The heat transfer characteristics of non-pretreated rice husk pyrolysis in a fluidized bed with alumina beads (500 μm - 590 μm) as bed material are studied. Assuming instantaneous heating of biomass to the reaction temperature, the effective overall heat transfer coefficient of the system (UA) is initially calculated based on the compositions of the collected products and reaction temperature. UA ranges from 0.82 to 2.95 W/K. This heat transfer coefficient study allows ad hoc product distributions to be predicted from theoretical bases. The effects of the biomass feeding rate (F) and the bed height (H/D) on UA values are also analyzed. Highest UA and specific heat of the pyrolysis reaction of −3.35 MJ/kg are found at F = 5 g/min and H/D = 1.0, where H/D is the largest and F is the lowest in the range studied. Upon feeding of the low thermal conductivity biomass, UA typically decreases. However, if the bed materials are limited, the fed biomass and its produced char act as an auxiliary heating medium to improve the effective heat transfer coefficient. High UA improves the efficiency of the pyrolysis reaction, but it decreases the bio-oil fraction in the product due to secondary decomposition.
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