range. A spherically bent quartz crystal (1012) with a lattice constant of 2d = 4.562 Å, a curvature radius of Rc = 3.0 m, and a size of 10 cm (high) × 5 cm (wide) was mounted on an adjustable displacement platform in the XICS system. The position was adjusted in three dimensions (vertical, inclined, rotation) to effectively record the spectra of the helium-like argon ions. The XICS has a tangential angle of 49° for the toroidal direction in the magnetic axis. This layout accounts for 65.6 % of the toroidal rotation velocity component. The XICS system was set at an 11° poloidal angle in the mid-plane to cover a plasma range of 10 cm above to 50 cm below the mid-plane, which corresponds to the q = 1 surface of the HL-3 plasma (elongation κ > 1.8). This XICS layout produced a spectrum with poloidal and toroidal rotational contributions, requiring decoupling through data processing. In general, because the contribution of the poloidal rotation velocity is much smaller than that of the toroidal rotation velocity, it can be ignored. The XICS system offers a spatial resolution of ∼1.5 cm and a temporal resolution of 5–10 ms on the basis of a high-performance PILATUS3 × 900 K detector. The spectral resolution is λ/Δλ∼4×104, which satisfies the experimental measurement requirements. Preliminary results of ion and electron temperature profiles were obtained for the HL-3 tokamak.

Advancements in experimental techniques for measuring dipole moments of short-lived particles at the LHC

ALADDIN is a proposed fixed-target experiment at the LHC for the direct measurement of charm baryon dipole moments. The detector features a spectrometer and a Cherenkov detector, while the experimental technique is based on the phenomena of particle channelling and spin precession in bent crystals. TWOCRYST, a proof-of-principle test at the LHC for the proposed experiment, is planned during the LHC Run 3. Recent channelling efficiency measurements performed at the CERN SPS of bent crystals developed at INFN are presented, marking significant progress towards its realisation. The silicon pixel detector for TWOCRYST is under construction. It will work in the secondary vacuum of a Roman Pot positioned inside the LHC beam pipe. The design, construction and integration of the pixel detector inside the Roman Pot will be discussed, along with the design and perspectives for the proposed ALADDIN experiment.

Testing the optical components for the National Ignition Facility time-resolved soft x-ray opacity spectrometer (OpSpecTR).

Opacity measurements are being carried out at the Z-facility at Sandia National Laboratories and at the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory. The current soft x-ray Opacity Spectrometer (OpSpec) used on the NIF uses two elliptically bent crystals in time-integrated mode on either an image plate or a film. Plans are under way to expand these opacity measurements into a mode of time-resolved detection, called OpSpecTR. Previously, considerations for the available hCMOS detector size and photometrics led to a crystal geometry redesign and the use of a grazing angle x-ray mirror. The mirror acts as a low-pass x-ray energy filter, reducing the contribution of higher energy x rays. The first tests of the mirror and the crystal for OpSpecTR are presented here. The size of the mirror reflection and the reflectivity is tested using a Manson x-ray source. The mirror coupled with the new elliptical crystal shape demonstrates OpSpecTR's spectral coverage. The results from the x-ray optics performance testing are shown along with the intended design.

Revisiting the ‘magic condition’ on the basis of the Takagi–Taupin theory

A numerical framework based on the integral solution of the Takagi–Taupin equations has been developed for cylindrically bent Laue crystals. On the basis of this framework, diffraction geometries that satisfy the `magic condition' have been studied from the perspective of dynamical theory. The numerical findings indicate that, in certain diffraction geometries, the focusing behaviour of cylindrically bent Laue crystals will be notably influenced by dynamical effects and the foci of different energies will not converge as predicted by the `magic condition', which is derived from geometric optics theory. These dynamical effects are further explained through a direct numerical analysis of the influence function.

Simulation of deflection and photon emission of ultra-relativistic electrons and positrons in a quasi-mosaic bent silicon crystal

Abstract A comprehensive numerical investigation has been conducted on the angular distribution and spectrum of radiation emitted by 855 MeV electron and positron beams while traversing a ‘quasi-mosaic’ bent silicon (111) crystal. This interaction of charged particles with a bent crystal gives rise to various phenomena such as channeling, dechanneling, volume reflection, and volume capture. The crystal’s geometry, emittance of the collimated particle beams, as well as their alignment with respect to the crystal, have been taken into account as they are essential for an accurate quantitative description of the processes. The simulations have been performed using a specialized relativistic molecular dynamics module implemented in the MBN Explorer package. The angular distribution of the particles after traversing the crystal has been calculated for beams of different emittances as well as for different anticlastic curvatures of the bent crystals. For the electron beam, the angular distributions of the deflected particles and the spectrum of radiation obtained in the simulations are compared with the experimental data collected at the Mainz Microtron facility. For the positron beam such calculations have been performed for the first time. We predict significant differences in the angular distributions and the radiation spectra for positrons versus electrons.

Performance predictions of the SPARC x-ray crystal spectrometers for ion temperature and toroidal rotation measurements.

SPARC will be outfitted with three systems of x-ray crystal spectrometer arrays. Two of these are designed using cylindrically bent crystals to achieve high spectral-resolution for ion temperature and toroidal velocity measurements via imaging He-like Kr and Ne-like Xe. The last acts as a spectral survey system to monitor Ne-like W and nearby H- and He-like emission from Cr, Fe, Co, Ni, and Cu. Line radiation intensities are calculated using the Flexible Atomic Code for atomic data and ColRadPy for collisional-radiative modeling, then convoluted with a Voigt line shape. Free-free, free-bound, and two-photon continuum radiation is also included. The ToFu code is used to perform volume-of-sight integration to produce synthetic detector images. In addition, presented is cross-validation performed using the XICSRT Monte Carlo ray-tracing code. Ion temperature and toroidal velocity profiles are reconstructed using ToFu via tomographic inversion.

Results from a synthetic model of the ITER XRCS-Core diagnostic based on high-fidelity x-ray ray tracing.

A high-fidelity synthetic diagnostic has been developed for the ITER core x-ray crystal spectrometer diagnostic based on x-ray ray tracing. This synthetic diagnostic has been used to model expected performance of the diagnostic, to aid in diagnostic design, and to develop engineering tolerances. The synthetic model is based on x-ray ray tracing using the recently developed xicsrt ray tracing code and includes a fully three-dimensional representation of the diagnostic based on the computer aided design. The modeled components are: plasma geometry and emission profiles, highly oriented pyrolytic graphite pre-reflectors, spherically bent crystals, and pixelated x-ray detectors. Plasma emission profiles have been calculated for Xe44+, Xe47+, and Xe51+, based on an ITER operational scenario available through the Integrated Modelling & Analysis Suite database, and modeled within the ray tracing code as a volumetric x-ray source; the shape of the plasma source is determined by equilibrium geometry and an appropriate wavelength distribution to match the expected ion temperature profile. All individual components of the x-ray optical system have been modeled with high-fidelity producing a synthetic detector image that is expected to closely match what will be seen in the final as-built system. Particular care is taken to maintain preservation of photon statistics throughout the ray tracing allowing for quantitative estimates of diagnostic performance.

Large Local Internal Stress in an Elastically Bent Molecular Crystal Revealed by Raman Shifts.

The structural dynamics involved in the mechanical flexibility of molecular crystals and the internal stress in such flexible materials remain obscure. Here, the study reports an elastically bending lipidated molecular crystal that shows systematic shifts in characteristic vibrational frequencies across the bent crystal region - revealing the nature of structural changes during bending and the local internal stress distribution. The blueshifts in the bond stretching modes (such as C═O and C-H modes) in the inner arc region and redshifts in the outer arc region of the bent crystals observed via micro-Raman mapping are counterintuitive to the bending models based on intermolecular hydrogen bonds. Correlating these shifts with the trends observed from high-pressure Raman studies on the crystal reveals the local stress difference between the inner arc and outer arc regions of the bent crystal to be ≈2GPa, more than an order of magnitude higher than the previously proposed value in elastically bending crystals. High local internal stress can have direct ramifications on the properties of molecular piezoelectric energy harvesters, actuators, semiconductors, and flexible optoelectronic materials.

Crystal channeling investigations at medical synchrotron regimes

An experimental setup to investigate ion channeling in the hundreds MeV/u energy range is described. A short bent crystal, aligned to the incoming beam by an angular actuator, should deflect ions into a single plane pixel detector used to identify channeled and unchanneled particles. In order to enhance the footprint of channeling on the recorded signals, the incoming particle emittance is tailored on the crystalline plane acceptance by means of massive collimators. Numerical simulations of low energy carbon ions are performed with FLUKA to fully understand the measurement conditions demonstrate the feasibility of the test, to be performed in the experimental room of the National Center for Oncological Hadrontherapy accelerator complex in Pavia, Italy.

On the resolution of the three-axis neutron diffractometer setting optimized for some powder diffractometry studies

Presented three-axis neutron diffractometer performance documents the feasibility of using it in special cases high-resolution powder diffraction studies, namely, for elastic and plastic deformation studies of bulk polycrystalline samples when the whole powder diffraction spectrum is not required. Contrary to the conventional double-axis setting the suggested alternative consists of an unconventional three axis set-up employing a bent perfect crystal (BPC) monochromator and analyzer with a polycrystalline sample in between. The analysis of the profile of the beam diffracted by a sample is carried out by rocking the BPC-analyzer and the neutron signal is registered by a point detector. Though the diffractometer alternative is, for measurements, much more time consuming, its resolution is, however, substantially higher and permits also plastic deformation studies on the basis of analysis of the sample diffraction profiles. The so-called analyzer rocking curve then provides a sample diffraction profile and could reflect the lattice or structural changes. Moreover, much larger widths (up to 10 mm) of the irradiated gauge volumes can be investigated when just slightly affecting the resolution of the experimental setting.

X-ray fluorescence detection system for trace elements in oil based on graphite curved crystal technology

Curved crystal technology is a key technology in the field of X-ray fluorescence trace detection. To detect trace sulfur, chlorine, and silicon in oil, the key parameters of Johann-type graphite curved crystal design were calculated based on geometrical optics theory and mathematical modeling, and a curved crystal optical system was designed. Subsequently, the hardware, firmware, software, and mechanical structure were designed according to specific requirements. Following the development of the relevant equipment, laboratory tests were performed on standard petroleum samples. Experimental results show that technology based on bent crystals can significantly reduce the detection limit of the instrument, and the detection limit of sulfur, chlorine, and silicon can reach below 1 ppm. In accordance with the experimental results, possible interference factors were analyzed, and suitable solutions were proposed. The performance of the proposed system was thus directly verified, showcasing its applicability in detecting trace elements.

High-Spatial-Resolution Benchtop X-ray Fluorescence Imaging through Bragg-Diffraction-Based Focusing with Bent Mosaic Graphite Crystals: A Simulation Study.

X-ray fluorescence imaging (XFI) can localize diagnostic or theranostic entities utilizing nanoparticle (NP)-based probes at high resolution in vivo, in vitro, and ex vivo. However, small-animal benchtop XFI systems demonstrating high spatial resolution (variable from sub-millimeter to millimeter range) in vivo are still limited to lighter elements (i.e., atomic number Z≤45). This study investigates the feasibility of focusing hard X-rays from solid-target tubes using ellipsoidal lens systems composed of mosaic graphite crystals with the aim of enabling high-resolution in vivo XFI applications with mid-Z (42≤Z≤64) elements. Monte Carlo simulations are performed to characterize the proposed focusing-optics concept and provide quantitative predictions of the XFI sensitivity, in silico tumor-bearing mice models loaded with palladium (Pd) and barium (Ba) NPs. Based on simulation results, the minimum detectable total mass of PdNPs per scan position is expected to be on the order of a few hundred nanograms under in vivo conform conditions. PdNP masses as low as 150 ng to 50 ng could be detectable with a resolution of 600 μm when imaging abdominal tumor lesions across a range of low-dose (0.8 μGy) to high-dose (8 μGy) exposure scenarios. The proposed focusing-optics concept presents a potential step toward realizing XFI with conventional X-ray tubes for high-resolution applications involving interesting NP formulations.

Bending, Twisting, and Propulsion of Photoreactive Crystals by Controlled Gas Release

AbstractThe rapid release of gas by a chemical reaction to generate momentum is one of the most fundamental ways to elicit motion that could be used to sustain and control the motility of objects. We report that hollow crystals of a three‐dimensional supramolecular metal complex that releases gas by photolysis can propel themselves or other objects and advance in space when suspended in mother solution. In needle‐like regular crystals, the reaction occurs mainly on the surface and results in the formation of cracks that evolve due to internal pressure; the expansion on the cracked surface of the crystal results in bending, twisting, or coiling of the crystal. In hollow crystals, gas accumulates inside their cavities and emanates preferentially from the recess at the crystal terminus, propelling the crystals to undergo directional photomechanical motion through the mother solution. The motility of the object which can be controlled externally to perform work delineates the concept of “crystal microbots”, realized by photoreactive organic crystals capable of prolonged directional motion for actuation or delivery. Within the prospects, we envisage the development of a plethora of light‐weight, efficient, autonomously operating robots based on organic crystals with high work capacity where motion over large distances can be attained due to the large volume of latent gas generated from a small volume of the crystalline solid.

Bending, Twisting, and Propulsion of Photoreactive Crystals by Controlled Gas Release.

The rapid release of gas by a chemical reaction to generate momentum is one of the most fundamental ways to elicit motion that could be used to sustain and control the motility of objects. We report that hollow crystals of a three-dimensional supramolecular metal complex that releases gas by photolysis can propel themselves or other objects and advance in space when suspended in mother solution. In needle-like regular crystals, the reaction occurs mainly on the surface and results in the formation of cracks that evolve due to internal pressure; the expansion on the cracked surface of the crystal results in bending, twisting, or coiling of the crystal. In hollow crystals, gas accumulates inside their cavities and emanates preferentially from the recess at the crystal terminus, propelling the crystals to undergo directional photomechanical motion through the mother solution. The motility of the object which can be controlled externally to perform work delineates the concept of "crystal microbots", realized by photoreactive organic crystals capable of prolonged directional motion for actuation or delivery. Within the prospects, we envisage the development of a plethora of light-weight, efficient, autonomously operating robots based on organic crystals with high work capacity where motion over large distances can be attained due to the large volume of latent gas generated from a small volume of the crystalline solid.