Average δ18O Values Research Articles

Groundwater evolutions in the semi-arid aquifers of Dodoma City, Tanzania using stable isotopes of water and hydrogeological facies

ABSTRACT The recent influx of people into Dodoma City, Tanzania has greatly increased pressure on freshwater sources. To manage such stressed water resources, an assessment of evolutions of various groundwater masses using stable isotopes (SI) and hydrogeochemical facies was performed. The major groundwater types were found to be NaHCO3 and NaCl. The groundwater in some areas was polluted with up to 223.7 ppm of nitrate-NO3-. The majority of water masses were found to be of meteoric origin and deep aquifers were mostly replenished by heavy rains, which are more depleted in SI (δ2H and δ18O). Further, δ2H and δ18O from Hombolo Dam (HD) and Matumbulu Dam (MD) were highly enriched by evaporation, with average δ2H and δ18O values, of 5.76 & 39.69 and 2.37 & 16.34 ‰ compared to average rain values of −5.52 and −32.99‰, respectively. The contributions of highly enriched HD and MD waters to respective shallow groundwater systems were 57.52 and 22.2%. Yet, it was found that 75.4% of groundwater in the Hombolo suburb originates from the Makutupora aquifer, and this is the first time the contribution is quantified. Generally, this study offers a robust tool for adapting a local groundwater management strategy impacted by climate change, pollution, and overabstraction.

Spatial ecology of moose in Sweden: Combined Sr-O-C isotope analyses of bone and antler.

The study of spatial (paleo)ecology in mammals is critical to understand how animals adapt to and exploit their environment. In this work we analysed the 87Sr/86Sr, δ18O and δ13C isotope composition of 65 moose bone and antler samples from Sweden from wild-shot individuals dated between 1800 and 1994 to study moose mobility and feeding behaviour for (paleo)ecological applications. Sr data were compared with isoscapes of the Scandinavian region, built ad-hoc during this study, to understand how moose utilise the landscape in Northern Europe. The 87Sr/86Sr isoscape was developed using a machine-learning approach with external geo-environmental predictors and literature data. Similarly, a δ18O isoscape, obtained from average annual precipitation δ18O values, was employed to highlight differences in the isotope composition of the local environment vs. bone/antler. Overall, 82% of the moose samples were compatible with the likely local isotope composition (n = 53), suggesting that they were shot not far from their year-round dwelling area. 'Local' samples were used to calibrate the two isoscapes, to improve the prediction of provenance for the presumably 'non-local' individuals. For the latter (n = 12, of which two are antlers and ten are bones), the probability of geographic origin was estimated using a Bayesian approach by combining the two isoscapes. Interestingly, two of these samples (one antler and one bone) seem to come from areas more than 250 km away from the place where the animals were hunted, indicating a possible remarkable intra-annual mobility. Finally, the δ13C data were compared with the forest cover of Sweden and ultimately used to understand the dietary preference of moose. We interpreted a difference in δ13C values of antlers (13C-enriched) and bones (13C-depleted) as a joint effect of seasonal variations in moose diet and, possibly, physiological stresses during winter-time, i.e., increased consumption of endogenous 13C-depleted lipids.

VARIATIONS OF δ18О AND δ2H VALUES OF PRECIPITATION IN MOSCOW FROM 2017 TO 2019

To reveal variations in the iso topic composition of O and H in the atmospheric precipitation in Moscow and the processes influencing the isotope composition, all events of precipitation in 2017-2019 were sampled at the Meteorological Observatory of the Moscow State University: 158 samples in 2017, 119 samples in 2018 and 143 samples in 2019. The study is a prolongation of continuous measurements of the isotope composition of precipitation, started by authors in 2014. The study of the isotope composition of precipitation at the MSU Meteorological Observatory was supported by the IAEA and became a part of the Global Network of Isotopes in Precipitation (GNIP) database. It has been found that the intra-annual variability of the isotop e composition of precipitation has a pronounced seasonality. The most isotopically heavy precipitation falls from May to August, and the most isotop ically light precipitation at December-February, mainly due to seasonal air temperature variations. The ratio of the average monthly δ18O values in precipitation and air temperature for the study period varied from 0.34 to 0.39‰/°C, which is consistent with the previously obtained data for precipitation in Moscow. The δ2H-δ18O ratio in precipitation was clos e to that of the Global Meteoric Water Line, pointing to the equilibrium conditions during precipitation formation. It was established that in the summer months isotopic composition is significantly influenced by undercloud evaporation. The deuterium excess va lues in precipitation are not markedly seasonal; however, lower dexc values (below the 3-year average of 11‰) are typical for the summer months (July-August). It is most likely due to undercloud evaporation in conditions of low relative humidity and high air temperatures. Higher dexc values (above 11‰) prevailed from October to April.

Chinese stalagmite δ18O records reveal the diverse moisture trajectories during the middle to late last glacial period

Abstract Based on 30 high-resolution U-Th dating controls, we reconstruct stalagmite δ18O records from 45 to 15 thousand years ago (ka B.P., before AD 1950) from the Shizhu Cave, which is located in southwestern China under the influence of both the Indian Summer Monsoon (ISM) and the East Asian Summer Monsoon (EASM). By integrating with the other stalagmite δ18O records in Asia during the middle to late last glacial, our results reveal two main moisture trajectories: one from the Indian Ocean, through the Shizhu Cave towards central China, and the other from the Pacific Ocean to central and northern China. The systematic decrease of the average values of stalagmite δ18O records from oceans to inland China reveals a spatial pattern of water vapour fractionation and moisture trajectory during the middle to late last glacial. In contrast, the variation amplitude, which is defined as the departures apart from the background δ18O records during Heinrich stadials 1 to 4 (HS1–HS4), show an increasing trend from the coastal oceans to mid-latitude inland China, presenting a ‘coastal-inland’ pattern, which can be interpreted by the enhanced East Asian Winter Monsoon (EAWM) and the weakened EASM. More specifically, the enriched stalagmite δ18O records in the EASM region during HS1 to HS4 are caused by the decreased summer rainfall amount or/and the increased proportion of summer moisture resources from the Pacific Ocean. These new observations deepen our understanding of the complicated stalagmite δ18O records in the EASM region.

Determining the source water and active root depth of woody plants using a deuterium tracer at a Savannah site in northern Stampriet Basin, Namibia

Woody plants play a significant role in the global water cycle through water uptake by roots and evapotranspiration. A deuterium tracer was used to assess the active root depths for Salvia mellifera and Boscia albitrunca in the Ebenhaezer area (western Namibia). The tracer was inserted at different soil depths in December 2016. Xylem cores were obtained using an increment borer, and transpired water was collected using transpiration bags zipped around the plants’ leaves. Groundwater was collected from boreholes. Soil samples were collected after the rainy season using a hand auger. Xylem and soil water were extracted using a cryogenic vacuum extraction method and analysed for stable water isotopes. Only one S. mellifera transpiration sample showed a high deuterium content (516‰) where the tracer was inserted at 2.5-m soil depth. Elevated deuterium contents were observed in two S. mellifera xylem samples; tracer had been applied at 2.5 and 3 m depth (yielding 35 and 31‰ deuterium, respectively), which constitutes a possible active-root depth range for S. mellifera. At the end of the study period (May 2017), the average δ18O value for B. albitrunca xylem samples was similar to that of groundwater. The δ18O value for S. mellifera was between that of soil water and groundwater, indicating that this species uses groundwater and soil water available for groundwater recharge. Determination of the active root depth and source water for these species would help improve hydrological modelling by incorporating the influence of woody plants on groundwater recharge.

Tracing fluid infiltration into oceanic crust up to ultra-high-pressure conditions

Fluid–rock interaction within the altered oceanic crust and across the slab–mantle boundary during subduction facilitates element transfer, but the dynamics of fluid transport and fluid–rock exchange during upward fluid migration are still unclear. A study of metamorphic fluid–rock interaction within a section of subducted oceanic crust was carried out on eclogites and metasediments of the ultra-high-pressure Lago di Cignana Unit (NW Italian Alps). The P–T modeling of a quartzschist shows that garnet grew during the prograde and sporadically during the retrograde path and that phengite mainly records the peak to retrograde conditions. Microscale geochemical analysis of garnets has revealed a systematic evolution of oxygen isotopic composition with garnet major element zonation, with extreme within-sample core–rim variations in δ18O between 18 and 4‰ providing evidence for external fluid influx. Garnet in eclogites and calcschists, as well as garnet cores in quartz-rich lithologies, shows normal compositional zoning, as expected for prograde garnet growth, and a relatively constant oxygen isotopic composition. The outer garnet growth zones within a few metasediments show reverse or discontinuous zoning and progressively lower δ18O. Despite major element zoning, the isotopic composition of mica is homogeneous across chemical zoning in one eclogite and one quartzschist, but shows 6‰ variability in another quartzschist. In the underlying Zermatt–Saas serpentinites, antigorite from nine serpentinite samples shows some variation in δ18O, with average δ18O values for individual samples ranging from 1 to 6‰. These results provide evidence for two main stages of external fluid infiltration: (i) fluids from the dehydration of mafic lithologies entered the sequence at peak conditions around 3 GPa, as indicated by the oxygen composition of intermediate zones of mica and garnet, and (ii) low δ18O fluids from serpentinites infiltrated parts of the sedimentary package during exhumation prior to 1.5 GPa, as recorded by the 4‰ garnet outer rims. Samples recording external fluid infiltration are concentrated in the lower part of the sequence, indicating channelized fluid flow, suggesting focused fluid infiltration due to permeability contrasts between metasedimentary and eclogitic lithologies. Channelized fluid flow in the ultra-high-pressure metasediments of Lago di Cignana has not resulted in systematic decarbonation of the metasediments.

Exploring the Deuterium Excess of Cretaceous Arctic Paleoprecipitation Using Stable Isotope Composition of Clay Minerals from the Prince Creek Formation (Maastrichtian) in Northern Alaska

We report estimated stable isotope compositions of Artic paleoprecipitation using phyllosilicates sampled from three paleosols and two bentonites in the Prince Creek Formation (Maastrichtian) in northern Alaska. Previous studies reported a deuterium excess in estimates of Arctic paleoprecipitation from the Late Cretaceous by combining hydrogen and oxygen proxy sources, including pedogenic minerals, dinosaurian tooth enamel phosphates, pedogenic siderites, and n-alkane biomarkers. The new dataset produced in this study removes uncertainty on possible explanations (photosynthetic and transpiration) of the deuterium excess by producing stable hydrogen and oxygen isotopic signatures from the same source material. The δD of the phyllosilicates range from −171‰ to −72‰ VSMOW and δ18O ranges from 5.0 to 11.8‰ VSMOW. By assuming a MAT of 6.3 °C and calculating uniquely derived fractionation equations for each phyllosilicate, we report estimated isotopic composition of Late Cretaceous paleoprecipitation with an average δD value of −133‰ VSMOW, corresponding to an average δ18O value of −20.3‰ VSMOW. The estimates of Late Cretaceous paleoprecipitation do not intersect the Global Meteoric Water Line and reveal a reported deuterium excess ranging from 7 to 46 per mil. These results confirm the presence of a deuterium excess in Late Cretaceous Arctic paleoprecipitation and provide new insight to assessing possible explanations for this phenomenon.

A High-δ18O Mantle Source for the 2.06 Ga Phalaborwa Igneous Complex, South Africa?

ABSTRACTThe 2060 ± 2 Ma Phalaborwa Complex is a pipe-like, ultramafic to carbonatite intrusion formed from multiple magma pulses. The complex is made up of a main pipe consisting of clinopyroxenites, ultramafic pegmatoids, carbonatites and foskorite (olivine-apatite-magnetite-calcite assemblage), surrounded by many smaller syenite plugs. The range in mineral δ18O values for all rock types and minerals analysed in the Phalaborwa Complex is 2.24 to 18.3‰. However, 24 analyses of the most abundant and robust mineral, diopside, all have δ18O values between 6.5 and 8.1‰. The δ18O values of baddeleyite, olivine, diopside, magnetite, apatite and aegirine are thought to be magmatic. Most mineral pairs have differences in δ18O values that are consistent with magmatic equilibrium at high temperatures down to closure temperature. Alkali feldspar and phlogopite have more variable δ18O values, and both minerals may have undergone subsolidus O exchange. The δD values for petrographically fresh Phalaborwa Complex phlogopite range from −79 to −48‰ with a mean of −64 ± 9‰ (1σ, n = 19). The phlogopite δD values are consistent with subduction-related magmatic water. Despite petrographic evidence for fluid–rock interaction in the carbonatite–foskorite rocks, the carbonatite δ13C and δ18O range (δ18O, 8.13 to 12.00‰; δ13C, −3.19 to −5.60‰) overlaps with the unaltered, primary igneous carbonatite field.Magma δ18O values estimated from silicate and oxide minerals are mostly higher than normal mantle magmas (pyroxenites, ~7.6‰; foskorite, 7.2‰). The δ18O value of syenite magma estimated from aegirine is 7.8 ± 0.9‰ (1σ, n = 8), in equilibrium with whole-rock syenite δ18O values (8.7 ± 0.4‰, 1σ, n = 5). Local basement rocks have average bulk δ18O values of 8.6‰, and realistic proportions of assimilation by a mantle-derived magma (δ18O, 5.7‰) could not have produced the δ18O values in the pyroxenites or foskorites. Instead, it is proposed that the high-δ18O values of Phalaborwa Complex magmas reflect that of the mantle source. High δ18O values are also a feature of the Rustenburg Layered Suite of the Bushveld Complex (2060 to 2055 Ma), which may have had a similar high-δ18O mantle source. The higher δ18O values of the satellite syenites are consistent with an origin by partial melting of metasomatised country rock.

Temporal variability of precipitation isotopes in Damascus, Syria — implications for regional climate change

Records of stable isotopes (2H and 18O), deuterium excess (d-excess) and tritium (3H) values in precipitation (P) during 1990–2022, together with long-term time series (1919–2022) of air temperature (T) and P-amount values at the Damascus station, were analysed to explore the seasonal and annual variability patterns of those parameters in P and assess the vulnerability to climate change in this area. Variation of the annual average air T values over the period 1919–1969 shows an increase gradient of ≈ + 0.1 °C/decade. However, a remarkable much higher gradient (+ 0.64 °C/decade) is calculated for the period 1990–2022. The average P-amount value calculated for the last three decades (≈185 mm) was lower by ≈28 mm, compared to the value (≈213 mm), relative to the reference period (1919–1969). This significant decline in the annual P-amount value by ≈11–13%, accompanied by an annual heating of 0.2–0.6 °C/decade in the annual air T, is likely the result of the climate change affecting this area. The linear relationships between annual average δ18O and annual average δ2H values versus time over the period 1990–2019 indicate increased gradients in both stable isotopes (≈0.3–0.5‰ and ≈1.1–3.2‰ per decade for δ18O and δ2H, respectively), accompanied with a decrease gradient of ≈0.9–1.1‰ per decade in d-excess values. Variability of annual 3H concentrations towards low levels (< 6 TU) during the later years strongly suggests the return back towards the cosmogenic production of this radioisotope in the upper atmosphere. Information gained from this work would offer new insights to improve the understanding of the temporal variability of P isotopes and assess the risks associated with climate change on the natural water resources in the Eastern Mediterranean region.

Environmental isotope constraints and hydrogeochemical evolution of groundwater in the semi-arid national capital environs of Delhi, India

Changes in hydrological regimes due to rapid urbanization and increasing anthropogenic stress on hydro-geological system creating an alarming condition for the management of ground water resources. Isotope and hydro-geochemical integrated approach has been used to determine the processes governing chemical composition of groundwater and the mechanism influencing the chemical composition of groundwater in National Capital Region (NCR), Delhi. The chemical evolution of groundwater has studied by using flow direction, hydro-chemical facies, bivariate plots of ionic ratios and saturation index. Stable isotopes and tritium are used to understand the recharge mechanism. Pollution index of groundwater (PIG) is also used to check the level of contamination in the groundwater. In total, 57 water samples were collected for water chemistry, 36 water samples for environmental isotopes and 13 samples for tritium measurement. The dominant water type is Ca-Mg-HCO3 and mixed water type. The dominant cation are Ca2+ > Na+ > Mg2+ > K+ and dominant anions are HCO3− > Cl− > SO42− > NO3−. The bicarbonate type water is dominant in quartzite, implies rapid and direct recharge through fracture and joints. Ionic ratios and saturation indices show that major processes controlling groundwater evolution are silicate hydrolysis and reverse cation exchange in the quartzite. Average values of δ2H and δ18O are −43.66 ‰ and −6.28‰. Stable isotopic ratio of groundwater of alluvium area falling on evaporation line, due to the prevailing semi-arid and arid climatic conditions, evaporation is the predominant factor affecting the chemistry of groundwater. The stable isotope shows that the groundwater in the quartzite is mostly meteoric in origin and acting as a recharge area for the nearby alluvium aquifer. Tritium results reveal that groundwater occurring in quartzite and alluvium aquifer in western parts are older than that of groundwater occurring in alluvium aquifer in the eastern parts.13% of groundwater samples are falling in very high pollution zone mainly occurring in alluvium aquifer that lies in the Eastern parts. It is inferred that alluvium aquifer (low lying) is having greater impact of anthropogenic activity than quartzite aquifer (high land).

Isotopic compositions (δD, δ18O) and end-member mixing for the control interface in a complex tidal region

Identifying the mixing processes of waters and currents in tidal reach is an important aspect of environmental management to protect freshwater resources and prevent water pollution. In this study, three field investigations conducted in a typical tidal reach in August, November and the following April focused on two isotopes (δD and δ18O) and salinity. A salinity-isotope conservative mixing model was established to differentiate water flows of the important control interface (CI) from freshwater, transition zone and saltwater end-members. Results suggested that the average δD and δ18O values during the ebb and flood tides depleted from August to November, then enriched significantly in the following April and were even higher than those in August. The δD and δ18O values in the saltwater zone enriched markedly compared with those in freshwater zone and transition zone due to the stronger evaporation occurring in the saltwater zone. Based on the revised model, the average contributions of freshwater end-member, transition zone end-member and saltwater end-member in three months were, respectively, 51.50 %, 36.93 % and 11.57 %. However, the contributions of freshwater and transition zones in April end-member were equivalent (47.45 % vs 44.31 %). Meanwhile the largest contribution of saltwater end-member was 20.56 % and occurred in August. The proportions of three end-members that contributed to CI changed with different evaporation scenarios and moisture sources of precipitation. Our research provides important information that furthers our understanding of the isotopes and their applications to environmental management in estuarine regions.

Equilibrium Fractionation of Oxygen Isotopes in the U3O8-Atmospheric Oxygen System.

As a major component in the nuclear fuel cycle, octoxide uranium is subjected to intensive nuclear forensics research. Scientific efforts have been mainly dedicated to determine signatures, allowing for clear and distinct attribution. The oxygen isotopic composition of octoxide uranium, acquired during the fabrication process of the nuclear fuel, might serve as a signature. Hence, understanding the factors governing the final oxygen isotopic composition and the chemical systems in which U3O8 was produced may develop a new fingerprint concerning the history of the material and/or the process to which it was subjected. This research determines the fractionation of oxygen isotopes at different temperatures relevant to the nuclear fuel cycle in the system of U3O8 and atmospheric O2. We avoid the retrograde isotope effect at the cooling stage at the end of the fabrication process of U3O8. The system attains the isotope equilibrium at temperatures higher than 300 °C. The average δ18O values of U3O8 in equilibrium with atmospheric oxygen have been found to span over a wide range, from -9.90‰ at 300 °C up to 18.40‰ at 800 °C. The temperature dependency of the equilibrium fractionation (1000 ln αU3O8-atm.O2 ) exhibits two distinct regions, around -33‰ between 300 °C and -500 °C and -5‰ between 700 °C and -800 °C. The sharp change coincides with the transition from a pseudo-hexagonal structure to a hexagonal structure. A depletion trend in δ18O is associated with the orthorhombic structure and may result from the uranium mass effect, which might also play a role in the depletion of 5‰ versus atmospheric oxygen at high temperatures.

NanoSIMS as an analytical tool for measuring oxygen and hydrogen isotopes in clay minerals from palaeosols: Analytical procedure and preliminary results

Oxygen and hydrogen isotope composition of neoformed clay minerals is commonly used as a palaeoclimatic proxy. Usually, sediments and rocks (including palaeosols) contain not only neoformed clay minerals, but also detrital and/or diagenetic ones. Together with the usually small size (micro- or nanometric) of the clay minerals in these materials, this can generate difficulties during isotopic analyses by conventional spectrometry. To avoid this problem, we used nanoscale secondary ion mass spectrometry (NanoSIMS) to analyse neoformed clay minerals included in palaeosol levels in early Barremian continental profiles located in NE Spain. The bottom levels of the profiles are rich in kaolinite, whereas the top levels contain smectite (beidellite-type). The isotopic compositions of pure powder standards of kaolinite and beidellite were measured in bulk by conventional mass spectrometry to obtain reference values for calibrating the instrumental mass fractionation. Two common preparation techniques for geological samples were tested (thin sections and thick polished sections), revealing that thin sections are more suitable for NanoSIMS analysis due to their lower resin content. The high spatial resolution of the instrument allowed the elemental mapping of the samples, permitting the localization of the minerals of interest and the measurement of isotopic ratios at selected points (1 x 1 μm2) within the samples. The preliminary isotopic results allowed to distinguish a decrease in the average 18O/16O and D/H ratios from the kaolinite in the bottom levels to the smectite in the top levels, reflecting a change in the climatic conditions. The average δ18O and δD values obtained for kaolinite (δ18OSMOW=18±15‰; δDSMOW=-82±36‰ and δ18OSMOW=14±4‰; δDSMOW=-97±37‰) and smectite (δ18OSMOW=13±14‰; δDSMOW=-167±87‰ and δ18OSMOW=11±6‰; δDSMOW=-180±40‰;), respectively, are consistent with the crystallization of the clays in weathering conditions. Despite the uncertainties of these preliminary isotopic measures, the results obtained allowed to estimate an average temperature for kaolinite formation of 21-22°C, and of 16-17°C for smectite. Given suitable calibration using pure isotopic standards and adequate sample preparation, NanoSIMS can thus have a great applicability in palaeoclimatic studies involving the oxygen and hydrogen isotopic composition of nanometre-sized clay minerals from palaeosols samples.

Diet and habitat of late Miocene herbivore mammals from Nurpur, District Kangra, Himachal Pradesh, India

We present the stable carbon (δ13C) and oxygen (δ18O) isotopic composition of 75 serial samples (tooth enamels) from five mammalian fossil groups, which include giraffids, equids, bovids, tragulids, and suids, to reconstruct their diet and habitat. These mammalian faunas were recovered from a late Miocene Middle Siwalik succession exposed in Nurpur, Himachal Pradesh, India (8.14–5.26 Ma). The average δ13C data of the studied mammals, that is, −13.30 ± 0.71 (giraffids), −11.29 ± 0.63 (equids), −12.68 ± 0.49‰ (bovids), −12.97 ± 1.11 (tragulids), and −12.01 ± 0.47 (suids) indicates a mainly C3 diet with a minor component of C4 grass (up to 17%) and a habitat dominant by forest/woodland. The average δ18O value of giraffids (−5.83 ± 0.85) is slightly enriched as compared to other herbivore mammals, such as equids (−8.85 ± 1.71), bovids (−7.86 ± 0.62‰), tragulids (−8.26 ± 1.92), and suids (−10.65 ± 0.23). It suggests that the browsing giraffids could likely intake water from enriched 18O sources, whereas the other browsing mammals consume water from depleted 18O sources in the local ecosystem. However, the δ18O values indicate the existence of a warm, humid climate and more precipitation in the Siwalik during the late Miocene.

Clumped-isotope-derived climate trends leading up to the end-Cretaceous mass extinction in northwestern Europe

Abstract. Paleotemperature reconstructions of the end-Cretaceous interval document local and global climate trends, some driven by greenhouse gas emissions from Deccan Traps volcanism and associated feedbacks. Here, we present a new clumped-isotope-based paleotemperature record derived from fossil bivalves from the Maastrichtian type region in southeastern Netherlands and northeastern Belgium. Clumped isotope data document a mean temperature of 20.4±3.8 ∘C, consistent with other Maastrichtian temperature estimates, and an average seawater δ18O value of 0.2±0.8 ‰ VSMOW for the region during the latest Cretaceous (67.1–66.0 Ma). A notable temperature increase at ∼66.4 Ma is interpreted to be a regional manifestation of the globally defined Late Maastrichtian Warming Event, linking Deccan Traps volcanic CO2 emissions to climate change in the Maastricht region. Fluctuating seawater δ18O values coinciding with temperature changes suggest alternating influences of warm, salty southern-sourced waters and cooler, fresher northern-sourced waters from the Arctic Ocean. This new paleotemperature record contributes to the understanding of regional and global climate response to large-scale volcanism and ocean circulation changes leading up to a catastrophic mass extinction.

Isoscapes to address the regional precipitation trends in the equatorial region of Southeast Asia

This research was an attempt to understand spatiotemporal characteristics of stable isotopes in precipitation samples and their regional circulation patterns in Borneo. Two locations were selected in the Limbang River Basin (LRB). Monthly rainwater samples were collected from October 2016 to September 2017. Samples were analysed for δ2H and δ18O isotopes. Local meteoric water line (LMWL) for two locations showed common source of moisture. δ2H and δ18O composition did not show effect of temperature; but, inverse correlation with amount of rainfall was noted. The d-excess values more than 12‰ during northeast monsoon showed enhanced terrestrial recycled moisture; precipitation was inferred to be from evaporative moisture source during southwest monsoon with ∼9‰–∼15‰ d-excess. Average δ2H and δ18O values from the International Atomic Energy Association/Global Network of Isotopes in Precipitation stations of adjoining countries and LRB were considered to derive the regional meteoric water line for Southeast (SE) Asia. Comparison of LWML with global meteoric water line and available datasets from IAEA/GNIP locations showed the variation in rain events, evaporation effect, and change in source of atmospheric moisture. LRB slope value showed similar values with China, Indonesia, Myanmar, Singapore, and Thailand, indicating similar meteorological trend and moisture source. Backward air mass movement trajectory indicated that predominant air mass reaching LRB were from the Indian Ocean, Pacific Ocean, and terrestrial source. Results pointed the need of detailed and site-specific collection of rainwater samples for long period to detect climate change over water resources in SE Asia.

Hydrogen and Oxygen Isotopic Characteristics of Different Water and Indicative Significance in Baiyangdian Lake

In order to better understand the water cycle processes in Baiyangdian Lake, samples for precipitation, river water, lake water, and groundwater were collected in 2020 via the analysis of oxygen and hydrogen isotopes and the total dissolved solids. A combined approach including correlation analysis, end-member modeling, and evaporation modeling was used to identify hydrogen and oxygen isotopic characteristics of different water types and their indicative significance to evaporation, hydrodynamics, and lake-groundwater interactions. The results showed that the compositions of hydrogen and oxygen isotopes in surface water and groundwater differed from each other. The average values of δD and δ18O were the highest in samples from lake water in June, secondary for lake water in October, and the lightest in groundwater. The slope of the lake water line was lower than that of the local meteoric water line, which could be attributed to a greater evaporative enrichment in lake water. The water loss ratio was estimated to be 18.8%-42.3% in June and 2.7%-30.3% in October by applying an evaporation model using deuterium excess. Lake water isotopes exhibited highly spatial heterogeneity, which indicated that Baiyangdian Lake was a poor-mixed lake controlled by the complex hydrodynamic conditions. The values of δD and δ18O were lighter around the estuary area and higher in the district far from the estuary. Although the main water isotopes in areas such as channels had a short residence time, the spatial differences in lake water isotopes were not remarkable, which suggested that the well-mixed conditions of the lake water contributed to reducing the heterogeneity of the lake water isotopic compositions on a spatial scale. The contribution ratios of lake leakage to groundwater were 0-91.7% and varied spatially. It had a negative relationship with the buried depth of groundwater and the distance to the lakeshore. No obvious relationship was found between lake leakage magnitude and groundwater level gradient. This study could provide a theoretical basis and technical support for the sustainable development of water resources and ecological environment protection in Baiyangdian Lake.

Stable Isotope Tracers of Cretaceous Arctic Paleoprecipitation

We report estimated stable isotope compositions of depositional waters and paleoprecipitation from the Cretaceous Arctic to further elucidate the role of the global hydrologic cycle in sustaining polar warmth during that period. Estimates are based on new hydrogen isotopic analyses of n-alkane biomarkers extracted from Late Cretaceous and mid-Cretaceous terrestrial deposits in northern Alaska and the Canadian High Arctic. We integrate these new results with earlier published work on oxygen isotopic analyses of pedogenic siderites, dinosaurian tooth enamel phosphates, and pedogenic clay minerals from the same field areas. Average Late Cretaceous δD values of −143‰ VSMOW corresponded with average δ18O values of −24.1‰ VSMOW, and average mid-Cretaceous δD values of −106‰ VSMOW corresponded with average δ18O values of −22.1‰ VSMOW. The distributions of water isotope δD and δ18O values from Cretaceous Arctic deposits do not intersect with the Global Meteoric Water Line, suggesting an apparent deuterium excess ranging from about 40 to 60 per mil. We considered several possible explanations for these Cretaceous results including (1) mass-balance changes in zonal patterns of evaporation and precipitation at lower latitudes, (2) concentration of 2H in leaf tissue waters from continuous transpiration by coniferous paleofloras during the Arctic growing season, and (3) concentration of 2H in the groundwaters of methane-emitting Arctic soils.

Верхнебашкирские карбонатные отложения в бассейне реки Шаръю (гряда Чернышева): литология, изотопия углерода и кислорода, условия осадконакопления

The Upper Bashkirian deposits in the Srednievorota section (the Sharyu River, the Chernyshev Ridge) are composed of un¬changed limestones. In their composition δ13CPDB = 0.3...3.9‰, δ18ОSMOW = 19.0...24.3‰. Isotopic ratios depend on changes of sedimentation conditions during Late Bashkirian. Formation of studied deposits took place in two stages. At the first stage, during the period of maximum regres¬sion and activation of tectonic mode, rock associations of microbial-pelitomorphic and bioclastic limestones were formed. δ13C gradually increases from 1,4 to 3,1‰, and then decreases to 1,2‰, and δ18О is first equal to 22,3...23,2‰, and then decreases to 20,9‰. At the second stage rock associations of algal, microbial-bioclastic and bioclastic limestones with crinoids and corals were formed on a shallow carbonate shelf during the gradual deepening of the sea. In the isotopic system, there is a gradual increase of average values of δ13C from 2,75 to 3,69‰, and average values of δ18O are equal to 22,18...22,88‰ with deviations of 2–3‰.

Isotope-geochemical characteristics of Wenlock carbonate and terrigenous-carbonate deposits of the Subpolar Urals and the southern part of the Chernyshev ridge

Research subject. Wenlock deposits in the Subpolar Urals and southern part of the Chernyshev Ridge. Materials and methods. Carbonate and terrigenous-carbonate rock samples from sections of the Subpolar Urals (outcrops 212, 217) and the southern part of the Chernyshev Ridge (outcrop 479) were studied by isotope analysis of carbonate carbon and oxygen.Results. The isotopic composition of the studied sections varies across a wide range of δ13С (–6.4…–0.05‰) and δ18O (20.0–26.9‰). Therefore, three time intervals characterized by distinctive isotopic characteristics can be distinguished, roughly corresponding to early Sheinwoodian (I), late Sheinwoodian (II) and Homerian (III). Interval I is characterized exclusively by the rocks of outcrop 479 with δ13С (–3.6…–3.0‰) and δ18O (22.4–23.6‰). In Interval II, the average values of isotopic characteristics of outcrop 479 indicate a tendency to weighting carbon (–5.5…–3.5‰) and somewhat heavier oxygen (23.2–25.2‰) isotopes. In outcrop 212, the average isotopic values for carbon and oxygen vary from –2.9 to –1.3‰ and from 21.9 to 24.3‰, respectively. In outcrop 217, the average values are δ13C (–1.8…–0.8‰) and δ18O (22.4–25.4‰). In Interval III, the average values of carbon isotopic composition in outcrop 479 are becoming heavier from –2.5 to –0.7‰. In outcrop 212, the isotopic values of oxygen (21.9–23.1‰) and carbon (–4.9…–2.5‰) tend to become weighting; however, in outcrop 217, the average isotopic values of δ13C (–1.9…–0.5‰) and δ18O (22.3–24.5‰) remain constant. The conducted litho-facial studies showed that the weighting carbon isotopic composition ranging from –6.4…to –3.0‰ is associated with an increase in microbial activity in sediments, the manifestation of vadose-phreatic conditions, and the intake of light carbon dioxide with a flow of terrigenous material from the earth. In the latter case, oxygen isotopic values are also the most lightweight (20.0–23.0‰).Conclusions. The obtained isotopic characteristics of the Wenlock rocks under study indicate the expedience of identifying three time intervals and their correlation with paleogeographic reconstructions of Wenlockian sedimentation in the Timan-northern Ural region.