Sodium-ion batteries (SIB) have been heavily researched, as a potential replacement for Lithium ion batteries (LIB) as their components are more readily obtainable, lower cost and they have similar working principles to LIB. Hard Carbon (HC) is the current state-of-the-art anode for SIB material due to its relatively low cost, overall performance and availability. Great effort has been focused into improving and better understanding the overall mechanism of HC, which is still a subject of debate.To better understand the mechanism of, and the obstacles to, charge transfer during charge and discharge of the cell, Hard carbon has been studied at different temperatures. The transitions between different stable and unstable phases are observed which have not been taken into consideration as of now in the literature. Exploring the thermodynamics and kinetics of the cell-system during the charge and discharge at different temperature with different methods, such as Galvanostatic Intermittent Titration Technique (GITT) and Electrochemical impedance spectroscopy (EIS) provides much-needed insights to elucidate the limits and obstacles to ion transport, which can then be addressed. EIS is one a key tool which provides the exchange current density, a measure of the rates of electron transfer as the ions migrate between the electrolyte and the electrodes, indicating the impedance of the different components in the cell at different frequencies. This is combined with Raman to further investigate these phase changes at different temperature.The understanding gained of the limits and obstacles to charge transfer will be highly beneficial in designing better suited hard carbons to improve their overall cell performance in SIBs.