Anisotropy Axis Research Articles

Effects of mixed metal exposures on MRI diffusion features in the medial temporal lobe

BackgroundEnvironmental exposure to metal mixtures is common and may be associated with increased risk for neurodegenerative disorders including Alzheimer’s disease. This study examined associations of mixed metal exposures with medial temporal lobe (MTL) MRI structural metrics and neuropsychological performance. MethodsMetal exposure history, whole blood metal, MRI R1 (1/T1) and R2* (1/T2*) metrics (estimates of brain Mn and Fe, respectively), and neuropsychological tests were obtained from subjects with/without a history of mixed metal exposure from welding fumes (42 exposed subjects; 31 controls). MTL structures (hippocampus, entorhinal and parahippocampal cortices) were assessed by morphologic (volume or cortical thickness) and diffusion tensor imaging [mean (MD), axial (AxD), radial diffusivity (RD), and fractional anisotropy (FA)] metrics. In exposed subjects, effects of mixed metal exposure on MTL structural and neuropsychological metrics were examined. ResultsCompared to controls, exposed subjects displayed higher MD, AxD, and RD throughout all MTL ROIs (p’s<0.001) with no morphological differences. They also had poorer performance in processing/psychomotor speed, executive, and visuospatial domains (p’s<0.046). Long-term mixed metal exposure history indirectly predicted lower processing speed performance via lower parahippocampal FA (p’s<0.023). Higher entorhinal R1 and whole blood Mn and Cu levels predicted higher entorhinal diffusivity (p’s<0.043) and lower Delayed Story Recall performance (p=0.007). DiscussionMixed metal exposure predicted certain MTL structural and neuropsychological features that are similar to those detected in Alzheimer’s disease at-risk populations. These data warrant follow-up as they may illuminate a potential path for environmental exposure to brain changes associated with Alzheimer’s disease-related health outcomes.

Viscous tweezers: Controlling particles with viscosity

Control of particle motion is generally achieved by applying an external field that acts directly on each particle. Here, we propose a global way to manipulate the motion of a particle by dynamically changing the properties of the fluid in which it is immersed. We exemplify this principle by considering a small particle sinking in an anisotropic fluid whose viscosity depends on the shear axis. In the Stokes regime, the motion of an immersed object is fully determined by the viscosity of the fluid through the mobility matrix, which we explicitly compute for a pushpin-shaped particle. Rather than falling upright under the force of gravity, as in an isotropic fluid, the pushpin tilts to the side, sedimenting at an angle determined by the viscosity anisotropy axis. By changing this axis, we demonstrate control over the pushpin orientation as it sinks, even in the presence of noise, using a closed feedback loop. This strategy to control particle motion, that we dub viscous tweezers, could be experimentally realized in systems ranging from polyatomic fluids under external fields to chiral active fluids of spinning particles by suitably changing their direction of global alignment or anisotropy. Published by the American Physical Society 2024

Effect of Thermal Processing on the Structural and Magnetic Properties of Epitaxial Co2FeGe Films.

The structure and magnetic properties of epitaxial Heusler alloy films (Co2FeGe) deposited on MgO (100) substrates were investigated. Films of 60 nm thickness were prepared by magnetron co-sputtering at different substrate temperatures (TS), and those deposited at room temperature were later annealed at various temperatures (Ta). X-ray diffraction confirmed (001) [110] Co2FeGe || (001) [100] MgO epitaxial growth. A slight tetragonal distortion of the film cubic structure was found in all samples due to the tensile stress induced by the mismatch of the lattice parameters between Co2FeGe and the substrate. Improved quality of epitaxy and the formation of an atomically ordered L21 structure were observed for films processed at elevated temperatures. The values of magnetization increased with increasing TS and Ta. Ferromagnetic resonance (FMR) studies revealed 45° in-plane rotation of the easy anisotropy axis direction depending on the degree of the tetragonal distortion. The film annealed at Ta = 573 K possesses the minimal FMR linewidth and magnetic damping, while both these parameters increase for another TS and Ta. Overall, this study underscores the crucial role of thermal treatment in optimizing the magnetic properties of Co2FeGe films for potential spintronic and magnonic applications.

Effects of Mixed Metal Exposure on MRI Metrics in Basal Ganglia.

Welding fumes contain various metals. Past studies, however, mainly focused on Manganese (Mn)-related neurotoxicity. This study investigated welding-related mixed metal exposure effects on MRI metrics in the basal ganglia (BG) and their dose-response relationship. Subjects with (N = 23) and without (N = 24) a welding exposure history were examined. Metal exposure was estimated with exposure history questionnaire and whole blood metal levels. T1 (weighted-intensity and relaxation time; estimates of brain Mn accumulation), diffusion tensor imaging [Axial (AD), mean (MD), radial diffusivity (RD), and fractional anisotropy (FA); estimates of microstructural differences] metrics in BG [caudate nucleus, putamen, and globus pallidus (GP)] and voxel-based morphometry (for volume) were examined and related with metal exposure measures. Compared to controls, welders showed higher GP R1 (1/T1; p = 0.034) but no differences in blood metal and T1-weighted (T1W) values in any ROIs (p's > 0.120). They also had higher AD and MD values in the GP (p's < 0.033) but lower FA values in the putamen (p = 0.039) with no morphologic differences. In welders, higher blood Mn and Vanadium (V) levels predicted higher BG R1 and T1W values (p's < 0.015). There also were significant overall metal mixture effects on GP T1W and R1 values. Moreover, GP AD and MD values showed non-linear associations with BG T1W values: They increased with increasing T1W values only above certain threshold of T1 values. The current findings suggest that Mn and V individually but also metal mixtures jointly predict GP T1 signals that may in turn contribute to altered DTI metrics in the BG after certain exposure threshold levels.

Nonreciprocity of surface acoustic waves coupled to spin waves in a ferromagnetic bilayer with noncollinear layer magnetizations

Nonreciprocity of propagation of surface acoustic waves (SAWs) in the microwave frequency band can be achieved using the magnetoelastic interaction of SAWs with spin waves (SWs) propagating in magnetic heterostructures. Recent works have shown that the ultimate isolation of a counterpropagating hybridized SAW/SW is achieved in heterostructures consisting of a synthetic antiferromagnet—a ferromagnetic (FM) bilayer with antiferromagnetic Ruderman-Kittel-Kasuya-Yosida interlayer coupling—placed on top of a piezoelectric acoustic waveguide. In this work, we study in detail a more practical and technologically simpler system based on an FM bilayer, where layers are coupled by only dipole-dipole interaction, and having noncollinear magnetizations of the FM layers. A weak in-plane anisotropy with noncollinear easy axes in the layers is shown to be the only essential factor for the realization of strongly nonreciprocal propagation of a hybridized SAW/SW. We formulate requirements for the relative orientation of the layer’s magnetizations and wave propagation direction necessary to realize an efficient SAW isolator, and demonstrate examples of SAW transmission characteristics which prove the possibility of achieving an isolation exceeding 50 dB for a submillimeter-long FM bilayer with insertion losses of just a few decibels more than those of a pure SAW device. In addition to relative fabrication simplicity, the proposed magnetoelastic heterostructure exhibits a reasonable robustness in respect to deviations in the anisotropy axes and/or bias field directions—an important benefit for device mass production. Published by the American Physical Society 2024

Detection of natural pulse waves (PWs) in 3D using high frame rate imaging for anisotropy characterization

IntroductionNumerous studies have shown that natural mechanical waves have the potential to assess the elastic properties of the myocardium. When the Aortic and Mitral valves close, a shear wave is produced, which provides insights into tissue stiffness. In addition, the Atrial Kick (AK) generates a wave similar to Pulse Waves (PWs) in arteries, providing another way to assess tissue stiffness. However, tissue anisotropy can also impact PW propagation, which is currently underexplored. This study aims to address this gap by investigating the impact of anisotropy on PW propagation in a phantom.MethodsTube phantoms were created using Polyvinyl Alcohol (PVA). Anisotropy was induced between two sets of two freeze-thaw cycles by stretching and twisting the material. The study first tests and validates the procedure of making helical anisotropic vessel phantoms using the shear wave imaging technique (by estimating the shear wave speed at different probe angles). Using plane wave ultrasound tomography synchronized with a peristaltic pump, 3D high frame rate imaging is performed and used to detect the 3D propagation pattern of PW for each manufactured vessel phantom. Finally, the study attempts to extract the anisotropic coefficient of the vessel using pulse wave propagation angle.ResultsThe Shear wave imaging results obtained for the isotropic vessel show very similar values for each probe angle. On the contrary, the results obtained for the axial anisotropy vessel show a region with a higher shear wave speed at about 0°, corresponding to the long axis of the vessel. Finally, the results obtained for the helical anisotropy depicted increasing shear wave velocity value from −20° to 20°. For the axial phantom, the wavefront of the pulse wave is perpendicular to the long axis of the vessel, while oriented for the helical anisotropic vessels phantom. The pulse wave propagation angle increased with the number of twists made during the vessel manufacturing.DiscussionThe results show that anisotropy can be induced in PVA vessel phantoms by stretching and twisting the material in freeze-thaw cycles. The findings also suggest that vessel anisotropy affects pulse wave propagation angles. Estimating the pulse wave propagation angle may be interesting in characterizing tissue anisotropy in organs where such waves are naturally present.

Enhancement of Effective Energy Barrier and Magnetic Blocking Temperature in Tetraoxolene Radical Coupled Dinuclear Dysprosium Complex.

A well-judged combination of a high axial ligand field and a bridging radical ligand in a dinuclear lanthanide complex provides a single-molecule magnet with a higher effective energy barrier for magnetic relaxation and blocking temperature compared to its non-radical analog due to significant magnetic exchange coupling between radical and Ln(III) ions. In this work, we report two chloranilate (CA) bridged dinuclear dysprosium complexes, [{(bbpen)Dy(μ2-CA)Dy(bbpen)}] (1Dy) and [{(bbpen)Dy(μ2-CA•)Dy(bbpen)}-{CoCp2}+] (2Dy), where 2Dy is the radical bridged Dy-complex obtained via the chemical reduction of bridging CA moiety (H2bbpen = N,N'-bis(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)ethylenediamine). The presence of high electronegative phenoxide moiety enhances the axial anisotropy of pseudo-square antiprismatic Dy(III) ions. The diffused spin of radical is efficiently coupled with anisotropic Dy(III) centres and decreases the quantum tunnelling of magnetization (QTM) in the magnetic relaxation process. The magnetic relaxation of 1Dy follows Orbach, Raman, and QTM processes whereas for 2Dy it follows Orbach and Raman Processes. Due to less involvement of the QTM relaxation process, 2Dy shows a higher thermal energy barrier (Ueff = 700 K) and a high blocking temperature (6.7 K), compared to its non-radical analog. Remarkably, the radical coupled 2Dy complex shows the highest energy barrier among the radical bridged Dy(III)-based SMMs to date.

Tilted Spins in Chains of Molecular Switches on Pb(100).

A complex based on a Ni(II) porphyrin exhibiting spin crossover on Ag(111) is studied on Pb(100) by scanning tunneling microscopy at 0.3 K. Strong molecular interactions between the phenyl and pentafluorophenyl moieties lead to the formation of molecular chains and cause a faceting of the substrate surface. The chains are located along double and multiple substrate steps that deviate from high-symmetry directions. Tunneling spectroscopy reveals spin-flip excitations of an S = 1 system. Measurements in high magnetic fields are used to identify a tilt of the complex and its hard anisotropy axis with respect to the surface normal. Electron injection into the substrate near the molecular rows induces a transition to a state with larger inelastic cross section, leaving the spin state unchanged.

Anisotropic structure at shallow depths across the Japan Trench

Anisotropic structures within the crust are frequently perceived to originate from stress-induced cracks, which have been mainly estimated on land through different wave speeds of orthogonally polarized S waves propagating in the anisotropic media. However, such estimations of crustal anisotropic structures in ocean areas, particularly for subduction zones around trenches, have not been investigated in detail due to the lack of long-term ocean bottom observations. In this study, we used ocean bottom seismometers of a permanent network deployed across the Japan Trench and the southern part of the Kuril Trench and applied the shear-wave splitting analysis to P-to-s converted waves extracted by receiver function analyses using teleseismic events. We estimated the anisotropic structures in marine sediments and oceanic crust for the incoming Pacific Plate and marine sediments for the overriding North American Plate. The obtained fast polarization directions for the incoming plate are mainly oriented to be parallel to the trench axis for the marine sediment and oceanic crust, which are formed by normal faults and cracks due to the upward plate bending in the outer-rise region, whereas results for marine sediments at the northern part of the Japan Trench are obliquely aligned to the trench axis. The oblique direction is consistent with the magnetic lineations of the incoming plate, indicating that ancient faults within the plate, which were formed in the shallow part of the crust during the creation of the oceanic plate at the ridge, are reactivated by the plate flexure. For the overriding plate, the fast polarization directions in the northern and southern parts of the study area are nearly normal to the trench axis. The central part shows two distinct features: the fast polarization directions parallel to the trench axis and small degrees of anisotropy. These patterns may reflect crack alignments associated with the lateral variation in postseismic crustal deformation after the 2011 Tohoku-Oki earthquake. Our results suggest substantial lateral variations in the stress field at the tip of the overriding plate along the strike direction.Graphical

The Role of Rare-Earth Atoms in the Anisotropy and Antiferromagnetic Exchange Coupling at a Hybrid Metal-Organic Interface.

Magnetic anisotropy and magnetic exchange interactions are crucial parameters that characterize the hybrid metal-organic interface, a key component of an organic spintronic device. It is shown that the incorporation of 4f RE atoms to hybrid metal-organic interfaces of CuPc/REAu2 type (RE = Gd, Ho) constitutes a feasible approach toward on-demand magnetic properties and functionalities. The GdAu2 and HoAu2 substrates differ in their magnetic anisotropy behavior. Remarkably, the HoAu2 surface promotes the inherent out-of-plane anisotropy of CuPc, owing to the match between the anisotropy axis of substrate and molecule. Furthermore, the presence of RE atoms leads to a spontaneous antiferromagnetic exchange coupling at the interface, induced by the 3d-4f superexchange interaction between the unpaired 3d electron of CuPc and the 4f electrons of the RE atoms. It is shown that 4f RE atoms with unquenched quantum orbital momentum ( ), as it is the case of Ho, induce an anisotropic interfacial exchangecoupling.

Integrating Polyoxometalate into Dy(III)-based Single-molecule Magnets with Pentagonal Bipyramidal Symmetry.

Polyoxometalates (POMs) with various coordination fashions are versatile ligands for constructing single-ion magnets (SIMs), but enforcing POM-SIMs with a specific geometry remains a synthetic challenge. Herein, we synthesized a POM-cocrystallized DyIII-SIM [Dy(OPPh3)4(H2O)3][PW12O40]·4EtOH (1Dy) and a POM-ligated DyIII-SIM [{Dy(OPPh3)3(H2O)3}{PW12O40}]·Ph3PO·H2O (2Dy) with pentagonal bipyramidal local coordination geometry. Magnetic measurements indicate that 1Dy displays field-induced single-molecule magnet (SMM) behavior and the relaxation is dominated by under-barrier processes. 2Dy exhibits spin-lattice relaxation at a broader temperature region with a reversal barrier over 300 K. Magneto-structural analysis reveals that the enhancement of SMM behavior originated from the equatorial replacement of Ph3PO by POM, which strengthens the axial anisotropy in 2Dy. Luminescent experiments indicate that the characteristic DyIII emissions of 1Dy are covered up by the strong π-π* emission of Ph3PO at low-temperature regions. As for 2Dy, partial DyIII emission persists thanks to the antenna effect between DyIII and POM.

Hydrodynamics of a disk in a thin film of weakly nematic fluid subject to linear friction

To make progress towards the development of a theory on the motion of inclusions in thin structured films and membranes, we here consider as an initial step a circular disk in a two-dimensional, uniaxially anisotropic fluid layer. We assume overdamped dynamics, incompressibility of the fluid, and global alignment of the axis of anisotropy. Motion within this layer is affected by additional linear friction with the environment, for instance, a supporting substrate. We investigate the induced flows in the fluid when the disk is translated parallel or perpendicular to the direction of anisotropy. Moreover, expressions for corresponding mobilities and resistance coefficients of the disk are derived. Our results are obtained within the framework of a perturbative expansion in the parameters that quantify the anisotropy of the fluid. Good agreement is found for moderate anisotropy when compared to associated results from finite-element simulations. At pronounced anisotropy, the induced flow fields are still predicted qualitatively correctly by the perturbative theory, although quantitative deviations arise. We hope to stimulate with our investigations corresponding experimental analyses, for example, concerning fluid flows in anisotropic thin films on uniaxially rubbed supporting substrates.

Simulation of magnetization process and Faraday effect of magnetic bilayer films

Abstract We described ferromagnetic film and bilayer films composed of two ferromagnetic layers coupled through antiferromagnetic interfacial interaction by classical Heisenberg model and simulated their magnetization state, magnetic permeability, and Faraday effect at zero and finite temperature by using the Landau–Lifshitz–Gilbert (LLG) equation. The results indicate that in a microwave field with positive circular polarization, the ferromagnetic film has one resonance peak while the bilayer film has two resonance peaks. However, the resonance peak disappears in ferromagnetic film, and only one resonance peak emerges in bilayer film in the negative circularly polarized microwave field. When the microwave field’s frequency exceeds the film’s resonance frequency, the Faraday rotation angle of the ferromagnetic film is the greatest, and it decreases when the thickness of the two halves of the bilayer is reduced. When the microwave field’s frequency remains constant, the Faraday rotation angle fluctuates with temperature in the same manner as spontaneous magnetization does. When a DC magnetic field is applied in the direction of the anisotropic axis of the film, the Faraday rotation angle varies with the DC magnetic field and shows a similar shape of the hysteresis loop.

New Anisotropic Cosmic-Ray Enhancement (ACRE) Event on 5 November 2023 Due to Complex Heliospheric Conditions

The variability of galactic cosmic rays near Earth is nearly isotropic and driven by large-scale heliospheric modulation but rarely can very local anisotropic events be observed in low-energy cosmic rays. These anisotropic cosmic-ray enhancement (ACRE) events are related to interplanetary transients. Until now, two such events have been known. Here, we report the discovery of the third ACRE event observed as an increase of up to 6.4% in count rates of high- and midlatitude neutron monitors between ca. 09 – 14 UT on 5 November 2023 followed by a moderate Forbush decrease and a strong geomagnetic storm. This is the first known observation of ACRE in the midrigidity range of up to 8 GV. The anisotropy axis of ACRE was in the nearly anti-Sun direction. Modeling of the geomagnetic conditions implies that the observed increase was not caused by a storm-induced weakening of the geomagnetic shielding. As suggested by a detailed analysis and qualitative modeling using the EUHFORIA model, the ACRE event was likely produced by the scattering of cosmic rays on an intense interplanetary flux rope propagating north of the Earth and causing a glancing encounter. The forthcoming Forbush decrease was caused by an interplanetary coronal mass ejection that hit Earth centrally. A comprehensive analysis of the ACRE and complex heliospheric conditions is presented. However, a full quantitative modeling of such a complex event is not possible even with the most advanced models and calls for further developments.

Coercive Fields Exceeding 30 T in the Mixed-Valence Single-Molecule Magnet (CpiPr5)2Ho2I3.

Mixed-valence dilanthanide complexes of the type (CpiPr5)2Ln2I3 (CpiPr5 = pentaisopropylcyclopentadienyl; Ln = Gd, Tb, Dy) featuring a direct Ln-Ln σ-bonding interaction have been shown to exhibit well-isolated high-spin ground states and, in the case of the Tb and Dy variants, a strong axial magnetic anisotropy that gives rise to a large magnetic coercivity. Here, we report the synthesis and characterization of two new mixed-valence dilanthanide compounds in this series, (CpiPr5)2Ln2I3 (1-Ln; Ln = Ho, Er). Both compounds feature a Ln-Ln bonding interaction, the first such interaction in any molecular compounds of Ho or Er. Like the Tb and Dy congeners, both complexes exhibit high-spin ground states arising from strong spin-spin coupling between the lanthanide 4f electrons and a single σ-type lanthanide-lanthanide bonding electron. Beyond these similarities, however, the magnetic properties of the two compounds diverge. In particular, 1-Er does not exhibit observable magnetic blocking or slow magnetic relaxation, while 1-Ho exhibits magnetic blocking below 28 K, which is the highest temperature among Ho-based single-molecule magnets, and a spin reversal barrier of 556(4) cm-1. Additionally, variable-field magnetization data collected for 1-Ho reveal a coercive field of greater than 32 T below 8 K, more than 6-fold higher than observed for the bulk magnets SmCo5 and Nd2Fe14B, and the highest coercive field reported to date for any single-molecule magnet or molecule-based magnetic material. Multiconfigurational calculations, supported by far-infrared magnetospectroscopy data, reveal that the stark differences in magnetic properties of 1-Ho and 1-Er arise from differences in the local magnetic anisotropy of the lanthanide centers.

Heteroleptic Ni(II) complexes containing chelating benzoato ligand with sharp bite angle: syntheses, crystal structures, and magnetism

From the system Ni(OH)2 – 4,4′-dmbpy – HBz (HBz = benzoic acid; 4,4′-dmbpy = 4,4′-dimethyl-2,2′-bipyridine) under various experimental conditions three complexes were isolated, namely light blue [Ni(4,4′-dmbpy)(Bz)2(H2O)] (1), violet [Ni(4,4′-dmbpy)2(Bz)](Bz)·2HBz (2), and pink microcrystalline product [Ni(4,4′-dmbpy)3](Bz)2·3.5H2O (3). The crystal structures of 1 and 2 were determined, that of 2 at two temperatures (100 and 277 K). The crystal structure of 1 is formed of neutral molecules, in which the Ni(II) central atom is hexa-coordinated by one chelating diamine ligand, one chelating and one monodentate benzoato ligands, and one aqua ligand. The crystal structure of 2 is ionic and in the complex cation the Ni(II) atom is hexa-coordinated by two chelating diamine ligands and one chelating benzoato ligand. The positive charge of the complex cation is counterbalanced by a benzoate anion, and two additional molecules of benzoic acid are present in the asymmetric unit. Magnetic properties of 1 and 2 were studied in the temperature range 1.8 – 300 K and confirmed strong axial single-ion anisotropy (D/kB = -7.78 K for 1, D/kB = -6.52 K for 2) of the Ni(II) ions in line with the deformed coordination spheres of the central atoms. In addition, antiferromagnetic spin dimers of Ni(II) ions mediated by hydrogen bonds are present in 1 with exchange coupling J/kB = -2.19 K. The obtained experimental results were supported by ab initio and DFT calculations.

Spin-orbit torque-driven domain wall motion in the absence of Dzyaloshinskii-Moriya interactions

The fine structure and dynamics of magnetic domain walls in ultrathin films with perpendicular magnetization, in the presence of a secondary anisotropy, is analysed owing to micromagnetics. Two cases are considered, a cubic anisotropy typical for (111) oriented garnet epitaxial films, and an orthorhombic anisotropy as found in, e.g., Co/W(110) films. The statics is solved first, showing that, in general, domain walls are not of the pure Bloch type. The dynamics under the spin Hall effect induced by a current flowing in an adjacent layer is then monitored. Finite and non-negligible domain wall velocities are predicted in both cases, in the absence of Dzyaloshinskii-Moriya interactions, with distinct behaviours regarding the current density and its orientation with respect to the secondary anisotropy axes. The relevance of these results to recent reports of current-driven domain wall dynamics in insulating ultrathin garnet films, capped with platinum, is discussed.

Constraints on Bianchi-I type universe with SH0ES anchored Pantheon+ SNIa data

We study the Bianchi-I cosmological model motivated by signals of statistical isotropy violation seen in cosmic microwave background (CMB) observations and others. To that end, we consider various kinds of anisotropic matter that source anisotropy in our model, specifically Cosmic strings, Magnetic fields, Domain walls and Lorentz violation generated magnetic fields. These anisotropic matter sources, taking one at a time, are studied for their co-evolution with standard model (isotropic) sources viz., dust-like (dark/normal) matter, and dark energy modelled as cosmological constant. We constrain the Hubble parameter, density fractions of anisotropic matter, cold dark matter (CDM), and dark energy (Λ) in a Bianchi-I universe with planar symmetry i.e., which has a global ellipsoidal geometry, and try to find signatures of a cosmic preferred axis if any.The latest compilation of Type Ia Supernova (SNIa) data from Pantheon+SH0ES collaboration is used in our analysis to obtain constraints on cosmological parameters and any preferred axis for our universe.In our analysis, we found mild evidence for a cosmic preferred axis. It is interesting to note that this preferred axis lies broadly in the vicinity of other prominent cosmic anisotropy axes reported in the literature from diverse data sets.Also we find some evidence for non-zero (negative) cosmic shear and eccentricity that characterize different expansion rates in different directions and deviation from an isotropic scale factor respectively.The energy density fractions of two of the sources considered are found to be non-zero at a2σ confidence level.To be more conclusive, we require more SNIa host galaxy data for tighter constraints on distance and absolute magnitude calibration which are expected to be available from the future JWST observations and others.

Optimizing preparation conditions and characterizing for CoxPt1-x alloy cylindrical nanowires fabricated by electrodeposition on nanoporous polycarbonate membranes

This study investigated the influence of the preparation conditions on the Co composition, crystal structure, and magnetic and electric conduction properties of cylindrical CoxPt1-x alloy nanowires having 0.08 ≤ x ≤ 0.90, which were electrodeposited on nanoporous templates. When prepared with an optimal concentration ratio of Co and Pt aqueous solutions and electrodeposition potentials, highly oriented crystal structures of fcc Co-Pt (111) was obtained in CoxPt1-x nanowires (0.58 ≤ x ≤ 0.80). Nanowires with (111)-oriented fcc Co-Pt crystals exhibited average lengths and diameters of 5.8–10.8 μm and 130 nm, respectively, and showed an easy axis of magnetocrystalline anisotropy in the longitudinal direction of the nanowire. These results indicate a direct correlation between the crystal structure and magnetic properties. The concentration ratio of Co and Pt in the electrolytes and the electrodeposition potentials for fabricating CoxPt1-x alloy nanowires using the diluted Co composition (0.08 ≤ x ≤ 0.25) were determined. These nanowires were polycrystalline and had a small saturation magnetization. Furthermore, the anisotropic magnetoresistance (AMR) for a single CoxPt1-x nanowire was measured to estimate the domain wall (DW) width in the single CoxPt1-x nanowire. The value of the magnetoresistance (MR) ratio for the single nanowire (0.58 ≤ x ≤ 0.80) with highly (111)-oriented fcc Co-Pt crystal was 0.082–0.23 %, and the estimated value of DW width was 17–25 nm. These findings provide valuable information for constructing three-dimensional magnetic memory devices.

Field-induced slow magnetic relaxation in a distorted trigonal prismatic cobalt(II) complex

Two mononuclear complexes [M(DQ)(OTf)](OTf)·H2O (M = Co for 1 and Fe for 2, DQ = 6,6′′-di(quinolin-8-yl)-4′-phenyl-2,2′:6′,2′′-terpyridine) with distorted trigonal prismatic geometry have been synthesized and characterized. Crystal structures show that the 3d ions are helically coordinated by a pentadentate DQ and encapsulated by a terminal OTf− anion, resulting in [MN5O] coordination environments. Magnetic measurements and ab initio calculation indicate that complex 1 displays easy axis anisotropy and exhibits field-induced slow magnetic relaxation which is dominated by Raman and direct processes. For 2, no slow magnetic relaxation had been recorded owing to the significant fast quantum tunneling of magnetization.