Laser-induced graphene (LIG) is a highly porous carbon material with prospects for application in various fields of modern electronics, energy and medicine. In this work, LIG film samples with the size of 5 × 10 mm were synthesized on the surface of polyimide film using line-by-line scanning of focused radiation from a cw carbon dioxide laser. Studies using scanning electron microscopy and Raman spectroscopy revealed that the structure of the resulting material depends significantly on the laser power. Measurements of the specific surface area Ssa of the synthesized carbon material, carried out by the well-known BET method during adsorption and desorption of gaseous nitrogen, showed that Ssa significantly depends on the laser power. At a line scanning speed of 220 mm/s, 25 μm spacing between lines and a focused laser beam diameter of 120 μm, an increase in power from ~1.7 to 8.2 W leads to a decrease in Ssa from ~370 to ~100 m2/g. At the same time, the ratio of the total area of all LIG pores to the area of the obtained film varies in the range ~ 365–660 and reaches its maximum value of 660 at a power ~ 4.3 W.