This paper reports on the bond behavior of glass fine aggregate reinforced concrete (GFARC) under chloride erosion, considering the chloride solution and glass fine aggregate (GFA) exchange rates as variable parameters. The 16 groups of specimens are designed to conduct central pull-out tests after chloride erosion. The experimental results are analyzed, such as the τ–s curve, ultimate bond strength, peak slip, and bond stiffness. The results indicated that the degree of reinforcement corrosion in GFARC is low under the action of chloride corrosion. Compared with natural aggregate-reinforced concrete (NARC), the ultimate bond strength and bond stiffness of GFARC improve under the same chloride corrosion. The ultimate bond strengths of 25% GFARC, 50% GFARC, and 75% GFARC increased by 7%, 7.85%, and 17.31%, respectively, under natural conditions. Under 3.5% chlorine erosion, the GFARC group increased by 4.67%, 4.83%, and 13.53%, respectively. Under 5% chlorine erosion, the GFARC group increased by 5.54%, 6.24%, and 12.64%, respectively. Glass fine can improve the bonding performance between concrete and steel bars, and its effect is related to the replacement rate. The shape and chemical characteristics of glass sand play an important role in this process and became more prominent with the deepening of the effect. Through the analysis of the experimental results, this paper further elaborated on the bonding mechanism of GFARC under the influence of chloride corrosion. The research indicates that the use of GFA has a great advantage in improving the bond performance under chloride erosion.