ABSTRACT In two-stage electric vehicle (EV) battery chargers, ac-dc conversion stage contributes significantly in determining the power quality. At this stage, multilevel rectifiers (MLRs) featuring switches with lower voltage rating and better input voltage waveform quality can be adopted. However, balancing capacitor voltage in MLR is an important challenge. In this paper, a single-phase five-level power factor correction (PFC) rectifier with self-balancing capacitor is implemented for EV battery charging. The complimentary switching scheme adopted for rectifier reduces number of gate driver circuits and ensures capacitor voltage balancing. The rectifier shows added benefit of reduced voltage stress across switches and not requiring an external filter at the dc side as the load is parallelly connected with one of the capacitors. The operating principle, control strategy, modulation technique and design features of the implemented five-level rectifier is discussed in detail. The implemented control scheme enhances rectifier performance by establishing precise output voltage regulation during load fluctuations while maintaining unity power factor at input side. The five-level rectifier is validated experimentally and compared with other existing multilevel and non-multilevel rectifier topologies. The peak efficiency of 93.8% is achieved at 2 kW of output power.