Background Gas Research Articles

Influence of magnetic field gradient on the capacitive argon discharge at 8 MHz and 40 MHz

A one-dimensional implicit particle-in-cell/Monte Carlo collision model is used to study the effects of magnetic field gradients on the capacitively coupled argon plasma at 8 MHz and 40 MHz. The magnetic field strength at the powered electrode is fixed at 10 G, while varies from 30 to 100 G at the grounded electrode. The simulations show that the magnetic field with variable gradient can produce controllable asymmetry in the plasma density and ion flux profiles to each electrode. Increasing the magnetic field gradient will generate a significant dc self-bias, which results in a large ion bombardment energy at the powered electrode. The magnetic field gradients have been demonstrated to be an approach to create the dc self-bias and also effectively improve the plasma density. It is also found that at a higher frequency of 40 MHz, the dc self-bias voltage decreases, due to the fact that high collision rate of electrons with background gas will disturb the cyclotron motion of electrons, so the effect of the magnetic field is weakened. As a result, the ability to independently control ion energy and flux is weakened.

Monte Carlo simulation of ion kinetics in nitrogen and oxygen plasmas under non-uniform electric field conditions

The kinetics of N4+ and O− ions was numerically studied in nitrogen and oxygen plasmas in a highly non-uniform electric field. Mean ion energy and reaction rate coefficients in a background gas at pressures from 1 to 10 Torr were calculated through a Monte Carlo simulation. The ion characteristics followed the local reduced electric field at high pressures, whereas nonhydrodynamic effects leading to a nonlocal dependence of the mean ion energy and rate coefficients on the field were obtained at low pressures. As a result, the rates of N4+ ion dissociation, electron detachment from O− ions, and charge exchange in collisions between O− and O2 lagged the local field value. The non-local effect on the ion rate coefficients was more profound when the field decreased in space. We suggested a simplified method of describing ion rates in spatially varying electric fields on the basis of the Monte Carlo simulation of these rates for uniform electric field conditions and mean ion energy calculations in non-uniform fields. This method is similar to the local-mean-energy approximation utilized for describing electron swarm parameters in varying electric fields. The results of the simplified method were compared with the results of the direct Monte Carlo simulation.

Partial discharge and decomposition characteristics of environmental insulating gas C5F10O under different background gases

SF6 is widely developed and applied in gas insulated electrical equipment due to its excellent arc extinguishing performance and insulation performance. However, SF6 is very destructive to the ozone layer and has a strong cumulative effect on the greenhouse effect of global warming. Therefore, the inevitable trend of the development of power grid equipment in the future is to reduce or even prohibit the use of SF6 gas in the power system, power industry and electrical equipment, or to find insulation media that can replace SF6. As a result, the research on environment-friendly insulating gas has become popular. In this paper, power frequency partial discharge platform and GC–MS​ detection platform are used to systematically study the partial discharge and decomposition characteristics of C5F10O under N2 and CO2 background gases. The partial discharge extinction voltage (PDIV) and partial discharge statistical characteristics of C5F10O under two different background gases, as well as the variety and concentration change of mixed gas decomposition products are theoretically analyzed and compared with SF6. It is found that, similar to SF6, the PDIV of C5F10O under two kinds of background gases increases linearly with the increase of air pressure. The PDIV under N2 background is smaller than that under CO2 background under the same conditions, and its insulation performance is slightly better than that under CO2 background. The partial discharge decomposition of C5F10O mixed gas mainly produces fluorocarbons such as CF4, C2F4, C2F6, C3F8, C3F6, and a small amount of CO, COF2, C3HF7, and CHF3. The increase of air pressure inhibits the partial discharge decomposition of mixed gas.

Breakdown of dipole Born approximation and the role of Rydberg’s predissociation for the electron-induced ion-pair dissociation to oxygen in the presence of background gases

We study the electron-induced ion-pair dissociation to gas-phase oxygen molecules using a state-of-the-art velocity-map ion-imaging technique. The analysis is entirely based on the conical time-gated wedge-shaped velocity slice images of O-/O2 nascent anionic fragments, and the resulting observations are in favor of Van Brunt et al.'s report [R. J. Van Brunt and L. J. Kieffer, J. Chem. Phys. 60, 3057 (1974)]. A new image reconstruction method, Jacobian over parallel slicing, is introduced to overcome the drawback of ion exaggeration in determining the kinetic energy distribution from the time-gated parallel slicing technique, which offers an alternative approach to the wedge slicing method. Most importantly, the role of the quintet-heavy Rydberg state has been drawn out to the complex ion-pair formalism. The extracted kinetic energy and angular distributions from the wedge slice images reveal a high momentum transfer during the ion-pair dissociation process, which could be the finest rationale to observe the breakdown of dipole Born approximation driven by multipole moment associated with the incident electron beam. Three distinct dissociative momentum bands have been precisely identified for O- dissociation. However, radiationless Rydberg's predissociation continuum (≥15%) has become an inherent character of electron-induced ion-pair dissociation, which could be dealt with using the beyond Born-Oppenheimer treatment. The incoherent sum of Σ and Π symmetric-associated ion-pair final states has been precisely identified by modeling the angular distribution of O-/O2 for each of the kinetic energy bands. A negligibly small amount of forward-backward asymmetry is observed in the angular distribution of O-/O2, which might be explained by the dissociative state-specific quantum coherence mechanism as reported [Krishnakumar et al., Nat. Phys. 14, 149 (2018); Kumar et al., arXiv:2206.15024 (2022)] by Prabhudesai et al.

Optical measurements of two cylindrical and conical heavy-duty diesel injector nozzels – A comparison of reference diesel, HVO, and RME fuels

In the present work, a constant volume/constant pressure combustion chamber was utilized to measure the major parameters of vapour/liquid phases and combustion of fuel spray introduced by two heavy-duty, large-diameter diesel injectors. A conical nozzle (K factor 4) with a 300 µm outlet diameter and a 1300 µm length and a cylindrical nozzle (K factor 0) with a 300 µm outlet diameter and a 650 µm length display notably distinct impacts on the formation of the mixture, the air entrainment process, and the combustion behaviour. Several parameters, including jet and liquid spray penetration lengths, jet cone angle, and jet projected area are combined to describe spray characteristics in an inert background gas, and ignition incidence, flame lift-off length, and soot appearance time parameters are calculated to explain the combustion trend of the nozzles in a reactive gas background. These observations were conducted using four distinct optical techniques, two of Schlieren and Mie-Scattering for inert condition, and two of OH* Chemiluminescence and Natural Flame Luminosity for reactive condition. This study collects a wide variety of boundary conditions, comprising ambient pressure/temperature and fuel rail pressure, with diverse fuels, including reference diesel, HVO, and RME fuels.The findings are categorized by the jet and liquid spray behaviours in the first part, demonstrating that the jet cone angle is an injector geometry-based parameter and that the cylindrical nozzle has a larger cone angle and a shorter liquid spray length. Three distinct scenarios of the computed air-to-fuel mass ratio at the same axial positions, time steps, and injected fuel mass indicate a marginally higher air entrainment in the cylindrical nozzle and, presumably, a faster and better mixture formation. The thorough examination of the combustion characteristics indicates that a quicker formation of the initial stoichiometric region in the cylindrical nozzle results in a shorter ignition delay at most experimental locations, which ultimately results in a faster soot initiation. However, depending on the flame lift-off length and the boundary conditions, the interval between ignition and the development of soot varies considerably. Finally, it is demonstrated that, with the exception of fuel pressure variation, the flame lift-off length, which is crucial in providing the initial mixture formation prior to combustion occurrence, follows the ignition delay trend and exhibits a shorter length with a shorter ignition delay.

Optimization of Pulsed Laser Ablation and Radio-Frequency Sputtering Tandem System for Synthesis of 2D/3D Al2O3-ZnO Nanostructures: A Hybrid Approach to Synthesis of Nanostructures for Gas Sensing Applications.

In this paper, a unique hybrid approach to design and synthesize 2D/3D Al2O3-ZnO nanostructures by simultaneous deposition is presented. Pulsed laser deposition (PLD) and RF magnetron sputtering (RFMS) methods are redeveloped into a single tandem system to create a mixed-species plasma to grow ZnO nanostructures for gas sensing applications. In this set-up, the parameters of PLD have been optimized and explored with RFMS parameters to design 2D/3D Al2O3-ZnO nanostructures, including nanoneedles/nanospikes, nanowalls, and nanorods, among others. The RF power of magnetron system with Al2O3 target is explored from 10 to 50 W, while the ZnO-loaded PLD's laser fluence and background gases are optimized to simultaneously grow ZnO and Al2O3-ZnO nanostructures. The nanostructures are either grown via 2-step template approach, or by direct growth on Si (111) and MgO<0001> substrates. In this approach, a thin ZnO template/film was initially grown on the substrate by PLD at ~300 °C under ~10 milliTorr (1.3 Pa) O2 background pressure, followed by growth of either ZnO or Al2O3-ZnO, using PLD and RFMS simultaneously under 0.1-0.5 Torr (13-67 Pa), and Ar or Ar/O2 background in the substrate temperate range of 550-700 °C. Growth mechanisms are then proposed to explain the formation of Al2O3-ZnO nanostructures. The optimized parameters from PLD-RFMS are then used to grow nanostructures on Au-patterned Al2O3-based gas sensor to test its response to CO gas from 200 to 400 °C, and a good response is observed at ~350 °C. The grown ZnO and Al2O3-ZnO nanostructures are quite exceptional and remarkable and have potential applications in optoelectronics, such in bio/gas sensors.

The use of remote Femto Second technology in the preparation of black silicon material and optical devices.

The research aims to study the application of remote Femto Second (FS) technology in black silicon material preparation and optical devices. Based on the principle and characteristic research of FS technology, the interaction between FS and silicon is adopted to propose a scheme for preparing black silicon material through experiments. Moreover, the experimental parameters are optimized. Then, the scheme of using the FS for etching polymer optical power splitter as a new technical means is proposed. In addition, while ensuring processing accuracy, the appropriate process parameters of laser etching photoresist are obtained. The results show that the performance of black silicon prepared with SF6 as the background gas is greatly improved in the 400-2200nm range. However, the performance of black silicon samples with the two-layer structure etched at different laser energy densities has little difference. Black silicon with a Se+Si two-layer film structure has the best optical absorption performance in the infrared range of 1100nm-2200nm. Besides, the optical absorption rate is the highest when the laser scanning rate is 0.5mm/s. In the band of >1100nm, when the maximum laser energy density is 6.5kJ/m2, the overall absorption of the etched sample is the worst. The absorption rate is the best when the laser energy density is 3.9kJ/m2. It suggests that the proper parameter selection greatly impacts the quality of the final laser-etched sample.

Investigation of hybrid plasma-catalytic degradation of toluene over FeOOH/γ-Al2O3 catalysts

In the present study, FeOOH/γ-Al2O3 catalyst was first introduced into dielectric barrier discharge (DBD) plasma-catalysis system for toluene degradation, and its catalytic performance and mechanism were studied. It was found that the toluene degradation efficiency, energy yield (EY), and COx selectivity were significantly improved in the plasma-FeOOH/γ-Al2O3 system by comparison to the plasma-only process. The ozone concentration detected in this study decreased significantly in plasma-FeOOH/γ-Al2O3 system, which could be concluded that the ozone catalytic process played an important role in the plasma-FeOOH/γ-Al2O3 system for toluene degradation. The toluene and intermediates adsorbed on the surface FeOOH catalysts could react with O* from O3 decomposition and Oads derived from oxygen vacancies, which was conducive to an improved degradation and mineralization performance. Besides, the transformation of O3 to·OH on FeOOH surface was considered as one of the main mechanisms for enhancing toluene degradation when the relative humidity of the background gas was increased from 30% to 50%. The key process parameters, including specific energy input (SEI), catalyst loading, and oxygen content of the background gas, were optimized by response surface methodology (RSM) integrated Box-Behnken design (BBD). The results showed that oxygen content of the background gas was the most significant factor affecting the degradation efficiency of toluene, while energy yield was mainly determined by SEI. The possible toluene degradation pathways in plasma-FeOOH/γ-Al2O3 system were proposed according to the identification of intermediates using GC-MS.

Performance and reliability of two frequently used point-of-care blood gas analyzers at 423 and 4,559 m

Background and ObjectivesBlood gas analyzers (BGA) aid medical decision-making. Their specified performance criteria are based on sea level conditions. However, millions of people are living at high altitude (HA) where the performance of BGAs is poorly characterized. We investigated the effect of exposure to 4,559 m on the reliability and robustness of two BGAs widely used at HA. MethodsIn this prospective study arterial blood samples from 13 volunteers (2 female) with susceptibility to the development of high-altitude pulmonary edema were collected once near sea level at 423 m (nSL423) and three times at high altitude (HA4,559). Samples were measured in triplicate with the cartridge BGAs Rapidpoint 500 (SIE; Siemens Healthcare) and the ABL90 (RAD; Radiometer) to calculate coefficients of variation (CV) and intraclass correlation coefficients (ICC) within a mixed model. ResultsAt nSL423 and HA4,559, 3% and 17% of all data were not reported with SIE, mainly due to clotting of the sample caused by delays because of the frequent automated calibration routines. No data were missing with RAD. ICCs were not significantly lower (mean (min–max) 0.87 (0.68–0.98) vs. 0.94 (0.84–1.00); p = 0.217) with SIE at nSL423, but significantly lower at HA4,559 (0.87 (0.49–1.00) vs. 0.99 (0.96–1.00); p = 0.025). All CVs, except that for arterial oxygen saturation at HA4,559,were higher with SIE . ConclusionIn this study, the reliability of RAD was superior to SIE at nSL423 and HA4,559. In contrast to RAD, the performance of SIE declined at HA4,559. SIE was more prone to not reporting all variables, especially at HA4559.

Breakdown mode and parameter space of micro-discharge sustained by thermionic emission

Gas breakdown driven by thermionic emission in a microgap to produce low-temperature plasma is studied using a 1D implicit particle-in-cell/Monte Carlo collision model. The influence of background gas pressure, external driving voltage, cathode temperature and discharge gap on argon glow micro-discharge in the parallel plate was simulated. Different parameters and conditions have different effects on the gas breakdown at small size. The discharge gap of hundreds of µm has little influence on the gas breakdown and only changes the plasma distribution. As the applied voltage increases, the gas changes from a non-breakdown mode to a breakdown mode, and the gas breakdown is more sensitive to the applied voltage than the gas pressure at low voltages. In all breakdown modes, the gas pressure hardly changes the plasma evolution characteristics. At appropriate cathode temperatures, the density of electrons and ions increases rapidly, forming a stable sheath, and the equivalent resistance of the discharge gap becomes smaller as the temperature rises and the plasma is in abnormal glow discharge.

The deposition of Ir/YSZ double-layer thin films on silicon by PLD and magnetron sputtering: Growth kinetics and the effects of oxygen

This work focuses on the epitaxial growth process and kinetics of silicon-based Ir/yttria-stabilized zirconia (YSZ) bilayer films prepared by PLD and magnetron sputtering, including the sequential growth of a YSZ film, an Ir seed layer, and an Ir film on a silicon substrate. The results show that for growing YSZ films by PLD at the target-to-substrate distance of 60 mm, the higher the laser energy density and the oxygen pressure, the lower the laser frequency, the higher the epitaxy quality. In addition, for the preparation of the Ir-seed layer by PLD, background gas decelerates the plasma and suppresses self-sputtering and implantation, which is beneficial to obtaining a high-quality seed layer. In particular, introducing a small amount of oxygen is able to improve the epitaxial quality of the films during the growth of Ir-seed and Ir films, and the mechanism of oxygen is proposed. For the growth of Ir films by magnetron sputtering, the growth rate and the energy of argon ions increased with the increase of RF power, while the epitaxial quality is the opposite. The kinetic theory and simulation results demonstrate that this trend is mainly caused by the increase in the number of particles reaching the substrate without significantly increasing the distribution of high-energy particles. Finally, high-quality Ir (100) films on the YSZ (100) with a fresh surface are prepared. It is shown that increasing the epitaxy quality of the YSZ (100) film and the growth temperature of the Ir film can improve the quality of Ir film. Based on our results, the growth of Ir films on YSZ films with fresh surfaces resulting from in-situ argon plasma cleaning provides a new idea for preparing Ir (100)/YSZ (100) bilayer epitaxial film.

Verification and benchmarking relativistic electron beam transport through a background gas

It is necessary to establish confidence in high-consequence codes containing an extensive suite of physics algorithms in the regimes of interest. Verification problems allow code developers to assess numerical accuracy and increase confidence that specific sets of model physics were implemented correctly in the code. The two main verification techniques are code verification and solution verification. In this work, we present verification problems that can be used in other codes to increase confidence in simulations of relativistic beam transport. Specifically, we use the general plasma code EMPIRE to model and compare with the analytical solution to the evolution of the outer radial envelope of a relativistic charged particle beam. We also outline a benchmark test of a relativistic beam propagating through a vacuum and pressurized gas cell, and present the results between EMPIRE and the hybrid code GAZEL. Further, we discuss the subtle errors that were caught with these problems and detail lessons learned.

Dependence of ion wake characteristics on experimental conditions

Two-dimensional microparticle crystals can be formed in the sheath of a gas discharge plasma. Ions from the bulk plasma are accelerated in the sheath electric field, flowing past the grains to create a positive ion wake downstream from the grains. Interaction between the ion wake and neighboring grains creates additional coupling between oscillation modes and can trigger mode-coupling instability (MCI). In order to better understand MCIs, the interaction between dust grains and ion wakes must be understood; however, the relationship between the discharge parameters and ion wake characteristics is unknown. A molecular dynamics simulation of ion dynamics and dust charging is used to self-consistently determine the dust charge and ion wake characteristics for different synthetic experimental conditions. It is found that the ion wake is strongly dependent on the background gas pressure but not affected much by the discharge power.

An integration design model for a large-scale negative ion accelerator of neutral beam injection system for fusion application

Design processes of a large-scale negative ion accelerator for neutral beam injection (NBI) application involve a series of physics and engineering issues, which include high voltage holding, background gas and stripping losses, beamlets optics and steering, particle and power flux on the grid electrodes, heat removal, thermal deformation, and stress of the grids. A self-consistent design model covering all these critical issues has been developed, where the results of one design aspect can be directly plugged into another one as the input conditions with little approximation or assumption. This design model has been applied to the negative ion accelerator of the NBI test facility of CRAFT (Comprehensive Research Facility for Fusion Technology), which is designed to produce a negative hydrogen ion beam of 25 A with the particle energy of 400 keV and the pulse duration of 3600 s. The accelerated current density is required to be 210 A/m2 from 768 apertures with a diameter of 14 mm. The evaluated results of the CRAFT accelerator design are quantitatively analyzed. Additionally, the modeling is applied to a large-scale and relatively complete structure of the multi-grid electrodes. Hence, some nonuniformities or special distributions appear in different design issues, which were not noticed in the reference works.

Key process of the defection of PET buffer layer in XLPE power cable by a case study: Thermo-oxidative degradation

Buffer tape ablation failures in the buffer layer of high voltage XLPE cables have become a common failure mode in cable transmission system. In this work, we aimed to analyze the degradation mechanism and evolution process of the buffer tape, which mainly consists of polyethylene terephthalate (PET) fibers, based on a fault in a 110 kV cable line. First, the gas inside the cable were extracted on site, and the gas components were analyzed using gas chromatography technology. Then the mechanism of the combustion phenomenon caused by thermo-oxidative degradation of PET fibers was proposed. Subsequently, the discharge simulation experiment of the PET buffer tape under different background gas was conducted to study the effect of oxygen on the thermal-oxidative degradation process. The research results show that oxygen plays a key role in the discharge ablation process of the PET buffer tape. Due to the thermal-oxygen degradation process, the O2 concentration in the buffer layer decreases, and the CO and CO2 concentration increases, and at the same time the combustible gases such as hydrogen and methane are generated. The internal pressure of the buffer layer also increases under the influence of the gas partial pressure. The gas components mentioned above are not generated by the discharge under anaerobic conditions. Finally, a method of preventing the ablation defect of the buffer layer of the high-voltage cable according to the thermo-oxidative degradation mechanism of the buffer tape PET material is proposed.

Flocking of two unfriendly species: The two-species Vicsek model.

We consider the two-species Vicsek model (TSVM) consisting of two kinds of self-propelled particles, A and B, that tend to align with particles from the same species and to antialign with the other. The model shows a flocking transition that is reminiscent of the original Vicsek model: it has a liquid-gas phase transition and displays micro-phase-separation in the coexistence region where multiple dense liquid bands propagate in a gaseous background. The interesting features of the TSVM are the existence of two kinds of bands, one composed of mainly A particles and one mainly of B particles, the appearance of two dynamical states in the coexistence region: the PF (parallel flocking) state in which all bands of the two species propagate in the same direction, and the APF (antiparallel flocking) state in which the bands of species A and species B move in opposite directions. When PF and APF states exist in the low-density part of the coexistence region they perform stochastic transitions from one to the other. The system size dependence of the transition frequency and dwell times show a pronounced crossover that is determined by the ratio of the band width and the longitudinal system size. Our work paves the way for studying multispecies flocking models with heterogeneous alignment interactions.

Moist Convection Is Most Vigorous at Intermediate Atmospheric Humidity

In Earth’s current climate, moist convective updraft speeds increase with surface warming. This trend suggests that very vigorous convection might be the norm in extremely hot and humid atmospheres, such as those undergoing a runaway greenhouse transition. However, theoretical and numerical evidence suggests that convection is actually gentle in water-vapor-dominated atmospheres, implying that convective vigor may peak at some intermediate humidity level. Here, we perform small-domain convection-resolving simulations of an Earth-like atmosphere over a wide range of surface temperatures and confirm that there is indeed a peak in convective vigor, which we show occurs near T s ≃ 330 K. We show that a similar peak in convective vigor exists when the relative abundance of water vapor is changed by varying the amount of background (noncondensing) gas at fixed T s , which may have implications for Earth’s climate and atmospheric chemistry during the Hadean and Archean eons. We also show that Titan-like thermodynamics (i.e., a thick nitrogen atmosphere with condensing methane and low gravity) produce a peak in convective vigor at T s ≃ 95 K, which is curiously close to the current surface temperature of Titan. Plotted as functions of the saturation-specific humidity at cloud base, metrics of convective vigor from both Earth-like and Titan-like experiments all peak when cloud-base air contains roughly 10% of the condensible gas by mass. Our results point to a potentially common phenomenon in terrestrial atmospheres: that moist convection is most vigorous when the condensible component is between dilute and nondilute abundance.

Self-regulation of black hole accretion via jets in early protogalaxies

ABSTRACT The early growth of black holes (BHs) in high-redshift galaxies is likely feedback regulated. While radiative feedback has been extensively studied, the role of mechanical feedback has received less scrutiny to date. Here, we use high-resolution parsec-scale hydrodynamical simulations to study jet propagation and its effect on 100 M⊙ BH accretion in the dense, low-metallicity gas expected in early protogalaxies. As the jet propagates, it shocks the surrounding gas forming a jet cocoon. The cocoon consists of a rapidly cooling cold phase at the interface with the background gas and an overpressured subsonic phase of reverse shock-heated gas filling the interior. We vary the background gas density and temperature, BH feedback efficiency, and the jet model. We found that the width of the jet cocoon roughly follows a scaling derived by assuming momentum conservation in the jet-propagation direction and energy conservation in the lateral directions. Depending on the assumed gas and jet properties, the cocoon either stays elongated to large radii or isotropizes before reaching the Bondi radius, forming a nearly spherical bubble. Lower jet velocities and higher background gas densities result in self-regulation to higher momentum fluxes and elongated cocoons. In all cases, the outward cocoon momentum flux balances the inward inflowing gas momentum flux near the Bondi radius, which ultimately regulates BH accretion. The time-averaged accretion rate always remains below the Bondi rate, and exceeds the Eddington rate only if the ambient medium is dense and cold, and/or the jet is weak (low velocity and mass loading).

Thin Films Fabricated by Pulsed Laser Deposition for Electrocatalysis

Thin Films Fabricated by Pulsed Laser Deposition for Electrocatalysis

Gas Phase Reactivity of [Mo6X14]2– Dianions (X = Cl – I)

We investigate collision-induced dissociation (CID) of [Mo6X14]2- (X = Cl, Br, I) and the reactivity of fragment ions of these precursors with background gases. Ion mobility measurements and theoretical calculations provide structural information for some of the observed ions. Sequential losses of MoX2 units dominate the dissociation pathways of [Mo6Cl14]2-. Meanwhile, loss of X radicals is the main channel for X = Br and I. Ion mobility measurements and computational investigations indicate minor structural changes in the octahedral Mo6 unit for [Mo6Im]- (m = 6-13) fragments. We observe that mass spectra obtained using CID substantially vary among mass spectrometers: Specifically, ions with molecular formula [Mo6Xm(O2)n]- (X = Br and I) are observed as dominant species produced through reactions with O2 in several mass spectrometers, but also adduct free fragment ions were observed in other instruments, depending on the background conditions. Ion-trap fragmentation combined with theoretical investigations indicates that spontaneous losses of X radicals occur upon binding of O2 to [Mo6Im]- fragments (m ≤ 12). Theoretical investigations indicate that both oxygen atoms are bound to the vacant sites of the Mo6 units. This study opens up a new vista to generate and study a large variety of hexanuclear Mo6Xm(O2)n anions.