Asymmetric Structure Research Articles

Regioselective super-assembly of Prussian blue analogue

The construction of high-asymmetrical structures demonstrates significant potential in improving the functionality and distinctness of nanomaterials, but remains a considerable challenge. Herein, we develop a one-pot method to fabricate regioselective super-assembly of Prussian blue analogue (PBA) —— a PBA anisotropic structure (PBA-AS) decorated with epitaxial modules——using a step-by-step epitaxial growth on a rapidly self-assembled cubic substrate guided by thiocyanuric acid (TCA) molecules. The epitaxial growth units manifest as diverse geometric shapes, which are predominantly concentrated on the {100}, {111}, or {100}+{111} crystal plane of the cubic substrate. The crystal plane and morphology of epitaxial module can be regulated by changing the TCA concentration and reaction temperature, enabling a high level of controllability over specific assembly sites and structures. To illustrate the advantage of the asymmetrical structure, phosphated PBA-AS demonstrates improved performance in the oxygen evolution reaction compared to simple phosphated PBA nanocube. This method offers valuable insights for designing asymmetrical nanomaterials with intricate architectures and versatile functionalities.

Manufacturers' vertical integration strategies in competing three‐tier supply chains with asymmetric customer loyalty

AbstractThis study investigates manufacturers' vertical integration strategies within two competing three‐tier supply chains, focusing on the dynamics of asymmetric supply chains. This asymmetry stems from varying customer loyalties toward two products engaged in pricing and quality competition. By characterizing the equilibrium operational decisions and integration choices, we provide insights into how asymmetric customer loyalty compares and price–quality competition collectively influence the equilibrium channel structure. Our findings highlight that the option for backward integration can lead to an asymmetric equilibrium channel structure, driven by disparities in customer loyalty. In cases marked by significant differences in customer loyalty and a high market demand for product quality, the manufacturer with weaker customer loyalty might unilaterally implement decentralization. This analysis illuminates scenarios where manufacturers diverge from conventional integration norms and offers valuable insights into evolving supply chain dynamics.

γ-TuRC asymmetry induces local protofilament mismatch at the RanGTP-stimulated microtubule minus end

The γ-tubulin ring complex (γ-TuRC) is a structural template for de novo microtubule assembly from α/β-tubulin units. The isolated vertebrate γ-TuRC assumes an asymmetric, open structure deviating from microtubule geometry, suggesting that γ-TuRC closure may underlie regulation of microtubule nucleation. Here, we isolate native γ-TuRC-capped microtubules from Xenopus laevis egg extract nucleated through the RanGTP-induced pathway for spindle assembly and determine their cryo-EM structure. Intriguingly, the microtubule minus end-bound γ-TuRC is only partially closed and consequently, the emanating microtubule is locally misaligned with the γ-TuRC and asymmetric. In the partially closed conformation of the γ-TuRC, the actin-containing lumenal bridge is locally destabilised, suggesting lumenal bridge modulation in microtubule nucleation. The microtubule-binding protein CAMSAP2 specifically binds the minus end of γ-TuRC-capped microtubules, indicating that the asymmetric minus end structure may underlie recruitment of microtubule-modulating factors for γ-TuRC release. Collectively, we reveal a surprisingly asymmetric microtubule minus end protofilament organisation diverging from the regular microtubule structure, with direct implications for the kinetics and regulation of nucleation and subsequent modulation of microtubules during spindle assembly.

NLNet: A narrow-channel lightweight network for finger multimodal recognition

Multimodal biometric recognition has attracted more and more attention in recent years because of its security and accuracy. Compared with the single use of fingerprint or finger vein feature recognition, the multi-modal feature recognition method based on fingerprint and finger vein significantly improves the recognition performance. However, most of the multi-modal feature recognition networks have the disadvantages of large number of parameters and high training cost. In this paper, a narrow-channel lightweight network NLNet for fingerprint and finger vein recognition is proposed. The network adopts asymmetric narrow channel structure for lightweight design, and combines shallow network to improve the discriminating nature of the extracted features, which significantly reduces the model parameters and computation. In addition, a lightweight feature extraction module for building feature extraction branches is designed for NLNet. This module takes dimensional transformation feature extraction as the backbone, and the joint extension module and attention mechanism obtain low-redundancy multi-scale feature information. In terms of feature fusion, a feature fusion method based on PatchPooling is proposed. This method combines the characteristics of modal images, and uses Spatial dimension local mapping to increase the utilization rate of low-dimensional features, which effectively improves the richness of classified features. In this paper, experiments were carried out on the SDUMLA-HMT, NUPT-FPV, FVCHKP and HDPR-310 multimodal finger datasets, and the recognition accuracy was high as 97.72 %, 99.10 %, 99.67 % and 99.74 %, respectively. In addition, the effectiveness of the model is verified by comparing with other advanced methods.

The Angular Momentum Unloading of the Asymmetric GEO Satellite by Using Electric Propulsion with a Mechanical Arm

A high-precision attitude control satellite uses an angular momentum exchange device such as a flywheel or a control moment gyro as the actuator for attitude stability control. Once the accumulation of angular momentum exceeds the upper limit of the angular momentum exchange device, the satellite will lose its attitude control ability. Therefore, it is necessary to unload the angular momentum exchange device to ensure the attitude control ability of the satellite platform. The angular momentum accumulation of GEO(Geosynchronous Orbit, GEO) satellites with asymmetric structure can reach 40 Nms per day, and the accumulation speed is more than 20 times that of GEO satellites with symmetrical structure. Therefore, it is necessary to carry out angular momentum unloading for GEO satellites with asymmetric structure every day. The previous method of angular momentum unloading using electric propulsion has weak unloading capacity, which is not suitable for angular momentum unloading of asymmetric satellites. This paper presents a method of angular momentum unloading using a four-joint mechanical arm plus an electric thruster. Large angular momentum unloading with near-zero burn-up can be achieved through the thrust generated by station keeping. In addition, the problem of attitude and orbit coupling control can be solved by controlling the thrust direction of the electric thruster with a mechanical arm.

A Superhuman Sensing Triboelectric Nanogenerator with Boosted Power Density and Durability via a Bio‐Inspired Janus Structure

AbstractTriboelectric nanogenerators (TENG) not only enable sustainable self‐powered sensing of devices, but also have superhuman noncontact/contact identification capabilities, which are propelling humanity toward the intelligent era. However, the inherently low dielectric constant of triboelectric materials as well as the mechanical mismatch between electrodes and dielectric materials severely limited their efficient and stable output performance. Taking inspiration from the asymmetric structure and function of human skin, a novel single‐electrode TENG is developed, whose electrode and dielectric layer are integrated in a Janus architecture. By tuning the balance between gravity and the internal noncovalent interactions, gradient dispersion of carbon nanotubes in waterborne polyurethane networks can be feasibly achieved, which can boost the device performance by reinforcement in both the charge trapping capacity of the dielectric layer and the charge transfer of the electrode layer. As a proof‐of‐concept, triboelectric sensing and deep learning are integrated to realize the evolution from perception to identification under both noncontact (motion prediction) and contact (material identification) modes. The bionic design strategy of gradient Janus film can offer valuable insights into improving the output performance and durability of TENG. Additionally, the proximal prediction and tactile identification functions are also desirable attempts for future human‐machine interfaces.

Seismic analysis of RC building with plan irregularity in Baghdad/Iraq to obtain the optimal behavior

Abstract A study was conducted for four-story reinforced concrete (RC) structure existing in Baghdad-Iraq (residential building) to evaluate the accuracy and reliability of the equivalent lateral force procedure (ELFP) analysis and the response spectrum model (RSA) according to Iraqi seismic code (ISC 2016) for designing and analyzing irregular buildings. The building was classified as an irregular in plan according to American Society of Civil Engineers (ASCE 7-16). The seismic behavior of the building was investigated by verifying many parameters: the ratio of shear demand to shear strength on the columns ( V V / V n {V}_{n} ), internal force (bending moment, shear force, and axial force) for beams and columns, and the inter-story drift ratio (IDR) obtained from the (ELFP and RSA); then, the results were compared with the nonlinear static procedure (NSP) and the nonlinear dynamic procedure (NDP) according to ASCE 7-16. Also, this study investigated the effects of the higher modes in the plan (roof plan displacement). From the results, it can be concluded that ELFP and RSA are not a suitable analysis for asymmetric structures and should use appropriate methods such as the NSP and NDP.

When Less Is More: The Semiotic Privilege of Status Downplay

Why do affluent people drive used cars, elite chefs praise basic ingredients, and upper‐middle couples arrange backyard weddings? What makes senior professors feel comfortable dressing down and allows men to bring their kids into the office? This article takes a formal sociological approach to explore the cultural phenomenon of “Status Downplay”—a paradoxical type of status display, where more social status is signaled through a subtraction of status symbols. The trans‐contextual analysis of diverse manifestations of status downplay uncovers the inverted cultural presumptions of “doing” and “being” and the hierarchical classifications underlying such parodical presentation of self. The proposed semiotic model articulates the social privilege of unmarked actors' performative flexibility: the social license of those considered “normals” to deviate from the performative norm. Under this asymmetrical structure, status underdoings are revealed as markers of cultural dominance.

Arab teacher educators and the moral work of teaching in Israel

ABSTRACT This qualitative study explores how 14 Arab teacher educators perceive the moral preparation of teachers for Arab schools in Israel. The first theme highlights the contingent (institutional) factors that influence and may restrain the teacher educators’ mission of moral preparation. It highlights the importance of an organisational culture that supports student teachers’ learning to provide moral education, of empowering and unsilencing of student teachers, and of promoting morally oriented reflective practice in students’ clinical experiences. The second theme illustrates the teacher educators’ psychological assumptions about morality as represented by the possibilities and constraints of role modelling in preparing moral teachers. The third theme addresses the teacher educators’ socio-educational (universal, counter-hegemonic, and liberal) assumptions about the moral purposes of schooling. These assumptions are influenced by the asymmetrical structure of Arab-Jewish power relationships, as well as by the transitional status of Arab society in Israel.

Preparation of novel zwitterionic polysulfone ultrafiltration membranes for the dual-enhanced antifouling and antibacterial properties by in-situ one pot crosslinking reaction

Zwitterionic polysulfone (PSf) ultrafiltration membranes were fabricated by non-solvent phase separation (NIPS) method. Herein, a casting solution at 45 °C was developed by using chloromethylated polysulfone (CMPSf), N, N-dimethylacetamide (DMAc) as a solvent, 4-amino-benzenesulfonic acid monosodium salt (ABS) as a cross-linking agent, and Na2CO3 as an acid binder. Simultaneously, the occurrence of the electrophilic substitution reaction between ABS and CMPSf caused the formation of ABS grafting CMPSf (CMPSf-g-ABS). After a specific reaction time, the casting solution was applied to cast membranes, which were subsequently submerged in coagulation bath. A zwitterionic ultrafiltration (ZUF) membrane was obtained using NIPS following the treatment of hydrochloric acid (HCl) solution (1 M mol). Because of the formation of cross-linked CMPSf-g-ABS, the results revealed that the casting solution's viscosity increased sharply from 425.4 mPa s at the initial stage (0 h) to 4810.8 mPa s (22 h). Interestingly, the morphology of the membranes with an asymmetric finger-like structure at 0 h gradually transformed to a gradient sponge-like structure after 22 h. Specifically, the ZUF membrane (M22-H) with the gel fraction of 72.1% procured after the reaction of 22 h demonstrated a low water contact angle (40.17°) and a high pure water permeance (420.4 L m−2 h−1 bar−1). The M22-H also exhibited a high flux recovery rate (FRR) (90.2%), bovine serum albumin (BSA) rejection (>95%), and Escherichia coli (E. coli) antibacterial rate (96.2%). The surface of the ZUF membrane with numerous zwitterionic groups enhances the hydration layer's energy (i region <16 nm) and creates a thick hydration layer (ii region >16 nm), causing a significant improvement in the antifouling performance. This research opens new avenues for preparing zwitterionic functional membranes.

Electronic and optical properties of two-dimensional Janus Sn0.5Ge0.5S monolayer

Janus two-dimensional (2D) materials have received widespread attention in recent years due to their out-of-plane asymmetric structures which makes them promising candidates for sustainable energy devices. In this work, using first-principles calculations, we study a novel 2D Janus monolayer Sn0.5Ge0.5S for recently synthesized SnS monolayer. We investigate structural, electronic and optical properties of this new 2D Janus material. Our results show that monolayer Sn0.5Ge0.5S is an indirect band gap semiconductor with the lowest conduction band is nearly flat around the band minimum. Atom projected band structure reveals that this flattened valley is mainly originated from orbitals of Sn atom. In addition, the inclusion of spin–orbit coupling leads to splitting of the bands, largely along Γ-Y direction. Optical absorption spectra indicate superior sunlight absorption in the visible and ultraviolet regions. Interestingly, absorption spectra of Janus monolayer Sn0.5Ge0.5S are polarization dependent owing to its anisotropic crystal structure along zigzag and armchair directions.

Effect of fluoride (CoF2) based electrode material for high energy and power density asymmetric flexible supercapacitors

Herein, an asymmetric supercapacitor (ASC) device was assembled by employing the pristine CoF2 as active positive electrode material and activated carbon (AC) as negative electrode material. The CoF2 electrode exhibited an outstanding electrochemical behavior with enhanced specific capacitance (Cs) of 872 F/g at 1 A/g current density in three electrode configurations. The reversible Faradaic redox reactions in CoF2 instigate the formation of cobalt-oxyfluorides and generating the mixed valence state of Co (Co2+ and Co3+) which improves its electrical conductivity and electrochemical behaviors. Furthermore, the room temperature paramagnetic nature of CoF2 increases the gradient force of ions which could possibly increase the redox reactions at the electrolyte/electrode interface. The constructed asymmetric device structure of CoF2//AC revealed a quasi-rectangular shaped cyclic voltametric curve and symmetrical semi-triangular shaped galvanostatic charge-discharge profiles, respectively, which affirms the combined electric double layer capacitance and pseudocapacitive nature by its hybrid assembly. Hence, the constructed CoF2//AC ASC demonstrated a remarkable specific capacitance of 141 F/g, energy density of 44.06 Wh.Kg−1, and power density of 422.97 W.Kg−1 at 1 A/g with the high cell voltage of 1.5 V. The CoF2//AC ASC device retained c.a. 92 % of its initial capacitance and attained over 96 % of Coulombic efficiency after 2000 cycles of charge-discharge profiles at 1 A/g, which suggests the high electrochemical stability. This admirable electrochemical performance and the origin towards the magneto-capacitance of CoF2 could pave a new way to explore next generation high-performance supercapacitors.

Impact of Dual-Gate Configuration on the Endurance of Ferroelectric Thin-Film Transistors With Nanosheet Polycrystalline-Silicon Channel Film

This work explores the characteristics of ferroelectric thin-film transistors (FeTFTs) utilizing an asymmetric dual-gate (DG) structure in both single-gate (SG) and DG operation modes. In the transfer characteristics, DG mode exhibits a memory window (MW) of 1.075 V, smaller than SG mode’s MW of 1.402 V, attributed to the back-gate bias effect causing a reduction in the device’s threshold voltage. However, DG mode demonstrates superior endurance characteristics with 106 cycles compared to SG mode’s 105 cycles. Additionally, the increase in erase pulse voltage (VERS) exacerbates the polycrystalline-silicon channel lattice damage of FeTFT, resulting in subthreshold swing (SS) degradation. Nevertheless, the extent of SS degradation from DG mode operation is significantly lower than that of SG mode, contributing to the superior endurance of DG mode. The elevation of program pulse voltage (VPRG) induces imprint and charge-trapping effects in the top-gate ferroelectric dielectric, leading to reduced endurance. Due to the use of SiO2 as the back-gate dielectric in FeTFT, DG mode exhibits lower impacts of charge-trapping effects from the top-gate ferroelectric dielectric layer, resulting in better endurance compared to SG mode. The asymmetric DG structure provides greater tolerance in the selection of VPRG and VERS.

Discovery of Asymmetric Spike-like Structures of the 10 au Disk around the Very Low-luminosity Protostar Embedded in the Taurus Dense Core MC 27/L1521F with ALMA

Recent Atacama Large Millimeter/submillimeter Array (ALMA) observations have revealed an increasing number of compact protostellar disks with radii of less than a few tens of astronomical units and that young Class 0/I objects have an intrinsic size diversity. To deepen our understanding of the origin of such tiny disks, we have performed highest-resolution configuration observations with ALMA at a beam size of ∼0.″03 (4 au) on the very low-luminosity Class 0 protostar embedded in the Taurus dense core MC 27/L1521F. The 1.3 mm continuum measurement successfully resolved a tiny, faint (∼1 mJy) disk with a major axis length of ∼10 au, one of the smallest examples in the ALMA protostellar studies. In addition, we detected spike-like components in the northeastern direction at the disk edge. Gravitational instability or other fragmentation mechanisms cannot explain the structures, given the central stellar mass of ∼0.2 M ⊙ and the disk mass of ≳10−4 M ⊙. Instead, we propose that these small spike structures were formed by a recent dynamic magnetic flux transport event due to interchange instability that would be favorable to occur if the parental core has a strong magnetic field. The presence of complex arc-like structures on a larger (∼2000 au) scale in the same direction as the spike structures suggests that the event was not single. Such episodic, dynamical events may play an important role in maintaining the compact nature of the protostellar disk in the complex gas envelope during the main accretion phase.

Willis coupling in one-dimensional poroelastic laminates

We employ the Baker–Campbell–Hausdorff formula to derive closed-form expressions for the effective properties, including emergent Willis coupling, of a one-dimensional heterogeneous poroelastic medium consisting of a periodically repeating two-layer unit-cell. In contrast to the elastic and fluidic analogs, the Willis coupling of this periodic poroelastic medium does not vanish in the low-frequency limit. However, the effective wavenumber and impedance of this asymmetric lamellar material demonstrate symmetric reflection and absorption behavior that is indicative of symmetric structures in the low-frequency limit due to the effect of Darcy’s law on the dynamic effective density, which is inversely proportional to frequency. These closed-form expressions are validated against results obtained by direct numerical evaluation. The scattering coefficients, particularly the two reflection coefficients for incidence from either side of a finite length asymmetric structure, are different at non-zero frequencies but still in the metamaterial limit and are correct when the Willis coupling is included. The results show that asymmetry in poroelastic layers results in direction-dependent absorption coefficients, one of which could be optimized based on layer properties and asymmetry factors. As a consequence, the frequency range of validity of these scattering coefficients is wider when the Willis coupling matrix is accounted for than in its absence. This work paves the way for better control of elastic and acoustic waves in multiphase materials by considering poroelastic behavior.

Complementary structures of the yeast phosphate transporter Pho90 provide insights into its transport mechanism

Phosphate homeostasis is essential for all living organisms. Low-affinity phosphate transporters are involved in phosphate import and regulation in a range of eukaryotic organisms. We have determined the structures of the Saccharomyces cerevisiae phosphate importer Pho90 by electron cryomicroscopy in two complementary states at 2.3 and 3.1Å resolution. The symmetrical, outward-open structure in the presence of phosphate indicates bound substrate ions in the binding pocket. In the absence of phosphate, Pho90 assumes an asymmetric structure with one monomer facing inward and one monomer facing outward, providing insights into the transport mechanism. The Pho90 transport domain binds phosphate ions on one side of the membrane, then flips to the other side where the substrate is released. Together with functional experiments, these complementary structures illustrate the transport mechanism of eukaryotic low-affinity phosphate transporters.

Electromagnetic interference shielding composite aerogels with asymmetric structures developed in aid of neural network

Along with the increasingly serious electromagnetic interference (EMI) pollution, it is in urgent need of exploiting high-performance EMI shielding materials. However, the conventional experimental methods always require a series of tedious preparation and characterization processes, resulting in the long period and high cost. Herein, a fully connected neural network (FCNN) was applied to aid in exploiting silver nanowires/waterborne polyurethan/multi-walled carbon nanotubes (AgNWs/WPU/MWCNTs) EMI shielding aerogels with asymmetric structures to optimize new material evolution and reduce experiment burden. Firstly, the special AgNWs/WPU/MWCNTs aerogels were fabricated with various MWCNTs content (0 wt%, 2 wt%, and 4 wt%) and AgNWs mass (10 mg, 20 mg, 30 mg, and 40 mg) via a combination of directional freezing and spraying procedures, leading to 12 distinct samples. AgNWs/WPU/MWCNTs aerogels hold excellent EMI shielding properties and absorption-dominant shielding mechanism. The experimental EMI shielding effectiveness (SE) data at different frequency were leveraged to establish, train, and test the FCNN model based on Adam optimizer (Adam-FCNN). It is worth noting that Adam-FCNN model predictions are in good accordance with the EMI SE of the physically measured samples, with the lowest root mean square error RMSE of 0.7899, the highest correlation coefficient (R) of 0.9895, and excellent computational efficiency and reliability. Moreover, Adam-FCNN can accurately prognosticate EMI SE of unobtained AgNWs/WPU/MWCNTs aerogels in mechanics-intuitions to reduce repeated preparation and characterizing conditions. Thereby, Adam-FCNN soft model approach opens significant potential for alleviating the experimental burden, accelerating the discovery of innovative materials, and exploring the complex mechanism.

The temperature profile within Er3+: Yb3+: LuAl3(BO3)4 crystal: Insights uncovered by a combined theoretical and experimental study

This work reports a measured temperature profile along the pump light beam inside the Er3+:Yb3+: LuAl3(BO3)4 crystal and the simulated ones. The temperature profile featured by a high and asymmetrical peak structure shows rather localized nature with respect to its transversal distribution. By scrutinous examination of the discrepancies between the experimental and simulated ones, a) a heat deposition mechanism elucidating the steady state of local heat generations and various heat transfers was suggested; b) a three-beam of lights model together with a formula for analyzing the fractional thermal load was developed, which leads to a good agreement between the simulated and experimental temperature profiles. The new formula provides a more transparent tool in physics to evaluate the various energy losses; The model can easily be adapted to solve the thermal problem in a laser medium, in particular when a medium show unignorable absorption effect for the laser signal.

Mode-selective power splitters for mode-division multiplexing optical networks

We propose an all-fiber mode-selective power splitter (MSPS) for non-circular-symmetric LP lm (l = 1, 2, …) modes, which is suitable for multicasting and optical performance monitoring in mode-division multiplexing optical fiber networks. The MSPSs are asymmetric two-core few-mode directional couplers composed of a few-mode fiber and a two-mode fiber. We theoretically studied the three conditions required by the MSPSs. By carefully choosing the core-to-core distance and coupling length, the MSPS can achieve arbitrary splitting ratio regardless of the modal field orientation of the input non-circular-symmetric LP mode. By using an asymmetric structure, the MSPS can ensure the power splitting only happens on the target non-circular-symmetric LP mode when the phase matching condition is satisfied. In addition, we designed and numerically simulated LP31 MSPSs with four kinds of splitting ratios, among which the one with 90/10 splitting ratio was fabricated based on tapering and polishing method. The fabricated LP31 MSPS is characterized and the results show that its splitting ratio is much more stable than regular LP31 mode-selective coupler.

1.3 μm InAs/GaAs quantum-dot lasers grown on planar on-axis Si (001) substrates with high slope-efficiency and low differential resistance

We report electrically pumped continuous-wave (CW) InAs/GaAs quantum dot lasers monolithically grown on planar on-axis Si (001) substrates. Combining an asymmetric waveguide epitaxy structure with aluminium-free upper cladding layers and a symmetrical cathode chip structure, 1.3 μm band lasers with low differential resistance and high slope-efficiency have been achieved. Moreover, the optimized symmetrical cathode structure of the laser chips is used to improve the slope-efficiency by reducing the differential resistance and waste heat. The Fabry–Perot broad-stripe edge-emitting lasers with 2000 μm cavity length and 15 μm stripe width achieve a single-facet output power of 73 mW, a single-facet slope efficiency of 0.165 W A−1, and a differential resistance of 1.31 Ω at ∼1.31 μm wavelength under CW conditions at room temperature (25 °C). Importantly, these results provide an effective strategy to achieve 1.3 μm wavelength band single-mode distributed feedback lasers directly on planar on-axis Si (001) substrates with high efficiency.