Battery Configuration Research Articles

Recent Advances in Rechargeable Zn-Air Batteries

Rechargeable Zn-air batteries are considered to be an effective energy storage device due to their high energy density, environmental friendliness, and long operating life. Further progress on rechargeable Zn-air batteries with high energy density/power density is greatly needed to satisfy the increasing energy conversion and storage demands. This review summarizes the strategies proposed so far to pursue high-efficiency Zn-air batteries, including the aspects of the electrocatalysts (from noble metals to non-noble metals), the electrode chemistry (from the oxygen evolution reaction to the organic oxidation reaction), electrode engineering (from powdery to free-standing), aqueous electrolytes (from alkaline to non-alkaline) and the battery configuration (from liquid to flexible). An essential evaluation of electrochemistry is highlighted to solve the challenges in boosting the efficiency of rechargeable metal-air batteries. In the end, the perspective on current challenges and future research directions to promote the industrial application of rechargeable Zn-air batteries is provided.

Ti3C2Tx MXene Electrode‐Electrolyte Interface Reactions at Different Stages of Charge/Discharge in Lithium and Sodium Half‐Cells

AbstractEnergy storage technologies necessitates efficient, cost effective, and durable storage systems like Li‐ion batteries (LIBs), with high energy density. Emerging 2D materials like MXenes have become significant for battery applications. Herein, titanium carbide (Ti3C2Tx) synthesized and lattice engineered via ‐OH surface terminations removal by thermal processing is well explained. The synthesized samples were subjected to annealing at 250 and 500 °C. All the samples were characterized using XRD, TEM, XPS, etc. Subsequently, they were tested in the half‐cell configuration for both lithium and sodium ion batteries (NIBs). It is observed that the best performance for lithium‐ion storage capacity was 200 mAh/g at 50 mA/g and 125 mAh/g at the same specific current for sodium‐ion storage for the 500 °C processed sample. However, for both the systems the cycling stability was exceptional maintaining high retention till the end of 1000 cycles. To establish the performance, electrochemical impedance and ex situ XPS results at different voltage of 1st charge/discharge were correlated for the best sample. Thus, providing information that is unavailable in the literature on MXene‐electrolyte interactions, kinetics and the chemical nature of solid‐electrolyte interface layer for both lithium and sodium‐ion batteries.

Separator‐Supported Electrode Configuration for Ultra‐High Energy Density Lithium Secondary Battery

AbstractSignificant efforts are being made to develop high‐performance battery materials, particularly active materials. However, material‐dependent strategies for increasing energy density face challenges such as raw material costs and supply limitations, reducing their versatility to some extent. In this regard, the development of efficient battery designs can be a universal approach to increasing the energy density of lithium‐ion batteries with relatively low dependence on material properties. Herein, a novel configuration of an electrode‐separator assembly is presented, where the electrode layer is directly coated on the separator, to realize lightweight lithium‐ion batteries by removing heavy current collectors. Even on the hydrophobic separator, a poly(vinyl alcohol) binder enables uniform and scalable coating of aqueous electrode slurries through molecular interactions with the separator surface. Moreover, carbon nanotubes are utilized to reinforce the electronic conduction of the electrode, providing consistent electronic pathways regardless of SEI formation. Furthermore, owing to the superior permeability of liquid electrolytes through this electrode‐separator assembly, a multilayered electrode‐separator assembly can be suggested to further increase energy density when combined with a lithium metal anode. This lithium metal battery can achieve an areal capacity of ≈30 mAh cm−2 and an enhanced energy density of over 20% compared to conventional battery configurations.

Modeling and Simulation of Hybrid Electric Vehicles for Sustainable Transportation: Insights into Fuel Savings and Emissions Reduction

Most motor vehicles have historically utilized Internal Combustion Engines powered by a fossil fuel. Despite the technological advancements in fuel-efficient engines, further improvements are required to reduce the effect of fuel costs and global warming. This study models and simulates Hybrid Electric Vehicles (HEVs) to evaluate their potential for fuel cost savings and emissions reduction compared to traditional vehicles. Using MATLAB® version R2023a Update 5 (9.14.0.2337262) Simulink version 10.7 (R2023a) and the Advanced Vehicle Simulator (ADVISOR) version 2003-00-r0116, the research examines Series and Parallel HEV configurations. The simulation explores various battery configurations, engine capacities, and power unit models to analyze their impact on energy utilization. The data, collected from the simulations, show significant fuel savings and emissions reduction with HEVs. The Parallel HEV configuration consistently saves fuel with fewer battery modules, while the Series HEV configuration performs better but requires more modules to maintain the system’s State of Charge.

Simulation Study on Factors Affecting the Output Voltage of Extended-Range Electric Vehicle Power Batteries

The power battery configuration of an extended-range electric vehicle directly affects the overall performance of the vehicle. Optimization of the output voltage of the power battery can improve the overall power and economy of the vehicle to ensure its safe operation. Factors affecting the output voltage of power batteries under different operating conditions, such as nominal voltage and the number of series and parallel connections of the battery cells, have been studied. This study uses AVL Cruise to establish an overall model of an extended-range electric vehicle to simulate the output voltage characteristics under the different operating conditions of the NEDC (New European Driving Cycle), WLTC (World Light Vehicle Test Cycle) and CLTC (China Light Duty Vehicle Test Cycle). The influence of the output voltage of the power battery under different operating conditions is studied to ensure that the power battery can output energy with high efficiency. The operating conditions have an impact on the output voltage with an idle voltage fluctuation of the operating conditions. The nominal voltage variation and the number of series and parallel connections of the battery cells affect the frequency and time of breakdown.

A joint optimization strategy for electric vehicles and air conditioning systems with building battery configuration

Building air conditioning systems, electric vehicles and battery energy storage systems all provide substantial flexibility for grid operations. However, the joint optimization strategy involving these three demand response resources in buildings has been infrequently studied. This research proposes a day-ahead optimization strategy to coordinate the joint operation of air conditioning systems and electric vehicles. In this framework, cooling load is predicted using an autoregressive exogenous model, while electric vehicle charging load is predicted through Monte Carlo simulations. An evaluation method is introduced to assess the comprehensive benefits of the demand response strategy, considering thermal comfort, economic efficiency, and grid friendliness. Using an office building in Tianjin, China, as a case study, the results indicate that the joint optimization strategy reduces operational costs by 3.71 % and peak electricity load by 38.62 % compared to the original strategy. Furthermore, it enhances the grid friendliness of the energy system by 42.64 %. The configuration of the battery energy storage system is also explored in conjunction with the optimization strategy to further improve grid friendliness. The impact of economic factors and thermal comfort on the configuration of the battery energy storage system is discussed. In the case study, raising the upper temperature limit by 1 °C can save at least 17.1 % in capacity, while battery energy storage system investment and operational costs can respectively be reduced by 55.04 % and 27.14 % within the thermal comfort range.

Stable Long‐Term Cycling of Room‐Temperature Sodium‐Sulfur Batteries Based on Non‐Complex Sulfurised Polyacrylonitrile Cathodes

The cost‐effectiveness and high theoretical energy density make room‐temperature sodium‐sulfur batteries (RT Na–S batteries) an attractive technology for large‐scale applications. However, these batteries suffer from slow kinetics and polysulfide dissolution, resulting in poor electrochemical performance. Thus, the sulfurised polyacrylonitrile (SPAN) cathode is postulated as a suitable material due to the retention of sulfur through covalent bonds and the increase in the conductivity of sulfur. Furthermore, in this work the synthesis of SPAN has been carried out using simple synthesis methods, making it scalable, economical, and without the use of toxic compounds. The incorporation of the SPAN material helps mitigate the shuttle effect, reducing the capacity loss and improving both the efficiency and lifespan of Na–S batteries. The SPAN‐based cathode demonstrates that this RT Na–S battery configuration shows high stability, reaching 1000 cycles with a capacity loss per cycle of 0.11% and a satisfactory specific capacity of 400 mAh/gs at a high rate of 2C. This study demonstrates that the utilisation of SPAN derived from a non‐complex synthesis can be a viable alternative for enhancing the future of Na–S batteries technology.

A Breakthrough in the Application of Simonkolleite in All‐Solid‐State Zn‐Graphite Battery

ABSTRACTTo enhance the electrochemical performance of the Zn solid‐state battery, we introduce simonkolleite as a novel anode material. With oxygen vacancies on its surface, simonkolleite exhibits both electrical and chemical activity; these vacancies serve as n‐type donors, significantly improving the material's conductivity. In this research, simonkolleite is synthesized using a straightforward and cost‐effective method and employed as the anode. The all‐solid‐state Zn battery combines the simonkolleite anode, sodium silicate (SS) electrolyte, and graphite film (GF) cathode. Our battery configuration (simonkolleite/Ingot SS/GF) achieves a high 1280 mAh g−1 capacity and demonstrates improved cyclic stability. The large‐scale module battery can also power a motor‐fan unit for 1 h and 19 min.

Experimental Investigations into a Hybrid Energy Storage System Using Directly Connected Lead-Acid and Li-Ion Batteries

This paper presents experimental investigations into a hybrid energy storage system comprising directly parallel connected lead-acid and lithium batteries. This is achieved by the charge and discharge cycling of five hybrid battery configurations at rates of 0.2–1C, with a 10–50% depth of discharge (DoD) at 24 V and one at 48 V. The resulting data include the overall round-trip efficiency, transient currents, energy transfers between the strings, and the amount of energy discharged by each string across all systems. The general observation is that the round-trip efficiency drops from a maximum of around 94–95% in the first stages of the charge/discharge process, when only the Li-ion strings are active, to around 82–90% when the lead-acid strings reach a DoD of up to 50%. The most important parameters in the round-trip efficiency function are the ratio between the Li-ion and lead-acid energy available and the charge/discharge current. The energy transfer between the strings, caused by the transient currents, is negligible in the first stages of the discharge and then grows, with the DoD peaking at around 60% DoD. Finally, during the first stage of discharge, when only the Li-ion strings are active, the amount of energy discharged varies with the discharge C rate, decreasing to almost half at between 0.2 and 1C.

A Novel Self‐Reconfigurable Battery Pack Design with and without Active Cell Balancing

In electric vehicle industry, rechargeable multicell battery packs commonly with fixed configurations are adopted. Such fixed battery configurations have several drawbacks, including limited fault tolerance during unusual operating situations, poor cell state variation management, etc. Thus, this article proposes a self‐reconfigurable battery pack design considering two scenarios: with and without active cell balancing. Herein, the issue of cell state variation is mostly solved by the proposed configuration mode, and further monitoring, control, and protection can be easily appended to accomplish other functionalities, for example, meeting dynamic voltage requirement. Each proposed design is validated by simulation results for a six‐cell polymer lithium‐ion battery pack. The proposed design can maximally utilize the battery's capacity and help to protect cells from over‐charging and over‐discharging as well. This research could be further extended to other application scenarios involving wide‐range dynamic voltage requirements.

Revisiting the Electrochemical Impedance Spectroscopy of Porous Electrodes in Li‐ion Batteries by Employing Reference Electrode

AbstractElectrochemical impedance spectroscopy (EIS), characterized by its non‐destructive and in situ nature, plays a crucial role in comprehending the thermodynamic and kinetic processes occurring within Li‐ion batteries. However, there is a lack of consistent and coherent physical interpretations for the EIS of porous electrodes. Therefore, it is imperative to conduct thorough investigations into the underlying physical mechanisms of EIS. Herein, by employing reference electrode in batteries, we revisit the associated physical interpretation of EIS at different frequencies. Combining different battery configurations, temperature‐dependent experiments, and elaborated distribution of relaxation time analysis, we find that the ion transport in porous electrode channels and pseudo‐capacitance behavior dominate the high‐frequency and mid‐frequency impedance arcs, respectively. This work offers a perspective for the physical interpretation of EIS and also sheds light on the understanding of EIS characteristics in other advanced energy storage systems.

Comparison of Parabolic Troughs and Solar Photovoltaic as Solar Field Technology in Dispatchable Solar Power Plants

The use of thermal energy storage (TES) technologies, as means to provide dispatchability to thermally driven solar power production, has long stood as the main argument for the interest and potential competitiveness of Concentrated Solar Power (CSP) when compared to other non-dispatchable alternatives. Whereas reductions of the Levelized Cost of Electricity (LCOE) are observed for CSP in recent years, the notable LCOE reduction observed along this decade in large-scale solar photovoltaics (PV) plants is set to break the taboo of "power-to-heat-to-power" approaches, as its potential economic performance outcasts the associated thermodynamic inefficiency. The possibility of using available resistive heating technologies and components in PV-TES combinations, renders the configuration of a conventional CSP plant suitable for the replacement of a thermal conversion solar field by a photovoltaic field presenting further the possibility of delocalization and/or spatial distribution of the solar field (e.g. on a Carnot Battery configuration). As dispatchability no longer stands as an exclusive argument in favor of CSP over PV, the present article addresses the boundary conditions for the competitiveness of each technology as the champion of dispatchable solar power fields. The impact of both land and electrical heater costs variation in the variation of LCOE for PV-TES plants is much more modest than that observed for the impact of CSP solar field cost variations in the variation of LCOE for CSP plants, which leans for the latter and at present costs, towards better competitiveness for plant designs with a storage capacity in excess of 10.0 FLH (for GHI values in excess of 2100-2200 kWh∙m-2∙year-1).

Electrochemical Activation Inducing Rocksalt-to-Spinel Transformation for Prolonged Service Life of LiMn2O4 Cathodes.

LiMn2O4 spinel is emerging as a promising cathode material for lithium-ion batteries, largely due to its open framework that facilitates Li+ diffusion and excellent rate performance. However, the charge-discharge cycling of the LiMn2O4 cathode leads to severe structural degradation and rapid capacity decay. Here, an electrochemical activation strategy is introduced, employing a facile galvano-potentiostatic charging operation, to restore the lost capacity of LiMn2O4 cathode without damaging the battery configuration. With an electrochemical activation strategy, the cycle life of the LiMn2O4 cathode is extended from an initial 1500 to an impressive 14 000 cycles at a 5C rate with Li metal as the anode, while increasing the total discharge energy by ten times. Remarkably, the electrochemical activation enhances the diffusion kinetics of Li+, with the diffusion coefficient experiencing a 37.2% increase. Further investigation reveals that this improvement in capacity and diffusion kinetics results from a transformation of the redox-inert LiMnO2 rocksalt layer on the surface of degraded cathodes back into active spinel. This transformation is confirmed through electron microscopy and corroborated by density functional theory simulations. Moreover, the viability of this electrochemical activation strategy has been demonstrated in pouch cell configurations with Li metal as the anode, underscoring its potential for broader application.

Low-pressure dendrite-free sulfide solid-state battery with 3D LiSi@Li-Phen-Ether anode

Lithium-metal batteries with solid electrolytes (SEs) have emerged as promising electrochemical energy storage devices due to high energy density and safety. However, inherent challenges of deleterious lithium dendrite growth and poor interfacial stability hinder their practical application. Herein, a new type of room-temperature liquidous Li metal arene complex—Li-Phenanthrene (Phen)-Ether is explored to enable a 3D LiSi@Li-Phen-Ether (3D LSLL) anode with low cost, high safety and high ion/electron-conductivity. Symmetric cells with sulfide SE and 3D LSLL anode deliver an ultra-high critical current density (> 13 mA cm−2) and long cycle life (> 1000 h, 0.25 mA cm−2). Moreover, full battery (LFP/sulfide SE/3D LSLL) can operate at low-external pressure (0.5 MPa) and ambient temperature by introducing a flexible cathode/sulfide interlayer with high ion conductivity (2 mS cm−1). This unprecedented battery configuration demonstrates high-rate (2C) performance and long cycle life (over 300 cycles), which exceeds preciously-reported sulfide SE/lithium batteries at low stack pressures, and may open up a promising route for high-energy-density, cost-effective and safe rechargeable lithium batteries.

Optimal battery configuration for electrical vehicles in hot climates: A numerical comparative study of materials and cooling approaches

The battery plays a pivotal role in the electric vehicle (EV) sector, and the advancement of this industry hinges on enhancing the thermal performance and efficiency of batteries, especially in regions characterized by high-temperature extremes. The primary objective of this study is to propose a battery configuration capable of operating efficiently in hot regions. To achieve this goal, we have selected six battery materials, each possessing distinct physical characteristics, for an in depth investigation into their thermal behavior within a mini-channel Thermal Management System. Subsequently, we conducted a comparative analysis of various volumetric flow rates and flow directions to determine the optimal combination. Once the best configuration was identified, we conducted a case study using realistic ground-based meteorological data to evaluate the performance of the selected battery configuration under real conditions. The results of this study reveal that material which is characterized by the specific heat of 830J.kg-1.K-1, and a thermal conductivity of Kx = Ky = 34W.m-1.K-1 and Kz = 3.4W.m-1.K-1, exhibits the highest thermal performance. Taking into account the power required for the system, the most efficient volumetric flow rate is 0.05 L/min which requires a power of 3e-7W, with the same direction of fluid inlet and outlet in the minichannels. The selected material, volumetric flow rate, and flow direction in this study ensure that the maximum temperature of (Tmax) of the cell is maintained at 29.21 °C, with a temperature difference (Tdiff) of 1.56 °C. Regarding the case study, applying this optimal configuration under the climatic conditions of Benguerir, Morocco, results in a Tmax of 29.36 °C and a Tdiff of 1.58 °C, confirming the feasibility of the proposed battery configuration and its BTMS in high-temperature conditions.

Materials Design and Mechanistic Understanding of Tellurium and Tellurium-Sulfur Cathodes for Rechargeable Batteries.

ConspectusThe market demand for lithium-ion batteries (LIBs) has been proliferating in wide applications, from portable electronics and electric vehicles to renewable energy storage, due to their advantages of high energy density and reliable life cycles. Currently, further development of LIBs is hindered by the limited specific/volumetric capacity and high cost of conventional intercalation-type cathode materials. In this context, sulfur (S) has gained intensive attention as a conversion-type cathode because of its abundance, low cost, and high theoretical capacity (1675 mAh g-1). However, the insulating nature of S causes severe issues of sluggish redox kinetics, low S utilization, and unsatisfactory practical capacity. So far, extensive efforts have been devoted to boosting Li-S redox kinetics and enhancing cycling stability by inhibiting the shuttle effect, including developing functional electrolyte additives, introducing redox catalysts, and tailoring the S cathode structure. Partially substituting S atoms in S8 rings with high-electrical-conductivity elements (e.g., selenium, 1 × 10-3 S m-1) at the molecular level proves to be an effective strategy for tackling the above-mentioned challenges in Li-S batteries. It is noteworthy that tellurium (Te), with remarkable electrical conductivity (2 × 102 S m-1) and high density (6.24 g cm-3), is a promising battery electrode material that can realize fast electron transport and deliver volumetric capacity comparable to that of S or Se. Additionally, Te-S molecular regulation is one facile strategy to reshape Li-S chemistry, accelerate redox kinetics, and manipulate the lithiation/delithiation behaviors. Te is an effective eutectic accelerator that prevents polysulfide dissolution in Li-S batteries under the dissolution-deposition mechanism. Meanwhile, the Li-Te electrochemistry can contribute to reversible capacity in Li-TexSy batteries through Te-Li2Te conversion and enhance the materials utilization of TexSy.This Account highlights state-of-the-art advancements in applying Te or TexSy as high-capacity cathodes for rechargeable batteries. First, battery configuration and reaction pathways in Li-Te batteries are discussed, followed by the introduction of cathode design strategies to improve cathode structure stability. The limitations of this Te-only cathode are outlined in terms of the abundance, cost, and energy density. Second, the role of Te in Li-S chemistry is clarified by the analysis of the crystal structure, electrochemical behaviors, solid electrolyte interphase composition, and energy profiles. Third, recent progresses on quasi-solid-state Li-Te batteries have been introduced, focusing on flexible gel polymer electrolytes with adjustable ionic conductivity. Afterward, advancements in interface engineering by the atomic layer deposition technique in metal-Te batteries are highlighted. Additionally, mechanistic analysis in emerging zinc-TexSy batteries with outstanding areal capacity is demonstrated. Finally, we provide insightful perspectives on the future directions of material design in Te-based energy storage technologies. This Account is expected to deepen the fundamental understanding of metal-Te/TexSy chemistry and offer inspiration for the further development of Te-based high-energy-density rechargeable batteries.

Three-dimensional MoS2 nanosheets embeded within NiTe nanorods forming semicoherent heterojunctions achieving high-performance potassium-ion batteries

Three-dimensional MoS2 nanosheets uniformly embedded within NiTe nanorods are synthesized via one-step hydrothermal method and subsequently coated with a carbon layer to form stable NiTe@MoS2@C heterojunctions. The heterojunctions exhibit moderate lattice mismatch (δ =20.0 %), strong electric fields, and uniform carbon shells, resulting in unique electronic configurations and abundant active sites. As an anode for potassium-ion batteries, NiTe@MoS2@C demonstrated an high reversible capacity of 258.4 mAh g−1 after 100 cycles at a rate of 200 mA g−1. Moreover, it showed a stable reversible capacity of 177.5 mAh g−1 at a high rate of 5000 mA g−1, indicating excellent rate performance. Notably, even in the NiTe@MoS2@C//perylene tetracarboxylic dianhydride full battery configuration, a significant reversible capacity of 87.4 mAh g−1 was maintained after 100 cycles at a rate of 200 mA g−1, manifesting its remarkable potential for practical applications in potassium-ion batteries. Theoretical calculations further revealed that the well-designed NiTe@MoS2 heterojunction significantly enhances K+ ion diffusion.

Garnet and Li29Zr9Nb3O40 Modified PEO‐Based Hybrid Solid Electrolytes for All‐Solid‐State Lithium Metal Batteries

AbstractInorganic‐organic hybrid solid electrolytes (HSEs) are an important category of electrolyte materials for solid‐state batterie. It is of interest and importance to investigate the influence of composition and content of inorganic fillers on the electrochemical performance of HSEs. In this paper, we fabricated HSEs using polyethylene oxide (PEO) as matrix and incorporating different inorganic powders as active fillers. A series of HSEs with different contents of Ga/Nb co‐substituted garnet oxide (Li6.35Ga0.15La3Zr1.8Nb0.2O12, GN‐LLZO) and Y‐doped Li29Zr9Nb3O40 (Li29.3Zr8.7Y0.3Nb3O40, 0.3Y‐LZNO) were carefully designed. The ionic conductivity of these PEO‐based HSEs were studied, and their performance in solid‐state lithium‐ion batteries with LiFePO4 (LFP) as cathode material and Li metal as anode were evaluated. The results showed that the HSE with addition content of inorganic powders, namely PEOLiTFSI@5 % GN‐LLZO +5 %0.3Y‐LZNO (noted as PL3) showed the optimized ionic conductivity of 2.9×10−4 S cm−1 at room temperature with an activation energy Ea of 0.21 eV. It has an electrochemical stability window of 4.65 V and ionic transfer number of 0.242. The addition of inorganic powders not only enhanced the ionic conductivities of PEO‐based HSEs, but also exhibited superior stability and interfacial compatibility with electrodes, leading to the improved cycle stability in the LFP/PL3/Li solid‐state battery configuration.

(Digital Presentation) Innovative Cylindrical Cell Design for Sustainable Static Zinc-Bromine Battery Technology

Zinc-bromine flow batteries (ZBFBs) are suitable for large-scale stationary energy storage applications due to their scalability, flexibility, safety, and sustainability [1, 2]. However, the ZBFBs' efficiency is compromised by the heavy accessories and pumps involved in flowing electrolytes on the electrode surface [3]. Because of their heavy weight and other accessories, ZBFBs can only be used for large energy storage systems. Further research is required to expand the application fields of the small-scale static zinc-bromine battery, including portable applications. Therefore, we proposed an innovative cylindrical cell design for a static zinc-bromine battery with a non-flowing liquid electrolyte that offers substantial improvements over existing zinc-bromine flow battery technology. This design aims to enhance coulombic efficiency and energy density, particularly targeting portable applications such as electric vehicles and E-bikes. Our battery configuration involves electrodes (carbon felt and carbon sponge) separated by a microporous separator for ionic migration. The liquid electrolyte, comprising zinc bromide, zinc chloride, potassium chloride, and 1-ethyl-1-methyl pyrrolidinium bromide, facilitates the electrochemical reaction. The battery's electrochemical process involves the plating of zinc ions at the anode and the formation of a bromine complex at the cathode during charging, with reverse reactions during discharge. The entire proposed static battery configuration is made of recyclable Polytetrafluoroethylene (PTFE) polymer, ensuring environmental sustainability. The anode comprises highly conductive graphene-coated carbon felt, while the cathode employs a graphene-coated high-surface-area carbon fiber sponge. Here, we aim to provide more details on the manufacturing methods for the assembly, emphasizing slurry preparation, electrode modification, and electrolyte concentration to achieve enhanced battery performance. With 96 % coulombic efficiency and stable cyclability, the present technology outperforms the existing commercial zinc-bromine battery. Comparative analyses with conventional zinc-bromine flow batteries highlight the advantages of this static battery, including its compactness, reduced weight, and potential for higher energy density. This research represents a significant step towards developing static zinc-bromine batteries suitable for widespread use in portable applications, surpassing the limitations of current zinc-bromine battery technologies.

Exploring Sodium Gadolinium Silicate as a Solid Electrolyte for Next-Generation Sodium Batteries

Sodium-ion batteries (SIBs) represent a promising alternative to commercially prevalent Lithium-ion batteries (LIBs), primarily attributed to the economic feasibility and widespread availability of sodium resources. Solid-State Sodium Batteries (SSSBs) have garnered significant attention owing to their capacity to mitigate safety risks associated with organic liquid electrolytes by utilizing solid electrolytes. Additionally, they offer higher energy density and wide operational temperature for next-generation, cost-effective battery technology.[ 1 ] Sodium rare-earth silicates are emerging as a solid electrolyte with enhanced ionic conductivity of 10-3 S cm-1 at room temperature (RT), alongside notable mechanical stability and a wide electrochemical window, attributed to their three-dimensional framework structure.[ 2 ] In this study, sodium gadolinium silicates were synthesized through a conventional solid-state method followed by high-temperature sintering. The highest ionic conductivity of 7.25 x 10-4 S cm-1 at room temperature was achieved through sintering at 1075 °C. Galvanostatic cycling experiments were conducted to assess the compatibility of Na metal with the silicate solid electrolyte, achieving a critical current density (CCD) of 0.4 mA cm-2 and long-term stability for 6000 h at 0.1 mA cm-2. Charge-discharge studies employed a battery configuration comprising Na metal anode, silicate solid electrolyte, and Na3V2(PO4)3 cathode, demonstrating excellent capacity retention of 98% after 100 charge-discharge cycles at 0.1 C.[ 3 ] These findings highlight the potential of sodium gadolinium silicate as a promising solid electrolyte for next-generation sodium batteries, characterized by its high ion conductivity and stable interface compatibility.