Asymmetric Surface Research Articles

Superhydrophobic asymmetric pH-responsive soft actuators: Implications for the development of anti-fouling medical devices

Biomedical engineering strives for innovation to enhance the safety and effectiveness of medical tools, such as catheters and stents that need to be operated in confined spaces, with precise drug delivery control and should possess anti-fouling properties. Soft actuators with superhydrophobic surfaces can provide adaptable shape change together with non-fouling attributes required for medical devices. In this study, we have developed a Janus film with a hydrophilic solvent-responsive bottom and superhydrophobic top surface using a self-assembly strategy. The devised new strategy involves the dispersal of modified silica nanoparticles into a homogeneous solution, where they were segregated from the polymer matrix and self-assembled to form a superhydrophobic layer on the surface with a water contact angle of >150°. The resulting asymmetric actuator demonstrated bidirectional actuation in solvents with extreme pH values i.e., pH 1 and 13. It could be tailored for specific hydrophilicity by adjusting the ratio of dispersed superhydrophobic and hydrophilic silica nanoparticles in the polymer solution. These films exhibited exceptional chemical stability against strong acids, alkaline solutions, ethanol, and salt, as well as mechanical stability against abrasion from sandpaper. In vitro studies confirmed their superior anti-fouling and anti-bacterial properties. Furthermore, actuation of printed 3D structures with different patterns was demonstrated, showcasing the possibility of developing these superhydrophobic asymmetric surfaces via 3D printing and their potential as cardiovascular stents.

Determining the angle of the frontal working surface of the soil-piercing head asymmetrical tip for static soil-piercing

Problem. From the analysis of the technical literature, it was established that among the trenchless technologies for laying underground engineering communications and service pipelines, the technology with the possibility of forming a horizontally directed communication cavity in the soil using soil-piercing installations of static action is the most common. Goal. This method consists in forcefully pressing a soil-piercing working body, which has the form of a conical-cylindrical projectile, into the soil. At the same time, the well is formed by radial extrusion of the soil around the formed well. However, the use of such equipment does not provide high accuracy, which limits its practical application within 20 m. It is not sufficient for modern requirements of creating transitions during the laying of communications. Methodology. One of the ways to improve the efficiency of laying underground networks is to extend this method over a longer distance by correcting the trajectory of the working body. This is achieved by using a soil-piercing head with an asymmetric tip. Due to this, in addition to the axial resistance of the soil, a transverse component force appears, which deflects the head during its advancement in the soil. The question of determining the angle of displacement of such a tip is important in terms of the process control. Results. In the paper, a calculated dependence is proposed for determining the rational value of the angle of inclination of an asymmetric tip working surface, which is a flat plane cut at the angle of a cylinder. An analysis of the dependence of the angle of the working surface inclination on the physical and mechanical properties of the soil is also given. Originality. It was determined that the maximum angle of inclination of the frontal surface is determined by the conditions of soil descent from it. Its maximum value, for example when working in loam, should not exceed 55o-67o for a tip made of steel. Practical value. The obtained calculated dependence can be useful for determining the angle of inclination of the flat frontal surface of the tip of the soil piercing working tool for controlled static soil piercing at the stage of designing networks and choosing an effective method for drilling a well under roads or other obstacles.

Asymmetric Sea Surface Salinity Response to Global Warming: “Fresh Gets Fresher but Salty Hesitates”

AbstractEfforts to detect long‐term changes in global mean evaporation minus precipitation over the ocean remain ambiguous. Here we define an ad hoc sea surface salinity index to assess the observed and simulated intensification of the freshwater flux pattern over the global ocean and, thus, of the overall water cycle. A recent salinity reconstruction shows a long‐term amplification of the climatological patterns, thereby supporting the popular “fresh gets fresher, salty gets saltier” paradigm. Unlike in a previous study, no systematic underestimation of this amplification is found in the latest generation of global climate models. Yet, the “fresh gets fresher” paradigm is much more robust than its “salty gets saltier” counterpart and the proposed salinity index does not yet provide a strong constraint on the model‐dependent projected intensification of the global water cycle intensification along the 21st century.

Picosecond Laser Texturing of Al current collector to improve cycling performances and simplify recycling of Lithium-ion batteries

Lithium-ion batteries (LIBs) are one of the main energy storage technologies currently in use and recycling them offers significant economic, environmental, and material recovery benefits. Despite various recycling processes, separating the metallic current collector from the electrode composite film remains a crucial challenge. In this framework, the present study focuses on laser texturing of aluminum current collectors (CCs) to introduce a microscale surface architecture. The asymmetric surface pattern facilitated a controlled and directional adhesion, enhancing attachment to manage the significant volume variation of the active material (NMC811) during charging and discharging cycles. Additionally, it enabled an easy separation of the electrode composite layer from the current collector, during recycling, by applying a force in a specific direction. As a result, the laser-treated cathodes displayed low electrode polarization and increased cycling performances, with a capacity retention of 67.6 % after 300 cycles at 1C, thanks to the increased interfacial adhesion that reduced the active material delamination from the current collector upon cycling.

Ion current rectification coupled with asymmetric temperature and surface charge in ultrashort conical nanopores

Ion current rectification (ICR) is one of the electrodynamic properties in asymmetric nanochannels, which has been utilized to develop biosensors, heavy metal ion detection, and ion diodes. Previous studies on ICR mainly focused on long nanopores (length >500 nm), and relatively few studies on ion rectification performance in short nanopores. Here, we use a finite element numerical solution to simulate the effect of coupling asymmetric temperature and surface charge distribution on the ion rectification performance of ultrashort conical nanopores (length = 100 nm). The results show that the ion rectification performance is significantly improved when the inner and outer surfaces of the nanopore are charged non-uniformly, which is more than three times that when the inner surface of the nanopore is charged non-uniformly or the outer surface is charged non-uniformly. In addition, the positive temperature difference enhances the ion enrichment and dissipation and improves the ion rectification performance of nanopores. On the contrary, negative temperature difference inhibits ion enrichment and dissipation in pores, which is not conducive to improving ion rectification performance. Abnormal behavior is observed for nanopores non-uniform charged only on the outer wall surface, where the negative temperature gradient enhances the accumulation and dissipation of ions within the pores, thereby increasing the rectification ratio. In addition, in order to more clearly understand the ion transport behavior in the ultrashort nanopore under asymmetric temperature conditions, we further investigated the influence of the tip radius of the nanopore, the solution volume concentration, and the charge type of each surface charge distribution on the ion current rectification performance. The results reveal the ion transport mechanism of ultrashort conical nanopores and provide practical guidance for designing and optimizing nanofluidic devices.

Cobalt germanium hydroxides with asymmetric electron distribution and surface hydroxyl groups for superb catalytic degradation performances

Peroxymonosulfate (PMS)-based advanced oxidation processes (AOPs) are attractive approaches for solving the global problem of water pollution, due to the generation of highly-active reactive oxygen species (ROS). Therefore, highly-efficient PMS activation is crucial for promoting the catalytic degradation of environmental pollutants. Here, bimetallic CoGeO2(OH)2 nanosheets with abundant surface hydroxyl groups (CGH) were synthesized via a simple hydrothermal route for PMS activation and degradation of various organic contaminants for the first time. The abundant surface hydroxyl groups (≡Co–OH/≡Ge–OH) could promptly initiate PMS to generate highly-active species: singlet oxygen (1O2), sulfate radicals (SO4·−) and hydroxyl radicals (HO•), while the asymmetric electron distribution among Co–O–Ge bonds derived from the higher electronegativity of Ge than Co further enhances the quick electron transfer to promote the redox cycle of Co2+/Co3+ and Ge2+/Ge4+, thereby achieving an outstanding catalytic capability. The optimal catalyst exhibits nearly 100 % catalytic degradation performance of dyes (Methylene blue, Rhodamine B, Methyl orange, Orange II, Methyl green) and antibiotics (Norfloxacin, Bisphenol A, Tetracycline) over a wide pH range of 3–11 and under different coexisting anion conditions (Cl−, HCO3–, NO3–, HA), suggesting the excellent adaptability for practical usage. This study could potentially lead to novel perspectives on the remediation of water areas such as groundwater and deep-water areas.

Simultaneous close-contact melting on two asymmetric surfaces: Demonstration, modeling and application to thermal storage

The present study deals with melting in a geometry suitable for Latent-Heat Thermal Energy Storage (LHTES) systems, which are of importance for future industrial installations utilizing solar energy or waste heat. The intrinsically high thermal resistance of phase-change materials (PCM) can be remedied by taking advantage of close contact melting (CCM), where the solid phase is separated from a hot surface by only a thin liquid layer. The basic CCM takes place on a horizontal flat surface, but during the last decade its application in various finned LHTES units has been demonstrated experimentally and analyzed numerically.Specifically, the configuration studied in the present work is relevant to a horizontal double-pipe concentric storage unit with a longitudinally finned inner tube. While this rather simple geometry has been extensively studied in the past, the present work is completely novel in its demonstration and analysis of simultaneous close-contact melting on two generally asymmetric surfaces created by the longitudinal fins. A unique experimental apparatus is introduced, based on the so-called 'Mercedes' configuration of the fins. It is designed transparent, allowing for real-time observation of melting sequences. Close-contact melting is achieved by supplying heat to the outer shell of the unit: the solid phase is detached from the shell and moves, by translation and rotation, in the liquid phase. The results from these experiments demonstrate the feasibility of CCM on two asymmetric walls within this system, hinting at the potential for optimizing the melting rate by utilizing a larger portion of the extended surface for CCM.A key component of this study is the development of a reliable numerical approach, which goes beyond the limitations of widely-applied enthalpy-porosity method and combines the general enthalpy formulation, convective heat transfer and general rigid body motion that includes rotation. Therefore, a new numerical model has been devised, using an in-house code realized in MATLAB. A full set of the governing conservation equations is solved using a finite-difference framework, integrated with advanced numerical methods for the fluid-solid interaction and an enthalpy formulation for the phase change process. The model is validated carefully, and then numerical studies are conducted to elucidate the melting process.The present paper presents a further proof of the special role that close-contact melting (CCM) can play in properly designed thermal energy storage units and finned systems in general. It is demonstrated that the fins, when properly designed and oriented, can induce CCM in their vicinity, contributing to a very significant increase in the melting rate, which reflects charging of the unit.

Nanotopography by chromatic confocal microscopy of the endothelium in Fuchs endothelial corneal dystrophy, pseudophakic bullous keratopathy and healthy corneas

AimTo investigate the interest of chromatic confocal microscopy (CCM) to characterise guttae in Fuchs endothelial corneal dystrophy (FECD).MethodsDescemet’s membranes (DM) were obtained during endothelial keratoplasty in patients with FECD and...

Surface-energy ratchet motor with geometrical symmetry driven by biased random walk

A geometrically symmetric gear with asymmetric surface wettability exhibits one-way spin on a vibrating water bed. On the side face of the gear, a parafilm was coated to create asymmetry in the surface energy. The gear shows fluctuations in both directions within a shorter timescale; however, for a longer timescale, the gear exhibits a one-way spin. This unique motion is generated by a stochastic process with a biased driving force produced by the interaction between the vibrating water surface and the side face of the gear. This new model resembles an active Brownian ratchet. Until now, most ratchet motors, which obtain regular motion from nonthermal fluctuations, utilize a geometrical ratchet structure. However, in this study, the surface energy forms a ratchet that rectifies the noisy motion.

Understanding plasticity in multiphase quenching & partitioning steels: Insights from crystal plasticity with stress state-dependent martensitic transformation

This study develops a novel crystal plasticity (CP) model incorporating deformation-induced martensitic transformation (DIMT) and transformation-induced plasticity (TRIP) effect to predict the complex interplay between microstructural evolution and mechanical behavior in a third-generation advanced high-strength steel QP980. This model introduces phenomenological theory of martensite crystallography (PTMC) based TRIP theory and DIMT kinetics grounded on nucleation-controlled phenomenon. Notably, the DIMT model is improved by utilizing a geometric approach for calculating shear band intersections. A virtual multiphase representative volume element (RVE) based on the Voronoi tessellation is generated for the QP980 steel, which comprises ferrite, martensite, and retained austenite (RA). The study highlights how phase transformation affects mechanical properties, notably the strengthening from transformed martensite and the mechanical alterations in RA due to the TRIP effect. The DIMT kinetics dependent on stress states such as uniaxial tension (UT), uniaxial compression (UC), plane strain tension (PST), and equi-biaxial tension (EBT) are analyzed using the developed model. The role of microstructural surroundings on martensitic transformation is also examined. Furthermore, analysis under biaxial loading angles using the model reveals an asymmetric yield surface, with more pronounced changes in yield stress in the tensile region due to accelerated transformation behaviors, as opposed to the more gradual transformations in the compressive region. This study provides valuable insights into the deformation mechanisms of the third-generation advanced high-strength steels including relationship between plastic anisotropy, transformation kinetics, and microstructural evolution.

High-efficiency dysprosium-ion extraction enabled by a biomimetic nanofluidic channel

Biological ion channels exhibit high selectivity and permeability of ions because of their asymmetrical pore structures and surface chemistries. Here, we demonstrate a biomimetic nanofluidic channel (BNC) with an asymmetrical structure and glycyl-L-proline (GLP) -functionalization for ultrafast, selective, and unidirectional Dy3+ extraction over other lanthanide (Ln3+) ions with very similar electronic configurations. The selective extraction mainly depends on the amplified chemical affinity differences between the Ln3+ ions and GLPs in nanoconfinement. In particular, the conductivities of Ln3+ ions across the BNC even reach up to two orders of magnitude higher than in a bulk solution, and a high Dy3+/Nd3+ selectivity of approximately 60 could be achieved. The designed BNC can effectively extract Dy3+ ions with ultralow concentrations and thereby purify Nd3+ ions to an ultimate content of 99.8 wt.%, which contribute to the recycling of rare earth resources and environmental protection. Theoretical simulations reveal that the BNC preferentially binds to Dy3+ ion due to its highest affinity among Ln3+ ions in nanoconfinement, which attributes to the coupling of ion radius and coordination matching. These findings suggest that BNC-based ion selectivity system provides alternative routes to achieving highly efficient lanthanide separation.

Tuning electronic structure of metal-free dual-site catalyst enables exclusive singlet oxygen production and in-situ utilization

Developing eco-friendly catalysts for effective water purification with minimal oxidant use is imperative. Herein, we present a metal-free and nitrogen/fluorine dual-site catalyst, enhancing the selectivity and utilization of singlet oxygen (1O2) for water decontamination. Advanced theoretical simulations reveal that synergistic fluorine-nitrogen interactions modulate electron distribution and polarization, creating asymmetric surface electron configurations and electron-deficient nitrogen vacancies. These properties trigger the selective generation of 1O2 from peroxymonosulfate (PMS) and improve the utilization of neighboring reactive oxygen species, facilitated by contaminant enrichment at the fluorine-carbon Lewis-acid adsorption sites. Utilizing these insights, we synthesize the catalyst through montmorillonite (MMT)-assisted pyrolysis (NFC/M). This method leverages the role of MMT as an in-situ layer-stacked template, enabling controlled decomposition of carbon, nitrogen, and fluorine precursors and resulting in a catalyst with enhanced structural adaptability, reactive site accessibility, and mass-transfer capacity. The NFC/M demonstrates an impressive 290.5-fold increase in phenol degradation efficiency than the single-site analogs, outperforming most of metal-based catalysts. This work not only underscores the potential of precise electronic and structural manipulations in catalyst design but also advances the development of efficient and sustainable solutions for water purification.

Design Method of Freeform Surface Optical Systems with Low Coupling Position Error Sensitivity.

Freeform off-axis reflective systems are significantly more difficult to align and assemble owing to their asymmetric surface shapes and system structures. In this study, a freeform surface system design method with low coupling position error sensitivity (FCPESM) was proposed. First, we established a mathematical model of a reflective system when it was perturbed by coupling position errors and used the clustering-microelement method to establish the coupling error sensitivity evaluation function. The evaluation function was then applied to the design process of a freeform surface off-axis three-mirror optical system. The results showed that the FCPESM optical design method can significantly relax the assembly tolerance requirements of optical systems on the basis of ensuring image performance. In this study, the reflective system was perturbed by tilt and decenter simultaneously, and the disturbance mechanism of position errors on optical systems was further improved. Through this research, freeform surface systems with both image performance and error sensitivity can be obtained, which makes freeform off-axis reflective systems with better engineering realizability.

Bi-layered polyurethane nanofiber patches with asymmetrical surface prevent postoperative adhesion and enhance cardiac repair

The adhesion between heart and chest post-operation raises a significant challenge for the application of cardiac patches due to its severe influences on the recovery of heart function and increased risk of re-treatment. Anabatic inflammatory response and increased oxidative stress aggravate the damage to heart functions. Herein, a multi-functional cardiac patch was manufactured by successive electrospinning of two types of novel selenium-containing polyurethanes (PU), followed by click grafting of poly (ethylene glycol) (PEG) molecules on the top layer. This patch possessed dual-functions of postoperative anti-adhesion and anti-oxidative stress for efficient therapy post myocardial infarction (MI). The high redox reactivity of diselenium bonds were introduced into the main chains of PU, which reduced the level of reactive oxygen species (ROS) and modulated the inflammatory environment, alleviating the synechia formation simultaneously. The cardiac patch could effectively resist fibroblast adhesion, regulate the expression of vinculin and tissue-type plasminogen activator (t-PA), and inhibit the synechia formation. Meanwhile, it also restored significantly the heart function post MI by decreasing the local inflammation, facilitating less collagen formation, and improving cell signal transduction and angiogenesis. Collectively, this novel patch achieved anti-adhesion and therapeutic effect synergistically, bringing advancement in cardiac patch design and potential for translation of medicinal devices.

Fishbone-like micro-textured surface for unidirectional spreading of droplets and lubricity improvement

Directional spreading of droplets on asymmetrical micro-structures surface has attract interests of researchers for its significant application potential in scientific and engineering fields. In this paper, a fishbone-like micro-textured surface (FMS) is proposed, which exhibits efficient unidirectional spreading behavior of droplets (maximum forward-backward spreading coefficient up to 3.7). The effect of geometrical characters on spreading performance are studied, thus facilitating obtainment of optimal parameters of the FMS. Such type of micro-structured surface is arranged on noncontact areas of pin-on-disk tribological system. Experimental results demonstrate the FMS has lubrication retention effect, resulting in reduction of friction and wear. The maximum reduction rate of friction coefficient is 63.3 % compared with the bare specimen.

Solar water evaporation-induced long-term locomotion of self-propelled soft robots

Self-propelled soft robots have attracted extensive attention because of their unique application in exploring dangerous and complex environments that are unsuitable for human beings. However, these soft robots require cyclical chemical stimulation or external power and have short locomotion times, which limits their practical applications. It remains challenging to create self-propelled soft robots exhibiting long-term locomotion. Here, we couple an active hydrogel with a solar absorbing coating to realize self-propelled soft robots with long-term locomotion. The active hydrogel can move freely on the water surface by continuously establishing asymmetric surface tension through dynamic wetting. The sunlight absorbers promote water evaporation inside the self-propelled soft robot to delay or even disrupt the swelling equilibrium of the hydrogel, thus establishing dynamic balance between water absorption and evaporation. In this way, the locomotion time of this self-propelled soft robot under constant light irradiation equivalent to 1 sun (1 kW/m2) is 6.5 times higher than that of active hydrogel reported previously. Owing to the enhanced locomotion time through solar water evaporation water, this self-propelled soft robot is expected to be applied to oil pollution exploration, cargo transportation, and debris cleaning in small water areas.

Novel Proniosomes of Manidipine: Optimization and In-vivo Evaluation

The objective of the current study is to produce proniosomes of manidipine using the thin film hydration method for the management of hypertension. Statistical optimization was performed using the Box-Behnken design. The generated formulations were tested for particle size, entrapment effectiveness, and drug release at 12 hours. The improved proniosomes were further assessed for surface morphology, ATR, and differential scanning calorimetry (DSC). The improved proniosomes were also assessed for an in-vitro and in-vivo investigation on dexamethasone-induced hypertension. It was noted that there was no significant interaction with excipients. DSC indicated a considerable shift in the endothermal peak and showed interaction with the study’s excipients. Niosomes and drug crystals were seen to be dispersed in small areas during the scanning electron microscope (SEM) analysis. The study also showed that the optimized proniosomes have asymmetrical surfaces and appearances. The zeta value in the research was -6.7 mV, indicating stability. According to the optimized proniosomes formulation, F14 released 99.97% of the drug at its highest concentration in 12 hours. ANOVA results from an in-vivo investigation confirmed a satisfactory outcome in decreasing raised blood pressure, as shown by the F and p-values.

Janus Flexible Device with Microcone Channels for Sampling and Analysis of Biological Microfluidics.

Controlling the spontaneous directional transport of droplets plays an important role in the application of microchemical reactions and microdroplet detection. Although the relevant technologies have been widely studied, the existing spontaneous droplet transport strategies still face problems of complex structure, single function, and poor flexibility. Inspired by the spontaneous droplet transport strategy in nature, an asymmetric wettability surface with microcone channels (AWS-MC) is prepared on a flexible fabric by combining surface modification and femtosecond laser manufacturing technology. On this surface, the capillary force and Laplace pressure induced by the wettability gradient and the geometric structure gradient drive the droplet transport from the hydrophobic surface to the hydrophilic surface. Notably, droplets in adjacent hydrophilic regions do not exchange substances even if the gap in the hydrophilic region is only 1 mm, which provides an ideal platform for numerous detections by a single drop. The droplet transport strategy does not require external energy and can adapt to the manipulation of various droplet types. Application of this surface in the blood of organisms is demonstrated. This work provides an effective method for microdroplet-directed self-transport and microdroplet detection.

Predictive modeling of oleuropein release from double nanoemulsions: An analytical study comparing intelligent models and Monte Carlo simulation

The objective of this study was to evaluate the release of oleuropein (OLP) from double nanoemulsions stabilized with polymeric complexes. Initially, W1/O nano-emulsions loaded with OLP were prepared and re-emulsified into an aqueous phase (W2), which included a complex of whey protein concentrate (WPC)/pectin, to form W1/O/W2 emulsions. The microstructure of the final double emulsions was analyzed by scanning electron microscopy (SEM), and particles with smooth, comparatively spherical, and somewhat asymmetrical surfaces with a size range of 100–200 nm were observed, which were compatible with dynamic light scattering (DLS) data. The release trend of OLP was determined by fitting it to several empirical models including zero order, first order, Higuchi, Hixson-Crowell, Korsemeyer-Peppas, Baker-Lonsdale, and utilizing intelligent modeling techniques such as Fuzzy Logic (FL) and Artificial Neural Networks (ANNs). Among the mathematical models, the zero order equation had the highest coefficient of determination (R2 = 0.988), while the first order equation had the lowest root-mean-square error (RMSE = 0.0176) and sum of squared errors (SSE = 0.0009) for the goodness of fit of the model, when considering the release trend of OLP. FL and ANNs proved effective in modeling controlled release of OLP-loaded nanocarriers, achieving high R2 values. Additionally, Monte Carlo (MC) simulation showed potential for evaluating the release process when compared to other methods.

The South American precipitation trends under (or not) El Niño‐Southern Oscillation influences and relationship with large‐scale circulation

AbstractThe precipitation trend patterns in South America (SA) are determined using trend empirical orthogonal function analysis for the 1951–2016 period. The associated large‐scale tropical and extratropical anomalous circulation patterns are also examined. The words “total” and “residual” refer to the monthly anomalies and monthly anomalies without the El Niño–Southern Oscillation (ENSO) effects, respectively. The total precipitation features a positive trend in southeastern SA (SESA, southern Brazil, Uruguay, most of eastern Argentina) and northern Chile, and a negative trend over central‐eastern Brazil and central Amazonia. The residual precipitation shows an increased positive trend over most of the coastal extension of northern SA and Colombia; a weak positive trend over southern Brazil, northeastern Argentina, and northern Chile; and a negative trend over central‐eastern SA and western Amazonia. The differences between the total and residual precipitation trend patterns in tropical SA is explained as responses to total and residual zonally asymmetric anomalous sea surface temperature (SST) patterns, respectively. The total SST pattern along the equatorial Pacific configures the Pacific Decadal Oscillation, which impacts ENSO variability and as response intensifies the Walker circulation. Without the ENSO, the Walker cell is mainly driven by the tropical Indian and Atlantic Oceans, which configure residual asymmetric anomalous warming. Furthermore, the warming in the equatorial Indian and eastern Pacific Oceans, in the presence of ENSO, induces a Rossby wave train‐type anomalous pattern that extends across the South Pacific into SA and modulates the atmospheric anomalous circulation over SESA. In this region, an anomalous anticyclonic accompanied by an intensified South American Low‐Level Jet induces a moisture transport to SESA. This anticyclone is also observed in the absence of ENSO but is weaker. The results suggest the importance of ocean warming in the western Pacific‐Indian in the modulation of extratropical teleconnections to SESA in the tropical ocean warming scenario.