The L 3VV spectra of Me and the L 3M 2,3V spectra of Ti in equiatomic TiMe (where Me stands for Fe, Co, Ni, Pd) compounds and the L 3VV spectra of Ni in MeNi (where Me stands for Al, Zr, and Ti) have been recorded. As expected, the Co and Fe L 3VV spectra reveal a simple bandlike structure. The observed change in the L 3VV spectra parameters of Ni and Pd upon alloying indicates strengthening of the quasiatomic character of the spectra. The Ti LMV spectra are of particular interest. One established that the structure of the Ti Auger spectra after deconvolution exactly represents the local d DOS at Ti sites in the studied B2 (CsCl) TiMe compounds.