Average Concentrations Of Copper Research Articles

Physico-Chemical Treatment of a Wastewater Collector Loaded with Metals and Suspension Material by The Solution of Raw Carica papaya Latex

The papaya (Carica papaya), of the family Caricaceae, is a tree-like tropical plant, native to Central and South America. Papaya cultivation extends to all warm and humid countries. The present study consists in using the solution of raw Carica papaya latex (SLCP) cultivated in Benin as a natural biodegradable flocculant in a physico-chemical process to treat liquid discharges loaded with metals including iron, copper, zinc, and manganese; and suspended matter, and also to test its efficiency against other products commonly used in wastewater treatment. The tests were carried out on water samples from the wastewater collector that runs through the Agla district in Cotonou.
 The comparative study with a commonly used flocculant, aluminium sulphate, showed outstanding competitiveness with a high flocculation power for the solution of Carica papaya raw latex. In six water samples from the collector with average concentrations of iron, copper, zinc and manganese of 18.20 mg/L ; 2.50mg/L ; 3.80 mg/L and 3.70 mg/L respectively, the percentages of metal removal exceeded 90% for iron and manganese and around 85% for copper and zinc with the combination FeCl3 + SLCP. The NaOH + SLCP combination showed a very significant effect on the removal of metals (96% reduction) and suspended matter.

Analysis of water-ecological problems of Khmelnytsk region

At the present stage, in the conditions of growing scale of anthropogenic impact on water resources, shortage of quality drinking water and climate change, priority measures should be their rational use and comprehensive conservation. The article analyzes the environmental problems of surface waters of river basins, analyzed the existing potential of water resources and the state of water use, qualitative and quantitative indicators of surface waters of river basins of the Dnieper, Southern Bug and Dniester within Khmelnytsky region. The main problems of water resources of the region are highlighted and proposals for their effective use are formulated. A feature of the Khmelnytsky region is its location in three river basins – the rivers Dniester, Southern Bug and Dnieper. The main share of water intake in the region comes from surface objects, and s unevenly distributed throughout its territory. The study shows that in the sectoral structure of general use of water in Khmelnytsky region, the largest consumer is industry (58.6 %), and among industries electricity sector is the main and largest consumer. The main environmental problem of the region is the pollution of surface water bodies with untreated and insufficiently treated return water. In the territory of Khmelnytsky region, 80 water users discharge return water into water bodies. The average annual concentrations of manganese (2–6 times), copper (4–7 times) and nitrites (2–5 times) were exceeded in all control samples from water bodies of Khmelnytsky region. There is also an increase in the total amount of discharges of pollutants, including petroleum products, suspended solids, sulfates, total iron, and copper. In addition to pollution, the problem is the current structure of land within river basins. Excessive plowing is one of the main negative factors that contributes to the deterioration of the water regime and leads to pollution of water bodies. Within the Khmelnytsky region, arable land is the dominant form of land use, their share is 50–70 %. Restoration of the quality of water bodies involves the implementation of measures to reduce the environmental risk of deterioration based on the analysis of the impact of anthropogenic factors and a set of water protection measures.

Phenolic compounds, biological activities and trace elements of Capparis ovata var. canescens

Introduction: Capparis species (Capparaceae), also called caper, grow naturally in various regions of the world. Caper is a plant with medicinal and aromatic properties. Flower buds, root bark, and fruits of the plant are used in folk medicine due to their analgesic, wound healing, cell regeneration, tonic, and diuretic effects. Objective: The aim of this research was to evaluate in vitro (anti-urease, antioxidant, anticholinesterase) and in vivo (anti-inflammatory) biological activities of caper (C. ovata var. canescens). In addition, we aimed to identify its major phenolic compounds using high performance liquid chromatography with a photodiode array detector (HPLC-DAD) and confirmate them using quadrupole time-of-flight liquid chromatography with tandem mass spectrometry (Q-TOF-LC/MS). Also, we quantified the concentrations of several trace and major elements in plant samples using inductively coupled plasma-mass spectrometry (ICP-MS). Methods: The antioxidant, anti-urease and anticholinesterase activities of different plant extracts were evaluated using DPPH, FRAP, ABTS/TEAC, Indophenol and Ellman tests. The identification of phenolic compounds and trace element contents was performed using HPLC and Q-TOF-LC/MS and ICP-MS. Results: Soxhlet methanol extract exhibited the strongest anti-urease, antioxidant (ABTS/TEAC) and anticholinesterase activity. Soxhlet and maceration methanol extracts demonstrated significant anti-inflammatory effect in the altered edema size after the second hour of carrageenan injection. The active phenolic compounds in Soxhlet methanol extract were identified as rutin, quercetin-hexoside-hexoside, quercetin-3-O-hexoside and kaempferol-3-O-rutinoside. In addition, the average concentrations of vanadium, chromium, manganese, cobalt, copper, nickel, arsenic, selenium, zinc and lead were within the permissible limits defined by WHO for medicinal plants. However, it was found that the concentrations of cadmium and iron were higher than the maximum permissible limits. Conclusion: Our results suggest that although caper has a strong biological activity, it should be consumed carefully due to the excess amount of cadmium and iron elements it contains.

Evaluation of source of corn silage and trace minerals on lactational performance and total-tract nutrient digestibility in Holstein cows

We evaluated the effects of source of corn silage and trace minerals on lactational performance and total-tract digestibility (TTD) of nutrients in 16 Holstein cows averaging 82 (standard error = 3) days in milk in a replicated 4 × 4 Latin square design with a 2 × 2 factorial arrangement of treatments with 28-d periods. The diets consisted [dry matter (DM) basis] of 55% conventional (CON) or brown midrib-3 (BM3) corn silage, 2% chopped wheat straw, and 43% grain mix with either sulfate (STM) or hydroxy (HTM) sources of copper, manganese, and zinc trace minerals. The targeted supplemental concentrations of copper, zinc, and manganese were 194, 1,657, and 687 mg/d, respectively. The dietary treatments were CON-STM, CON-HTM, BM3-STM, and BM3-HTM. The dietary nutrient composition of the BM3 diets averaged 32.1% amylase neutral detergent fiber on an organic matter basis (aNDFom) and 6.9% undigested neutral detergent fiber at 240 h (uNDF240om; % of DM), and CON diets averaged 36.2% aNDFom and 8.6% uNDF240om (% of DM). The average supplemental concentrations of copper, zinc, and manganese for the STM diets were 10, 41, and 64 mg/kg, respectively, and the average supplemental concentrations of copper, zinc, and manganese for the HTM diets were 10, 40, and 62 mg/kg, respectively. The average total dietary concentrations of copper, zinc, and manganese for the STM diets were 17, 104, and 60 mg/kg, respectively, and the average total dietary concentrations of copper, zinc, and manganese for the HTM diets were 17, 91, and 66 mg/kg, respectively. Data were summarized by period and analyzed as a replicated Latin square design with fixed model effects for corn silage, trace minerals, corn silage × trace mineral interaction, period within replicated square, and replicated square using the MIXED procedure of SAS. Cow within replicated square was a random effect. Cows fed the BM3 diets had greater dry matter intake (DMI) and milk yield (28.1 and 47.0 kg/d) than cows fed the CON diets (27.5 and 44.7 kg/d). We found no significant interaction between corn silage and trace minerals for DMI and milk yield. Cows fed the HTM diets (28.1 kg/d) had a greater DMI than cows fed the STM diets (27.5 kg/d). Cows fed the BM3 diets had greater TTD of DM and OM (72.8 and 74.1% of DM) than cows fed the CON diets (71.1 and 72.3% of DM). Cows fed the HTM diets had a tendency for greater TTD of aNDFom than cows fed the STM diets (56.8 vs. 54.9% of DM). Cows fed the CON diets ruminated longer during the day than cows fed the BM3 diets (524 vs. 496 min/d). Corn silage with greater NDF digestibility and lower uNDF240om enhanced DMI, milk yield, and TTD of DM and OM, and hydroxy trace minerals improved DMI and tended to improve TTD of aNDFom. The source of corn silage and trace minerals should be taken into consideration when formulating diets for high-producing dairy cows.

Detection of cadmium and copper in fresh water and marine fishes

Cadmium and copper are very toxic heavy metals found in the environment and have public health hazard. Therefore, the current study was performed on 100 samples of fresh water fish (Clarias lazera & Oreochromis niloticus) and marine fish (Sardina pilchardus & Pagrus pagrus) collected at different times from various fish markets in kafr El –sheikh governorate, Egypt. The collected samples were analyzed for determination of their heavy metal residues (cadmium and copper) by Atomic Absorption spectrophotometer (AAS). The obtained results showed that the mean values of cadmium concentrations (mg/kg) were 0.25 ± 0.01, 0.17± 0.01, 0.09 ± 0.01 and 0.08 ± 0.01 in C. lazera, O. niloticus, S. pilchardus and P. pagrus, respectively. While, the average concentrations of copper were 3.05 ± 0.27, 2.62 ± 0.19, 2.10 ± 0.13 and 1.73 ± 0.08 (mg/kg) in such examined samples. The sources of contamination of fresh water and marine fishes with heavy metals and their public health significance as well as some recommendations to control such serious pollutants were discussed.

Evaluating the efficacy of DGT to quantify copper in stormwater at end-of-pipe

In many cases, stormwater compliance monitoring is labor intensive, expensive, and largely unsuccessful in providing the data needed to support stormwater management goals. To help address these issues, diffusive gradients in thin film (DGTs), time-integrative passive samplers for metals, were evaluated to monitor copper in stormwater runoff. DGTs were co-located with traditional autosamplers within the stormwater conveyance systems at Naval Base San Diego (NBSD) to provide a direct comparison with composite sampling. DGTs were exposed in the laboratory to flow-averaged composite samples from NBSD stormwater conveyance systems. These experiments showed increasing uptake over time (range = 1.5–24 h) for copper, with positive, linear correlations (r2 > 0.980) between exposure duration and copper mass accumulated. However, it appears that the corresponding calculations of the DGT-labile fraction (CDGT) relative to the dissolved fraction fluctuated across the different exposure durations. In general, trends observed for CDGT measurements from the field were consistent with trends in the lab DGT exposures and traditional dissolved metal measurements from composite samples. Finally, time-weighted average copper concentrations from DGTs deployed for the first and second phases of storm events were within 30% of measurements from DGTs that were deployed for the entire storm event in the same stormwater vault. Cumulatively, these results show promise for continuous monitoring with DGTs as an approach that produces data more representative of exposure to the receiving environment during episodic events than data from traditional grab or composite chemistry sampling, and can represent significant cost savings.

Features of copper accumulation in the soils of different functional areas of Novokuybyshevsk

The vegetation of the Samara Region is characterized by a relatively high content of copper. This biogeochemical feature is typical for natural and technogenic transformed ecosystems of the region. Copper is included in the group of elements of the 2nd hazard class. At certain concentrations it is necessary for the normal functioning of all organisms, but with increasing concentrations in the environment or in food it shows toxicity. The technogenic sources of copper include metalworking and machine-building enterprises, fertilizers, road and rail transport, wastewater, products of incomplete fuel combustion and refining characteristic of the Samara Region. The peculiarities of copper accumulation and distribution in soils of urban areas of the region are insufficiently studied. Previously, such studies were carried out only in certain areas of Samara. The paper analyzes in detail the level of technogenic copper pollution of the soil cover in Novokuybyshevsk. Ecological and geochemical studies in Novokuybyshevsk were carried out for 3 years (2016-2018) on 7 stationary test plots in its different functional areas and on 1 background test plot. The objects of research were soil samples taken from the upper humus horizon (layer 0-10 cm). The quantitative content of copper in soil samples was determined by the method of inversion voltammetry. A comparative analysis revealed territories of Novokuybyshevsk with relatively high, medium and low levels of copper in the soil. The first group included the Park Dubki in its elevated part, the old residential area on Kirov Street, the roadside area at the intersection of Pobeda Avenue and Dzerzhinsky Street (93,3-90,7 mg/kg). The second group with an average copper content (71,0-73,3 mg/kg) included the square Elochki and a new residential area on Ostrovsky Street. The third group with a relatively low copper content (38,3-54,7 mg/kg) included three sample areas: the lowland part of the Park Dubki, the industrial zone and the background area. The concentration of copper in the soils of all studied functional zones in Novokuybyshevsk has not reached the level of approximate permissible concentration (APC), but more than the clark of the world soils and the background indicators. The downward trend in the concentration of copper in the soils of most of the studied functional zones of Novokuybyshevsk in 2018 compared with 2016 and 2017 at the relatively low level of copper content in soils of the industrial area of the city allows to exclude oil refineries from the list of its major anthropogenic sources.

Soil pollution evaluation and health risk assessment of heavy metals around Douroud cement factory, Iran

Industrial activates have contaminated the soils around the industries to some pollutants such as heavy metals. Nowadays, among the different industries, cement factories are of major environmental pollutant sources. Therefore, the main objective of this study was to evaluate the soil pollution to heavy metals around Douroud cement factory in terms of geo-accumulation index, pollution index, and integrated pollution index. Also, a health-risk assessment was carried out. Sampling was performed at intervals of 500 m, 1250 m, and 2000 m from the factory site. Soil samplings were taken from the depths of 0–10 cm and 10–20 cm from the top surface. The health-risk assessment regarding soil around the factory was assessed based on the USEPA procedure. The study results showed that the average concentrations of chromium, nickel, copper, lead and zinc in the soil around the cement factory were 115.77 mg/kg, 139.07 mg/kg, 80.47 mg/kg, 56.27 mg/kg, and 135.73 mg/kg, respectively. Also, the results showed that the concentration of the heavy metals in the top soil was significantly higher than subsurface sampling layers. Furthermore, the findings showed that the concentrations of all evaluated heavy metals were higher than the USEPA standard. The pollution index values in the soil around the cement factory were Cu > Pb > Zn > Ni > Cr. Based on this study, the daily intake rate of all the elements by oral ingestion route was higher than the inhalation and dermal contact routes. The hazard quotient values of all metals in all studied sampling points were < 1.

Elemental characterization of surface and bulk of copper-based coins from the Byzantine-period by means of spectroscopic techniques

Thirty-three Byzantine copper-based coins (so-called anonymous follis) from 970 to 1085 CE were investigated in order to determine the elemental composition both of the bulk and of the surface. The ancient coins analysed - belonging to the Thomas Bertelè Collection, now located in the Bottacin Museum of Padova (Italy) - were studied by way of physical, chemical and chemometric testing techniques. This study aims to obtain information on socio-economic aspects of the Byzantine Empire using chemical and physical data of currency as indirect indicators. First, the weight, diameter and thickness of each piece were measured, then a micro-Energy Dispersive X-ray Fluorescence (μ-EDXRF) technique was applied on a cleaned and polished area of the surface of the coin to evaluate the presence of minor elements in a non-destructive fashion. A micro-destructive sampling method for both surface and bulk samples, based on mechanically drilling the edge, was finally employed, and Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES) was used for the quantitative determination of Cu (the major alloying element), Pb, As, Fe, Zn, Ag, Ni, Sn and Mn (minor elements) in the powder which resulted from drilling each coin, previously dissolved via aqua regia dissolution technique overnight at room temperature.The average copper concentration of the folles was 95.9 ± 3.1% for the bulk and 91.7 ± 3.5% for the surface. The Pb-Cu ratio appears to be an index which can be used to discriminate between different coins, in particular for Class B (from 1030 to 1042 CE), as confirmed by exploratory chemometric data analysis. According to our results, all the anonymous Byzantine folles under examination were minted in much the same way and using the same mineral raw materials. Using the chemical data measured on the bulk, we can grasp that the monetary choice of the period under study excluded silver, gold and bronze (concentrations of Pb is low, while Sn resulted undetectable or unquantifiable) to turn, substantially, to a copper-only coinage (deducted the impurities given by the gangue of the starting minerals). Moreover, along the observed period of 120 years, the mass of the coins was significantly reduced (with an overall loss of material of approximately 60%).

Evaluation of Heavy Metals Concentration and Its Consumption Risk in Trout Fish (Oncorhynchus Mykiss)

Background: Nowadays, the pollution of aquatic ecosystems caused by entry of heavy metals is an issue that makes it essential to check the wholesome of the aquatic animals that are consumed by human. When these metals enter the canvas of aquatic organisms, cause tension due to bioavailability, and their toxicity leads to teratogenic, mutagenic and carcinogenic effects in living organisms Methods: Thirty rainbow trout were prepared from each fishing farm pond which are located in Sanandaj (Nanale Village) and Kamyaran (Diwaznaw Village). Then, samples were prepared using acid digestion method in the laboratory and the concentration of these metals was measured using atomic absorption spectrometer (Phonix 986). The achieved data were analyzed using SPSS software.. Results: The average concentration of the copper in liver and muscle tissues was 1. 53 and 0.15, for magnesium 3.7 and 7.57, for iron 0.28 and 0.6, for zinc 4.52 and 1.05, and for Nickel was 0.04 and 0.03 micro grams per a gram of fresh weight. The maximum daily consumption allowance was 888.7 grams for adults and 177.77 for children Conclusion: The average concentration of copper, iron, zinc, nickel and magnesium in muscle tissue of rainbow trout compared to international standards, is slightly lower than that at current consumption rates, long-term health risks to consumers is realized.

Flotacijska ispitivanja majdanpečke rude bakra u cilju poboljšanja iskorišćenja bakra i kvaliteta koncentrata primenom različitih kolektora

This paper presents the results of mineralogical and flotation studies on the copper ore from the deposit North Revir in the Copper Mine Majdanpek, using different collectors. XRD and ore mineralogical analysis showed that the most common minerals are pyrite and chalcopyrite. Chemical analysis confirm that it is a complex low-grade copper ore with average copper content of 0,273%. The content of precious metals (Au and Ag) was 0.2 g/t and 1.2 g/t, respectively. The main aim of flotation studies have been the effect of collector type on the recovery and concentrate grade in the copper flotation process. Various collectors and combinations of them were used in the rough flotation tests of copper ore. The copper recovery was in the range from 79.43% (test no. 4) to 84.96% (test no. 7). The best flotation results were obtained with mixture collectors of sodium isopropyl xanthate (Z11), dialkyl dithiophosphinates (Aerophine 3404) and SKIK BZ 2000. The collector's dosages of 20 g/t Z11, 8 g/t AP3404 and 8 g/t SKIK BZ 2000 produced the copper recovery (84.96 %) with copper concentrate grade of 1.52% .

The effect of smelting and granulation on some properties of smelter slag

The technogenic copper deposit of slag Depo 1 is located in the industrial district of the Smelter and Refineries of RTB Bor. Exploitation reserves are 9 190 940 t of slag with the average copper content of 0.715%. Sample of this deposit was melted in a furnace and then cooled with a jet of water when it was poured into a thin jet, whereby the small - granulated pieces were formed. Comparison of some properties of this sample was done with the sample in the form in which it was deposited in the deposit. This paper presents the chemical analysis, SEM - EDS analysis, Bond working index in a rod and ball mill, grinding kinetics and experiments of flotation concentration of copper depending on the grinding fineness in the range of 60 - 95% - 0.075 mm.

Assessment of particulate matter and heavy metals concentration in the indoor and outdoor air of the houses of respiratory tract disease patients

The purpose of this study was to evaluate the concentration of airborne particulate matter and heavy metals in the houses of the respiratory tract disease patients and a control group of residents in the city of Gwangyang. The particulate matter was measured using a mini-volume air sampler and then weighed three times using a micro balance to calculate the weighted average value. The heavy metals in the particulate matter were extracted using a hot plate and analyzed using an inductively coupled plasma/mass spectrometer. The average concentration of particulate matter in the outdoor air (34.478 μm/m3) was higher than that in the indoor air (16.794 μm/m3), showing a statistically significant difference (p<0.001). The average concentration of copper, manganese and chromium in the indoor and outdoor air were higher in the houses of those in the study group than those of the control group. In addition, there was a generally high correlation between particulate matter in the outdoor air and heavy metals in the indoor and outdoor air concentration (p<0.05).

Copper, Manganese and Zinc Bioaccumulation in Some Common Poaceae Species Along Romanian Black Sea Coast

Copper, manganese and zinc bioaccumulation potential was screened for three common Poaceae species, Hordeum murinum ssp. murinum L., Leymus racemosus ssp. sabulosus (M. Bieb.) Tzvelev and Lollium perenne L., abundantly growing along the Romanian Black Sea Coastal area, Constanta County. The concentration of the selected heavy metals was analyzed though atomic absorption spectrometry in samples of aboveground plant organs and soils. To assess the potential for phytoaccumulation, the Biological Accumulation Coefficients (BAC) were calculated. Considering the minimal thresholds widely accepted in literature for Cu, Mn and Zn hyperaccumulators, none of the selected species can fit in this category. The highest average copper concentration was found in Hordeum murinum ssp. murinum L. (5.45 mg/kg). For manganese, the highest value was found in Lollium perenne L. (104.08 mg/kg), while for zinc, the maximum was reached in Leymus racemosus ssp. sabulosus (M. Bieb.) Tzvelev, tissue (62.95 mg/kg). BAC values showed that all species are manganese excluders, with a remarkable maximum value of 0.55 in Lollium perenne. L. All species had average BAC above 1 for Cu and Zn, with a maximum in Leymus racemosus ssp. sabulosus (M. Bieb.) Tzvelev (4.85 and 2.98, respectively). However, there was a significant variation among individuals, usually, a high metal content in plant tissue being associated with low metal concentration in soil. The exception was Lollium perenne L., with BAC constantly above 1 (average BAC of 2.27 for Cu and 1.69 for Zn). These results emphasize a significant potential for phytostabilization of copper- and zinc-rich soils and open the way for heavy metals phytoextraction capacity studies of the Poaceae species along Romanian littoral.

Determination of Heavy elements in Drinking Water from Different Regions of Baghdad City (Iraq) Using EDXRF Spectrometer

It was calculated the average concentrations of elements manganese, iron, cobalt, nickel, copper, zinc, arsenic, cadmium and lead in the sixteen samples of drinking water (tap water), were collected from different areas in the Baghdad city. The Results indicated that the average of concentrations of the elements Mn, Fe, Pb, Ni and Cd (0.44ppm, 0.49ppm, 0.04ppm, 0.17ppm and 1.2ppm respectively) higher than permissible limit while the concentrations of elements Cu and Zn (0.11ppm and 0.14ppm respectively) were lower than the permissible limit of World Health Organization (WHO) standards (1ppm and 3ppm) respectively for drinking water and the concentration of Arsenic in the nuclear lab sample in college of sciences - Mustansiriyah University was higher than permissible limit. &#x0D; All the drinking water samples were analyzed and determined the physical and chemical properties such as Electrical Conductivity (EC), pH, and Total Dissolved Solids (TDS). The highest value was (1064μS/cm) in Al-Tuwaitha sample and the lowest value (531μS/cm) in Al-Sadr City (Sector 7) sample for the Electrical Conductivity. The pH values ranged from (7.0-8.2). The average levels of Total Dissolved Solids (TDS), the highest value was 550 mg/L in the Diyala Bridge sample while the lowest value 276mg/L in Al-Sadr City (Sector 7) sample. The results were compared with national and international standards, and it’s also showed that the values of the parameters within the permissible limit of World Health Organization (WHO) standards, except the Electrical Conductivity values for some samples were higher than permissible limit. According to these results, all the water projects must be monitored as well as using the proper and modern techniques for treatment the drinking water.

Recovery of Cu(II) from aqueous solution by induced crystallization in a long-term operation

The feasibility of copper recovery by induced crystallization in a long period (174days) was investigated in a seeded fluidized bed reactor (FBR). The process was divided into 3 periods according to different influent conditions, and the period III was separated into III-a and III-b due to the adjustment of the molar ratio of CO32− concentration to copper concentration ([CT]/[Cu2+]). The removal efficiency could exceed 95% and the average effluent copper concentration decreased to 3.0mg/L. The mean particle size of seed grains with copper crystals coating on, raised to 0.36mm from initial 0.18mm. During period III-a, the supersaturation exceeded 2.88×104, the removal efficiency decreased to 60%–80% and the particle size dropped to 0.30mm, due to the generation of fines by homogeneous crystallization and seeds breaking. And the morphology of the crystals on the seed grains changed from rod-like to spherical which lead to the particle size decreasing. In period III-b, the supersaturation was modified by adjusting the molar ratio of [CT]/[Cu2+] to 1.2 from 2. The efficiency was back to 95% and the mean particle size grew to 0.36mm at the end of III-b, the crystals coating on the seeds turned back to rod-like products of good stability. This study illustrated that the copper salt crystal could keep on growing on the seed grains for over 150days, the feasibility and controllability of copper recovery by induced crystallization process in FBR were satisfactory, even under the dramatic changes in influent conditions.

Origin of native copper in the Paraná volcanic province, Brazil, integrating Cu stable isotopes in a multi-analytical approach

Different hypotheses exist on the origin of native copper mineralization in the Parana volcanic province that invoke magmatic, late magmatic, or hydrothermal events. The average copper content in the host basalts is ~200 ppm. Native copper occurs as dendrites in cooling joints, fractures, and cavities within amygdaloidal crusts. Cuprite, tenorite, chrysocolla, malachite, and azurite occur in breccias at the top of the lava flows. Chemical analyses, X-ray diffraction, Raman spectrometry, electron microprobe analyses, LA-ICP-MS, and Cu isotope analyses were used to evaluate the origin of native copper in the volcanic province. Copper contents in magnetite of the host basalt are close to 1 wt.%, whereas clinopyroxene contains up to 0.04 wt.% Cu. Cretaceous hydrothermal alteration of magnetite and clinopyroxene released copper to generate hydrothermal copper mineralization. The isotopic composition of the native copper in the Parana volcanic province varies from −0.9‰ in the southeastern portion (Rio Grande do Sul state) to 1.9‰ in the central portion (Parana state) of the province. This study supports a hydrothermal origin followed by supergene enrichment for native copper in the Parana volcanic province.

Nickel and copper residues in meat from wild artiodactyls hunted with nickel-plated non-lead rifle bullets

A nickel (Ni)-plated copper-solid bullet type released up to 93 μg Ni /10 g bullet mass when immersed into meat juice for 7 days (to simulate fragments remaining in venison). A non-nickel-plated counterpart of identical construction released no Ni, but up to 250 μg copper. During thermal processing of pork cubes with embedded bullets, an average of 2.8 and up to 4.3 (maximum) μg Ni were released from the Ni-plated bullet to the surrounding meat. Average nickel and copper content in meat samples (taken in 2–3 cm distance from the shot wounds) from 30 roe deer (Capreolus capreolus) and 3 sika deer (Cervus nippon) killed with nickel-plated copper bullets did not differ significantly from those in controls (roe deer haunch). Contamination scenarios would Cu and Ni contents per portion increase moderately by 20 and 3.3 μg, respectively. In order to limit alimentary Ni uptake, the technological need for Ni-plating of bullets should be carefully evaluated.

LEVELS OF HEAVY METALS IN PSEUDOTOLITHUS ELONGATUS FROM BADAGRY MARKET, NIGERIA

Fish plays a significant role in food and nutrition security across the world, especially in Nigeria, where the people consume fish as a major supplement to carbohydrate-based diets. Although the fish Pseudotolithus elongatus is present in Badagry coastal waters, it is one of the popular imported fish into Nigeria and has a high price in Badagry market because of its characterized good flavor and palatability. However, there are no recent reports on the safety of consuming this fish. In this study, 182 specimens of fresh P. elon-gatus purchased from Badagry market during October 2016 to April 2017 were examined for heavy metal composition (iron, copper, zinc, chromium, and lead) to assess their safety levels for human consumption. Samples were digested using the FAO and APHA procedures, while heavy metal concentrations were determined using an atomic absorption spectropho-tometer. Statistical analysis was carried out using ANOVA. The average concentrations of iron (Fe), copper (Cu), zinc (Zn), chromium (Cr), and lead (Pb) detected in the entire content of P. elongatus were 14.55±1.17, 0.20±0.02, 3.92±0.61, 0.06±0.02, and 0.35±0.02 mgkg−1, respectively. These concentrations were below the maximum limits recommended in fish and fishery products by the WHO and the FAO. Thus, this study confirms the safety of consumption of this fish from Badagry market. Nevertheless, sellers and processors must embrace hygienic practices to avoid contamina-tion of the fish.

Trace Metals Contamination of Bottom Sediments of Abu Dhabi Area, UAE

Seventy nine bottom sediment samples were collected from Abu Dhabi area from Ghantoout area in the north east from Abu Al Abyad island to determine the regional distribution of concentration of trace metals and pollution levels in the studied area. In general, a negative correlation has been reported between trace metals concentration and total organic matter with the exception of Cu, Zn, Co and Cr. A negative relation between trace metals concentrations and carbonate content was also found in the area of study. The present study focuses on the levels of copper, lead, iron, manganese, nickel, cadmium, zinc and vanadium in order to assess the extent of the environmental pollution and to discuss the origin of these contaminants in the sediments. The average concentrations of copper, zinc, lead, iron, manganese nickel, cadmium and vanadium are 4.65, 11.94, 1.91, 2800, 92.26, 10.55, 0.082 and 11.43 g/g respectively. These values are within the permitted levels in the marine activity areas and industrial activity areas, which means that trace metals are not derived from the pollutant sources.