Asymmetric Structure Research Articles

Engineering atomic Fe sites with asymmetrical nitrogen/sulfur coordination for stable and boosted sulfur conversion

Introducing nonmetallic heteroatoms into the conventional metal-N-C configuration is thought to be an effective strategy to regulate the coordinated chemistry environment of atomic metal centers and further improve the sulfur electrochemistry behavior in lithium-sulfur batteries. Nevertheless, the modulation of heteroatoms junction states (doped or coordinated) in carbocycle is rarely explored. Herein, based on the stable pre-coordination of Fe3+ and terminal sulfhydryl/amino groups in cysteine, an asymmetrical Fe-N3S1 coordination structure in cysteine-derived graphene (Fe/CG) is rationally designed and prepared. The intervention of S atom at the first-coordination shell of Fe centers could induce the distorted spatial coordination structure, which greatly reduces the Li2S decomposition barrier. Moreover, the bonded S atom increases the d-band center (Ɛda) of Fe and pronouncedly activates the surrounding atoms, enhancing the electronic conductivity and reaction activity/affinity of Fe/CG, which was evidenced through theoretical calculations. The serial electro-kinetic analysis further confirms the bidirectional catalytic effect of Li2S redox conversions on Fe/CG. Consequently, the S@Fe/CG cathodes exhibit outstanding cycling stability (718.8 mAh g−1 after 500 cycles at 1 C with a decay of 0.037 % per cycle) and rate performance (639 mAh g−1 at 4 C). This work provides a new perspective to regulate the local chemistry environment of metal centers via coordination engineering.

Poly(ethylene oxide)- and Polyzwitterion-Based Thermoplastic Elastomers for Solid Electrolytes.

In this article, ABA triblock copolymer (tri-BCP) thermoplastic elastomers with poly(ethylene oxide) (PEO) middle block and polyzwitterionic poly(4-vinylpyridine) propane-1-sulfonate (PVPS) outer blocks were synthesized. The PVPS-b-PEO-b-PVPS tri-BCPs were doped with lithium bis-(trifluoromethane-sulfonyl) imide (LiTFSI) and used as solid polyelectrolytes (SPEs). The thermal properties and microphase separation behavior of the tri-BCP/LiTFSI hybrids were studied. Small-angle X-ray scattering (SAXS) results revealed that all tri-BCPs formed asymmetric lamellar structures in the range of PVPS volume fractions from 12.9% to 26.1%. The microphase separation strength was enhanced with increasing the PVPS fraction (fPVPS) but was weakened as the doping ratio increased, which affected the thermal properties of the hybrids, such as melting temperature and glass transition temperature, to some extent. As compared with the PEO/LiTFSI hybrids, the PVPS-b-PEO-b-PVPS/LiTFSI hybrids could achieve both higher modulus and higher ionic conductivity, which were attributed to the physical crosslinking and the assistance in dissociation of Li+ ions by the PVPS blocks, respectively. On the basis of excellent electrical and mechanical performances, the PVPS-b-PEO-b-PVPS/LiTFSI hybrids can potentially be used as solid electrolytes in lithium-ion batteries.

Evidence of disordered local structure of ZnO buffered MgB2 films via polarized extended X-ray absorption fine structure analysis

Herein, we investigated the mechanism by which the critical temperature (Tc) of a magnesium diboride (MgB2) superconductor is altered by the buffer layer. Zinc oxide (ZnO) layers with different thicknesses (28, 80, and 134 nm) were deposited epitaxially on a Hastelloy substrate beneath a ∼ 1 μm MgB2 film. To measure the local structural distortion of the boron plane, three different angle polarizations (0°, 45°, and 90° parallel to the ab-axis) on the Mg K-edge, extended X-ray absorption fine structure (EXAFS) measurements were performed. The EXAFS analyses revealed that the ZnO buffer layer caused the boron layer to disorient, leading to buckling between the Mg and B layers, which affected the charge transfer capability in the intra-layer structure. Furthermore, the uneven distribution of B atoms amid the surrounding Mg atoms resulted in an asymmetric crystal structure, which leads to Tc fluctuation. This study reveals the relationship between modifications made to the boron plane condition of MgB2 by the ZnO buffer layer and the superconducting Tc behavior of MgB2.

Perpendicular magnetic properties and field-free current-induced switching in W/CoFeB/MgO trilayers with a compensating oblique W underlayer

Zero-field magnetization switching (ZFS) driven by current-induced spin–orbit torque (SOT) holds significant importance in spintronic applications. The introduction of a lateral asymmetric structure (LAS) through oblique deposition proves to be an effective strategy for breaking inversion symmetry, thereby enabling SOT-driven ZFS. However, the coexistence of wedge thickness structure and slanted columnar microstructure in the obliquely deposited films poses challenges in distinguishing their respective effects. In this study, we conducted a comparative investigation of the perpendicular magnetic properties and current-induced switching in W/Co40Fe40B20/MgO films by oblique sputtering of the W underlayer at a fixed tilting angle and at two opposite tilting angles with its wedge thickness compensated. We have found that the perpendicular magnetic properties of the Co40Fe40B20 layer are significantly altered at large tilting angles, irrespective of whether the W wedge thickness is compensated. Notably, at a tilting angle of 50°, ZFS is realized for both the conventional oblique sample and the compensating oblique sample, with the switching polarity contingent on the final tilting direction of the W layer. We have identified a gradient in perpendicular magnetic anisotropy in these samples, attributed to the laterally varying roughness associated with the slanted columnar microstructure of the W underlayer. This study underscores the dominant role of microscopic LAS in obliquely deposited films in breaking SOT symmetry. Our research sheds light on the impact of the slanted columnar microstructure on the magnetic and magneto-transport properties of films, offering valuable insights for advancing spintronic device research.

DKNN: deep kriging neural network for interpretable geospatial interpolation

Geospatial interpolation plays a pivotal role in spatial analysis because it provides high-quality data support for various spatiotemporal data mining (STDM) tasks. However, statistical methods, such as kriging, face challenges in dealing with complex geo-big data. Additionally, deep-learning-based methods, despite their exceptional performance, suffer from limitations, such as poor interpretability. To harness the complementary advantages of these statistical methods and deep learning approaches, this study proposes a novel geospatial artificial intelligence (GeoAI) framework called deep kriging neural network (DKNN). The primary contribution lies in the development of an asymmetric encoder-decoder structure, which includes a deep-learning-based spatial encoder and a geostatistics-based kriging decoder. The spatial encoder consists of three specialized neural networks, whereas the kriging decoder relies on the proposed unified kriging system. During forward propagation, the kriging decoder leverage messages from the spatial encoder to generate interpolation weights for prediction. Conversely, during backward propagation, the kriging decoder guides the spatial encoder in learning interpretable knowledge. Experiments were conducted using both synthetic and practical datasets. The results demonstrate an average improvement of 20.18% in MAE, 25.04% in RMSE and 24.06% in MAPE when compared to the best-performing baseline method. Furthermore, these results confirm the superior interpretability of our DKNN framework.

Laboratory visualization of damage asymmetry formation of rock fracture via acoustic emission and digital imaging correlation

Rock fracture mechanics and accurate characterization of rock fracture are crucial for understanding a variety of phenomena interested in geological engineering and geoscience. These phenomena range from very large-scale asymmetrical fault structures to the scale of engineering projects and laboratory-scale rock fracture tests. Comprehensive study can involve mechanical modeling, site or post-mortem investigations, and inspection on the point cloud of the source locations in the form of earthquake, micro-seismicity, or acoustic emission. This study presents a comprehensive data analysis on characterizing the forming of the asymmetrical damage zone around a laboratory mixed-mode rock fracture. We substantiate the presence of asymmetrical damage through qualitative analysis and demonstrate that measurement uncertainties cannot solely explain the observed asymmetry. The implications of this demonstration can be manifold. On a larger scale, it solidifies a mechanical model used for explaining the contribution of aseismic mechanisms to asymmetrical fault structures. On a laboratory scale, it exemplifies an alternative approach to understanding the observational difference between the source location and the in situ or post-mortem inspection on the rock fracture path. The mechanical model and the data analysis can be informative to the interpretations of other engineering practices as well, but may face different types of challenges.

MoS2-based polarization-sensitive photodetectors with asymmetric plasmonic structures and decreased detection time

This study analyzes the response time and sensitivity of photosensors that use 2D MoS2 semiconductor films with a high concentration of defects resulting from technological process sequences. In the developed photosensors, we introduce asymmetric plasmonic gratings providing their sensitivity enhancement as well as light polarization sensitivity. The photodetectors, as initially fabricated, exhibit an exceptionally long response time, surpassing a duration of a thousand seconds. This prolonged response time significantly impedes the practical application of these detectors. Nevertheless, the implementation of a specifically designed algorithm enables a dramatic reduction in detection time, by several orders of magnitude in comparison to the response time. It is based on a mathematical model that accounts for the dynamic features of these devices. Our study demonstrates that photodetectors, when enhanced with asymmetric plasmonic gratings, exhibit significantly improved performance metrics. These include a photosensitivity of approximately 60 mA/W and a degree of linear polarization at 0.78. Furthermore, the implementation of our proposed algorithm, which optimizes the calculation of detection time, dramatically reduces the characteristic detection time from over a thousand seconds to just around 10 s.

Sociology of Graft in Sierra Leone: A Foucault Cognizance

Imploring a Foucault cognizance to comprehending graft in Sierra Leone furnishes fascinating sociological inquiry of how primacy is at the mecca of this social curiosity. In Sierra Leone graft has dawned as the significant risk to impoverished folk’s subsistence as it influences social domains of people. This sociological inquiry accommodates a refined discourse of how graft is fundamentally a snag of primacy. It utilizes commonplace social case constructions of existence in Sierra Leone to emphasize the commonness of primacy in the social discourse of graft. The sociological inquiry accommodates a social substructure for the evolution of the sociology of graft in Sierra Leone by debriefing how graft and primacy are presently devised as personal exploits without comprehending the expansive nexus of primacy and consequently it affects admittance and snub. The sociological inquiry argues that dislodging graft political leaders or bureaucrats is not adequate to liquidate destitution nonetheless what is essential is a rudimentary transformation of the connections of primacy deployed on asymmetrical or unfair social structures.

A Close Look at Lyα Emitters with JWST/NIRCam at z ≈ 3.1

We study 10 spectroscopically confirmed Lyα emitters (LAEs) at z ≈ 3.1 in the Ultra Deep Survey field, covered by the James Webb Space Telescope/NIRCam in the Public Release Imaging for Extragalactic Research program. All LAEs are detected in all NIRCam bands from F090W to F444W, corresponding to rest frame wavelengths of 2200 Å to 1.2 μm. Based on morphological analysis of the F200W images, three out of the 10 targets are resolved into pair-like systems with separations of <0.″9, and another three show asymmetric structures. We then construct the spectral energy distributions (SEDs) of these LAEs, which show little to no extinction. All sources, including the pairs, show similar SED shapes, with a prominent flux excess in the F200W band, corresponding to extremely strong [O iii]+Hβ emission lines (EWrest = 740–6500 Å). The median effective radii, stellar mass, and UV slope of our sample are 0.36 kpc, 3.8 × 107 M ⊙, and −2.48, respectively. The average burst age, estimated by stellar mass over star formation rate, is <40 Myr. These measurements reveal an intriguing starbursting dwarf galaxy population lying off the extrapolations of the z ∼ 3 scaling relations to the low-mass end: ∼0.7 dex above the star-forming main sequence, ∼0.35 dex below the mass–size relation, and bluer in the UV slope than typical high-z galaxies at similar UV luminosities. We speculate that these numbers may require a larger main-sequence scatter or tail in the dwarf galaxy regime toward the starburst outliers.

Asymmetric non-fused ring acceptor with low energy loss for efficient organic solar cells

Non-fused ring acceptors (NFRA) show high structural diversity with low synthesis complexities and high cost-effectiveness, which holds the potential to boost the performance of organic solar cells (OSCs). For OSCs, it is crucial to broaden the absorption range while minimizing energy loss. One strategy involves creating acceptors with asymmetric structures. However, to date, there have been relatively few reports on NFRA with asymmetric backbones. Here, we designed a new NFRA molecule UF-ATT-2F with asymmetric π-bridges (thieno [3,2-b] thiophene and thiophene) and studied its performance in OSC. Compared with two symmetric reference molecules UF-T-2F and UF-TT-2F, the device based on the asymmetric acceptor UF-ATT-2F exhibits much lower energy loss, more appropriate phase separation scale and broader absorption range, consequently achieving a higher open-circuit voltage (Voc) exceeding 0.9 V and a decent PCE of 13.26 %. This work demonstrates that incorporating asymmetric π-bridge is an effective strategy for the design low-energy loss and high-performance organic photovoltaic acceptor.

Theoretical predicted Janus SrAlGaTe4: effects of strain and electric field and its topological properties

The asymmetric Janus SrAlGaTe4, constructed from its parent SrGa2Te4 monolayer, was predicted theoretically by first principle calculations. Its stability was confirmed by phonon structure without imaginary frequency and ab initio molecular dynamics (AIMD) simulations. The Janus structure reduces the symmetry of SrGa2Te4 monolayer, which causes the absence of topological states in free-standing Janus SrAlGaTe4. To explore the possible electronic and topological properties, the effects of strain and external electric field, working as effective modulation methods for the electronic properties, were investigated. The SrAlGaTe4 monolayer undergoes a direct-to-indirect bandgap transition when the in-plane biaxial compressive strain is −8%. When the tensile strain is 9% or the electric field is 0.5 V Å−1, the Janus SrAlGaTe4 monolayer exhibits topological insulator (TI) characters, which was confirmed by the evolution of the Wannier charge centers (WCC). And the critical values for the topological transition are 2% for the biaxial tensile strain, and 0.2 V/Å for the applied electric field. The asymmetric Janus structure induces a Rashba spin splitting not only in the valence band but also in the conduction band near the Fermi level when the spin–orbit coupling (SOC) is present. Our findings offer theoretical insights into the exotic physical properties of SrAlGaTe4 and also provide guides to new spintronic device designs.

Self‐strengthened hydrogel actuator based on the distribution of size‐differentiated PVA crystallites

AbstractSoft tissues, such as muscle could autonomously grow through re‐alignment and/or ‐combination of collagen nanofibrils upon the mechanical training. This adaptive capability is highly expected in artificial materials, particularly in hydrogel actuator. In order to avoid the failure for devices by suffering from the accumulated mechanical loading, in this work, a double layered thermo‐responsive hydrogel actuator capable of self‐strengthening was successfully prepared. In the bilayer, PVA nanocrystals with different particle sizes were uniformly distributed in each monolayer matrix, giving rise to the asymmetric structure and the resultant differentiated de‐swelling behaviors. Thus, the obtained hydrogel actuator with the semi‐interpenetrating network of P(NIPAM‐co‐NMA) can display diverse programmable transformations by varying the temperatures. The existence of PVA nanocrystals in both layers not only can enhance the mechanical strength, dramatically minimizing the collapse of hydrogel actuator in service due to the imbalance of the mechanical properties for bilayer structure, but also was greatly involved in the self‐reinforcing behavior. After repetitive tensile training with 80% strain, the tensile strength and fracture strain increased from 29.6 to 45.8 kPa and 95% to 104%, respectively. The experimental results indicated that the anisotropic orientation and strain‐induced‐crystallization for PVA crystalline domains readily occurred along the tensile direction, finally leading to the synchronous enhancement in mechanical strength for both layers. This work provides a new strategy for designing smart and robust biomimetic hydrogel systems that can be further used as the intelligent soft robotics in various fields.

Electron-Phonon Interaction Mediated Gigantic Enhancement of Thermoelectric Power Factor Induced by Topological Phase Transition.

We propose an effective strategy to significantly enhance the thermoelectric power factor (PF) of a series of 2D semimetals and semiconductors by driving them toward a topological phase transition (TPT). Employing first-principles calculations with an explicit consideration of electron-phonon interactions, we analyze the electronic transport properties of germanene across the TPT by applying hydrogenation and biaxial strain. We reveal that the nontrivial semimetal phase, hydrogenated germanene with 8% biaxial strain, achieves a considerable 4-fold PF enhancement, attributed to the highly asymmetric electronic structure and semimetallic nature of the nontrivial phase. We extend the strategy to another two representative 2D materials (stanene and HgSe) and observe a similar trend, with a marked 7-fold and 5-fold increase in PF, respectively. The wide selection of functional groups, universal applicability of biaxial strain, and broad spectrum of 2D semimetals and semiconductors render our approach highly promising for designing novel 2D materials with superior thermoelectric performance.

Monolayer Vacancy-Induced MXene Memory for Write-Verify-Free Programming.

The fundamental logic states of 1 and 0 in Complementary Metal-Oxide-Semiconductor (CMOS) are essential for modern high-speed non-volatile solid-state memories. However, the accumulated storage signal in conventional physical components often leads to data distortion after multiple write operations. This necessitates a write-verify operation to ensure proper values within the 0/1 threshold ranges. In this work, a non-gradual switching memory with two distinct stable resistance levels is introduced, enabled by the asymmetric vertical structure of monolayer vacancy-induced oxidized Ti3C2Tx MXene for efficient carrier trapping and releasing. This non-cumulative resistance effect allows non-volatile memories to attain valid 0/1 logic levels through direct reprogramming, eliminating the need for a write-verify operation. The device exhibits superior performance characteristics, including short write/erase times (100ns), a large switching ratio (≈3×104), long cyclic endurance (>104 cycles), extended retention (>4×106s), and highly resistive stability (>104 continuous write operations). These findings present promising avenues for next-generation resistive memories, offering faster programming speed, exceptional write performance, and streamlined algorithms.

Performance Assessment of Commercial Building for Symmetric and Asymmetric Plan Configurations in Different Seismic Zones of Bangladesh Using ETABS

Bangladesh is among the nations most vulnerable to earthquakes worldwide. Being a developing country, it has been a challenging issue to ensure commercial prosperity along with safety against seismic hazards. Structural engineers also face difficulties in accurately designing buildings with maximum economy and efficiency. ETABS, a leading global engineering software with BNBC 2020 guidelines plays a vital role in these cases. In this study, analysis of a B+G+6 storied building for Symmetric &amp; Asymmetric Plan configuration has been performed using ETABS software. Both kinds of structures have experienced a range of loads for example- dead loads, live loads, partition loads, wind loads, and seismic loads, as well as load combinations that have been pursued following BNBC 2020 requirements. The objective of this work is to evaluate the seismic impact resulting from varying seismic coefficients for four seismic zones in Bangladesh, given identical symmetric and asymmetric plan arrangements. Four required metrics were evaluated between the structural performances of symmetric and asymmetric structures: storey drift, overturning moment, storey shear, and storey stiffness. The structural software provided the analytical results and parameter computations. The comparison&amp;apos;s result demonstrates that the asymmetric structure exhibits greater storey rigidity and less storey drift over the longer axis.

Comparison of high power red-emitting diode laser designs for medical applications

A comparison is made between, on the one hand, the red-emitting laser structure currently widely used for medical applications and based on an ultranarrow waveguide layer with a compressively strained QW active layer in it and, on the other hand, the red emitting laser using a broadened asymmetric waveguide structure with a bulk active layer near the p-cladding, proposed by us. It is shown that the proposed design promises substantial improvements over the ultranarrow one including lower series and thermal resistances, and higher catastrophic degradation threshold, while maintaining relatively narrow far field and allowing the typical power required for medical applications to be achieved at lower currents, particularly at elevated temperatures.

Exploring the effect of concentration on hydrothermally synthesized mesoporous spherical nanoflowers of bismuth tungstate for hybrid supercapacitor and water-splitting applications

This paper describes how the synergistic effect of concentration changes the electrode conductivity and enhances the electrochemical and electrocatalytic activities of bismuth tungstate nanoflowers (BWO NFs). This research mainly aims to develop mesoporous spherical BWO NFs using a hydrothermal route. The structural analysis of the BWO NFs revealed the presence of an orthorhombic phase with a regular atomic arrangement. Scanning electron microscopy revealed that the different BWO NFs samples had nonuniform spherical NFs, which play an important role in supercapacitor and electrocatalytic applications. The identification of functional groups and stretching–bending vibrations of Bi–W–O bonds are revealed by FT-IR and Raman spectroscopy respectively. Additionally, the transmission electron microscopy and X-ray photoelectron spectroscopy confirmed the morphological, structural, and electronic states of the BWO NFs. Furthermore, the supercapacitive and electrocatalytic activity of BWO–nickel foam (NF) electrodes were investigated using an aqueous 1 M KOH electrolyte. The results revealed that the BWO-2 electrode exhibited an improved specific capacity (Csp) of (647 F/g) 72 mAh/g and excellent capacitive retention of 81 % over 5000 cycles. An asymmetrical hybrid device was fabricated using a two-electrode cell with BWO–NF and reduced graphene oxide acting as the positive and negative electrodes, respectively. The device demonstrated favorable electrochemical properties: a Csp of 52 mAh/g at 5 mV/s as well as a Csp of 46 mAh/g, the highest energy density of 32 Wh/kg, and the highest power density of 2330 W/kg at 5 mA/cm2. Furthermore, the BWO NFs were investigated for water-splitting activity, and the BWO-2 electrode was found to exhibit better electrocatalytic performance (overpotential: 328 mV, Tafel slope: 80.9 mV/dec, and electrochemical surface area: 41.2 cm2) and stability than the other electrodes. The designed asymmetric structure offers a suitable cathode material for energy storage and electrocatalytic applications.

Controllable Regulation of the Oxygen Redox Process in Lithium-Oxygen Batteries by High-Configuration-Entropy Spinel with an Asymmetric Octahedral Structure.

Designing bifunctional electrocatalysts to boost oxygen redox reactions is critical for high-performance lithium-oxygen batteries (LOBs). In this work, high-entropy spinel (Co0.2Mn0.2Ni0.2Fe0.2Cr0.2)3O4 (HEOS) is fabricated by modulating the internal configuration entropy of spinel and studied as the oxygen electrode catalyst in LOBs. Under the high-entropy atomic environment, the Co-O octahedron in spinel undergoes asymmetric deformation, and the reconfiguration of the electron structure around the Co sites leads to the upward shift of the d-orbital centers of the Co sites toward the Fermi level, which is conducive to the strong adsorption of redox intermediate LiO2 on the surface of the HEOS, ultimately forming a layer of a highly dispersed Li2O2 thin film. Thin-film Li2O2 is beneficial for ion diffusion and electron transfer at the electrode-electrolyte interface, which makes the product easy to decompose during the charge process, ultimately accelerating the kinetics of oxygen redox reactions in LOBs. Based on the above advantages, HEOS-based LOBs deliver high discharge/charge capacity (12.61/11.72 mAh cm-2) and excellent cyclability (424 cycles). This work broadens the way for the design of cathode catalysts to improve oxygen redox kinetics in LOBs.

Super-Assembled Multilayered Mesoporous TiO2 Nanorockets for Light-Powered Space-Confined Microfluidic Catalysis.

In the field of sustainable chemistry, it is still a significant challenge to realize efficient light-powered space-confined catalysis and propulsion due to the limited solar absorption efficiency and the low mass and heat transfer efficiency. Here, novel semiconductor TiO2 nanorockets with asymmetric, hollow, mesoporous, and double-layer structures are successfully constructed through a facile interfacial superassembly strategy. The high concentration of defects and unique topological features improve light scattering and reduce the distance for charge migration and directed charge separation, resulting in enhanced light harvesting in the confined nanospace and resulting in enhanced catalysis and self-propulsion. The movement velocity of double-layered nanorockets can reach up to 10.5 μm s-1 under visible light, which is approximately 57 and 119% higher than that of asymmetric single-layered TiO2 and isotropic hollow TiO2 nanospheres, respectively. In addition, the double-layered nanorockets improve the degradation rate of the common pollutant methylene blue under sustainable visible light with a 247% rise of first-order rate constant compared to isotropic hollow TiO2 nanospheres. Furthermore, FEA simulations reveal and confirm the double-layered confined-space enhanced catalysis and self-propulsion mechanism.

Plasma-Driven Selenization for Electrical Property Enhancement in Janus 2D Materials.

The recent emergence of Janus 2D materials like SnSSe, derived from SnS2, reveals unique electrical and optical features, such as asymmetrical electronic structure, enhanced carrier mobility, and tunable bandgap. Previous theoretical studies have discuss the electronic properties of Janus SnSSe, but experimental evidence is limited. This study presents a two-step method for synthesizing Janus SnSSe, involving hydrogen plasma treatment and in situ selenization. Optimized conditions (38W, 1.5min, 250°C) are determined using Raman spectroscopy and AFM analysis. XPS confirmed SnSSe's elemental composition, while KPFM reveals a significant reduction in the work function (from 5.26 down to 5.14eV) for the first time, indicating asymmetrically induced n-type doping. Finally, field-effect transistors (FETs) derived from SnSSe exhibited significantly enhanced mobility and on-current, as well as n-type doping, compared to SnS2-based FETs. These findings lay a crucial foundation for developing high-performance 2D electronic and optoelectronic devices.