Abstract The degradation processes that occurred on metal threads applied in the embroidery used for clothing and in the ornamentation of sculptures, the Sevillian Holy Week processions, and Portuguese and Spanish palace and museum are thoroughly analyzed. Some threads from the 14th and 18–19th centuries were considered. In the metal threads, sulphur- and chlorine-based compounds were detected either individually or together, depending on the degradation process. Basic silver carbonate, sodium bicarbonate and copper-based compounds were also observed. The different degradation processes were attributed to different factors, such as environmental contamination, degradation of the fibrous cores, and inadequate cleaning and/or mechanical treatments.