B2O3 SiO2 Research Articles

Large Room-Temperature Electrocaloric Effect in Lead-Free Relaxor Ferroelectric Ceramics with Wide Operation Temperature Range

In order to obtain large room-temperature electrocaloric effect (ECE) and wide operation temperature range simultaneously in lead-free ceramics, we proposed designing a relaxor ferroelectric with a Tm (the temperature at which the maximum dielectric permittivity is achieved) near-room temperature and glass addition. Based on this strategy, we designed and fabricated lead-free 0.76NaNbO3–0.24BaTiO3 (NN-24BT) ceramics with 1wt.% BaO–B2O3–SiO2 glass addition, which showed distinct relaxor ferroelectric characteristics with strongly diffused phase transition and a Tm near-room temperature. Based on a direct measurement method, a large ΔT (adiabatic temperature change) of 1.3 K was obtained at room temperature under a high field of 11.0 kV mm−1. Additionally, large ECE can be maintained (>0.6 K@6.1 kV mm−1) over a broad temperature range from 23 °C to 69 °C. Moreover, the ECE displayed excellent cyclic stability with a variation in ΔT below ±7% within 100 test cycles. The comprehensive ECE performance is significantly better than other lead-free ceramics. Our work provides a general and effective approach to designing lead-free, high-performance ECE ceramics, and the approach possesses the potential to be utilized to improve the ECE performance of other lead-free ferroelectric ceramic systems.

Structure and dynamic viscosity of CaO–SiO2 and CaO–SiO2–B2O3 model slag systems

Correlation dependencies between the dynamic viscosity of slag and its structural parameters were studied to determine an optimal basicity of silicon smelting slag under the addition of boron oxide to eliminate slagging of the bottom of ore-smelting furnaces. Experimental studies were conducted on CaO–SiO2 and CaO– SiO2–B2O3 model slags obtained at 1600°С. Raman spectroscopic analysis was carried out using a Horiba JobinYvon HR800UV analyzer (France). Theoretical calculations of slag viscosity were performed using Urbain and Mills models. During the experiments, the key structural parameters of slag systems varied within the following limits: the experimental Raman spectrum deconvolution function from 1.41 to 2.45 and optical basicity from 0.58 to 0.68. The obtained experimental and theoretical data were related by mathematical dependencies. It was found that the dynamic viscosity of slag can be promptly determined by Raman spectroscopy on the basis of mathematical models. The dependence obtained shows that slag viscosity decreases upon an increase in the number of bridging oxygen atoms in the silicate anion structure. Notably, this decrease in slag viscosity is observed up to the value of the experimental Raman spectrum deconvolution function of ~1.55-1.60 or slag optical basicity of 0.60–0.62. When B2O3 is added, the viscosity undergoes a further decrease. In practice, for CaO–SiO2 slag systems, the use of boroncontaining flux as a liquefying agent is reasonable at CaO/SiO2 = 0.61–0.63 while maintaining the content of B2O3 in the slag at a level of 1%. The two models (classical and modified) proposed by Urbain were established to be more suitable for theoretical calculation of viscosity in CaO–SiO2 and CaO–SiO2–B2O3 systems. Mills’ model is not suitable for these purposes, since the correlation coefficients in the corresponding mathematical model are not sufficiently large. Further research in this direction is required in order to establish appropriate dependencies of slag viscosity on its structural parameters at different temperatures.

Cerium oxide-reinforced Fe2O3–Na2O–SiO2–B2O3 glass matrix for protection against ionizing X and gamma rays

Radiation shielding glass is an interesting material in the field of radiation shielding due to its remarkable features. In the present paper, we investigated the physical properties of radiation-shielding glass materials that consist of sodium oxide (Na2O), cerium oxide (CeO2), and iron oxide (Fe2O3) incorporated into borosilicate glasses with the formula 90SiO2-(70-x)B2O3+ 20Na2O–1Fe2O3-xCeO2 (CeFeNaBS-glasses). One of the distinguishing characteristics of this glass system is its enhanced radiation shielding capabilities. The structural studies indicated a gradual rise in glass density from 1.954 to 2.658 g/cm with further CeO2 doping. Optical studies showed that the optical band gaps went down from 3.41 eV to 3.33 eV as the amount of CeO2 in the CeFeNaBS-glass matrix rose. The decrease in optical band gap has been correlated with the rising basicity. Also, the increased basicity behavior induces more conversion of Ce3+ to Ce4+ ions by losing a 4f electron. Moreover, with further CeO2 additions, the glass color changed from light brown to dark brown. The presence of Ce4+ ions with further CeO2 additions is responsible for this color transformation. The linear and non-linear refractive indices exhibit enhanced behaviors with higher CeO2 concentrations. We used declining basicity and polarizability behaviors to describe this behavior. The incorporation of larger CeO2 concentrations enhances the ability to improve radiation shielding properties, as demonstrated by the increased values of the mass attenuation coefficient and half-value layer, especially in the energy ranges of soft tissues X-ray and hard tissues X-ray. Hence, the investigated CeFeNaBS-glasses exhibit enhanced transparency and radiation shielding capabilities, rendering them highly suitable for implementation in this domain.

High-temperature aqueous corrosion of MO–Na2O–B2O3–SiO2 glass and glass-ceramic coatings on metallic substrates: Effect of alkaline earth metals M2+= {Ca2+, Sr2+, Ba2+}

This investigation aims to assess the impact of 2 A alkaline-earth oxides on the alteration of glass/glass-ceramic coatings on steel under conditions of exposure to hot water. Experiments involved integrating CaO, SrO, and BaO into sodium-borosilicate glass systems after that a melting-quenching process to obtain frits. Coated and sinter-crystallized samples denoted as GC-Ca, GC-Sr, and GCC-Ba were exposed to hot aqueous corrosion according to DIN 4753–3 at 95 °C, which determined weight loss after 42 days. ICP-MS analyzed aqueous solutions for element leaching. Results indicated that glass-ceramic coatings (GCC-Ba) outperformed glass coating(GC-Ca, GC-Sr). GCC-Ba demonstrated enhanced stability, attributed to limited ion exchange and diffusion at high temperatures, enhancing corrosion resistance, supported by sanbornite crystal phase presence. Total element release by ICP-MS and 42 days of hot water corrosion coatings' weight loss after 42-day corrosion test lined up: GC-Sr > GC-Ca > GCC-Ba.

Designing high-performance ion-exchangeable glasses with multi-objective optimization and machine learning

Ion exchange typically involves replacing smaller ions with larger ions below the glass transition temperature. This study introduces an innovative computational approach for the inverse design of ion-exchangeable glasses. It aims to simultaneously achieve high depth of layer (DOL) and surface compressive stress (CS), a task complicated by the inherent trade-offs between these properties. Traditional ion exchange experimental methods are not only time-consuming and expensive, but they also involve complex practical difficulties. Addressing these challenges, this paper introduces a novel computational approach that synergistically combines a multi-objective genetic algorithm with machine learning models. The approach involves training models on a diverse set of glass compositions to predict DOL and CS, which then guide an evolutionary algorithm to optimize these properties concurrently. Physics-informed parameters further refine the search, enabling a flexible design framework in glass manufacturing. Comprehensive experimentation and subsequent analysis affirm the proposed method's capacity to efficiently and effectively traverse the intricate design landscape of glass materials. The findings elucidated the influence of distinct compositional and process parameters on DOL and CS, facilitating the manual design process. Additionally, the study identified sixteen glass composition candidates within the SiO2–B2O3–Al2O3–MgO–Na2O system, exhibiting remarkable properties. Specifically, some compositions achieved a DOL of up to 95 μm with a corresponding CS of 890 MPa, while others attained a CS of up to 1654 MPa with a DOL of 14.72 μm.

Phase thermal stability and low thermal stress in MgO–BaO–CaO–Al2O3–B2O3–SiO2 glass-ceramic for long-term solid oxide fuel cells

The crystallization thermal stability plays an essential role in affecting thermal stress of glass-ceramic sealant for long-term planar-type solid oxide fuel cells (SOFC) to prevent fuel leakage during operation. Due to the lack of systematic research on regulating the stable performance of glass-based sealant with the working time at operation temperature, herein, the effect of MgO on crystallization kinetics, phase stability, and thermal and mechanical properties of MgO–BaO–CaO–Al2O3–B2O3–SiO2 (MBCABS) glass-ceramic has been firstly analyzed at heat-treatment of 750 °C with working time of 1∼1000h in this work. Subsequently, the relationship evolution of crystallization thermal stability-coefficient of thermal expansion (CTE) match-thermal stress was established by Finite Element Method (FEM). The main reasons for the decrease of CTE of MBCABS glass-ceramics with low-content MgO are the precipitation of hexagonal BaAl2Si2O8 phase and the transformation of hexagonal BaAl2Si2O8 to low-CTE monoclinic BaAl2Si2O8 phase, bring about that the Von Mises thermal stress of sealant itself and interface having tripled at 1000h (more than 200 MPa) according to FEM simulation results. The thermal stable and high-CTE BaMgSiO4, Ba8Mg16Si16O56, and BaCa2Mg(SiO4)2 phases crystallized in MBCABS glass-ceramics with high-content MgO, therefore the maximum stress at all time parameters was below 100 MPa for 1∼1000h. This study was useful for identifying the optimal phase option and CTE matching of glass-based sealant for efficient and stable long-term operation of solid oxide fuel cells.

Structural, thermo-mechanical, optical and gamma-ray shielding properties of lead-free BaO–ZnO–B2O3–SiO2 and lead-based PbO–Bi2O3–K2O–SiO2 glasses

Lead-free BaO–ZnO–B2O3–SiO2 glass (BZBS) and lead-based PbO–Bi2O3–K2O–SiO2 glass (LS) were synthesized by melt quench technique. Glass samples were irradiated using 60Co gamma source up to 50 kGy dose to study the changes in structural, thermo-mechanical, optical and gamma ray shielding properties. Measured density values of both the glasses were greater than 4.0 g/cc. X Ray Diffraction (XRD) studies confirmed amorphous nature of prepared glasses before and after gamma irradiation. The structural changes induced by gamma irradiation were also investigated using Raman, Positron annihilation lifetime spectroscopy (PALS) and Electron Paramagnetic Resonance (EPR) spectroscopy. PALS data revealed increase in free volume/voids after irradiation. Defect studies carried using EPR spectroscopy confirmed formation of electron trap centre in BZBS glass, whereas in LS glass in addition to the electron trap centers, non-bridging oxygen hole centers (NBOHC) and peroxy radical defects were also observed. Investigations on thermo-mechanical properties demonstrated higher glass transition temperature (Tg), hardness and modulus of elasticity values for BZBS glass as compared to the LS glass, which were found to be decreased after irradiation because of radiation induced defects. Visible transparency and band gap for BZBS glass were found to be higher than that in LS glass. After irradiation, colour change, reduction in transparency as well as band gap, and red shift in absorption edge were observed due to the formation of defects in both the glasses. The values of radiation induced absorption (α) at three different visible wavelengths have been determined for 50 kGy dose using UV–Vis transmission data. Analysis of refractive index data showed around 12 % reflection losses for both the glasses. Annealing of irradiated samples using UV light source showed significant improvement in transparency. Linear attenuation coefficient (LAC) was calculated using XCOM program and experimentally measured using 60Co 1.33 MeV gamma ray. Linear attenuation coefficient of BZBS glass was around 0.20 cm−1 whereas for LS glass value was 0.24 cm−1. Half value layer thickness of prepared glasses was also compared with available standard materials and it was found that prepared glasses may be suitable for shielding of high energy gamma rays.

ИЗУЧЕНИЕ ОСОБЕННОСТЕЙ СТЕКЛООБРАЗОВАНИЯ ЭМАЛЕВЫХ ФРИТТ ДЛЯ СТАЛЬНЫХ ОБЛИЦОВОЧНЫХ ПАНЕЛЕЙ

Cladding of buildings and structures, combining decorative, protective and thermal insulation functions, is currently in great demand in the construction industry. One of the effective areas for using vitreous and glass-crystalline enamel coat-ings is the protection of steel cladding panels for construction purposes. Therefore, there is a need to create and widely implement competitive enamel-coated panels made in Russia with specified properties. The work identifies the areas of glass formation and constructs a composition diagram in the SiO2–B2O3–Na2O–RxOy system of glass areas, which are the basis for the production of ground and top enamels. The physicochemical patterns of glass formation in the Na2O–B2O3–Al2O3–SiO2–RxOy system for the production of enamel coatings have been established by varying the values of the connectivity indicators of the aluminum-boron-silicon-oxygen framework.

Glass frit and method of forming electrical insulating coatings on steel substrates of film heaters

Electric film heaters (EFHs) applied on flat steel substrates show promising potential in the production of heating devices. The basis for manufacturing EHFs is heat-resistant steel, the surface of which is coated with a heat-resistant electrical insulation coating. These coatings are glass crystalline and are applied mainly by screen printing. Compared to screen printing, the electrophoretic method of coating is more productive. In this work, glass in the MgO–CaO–B2O3–SiO2 oxide system was chosen for obtaining glass crystalline coatings. The paper provides a description of the material composition and the method used to prepare a suspension for еру electrophoretic deposition of coating. The main technological parameters for forming electrophoretic coatings with a specific thickness are determined based on experimental results. Utilizing calculated data on the properties of the selected glass, the study substantiates the most rational temperature and time regime for coating firing. These conditions promote crystallization and result in the production of heat-resistant coatings with sufficient electrical insulating properties for steel substrates of EFHs.

Structural and performance variations of aluminoborosilicate glass substrates with mixed alkaline earth effect for applications in 3D integrated packaging

Alkali-free aluminoborosilicate glass substrates possess excellent chemical stability and outstanding thermodynamic and dielectric properties, rendering them promising candidates for applications in three-dimensional integrated packaging. This study investigates the structural and performance variations in RO (RBa,Sr)–Al2O3–B2O3–SiO2 glass substrates with a mixed alkaline earth effect under different BaO/SrO ratios (with a constant RO value of 20 mol%). The glass substrates were analyzed using various methods, including X-ray diffraction, differential scanning calorimetry, coefficient of thermal expansion, Raman spectroscopy, and 1 MHz–1 GHz dielectric property tests. Raman spectroscopy was used to measure the glass network connectivity using R12/34 (degree of [SiO4] units depolymerization) and N4 (degree of [BO4] units polymerization). The results show that the RABS15 sample had a significant reduction in dielectric loss at a frequency of 1 GHz compared with the other glass samples, corresponding to the best glass network connectivity. The main cause of high-frequency dielectric loss was the presence of [BO3] units in the glass network. During the preparation process, it was discovered that placing the crucible with mixed raw materials in an elevator-type furnace at a high temperature is an effective measure for solving the crystallization problem.

Effect of LiF and LBSCA glass on the microwave dielectric properties of 0.5BaCuSi4O10–0.5BaCuSi2O6‐based ceramics for LTCC applications

AbstractIn this work, the 0.5BaCuSi4O10–0.5BaCuSi2O6‐based ceramics were synthesized using a standard solid‐phase reaction process, and the inherent relationship between crystal structure and microwave dielectric properties was thoroughly explored. The crystal structure of the 0.5BaCuSi4O10–0.5BaCuSi2O6 ceramic was determined by X‐ray diffractometer, which confirmed the existence of two phases. Microstructure observation of the ceramics was obtained by scanning electron microscope (SEM). Excellent microwave dielectric properties with a low ԑr ∼6.52, a high Q × f ∼46 010 GHz, and the temperature coefficient of resonant frequency (TCF) ∼−14 ppm°C−1 were obtained in the 0.5BaCuSi4O10–0.5BaCuSi2O6 ceramic sintered at 1060°C. By adding sintering additives LiF and Li2O–B2O3–SiO2–CaO–Al2O3 (LBSCA) glass, the sintering temperature was decreased from 1060°C to 870°C. Good microwave dielectric properties with a ԑr ∼6.59, a Q × f ∼18 820 GHz, and TCF ∼−14 ppm°C−1 were achieved in the 0.5BaCuSi4O10–0.5BaCuSi2O6 ‐2 wt.% LiF, 1 wt.% LBSCA (2F1LBSCA) ceramic sintered at 870°C. The low‐temperature firing ceramics could also be well co‐fired with Ag with good chemical compatibility. These results indicated that the 0.5BaCuSi4O10–0.5BaCuSi2O6 ceramic with 2F1LBSCA additions can be utilized in low‐temperature co‐fired ceramics technology to produce high‐frequency communication components.

Metal oxides for electronics and the SPQEO journal

This article discusses the main trends in the physics and preparation of metal oxides and summarizes the results of research published by SPQEO in this area over the past decade. The main metal oxides studied include ZnO, Zn1-xCdxO, Zn1-xCoxO, MgxZn1–xO, ZnO:Mn, VO2, ZrO2–Y2O3, TiO2, WO3, Gd2O3, Er2O3, WO3–CaO–SiO2–B2O3: Tb3+, Dy2O3, NiO, FexOy, Ga2O3, Al2O3, ITO, Ag2O and graphene oxide. These oxides were obtained by the following methods: sintering in air or in a stream of various gases, magnetron sputtering, atomic layer deposition, explosive evaporation, sol-gel, spin coating, spray pyrolysis, rapid thermal annealing, green synthesis from plant solutions, melt quenching, rapid thermal annealing, self-ignition, ion-plasma co-sputtering, vacuum sputtering, reactive ion beam sputtering, and the Hammer method. The electrical and optical properties of the studied oxides are illustrated.

Accelerating densification of the terminal electrode with improved adhesion by sodium ions doping for MLCC copper paste

Glass frits effectively facilitate the sintering densification to produce high-density terminal electrodes, crucial for achieving high reliability of MLCC (Multilayer Ceramic Capacitors) devices. However, manufacturing terminal electrodes with high density and strong adhesion under low-temperature sintering condition still has enormous challenges. Herein, Na2O–BaO–ZnO–B2O3–SiO2 glass has been fabricated for low temperature sintering copper paste. We demonstrate that the densification degree and adhesion strength of the terminal electrode can be notably optimized by adjusting the Na2O content in the glass frit. The doping of Na+ in glass effectively improves the wettability of the melt on the copper substrate and the surface tension of the glass melt, enhancing the capillary force in the liquid phase sintering process. The rate of electrode densification is accelerated by the increase in capillary force, thus reducing the sheet resistance of copper film from 4.52 to 4.30 mΩ/□. Furthermore, with the increase in the Na+ content, the work of adhesion between glass and ceramic gradually increases, which effectively enhances the shear strength of the electrode from 19.66 MPa to 29.55 MPa. Our work provides novel insights for the design of glass compositions in the field of terminal paste.

Fabrication of sapphire/MgAl2O4/sapphire laminated transparent composite by brazing with BaO–B2O3–SiO2 glass filler

For improving the mechanical properties of MgAl2O4 ceramic and maintaining its wide band transparency, the sapphire/MgAl2O4/sapphire laminated transparent composites with thin sapphire layers were fabricated by brazing with BaO–B2O3–SiO2 (BBS) glass filler. The BBS glass filler had an appropriate CTE (coefficient of thermal expansion) value and good wettability on the surface of sapphire and MgAl2O4 ceramics. Joining experiments were first carried out to optimize the preparation process parameters of laminated composites. The results indicated that high bonding temperature promoted mutual dissolution and diffusion of BBS glass and MgAl2O4 ceramic, but led to the intergranular infiltration of glass filler and the formation of pores due to volatilization of B2O3. When the bonding temperature was 1000 °C, the sapphire/MgAl2O4 joints with the best transparency and acceptable shear strength could be obtained. On this basis, the laminated composites with 0.15 mm thick sapphire layers were fabricated by brazing using BBS glass at 1000 °C. The flexural strength of the laminated composite reached 320 ± 10 MPa, which was higher than that of MgAl2O4 (195 ± 15 MPa). The in-line transmittance of laminated composite was 80.9 % at 1000 nm, which was slightly lower than that of MgAl2O4 (82.2 %).

Effect of CaO on the dissolution property, surface zeta potential and antibacterial properties of ZnO–Na2O–B2O3–SiO2 glass system

Effect of CaO on the dissolution property, surface zeta potential and antibacterial properties of ZnO–Na2O–B2O3–SiO2 glass system

Adjusting photoluminescence of high thermostability Dy3+/Eu3+ co-doped borosilicate glass for white LED device

Due to the adoption of fluorescent powder encapsulated by organic resin, commercial light emitting diodes (LEDs) suffer from low thermal stability and poor light quality under high temperature, and luminescent glass is one of the effective ways to solve this problem. A series of borosilicate (B2O3–SiO2–Al2O3–PbO-Dy2O3–Eu2O3, marked as BSAP: DyEu) was prepared by the gas suspension technique. The basic characterization test indicate that the prepared glass has excellent thermal stability and stable structure. The optical properties of the luminescent glass were investigated in detail. By changing the Eu3+ doping amount, the Dy3+/Eu3+ co-doped glass can realize warm white light emission. The temperature-variable fluorescence spectra of BASP: Dy1.25Eu1.0 were analyzed, and the glass can produce strong warm white light emission in a wide temperature range. At 700 K, the luminous intensity of the glass remains above 38.49 % of the room temperature, and the chroma shift ΔC = 8.57 × 10−3. In addition, the w-LED device based on commercial GaN chip and BSAP: DyEu glass realizes warm white light output with excellent correlated color temperature (3063 K) and high color rendering index (90.3). The analysis shows that Dy3+/Eu3+ co-doped borosilicate glass can be used as a candidate material for w-LED applications.

Comprehensive study on structural, optical, mechanical and radiation blocking nature of Eu3+-doped bismuth tellurite glasses

A novel glass system B2O3–SiO2–Bi2O3–TeO2–BaO–ZnO doped with Eu2O3 (x = 0–4 mol%) is fabricated through melt-quench technique and coded as BiTeEu-x. Density and refractive index measurements done on the glasses resulted in the increase up to 5.4377 gcm−3 and 1.99, respectively, for 4 mol% addition of Eu2O3. Vickers micro-indentation measurements done on synthesized glasses gave increasing microhardness values with Eu3+ doping due to higher bond strength of Eu–O bond compared to Te–O bond. The Phy-X/PSD simulation software utilized for obtaining radiation shielding parameters produced highest range of mass attenuation coefficient (63.878–0.036 cm2/g) and lowest range of half-value layer (0.002–3.551 cm) for the same glass proving its superiority in radiation attenuating capacity. This article addresses the theoretical analysis of photon buildup occurring inside the fabricated glasses in 0.015–15 MeV energy range with respect to different penetration depths. Neutron shielding ability of BiTeEu-4 glass was found to be impressive with fast neutron removal cross section (FNR) value of 0.10362 cm−1.

Effect of Y2O3 on crystallization and mechanical properties of sodium aluminum silicate glass containing ZrO2

In this paper, high transmittance glass-ceramics containing Zirconium Yttrium Oxide (Zr0.82Y0.18O1.91) nanocrystals were successfully prepared by melt cooling and crystallization heat-treatment method. The effects of Y2O3 concentration on the structure, crystallization performance, transmittance, and indentation fracture toughness of Na2O–Al2O3–B2O3–SiO2–ZrO2 glass and glass-ceramics were explored. The addition of Y2O3 improved the Vickers hardness (4.81 GPa–5.25 GPa) and indentation fracture toughness (0.78 MPam1/2 to 0.95 MPam1/2) of the glasses. Y2O3 successfully facilitated the precipitation of the non-alkaline crystalline phase Zr0.82Y0.18O1.91 at low heat-treatment temperatures. The precipitation of Zr0.82Y0.18O1.91 nanocrystals improves the Vickers hardness (5.17 GPa–5.56 GPa) and indentation fracture toughness (0.90 MPam1/2 to 1.01 MPam1/2) in glass-ceramics, while concurrently preserving a high level of visible light transmittance (∼90 %). This demonstrates its potential applications in the field of protective covers for electronic displays.

Y2O3 reinforced B2O3–SiO2–BaO–Na2O glass system: A characterization study through physical, optical and gamma / neutron shields characteristics

Glasses with the composition 48B2O3– 13SiO2– 7BaO- (32-x) Na2O-xY2O3, (x = 0, 1, 2, 4, and 8 mol %) were synthesized by the melt quenching procedure. There is good transparency in every glass sample. The increase in density (2.825–3.894 gm/cm3) of the present glasses is what triggered the decline in molar volume (25.41–21.80 cm3/mol) and the decrease in the Boron–Boron distance (0.475–0.452 nm). The estimated values show that Eopt.indi. &Eopt.di are 2.317, 2.672, 2.8, 2.98 and 3.1 eV, 2.69, 2.92, 3.05, 3.25, and 3.44 eV respectively, whereas (Eu) values declined. As the Y2O3 increased the refractive index (nD) increased. (nD) of the synthesized glasses using Eopt.indi.&Eopt.di were estimated. To find the radiation properties of the suggested glasses, the Phy-X/PSD code was employed. We concluded that the current glasses have better radiation shielding capabilities when employed in such fields. As the Y2O3 replacing ratio increased ∑R increased.

An experimental and theoretical study to evaluate Al2O3–PbO–B2O3–SiO2–BaO radiation shielding properties

This study's objective is to evaluate an Al2O3–PbO–B2O3–SiO2–BaO glass system's radiation shielding characteristics. The composition of the glasses is 15Al2O3–25PbO–(60-x)B2O3–10SiO2–xBaO, with x in the 5–20 mol% range. Experimental results were used to determine the samples' linear attenuation coefficients (LAC), which were then confirmed by Phy-X program. Utilizing narrow beam transmission geometry, the experimental LAC values were determined. According to the results there was high agreement when comparing the theoretical and experimental values. The LAC values were used to calculate the prepared glasses' mass attenuation coefficients (MAC) and other relevant properties. The mean free path (MFP) values of the sample with 5 mol% BaO were 0.079, 2.549, 3.944 and 4.273 cm at 0.0595, 0.662, 1.173, and 1.332 MeV, thus demonstrating that raising the glass system's BaO enhances the prepared glasses' shielding capacity. According to radiation protection efficiency (RPE), the glasses' capacity to shield the photon is enhanced when their BaO content rises.