This paper focuses on the deterioration mechanism of hybrid basalt-polypropylene fiber-reinforced concrete (HBPRC) under the coupling of sulfate freeze-thaw cycles. The changes in the macroscopic properties of HBPRC under the influence of different volume contents of basalt fiber (BF), polypropylene fiber (PF) and hybrid BF-BF were investigated. The microstructure of HBPRC was characterized using the nuclear magnetic resonance (NMR) technique, X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the deterioration models of the BF- matrix interfacial transition zone (BF-ITZ) and the PF- matrix interfacial transition zone (PF-ITZ) in HBPRC were developed. The results showed that the fibers effectively reduced the cracking and macroscopic property damage induced by sulfate freeze-thaw cycles as the number of freeze-thaw cycles increased. When both BF and PF volume contents are mixed at 0.05 %, they can produce complementary effects, and their formation of a uniformly distributed three-dimensional mesh structure is more conducive to reducing the damage to the concrete, and their relative dynamic modulus of elasticity and compressive strength after 300 times of sulfate freeze-thaw cycles were increased by 67.10 % and 46.92 % compared with control concrete. At the same time, the addition of fibers resulted in a more stable evolution of the pore structure of the concrete, and the porosity of the specimens with fibers added at a volume admixture of 0.05 % and 0.1 % was reduced by 13.69–21.35 % after 300 cycles of sulfate freeze-thaw cycling, compared with control concrete. From the BF-ITZ and PF-ITZ deterioration models, it was concluded that the differences in the bonding performance of BF and PF to the concrete matrix affected the degree of frost damage to which they were subjected to coupling and the efficiency of salt solution replenishment, which in turn led to differences in the damage of each group of HBPRC. The reliability of the model was further verified by SEM observation of the morphological changes of different fiber-matrix ITZs before and after sulfate freeze-thaw cycles.
Read full abstract