Exoplanet Atmospheres Research Articles

A grid of self-consistent MSG (MARCS-StaticWeather-GGchem) cool stellar, sub-stellar, and exoplanetary model atmospheres

Context. In this paper we present a grid of self-consistent 1D model atmospheres of cool stars, sub-stellar objects, and exoplanets in the effective temperature range 300-3000 K, including cloud formation, chemical non-equilibrium effects, and stellar irradiation. Aims. The new grid extends the classical MARCS model atmosphere grid from 2008 towards lower effective temperatures and a broader range of object types. Methods. The new model atmosphere computations, MSG, are based on a combination of three well-tested codes, the classical MARCS 1D atmospheres, the StaticWeather cloud formation code, and the GGchem chemical equilibrium code. The combined code has been updated with new and more complete molecular and atomic opacities, cloud formation, and advanced chemical equilibrium calculations, and we also added new numerical methods at low temperatures to allow for a more robust convergence. Results. The coupling between the MARCS radiative transfer and GGchem chemical equilibrium computations has effectively made it possible to reach convergence based on the electron pressure for warmer models and gas pressure for cooler models, enabling self-consistent modelling of stellar, sub-stellar, and exoplanetary objects in a very wide range of effective temperatures. We will make new cloud-free and non-irradiated models for solar metallicity and a selected variety of other chemical compositions immediately available from our home page (https://cels.nbi.ku.dk). Illustrative examples of cloudy and irradiated models as well as models based on non-equilibrium chemistry are also presented, and we will describe these in more detail and make them available upon completion at the same place for a larger range of parameter space. Conclusions. For solar metallicity models, the new additional molecular opacities only affect the structure of models cooler than Teff = 2500 K, and the effect becomes substantial for models below Teff ~1500 K. Atomic line opacities are important for models warmer than ~3000 K. The line profile of the molecular opacities may have a larger effect on the model structure than previously anticipated, particularly in the uppermost layers at low gas pressure. The qualitative changes in the relative abundances of TiO, H2O, CH4, NH3, and other molecules in our models follow the observationally defined M, L, T (and Y) sequences, but they also reveal more complex and depth-dependent abundance changes and therefore a spectral classification depending on more parameters. The self-consistent coupling to StaticWeather cloud computations allows for detailed comparison between nucleation and observed relative dimming of different spectral bands, with advanced applications for new identification methods of potential exoplanetary biology.

How Landmass Distribution Influences the Atmospheric Dynamics of Tidally Locked Terrestrial Exoplanets

Interpretation of the ongoing efforts to simulate the atmospheres of potentially habitable terrestrial exoplanets requires that we understand the underlying dynamics and chemistry of such objects to a much greater degree than 1D or even simple 3D models enable. Here, for the tidally locked habitable-zone planet TRAPPIST-1e, we explore one effect which can shape the dynamics and chemistry of terrestrial planets: the inclusion of an Earth-like land–ocean distribution with orography. To do this we use the Earth-system model WACCM6/CESM2 to run a pair of TRAPPIST-1e models with N2–O2 atmospheres and with the substellar point fixed over either land or ocean. The presence of orography shapes atmospheric transport, and in the case of Earth-like orography, breaks the symmetry between the Northern and Southern Hemispheres which was previously found in slab ocean models. For example, peak zonal jet speeds in the Southern Hemisphere are 50%–100% faster than similar jets in the Northern Hemisphere. This also affects the meridional circulation, transporting equatorial material toward the south pole. As a result we also find significant changes in the atmospheric chemistry, including the accumulation of potentially lethal quantities of ozone at both the south pole and the surface. Future studies which investigate the effects of landmass distribution on the dynamics of exoplanetary atmospheres should pay close attention to both the dayside land fraction as well as the orography of the land. Simply modeling a flat landmass will not give a complete picture of its dynamical impact.

MAUVE: An Ultraviolet Astrophysics Probe Mission Concept

We present the mission concept “Mission to Analyze the UltraViolet universE” (MAUVE), a wide-field spectrometer and imager conceived during the inaugural NASA Astrophysics Mission Design School. MAUVE responds to the 2023 Announcement of Opportunity for Probe-class missions, with a budget cap of $1 billion, and would hypothetically launch in 2031. However, the formulation of MAUVE was an educational exercise and the mission is not being developed further. The Principle Investigator-led science of MAUVE aligns with the priorities outlined in the 2020 Astrophysics Decadal Survey, enabling new characterizations of exoplanet atmospheres, the early-time light curves of some of the universe’s most explosive transients, and the poorly-understood extragalactic background light. Because the Principle Investigator science occupies 30% of the observing time available during the mission’s 5 yr lifespan, we provide an observing plan that would allow for 70% of the observing time to be used for General Observer programs, with community-solicited proposals. The onboard detector (THISTLE) claims significant heritage from the Space Telescope Imaging Spectrograph on Hubble, but extends its wavelength range down to the extreme UV. We note that MAUVE would be the first satellite in decades with the ability to access this regime of the electromagnetic spectrum. MAUVE has a field of view of 900″ × 900″, a photometric sensitivity extending to m UV ≤ 24, and a resolving power of R ∼ 1000. This paper provides full science and mission traceability matrices for this concept, and also outlines cost and scheduling timelines aimed at enabling a within-budget mission and an on-time launch.

The greatest physics discovery of the 20th century: How did the expanding Universe make us?

Abstract The expanding Universe is unstable, owing to the energy released in gravitational interactions, leading to the complexity we now observe, from astrophysics to biology and psychology and combat. In just the last century, we discovered relativity, quantum mechanics, the fundamental particles (quarks, leptons and force carriers), the expanding Universe and the density fluctuations in the primordial material, and the astounding complexity of self-organised chaos feeding from energy flows. While we have not detected signs of life elsewhere, we know that about 20% of stars have planets with the right temperature and size to be like Earth. If life is not a miracle but a thermodynamic imperative, then it could be detectable through measurements of exoplanet atmospheres containing oxygen.

The Wanderer: Charting WASP-77A b’s Formation and Migration Using a System-wide Inventory of Carbon and Oxygen Abundances

The elemental and isotopic abundances of volatiles like carbon, oxygen, and nitrogen may trace a planet’s formation location relative to H2O, CO2, CO, NH3, and N2 “snowlines,” or the distance from the star at which these volatile elements sublimate. By comparing the C/O and 12C/13C ratios measured in giant exoplanet atmospheres to complementary measurements of their host stars, we can determine whether the planet inherited stellar abundances from formation inside the volatile snowlines, or nonstellar C/O and 13C enrichment characteristic of formation beyond the snowlines. To date, there are still only a handful of exoplanet systems where we can make a direct comparison of elemental and isotopic CNO abundances between an exoplanet and its host star. Here, we present a 12C/13C abundance analysis for host star WASP-77A (whose hot Jupiter’s 12C/13C abundance was recently measured). We use MARCS stellar atmosphere models and the radiative transfer code TurboSpectrum to generate synthetic stellar spectra for isotopic abundance calculations. We find a 12C/13C ratio of 51 ± 6 for WASP-77A, which is subsolar (∼91) but may still indicate 13C enrichment in its companion planet WASP-77A b (12C/13C = 26 ± 16, previously reported). Together with the inventory of carbon and oxygen abundances in both the host and companion planet, these chemical constraints point to WASP-77A b’s formation beyond the H2O and CO2 snowlines and provide chemical evidence for the planet’s migration to its current location ∼0.024 au from its host star.

The Challenge of Detecting Remote Spectroscopic Signatures from Radionuclides

The characterization of exoplanetary atmospheres through transit spectra is becoming increasingly feasible, and technology for direct detection remains ongoing. The possibility of detecting spectral features could enable quantitative constraints on atmospheric composition or even serve as a potential biosignature, with the sensitivity of the instrument and observation time as key limiting factors. This paper discusses the possibility that future remote observations could detect the presence of radioactive elements in the atmospheres of exoplanets. Such radionuclides could arise from cosmogenic or geologic sources, as well as from industrial sources, all of which occur on Earth. The detection of radionuclides in an exoplanetary atmosphere could reveal important properties about the planet’s geology or space environment and potentially could serve as a technosignature. However, many radionuclides, including those from industrial sources, attach to aerosol or other particles that cannot be remotely characterized. Limited experimental and theoretical spectral data exist for long-lived radionuclides, but the sensitivity required to detect the spectral features of some known radionuclides would be at least several orders of magnitude greater than required to detect the spectral features of molecular oxygen. Present-day remote spectroscopic observing mission concepts at ultraviolet to mid-infrared wavelengths are not sensitive to discern the presence of radionuclides in exoplanetary atmospheres. Interplanetary fly-by or probe missions may be more likely to provide such data in the future.

Abiotic Production of Dimethyl Sulfide, Carbonyl Sulfide, and Other Organosulfur Gases via Photochemistry: Implications for Biosignatures and Metabolic Potential

Among the atmospheric gases that have been proposed as possible biosignatures in exoplanetary atmospheres, organosulfur gases are currently considered one of the more robust indicators of extant life. These gases include dimethyl sulfide (DMS; CH3SCH3), carbonyl sulfide (OCS), and carbon disulfide (CS2), which are predominantly secondary metabolic products of living organisms on Earth. Here we present results that challenge this interpretation and provide constraints on the robustness of organosulfur gases as biosignatures. Through laboratory photochemical experiments, we show the abiotic production of organosulfur gases, including DMS, OCS, methane thiol (CH3SH), ethane thiol (C2H5SH), CS2, and ethyl methyl sulfide (CH3CH2SCH3) via photochemistry in analog atmospheres. Gas-phase products of H2S/CH4/N2 haze photochemistry, with or without CO2, were collected and analyzed using gas chromatography equipped with sulfur chemiluminescence detection. Depending on the starting conditions, we estimate that DMS, OCS, CH3SH, CH3CH2SH, CS2, and CH3CH2SCH3 are produced in mixing ratios >10−1 ppmv. We further demonstrate that as the mixing ratio of CO2 increases, so does the relative importance of OCS compared to DMS. Although our results constrain the robustness of common organosulfur gases as biosignatures, the presence of these compounds may serve as an indicator of metabolic potential on exoplanets.

The K2 and TESS Synergy. III. Search and Rescue of the Lost Ephemeris for K2's First Planet

K2-2 b/HIP 116454 b, the first exoplanet discovery by K2 during its Two-Wheeled Concept Engineering Test, is a sub-Neptune (2.5 ± 0.1 R ⊕, 9.7 ± 1.2 M ⊕) orbiting a relatively bright (K S = 8.03) K-dwarf star on a 9.1 day period. Unfortunately, due to a spurious follow-up transit detection and ephemeris degradation, the transit ephemeris for this planet was lost. In this work, we recover and refine the transit ephemeris for K2-2 b, showing a ∼40σ discrepancy from the discovery results. To accurately measure the transit ephemeris and update the parameters of the system, we jointly fit space-based photometric observations from NASA’s K2, Transiting Exoplanet Survey Satellite, and Spitzer missions with new photometric observations from the ground, as well as radial velocities from HARPS-N that are corrected for stellar activity using a new modeling technique. Ephemerides becoming lost or significantly degraded, as is the case for most transiting planets, highlights the importance of systematically updating transit ephemerides with upcoming large efforts expected to characterize hundreds of exoplanet atmospheres. K2-2 b sits at the high-mass peak of the known radius valley for sub-Neptunes, and is now well-suited for transmission spectroscopy with current and future facilities. Our updated transit ephemeris will ensure no more than a 13 minute uncertainty through 2030.

Why heterogeneous cloud particles matter. Iron-bearing species and cloud particle morphology affect exoplanet transmission spectra

The possibility of observing spectral features in exoplanet atmospheres with space missions like the James Webb Space Telescope (JWST) and Atmospheric Remote-sensing Infrared Exoplanet Large-survey (ARIEL) necessitates the accurate modelling of cloud particle opacities. In exoplanet atmospheres, cloud particles can be made from multiple materials and be considerably chemically heterogeneous. Therefore, assumptions on the morphology of cloud particles are required to calculate their opacities. The aim of this work is to analyse how different approaches to calculate the opacities of heterogeneous cloud particles affect the optical properties of cloud particles and how this may influence the interpretation of data observed by JWST and future missions. We calculated cloud particle optical properties using seven different mixing treatments: four effective medium theories (EMTs; Bruggeman, Landau-Lifshitz-Looyenga (LLL), Maxwell-Garnett, and Linear), core-shell, and two homogeneous cloud particle approximations. We conducted a parameter study using two-component materials to study the mixing behaviour of 21 commonly considered cloud particle materials for exoplanets. To analyse the impact on observations, we studied the transmission spectra of HATS-6b, WASP-39b, WASP-76b, and WASP-107b. Materials with large refractive indices, like iron-bearing species or carbon, can change the optical properties of cloud particles when they comprise less than 1<!PCT!> of the total particle volume. The mixing treatment of heterogeneous cloud particles also has an observable effect on transmission spectroscopy. Assuming core-shell or homogeneous cloud particles results in less muting of molecular features and retains the cloud spectral features of the individual cloud particle materials. The predicted transit depths for core-shell and homogeneous cloud particle materials are similar for all planets used in this work. If EMTs are used, cloud spectral features are broader and the cloud spectral features of the individual cloud particle materials are not retained. Using LLL leads to fewer molecular features in transmission spectra than when using Bruggeman.

High-resolution Dayside Spectroscopy of WASP-189 b: Detection of Iron during the GHOST/Gemini South System Verification Run

With high equilibrium temperatures and tidally locked rotation, ultra-hot Jupiters (UHJs) are unique laboratories within which to probe extreme atmospheric physics and chemistry. In this paper, we present high-resolution dayside spectroscopy of the UHJ WASP-189 b obtained with the new Gemini High-resolution Optical SpecTrograph (GHOST) at the Gemini South Observatory. The observations, which cover 3 hr of post-eclipse orbital phases, were obtained during the instrument’s System Verification run. We detect the planet’s atmosphere via the Doppler cross-correlation technique, and recover a detection of neutral iron in the planet’s dayside atmosphere at a significance of 7.5σ in the red arm of the data, verifying the presence of a thermal inversion. We also investigate the presence of other species in the atmosphere and discuss the implications of model injection/recovery tests. These results represent the first atmospheric characterization of an exoplanet with GHOST’s high-resolution mode, and demonstrate the potential of this new instrument in detecting and studying ultra-hot exoplanet atmospheres.

The atmospheric composition of the ultra-hot Jupiter WASP-178 b observed with ESPRESSO

Context. Ultra-hot Jupiters (UHJ) have emerged as ideal testbeds for new techniques for studying exoplanet atmospheres. Only a limited number of them are currently well studied, however. Aims. We search for atmospheric constituents for the UHJ WASP-178 b with two ESPRESSO transits. Additionally, we show parallel photometry that we used to obtain updated and precise stellar, planetary, and orbital parameters. Methods. The two transits we obtained were analysed with narrow-band transmission spectroscopy and with the cross-correlation technique to provide detections at different altitude levels. We focused on searching for Na I, Hα, Hβ, Hγ, Mg I, and Li I lines in narrow-band data, as well as Fe I and Fe II, and attempted to confirm Mg I with the cross-correlation technique. We corrected for the Rossiter-McLaughlin effect and regions with a low signal-to-noise ratio due to Na I absorption in the interstellar medium. We then verified our results via bootstrapping. Results. We report the resolved line detections of Na I (5.5σ and 5.4σ), Hα (13σ), Hβ (7.1σ), and tentatively Mg I (4.6σ). With a cross-correlation, we confirm the Mg I detection (7.8 σ and 5.8 σ), and we additionally report the detections of Fe I (12σ and 10σ) and Fe II (11σ and 8.4σ) on both nights separately. The detection of Mg I remains tentative, however, because the results on the two nights differ. The results also differ compared with the properties derived from the narrow-band data. Conclusions. None of our resolved spectral lines probing the middle to upper atmosphere shows significant shifts relative to the planetary rest frame. Hα and Hβ exhibit a respective line broadening of 39.6 ± 2.1 km s−1 and 27.6 ± 4.6 km s−1, however, indicating the onset of possible escape. WASP-178 b differs from similar UHJ by its lack of strong atmospheric dynamics in the upper atmosphere. The broadening seen for Fe I (15.66 ± 0.58 km s−1) and Fe II (11.32 ± 0.52 km s−1) might indicate the presence of winds in the mid-atmosphere, however. Future studies of the impact of the flux variability caused by the host star activity might shed more light on the subject. Previous work indicated the presence of SiO cloud-precursors in the atmosphere of WASP-178 b and a lack of Mg I and Fe II. However, our results suggest that a scenario in which the planetary atmosphere is dominated by Mg I and Fe II is more likely. In light of our results, we encourage future observations to further elucidate these atmospheric properties.

JWST-TST DREAMS: Nonuniform Dayside Emission for WASP-17b from MIRI/LRS

We present the first spectroscopic characterization of the dayside atmosphere of WASP-17b in the mid-infrared using a single JWST MIRI/LRS eclipse observation. From forward-model fits to the 5–12 μm emission spectrum, we tightly constrain the heat redistribution factor of WASP-17b to be 0.92 ± 0.02 at the pressures probed by this data, indicative of inefficient global heat redistribution. We also marginally detect a supersolar abundance of water, consistent with previous findings for WASP-17b, but note our weak constraints on this parameter. These results reflect the thermodynamically rich but chemically poor information content of MIRI/LRS emission data for high-temperature hot Jupiters. Using the eclipse mapping method, which utilizes the signals that the spatial emission profile of an exoplanet imprints on the eclipse light curve during ingress/egress due to its partial occultation by the host star, we also construct the first eclipse map of WASP-17b, allowing us to diagnose its multidimensional atmospheric dynamics for the first time. We find a day–night temperature contrast of order 1000 K at the pressures probed by this data, consistent with our derived heat redistribution factor, along with an eastward longitudinal hotspot offset of 18.7−3.8+11.1◦ , indicative of the presence of an equatorial jet induced by day–night thermal forcing being the dominant redistributor of heat from the substellar point. These dynamics are consistent with general circulation model predictions for WASP-17b. This work is part of a series of studies by the JWST Telescope Scientist Team, in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy.

A Network Approach for the Accurate Characterization of Water Lines Observable in Astronomical Masers and Extragalactic Environments.

The water molecule, crucial to the chemical composition and dynamics of the universe, is typically identified in its gas phase via radio and submillimeter transitions, with frequencies up to a few THz. To understand the physicochemical behavior of astronomical objects, accurate transition frequencies are required for these lines. From a set of 26 new and 564 previous Lamb dip measurements, utilizing our ultrasensitive laser-based spectrometers in the near-infrared region, ultrahigh-precision spectroscopic networks were set up for H2 16O and H2 18O, augmented with 40 extremely accurate frequencies taken from the literature. Based on kHz-accuracy paths of these networks, considerably improved line-center frequencies have been obtained for 35 observed or predicted maser lines of H2 16O, as well as for 14 transitions of astronomical significance of H2 18O. These reference frequencies, attached with 5-25 kHz uncertainties, may help future studies in various fields of astrochemistry and astrophysics, in particular when precise information is demanded about Doppler-velocity components, including the gas flows of galactic cores, the kinematics of planetary nebulae, or the motion in exoplanetary atmospheres.

HST SHEL: Enabling Comparative Exoplanetology with HST/STIS

The Hubble Space Telescope (HST) has been our most prolific tool to study exoplanet atmospheres. As the age of JWST begins, there are a wealth of HST archival data that are useful to strengthen our inferences from JWST. Notably, HST/Space Telescope Imaging Spectrograph (STIS), with its 0.3–1 μm wavelength coverage, extends past JWST’s 0.6 μm wavelength cutoff and holds an abundance of potential information: alkali (Na, K) and molecular (TiO, VO) species opacities, aerosol information, and the presence of stellar contamination. However, time-series observations with HST suffer from significant instrumental systematics and can be highly dependent on choices made during the transit fitting process. This makes comparing transmission spectra of planets with different data reduction methodologies challenging, as it is difficult to discern whether an observed trend is caused by differences in data reduction or underlying physical processes. Here we present the Sculpting Hubble’s Exoplanet Legacy (SHEL) program, which aims to build a consistent data reduction and light-curve analysis methodology and associated database of transmission spectra from archival HST observations. In this paper, we present the SHEL analysis framework for HST/STIS and its low-resolution spectroscopy modes, G430L and G750L. We apply our methodology to four notable hot Jupiters, WASP-39 b, WASP-121 b, WASP-69 b, and WASP-17 b, and use these examples to discuss nuances behind analysis with HST/STIS. Our results for WASP-39 b, WASP-121 b, and WASP-17 b are consistent with past publications, but our analysis of WASP-69 b differs and shows evidence of either a strong scattering slope or stellar contamination. The data reduction pipeline and tutorials are available on Github and Zenodo.

Evidence of Water Vapor in the Atmosphere of a Metal-rich Hot Saturn with High-resolution Transmission Spectroscopy

Transmission spectroscopy presents one of the most successful approaches for investigating the atmospheres of exoplanets. We analyzed the near-infrared high-resolution transmission spectrum of a hot Saturn, HD 149026 b, taken using CARMENES spectrograph ( R∼80,400 ). We found evidence of H2O at a signal-to-noise ratio (S/N) of ∼4.8. We also performed grid search using a Bayesian framework and constrained the orbital velocity K p and rest velocity V rest to 158.17−7.90+8.31 km s−1 and 2.57−0.57+0.54 km s−1, respectively. While the retrieved K p value is consistent with theoretical prediction, the retrieved V rest value is highly redshifted (>3σ). This might be an indication of either anomalous atmospheric dynamics at play or an orbit with nonzero eccentricity. Additionally, we searched for HCN but no successful detection has been made, possibly due to the relatively low-S/N data set. The detection of H2O and subsequent retrieval of its abundance, coupled with analysis of other species such as CO in the K band, for example, might help us to get some information about the atmospheric C/O ratio and metallicity, which in turn could give us some insight into the planet’s formation scenario.

Approximating Rayleigh Scattering in Exoplanetary Atmospheres using Physics-informed Neural Networks (PINNs)

Abstract This research introduces an innovative application of physics-informed neural networks (PINNs) to tackle the intricate challenges of radiative transfer (RT) modeling in exoplanetary atmospheres, with a special focus on efficiently handling scattering phenomena. Traditional RT models often simplify scattering as absorption, leading to inaccuracies. Our approach utilizes PINNs, noted for their ability to incorporate the governing differential equations of RT directly into their loss function, thus offering a more precise yet potentially fast modeling technique. The core of our method involves the development of a parameterized PINN tailored for a modified RT equation, enhancing its adaptability to various atmospheric scenarios. We focus on RT in transiting exoplanet atmospheres using a simplified 1D isothermal model with pressure-dependent coefficients for absorption and Rayleigh scattering. In scenarios of pure absorption, the PINN demonstrates its effectiveness in predicting transmission spectra for diverse absorption profiles. For Rayleigh scattering, the network successfully computes the RT equation, addressing both direct and diffuse stellar light components. While our preliminary results with simplified models are promising, indicating the potential of PINNs in improving RT calculations, we acknowledge the errors stemming from our approximations as well as the challenges in applying this technique to more complex atmospheric conditions. Specifically, extending our approach to atmospheres with intricate temperature-pressure profiles and varying scattering properties, such as those introduced by clouds and hazes, remains a significant area for future development.

Probing atmospheric escape through metastable He I triplet lines in 15 exoplanets observed with SPIRou

For several years, the metastable helium triplet line has been successfully used as a tracer to probe atmospheric escape in transiting exoplanets. This absorption in the near-infrared (1083.3 nm) can be observed from the ground using high-resolution spectroscopy, providing new constraints on the mass-loss rate and the temperature characterizing the upper atmosphere of close-in exoplanets. The aim of this work is to search for the He triplet signature in 15 transiting exoplanets – ranging from super-Earths to ultrahot Jupiters – observed with SPIRou, a high-resolution (R ~ 70 000) near-infrared spectropolarimeter at the CFHT, in order to bring new constraints or to improve existing ones regarding atmospheric escape through a homogeneous study. We developed a full data processing and analysis pipeline to correct for the residual telluric and stellar contributions. We then used two different 1D models based on the Parkerwind equations and nonlocal thermodynamic equilibrium (NLTE) radiative transfer to interpret the observational results. We confirm published He triplet detections for HAT-P-11 b, HD 189733 b, and WASP-69 b. We tentatively detect the signature of escaping He in HD 209458 b, GJ 3470 b, and WASP-76 b. We report new constraints on the mass-loss rate and temperature for our three detections and set upper limits for the tentative and nondetections. We notably report improved constraints on the mass-loss rate and temperature of the escaping gas for TOI-1807 b, and report a nondetection for the debated atmospheric escape in GJ 1214 b. We also conducted the first search for the He signature in GJ 486 b since its discovery and report a nondetection of the He triplet. Finally, we studied the impact of important model assumptions on our retrieved parameters, notably the limitations of 1D models and the influence of the H/He ratio on the derived constraints.

Peering above the clouds of the warm Neptune GJ 436 b with CRIRES+

Context. Exoplanets with masses between Earth and Neptune are amongst the most commonly observed, yet their properties are poorly constrained. Their transmission spectra are often featureless, which indicate either high-altitude clouds or a high atmospheric metallicity. The archetypical warm Neptune GJ 436 b is such a planet showing a flat transmission spectrum in observations with the Hubble Space Telescope (HST). Aims. Ground-based high-resolution spectroscopy (HRS) effectively probes exoplanet atmospheres at higher altitudes and can therefore be more sensitive to absorption coming from above potential cloud decks. In this paper we aim to investigate this for the exoplanet GJ 436b. Methods. We present new CRIRES+ HRS transit data of GJ 436 b. Three transits were observed, but since two were during bad weather conditions, only one transit was analyzed. The radiative transfer code petitRADTRANS was used to create atmospheric models for cross-correlation and signal-injection purposes, including absorption from H2O, CH4, and CO. Results. No transmission signals were detected, but atmospheric constraints can be derived. Injection of artificial transmission signals indicate that if GJ 436 b would have a cloud deck at pressures P > 10 mbar and a <300× solar metallicity, these CRIRES+ observations should have resulted in a detection. Conclusions. We estimate that the constraints presented here from one ground-based HRS transit are slightly better than those obtained with four HST transits. Combining HRS data from multiple transits is an interesting avenue for future studies of exoplanets with high-altitude clouds.

Light Scattering Measurements of KCl Particles as an Exoplanet Cloud Analog

Salt clouds are predicted to be common on warm exoplanets, but their optical properties are uncertain. The Exoplanet Cloud Ensemble Scattering System (ExCESS), a new apparatus to measure the scattering intensity and degree of linear polarization for an ensemble of particles, is introduced here and used to study the light scattering properties of KCl cloud analogs. ExCESS illuminates particles with a polarized laser beam (532 nm) and uses a photomultiplier tube detector to sweep the plane of illumination. Scattering measurements for KCl particles were collected for three size distributions representative of modeled clouds for the warm exoplanet GJ 1214b. Our measurements show that Lorenz–Mie calculations, commonly used to estimate the light scattering properties of assumedly spherical cloud particles, offer an inaccurate depiction of cubic and cuboid KCl particles. All of our measurements indicate that Lorenz–Mie scattering overestimates the backscattering intensity of our cloud analogs and incorrectly predicts the scattering at mid-phase angles (∼90°) and the preferential polarization state of KCl scattered light. Our results align with the general scattering properties of nonspherical particles and underscore the importance of further understanding the effects that such particles will have on radiative transfer models of exoplanet atmospheres and reflected light observations of exoplanets by the upcoming Nancy Grace Roman Space Telescope and Habitable Worlds Observatory.

Lessons from Hubble and Spitzer: 1D Self-consistent Model Grids for 19 Hot Jupiter Emission Spectra

We present a population-level analysis of the dayside thermal emission spectra of 19 planets observed with Hubble WFC3 and Spitzer IRAC 3.6 and 4.5 μm, spanning equilibrium temperatures 1200–2700 K and 0.7–10.5 Jupiter masses. We use grids of planet-specific 1D, cloud-free, radiative–convective–thermochemical equilibrium models (1D-RCTE) combined with a Bayesian inference framework to estimate atmospheric metallicity, the carbon-to-oxygen ratio, and day-to-night heat redistribution. In general, we find that the secondary eclipse data cannot reject the physics encapsulated within the 1D-RCTE assumption parameterized with these three variables. We find a large degree of scatter in atmospheric metallicities, with no apparent trend, and carbon-to-oxygen ratios that are mainly consistent with solar or subsolar values but do not exhibit population agreement. Together, these indicate either (1) formation pathways vary over the hot and ultra-hot Jupiter population and/or (2) more accurate composition measurements are needed to identify trends. We also find a broad scatter in derived dayside temperatures that do not demonstrate a trend with equilibrium temperature. Like with composition estimates, this suggests either significant variability in climate drivers over the population and/or more precise dayside temperature measurements are needed to identify a trend. We anticipate that 1D-RCTE models will continue to provide valuable insights into the nature of exoplanet atmospheres in the era of JWST.