The article presents the results of the stand tribological investigation and microscopic observations of brake pad materials for automotive disc brakes. The reasons for the scatter of the friction coefficient value are analysed. The results of the brake pads’ friction surface topography observations and chemical constitution are presented. The investigations were carried out with scanning electron microscopy SEM and energy dispersive X-ray spectroscopy EDS. The point, line, and surface analysis of friction layer were done. The average contents of the chemical elements on the friction surface are presented. The heterogeneous nature of the structure on the friction layer was observed. The analysis has shown that brake pads with a compact structure of friction layer and large quantity components (10 components with more than 1% content each) had a smaller scatter of the coefficient of friction value in relation to the materials with a loose structure and less quantity components. The next part of the article presents the structure and geometric parameter products of the wear of the friction material. The problem concerning the quantity limitation of the wear particles entering the environment as dust was discussed.