Waste materials are generated by every activity of modern industrial society. Combustion or thermal treatment can be a viable disposal technique for many of these waste streams because it can destroy hazardous organics and pathogens, and can significantly reduce mass and volume. The waste streams that are commonly burned include refuse from municipalities, medical and infectious waste from medical institutions, sludges from municipal sewage treatment, hazardous waste streams from industrial processes, and materials from the cleanup of abandoned landfill sites. The combustion systems used for these different waste streams are widely divergent because of the different physical characteristics of the materials. The state of the art in combustion systems that is discussed include liquid injection incineration systems for pumpable liquids, rotary kilns, reciprocating grate stokers, controlled air fixed hearths, and multiple hearths for unprocessed solids, and spreader stokers and fluidized beds for processed fuels from waste. In addition there is a wide range of industrial furnaces and boilers where waste streams are cofired with auxiliary fuels. The key challenges to waste combustion in the future are the optimization of the total combustion system to reliably burn wastes while minimizing emissions of all pollutants into any effluent stream (solid, liquid or air) and the development of performance assurance techniques to continually monitor the system. The ability to design, operate and monitor a waste combustion, system to assure the optimized control of all emissions requires detailed knowledge of physical and chemical processes taking place within the waste combustion system and the chemistry of formation and control of these pollutant species. The current state of the knowledge regarding the formation and control of these species in waste combustion systems has resulted in significant reductions in emissions; however significant data gaps exist that preclude further advances. These data gaps must be filled with basic engineering research and vertically integrated assessment and system development studies. This paper characterizes current combustible waste streams and control of important emissions species from full scale equipment, and suggests future directions for research which could lead to the next generation of waste combustion equipment.
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