In this paper, the coupled linear theory of thermoelasticity for nanomaterials with triple porosity is considered in which the combination of Darcy’s law and the volume fraction concept for three levels of pores (macro-, meso- and micropores) is provided. The 3D basic boundary value problems (BVPs) of steady vibrations of this theory are formulated and these BVPs are investigated using the potential method (boundary integral equation method) and the theory of singular integral equations. Namely, the formula of integral representation of regular vectors is obtained. The surface (single-layer and double-layer) and volume potentials are introduced and their basic properties are given. Some useful singular integral operators are defined for which Noether’s theorems are valid. The symbolic determinants and indexes of these operators are calculated. The BVPs of steady vibrations are reduced to the equivalent singular integral equations. Finally, with the help of the potential method, we prove the existence theorems for classical solutions of the aforementioned BVPs.