The determination of the accurate composition ratio of scattering mechanisms (volume scattering, double-bounce scattering, and surface scattering) within a radar backscatter is essential to validate current polarimetric decomposition techniques. Multiincidence angle and multipolarimetric synthetic aperture radar (MIMP SAR) observations at the X- and L-bands were applied to rice paddies at late vegetative stage in Niigata City in Japan in 2014 and 2016, respectively. In this paper, multifrequency MIMP SAR analysis is introduced based on the observation results. The approach, combined with theoretical characterization of the data by a discrete scatterer model, showed that rice panicles affect the backscatter from rice paddies. Contrary to expectation, an effect of transmissivity by using different bands is not obvious. The similar level of copolarization (HH and VV) backscatter at X- and L-bands could be explained by the effective size of rice panicles. They are the most characteristic scatters in rice paddy field with respect to multiple frequency polarimetric sensing. In addition, HV shows a distinct sensitivity to the mean orientation angle and the size of panicles regardless of the wavelength. The mean orientation angle affects the polarimetric randomness under azimuthal symmetry, whereas the size of panicles directly affects the attenuation of the volume scattering from the grains. The multifrequency MIMP SAR analysis also indicated the importance of considering the backscatter and attenuation in the interpretation of the backscattering cross section from vegetated fields.