Asymmetric Configuration Research Articles

Searches for mass-asymmetric compact binary coalescence events using neural networks in the LIGO/Virgo third observation period

We present the results on the search for the coalescence of compact binary mergers with very asymmetric mass configurations using convolutional neural networks and the LIGO/Virgo data for the O3 observation period. Two-dimensional images in time and frequency are used as input. Masses in the range between 0.01 Msun and 20 Msun are considered. We explore neural networks trained with input information from a single interferometer, pairs of interferometers, or all three interferometers together, indicating that the use of the maximum information available leads to an improved performance. A scan over the O3 data set using the convolutional neural networks for detection results into no significant excess from an only-noise hypothesis. The results are translated into 90% confidence level upper limits on the merger rate as a function of the mass parameters of the binary system.

Retina-inspired narrowband perovskite sensor array for panchromatic imaging.

The retina is the essential part of the human visual system that receives light, converts it to neural signal, and transmits to brain for visual recognition. The red, green, and blue (R/G/B) cone retina cells are natural narrowband photodetectors (PDs) sensitive to R/G/B lights. Connecting with these cone cells, a multilayer neuro-network in the retina provides neuromorphic preprocessing before transmitting to brain. Inspired by this sophistication, we develop the narrowband (NB) imaging sensor combining R/G/B perovskite NB sensor array (mimicking the R/G/B photoreceptors) with a neuromorphic algorithm (mimicking the intermediate neural network) for high-fidelity panchromatic imaging. Compared to commercial sensors, we use perovskite "intrinsic" NB PD to exempt the complex optical filter array. In addition, we use an asymmetric device configuration to collect photocurrent without external bias, enabling a power-free photodetection feature. These results display a promising design for efficient and intelligent panchromatic imaging.

Development of a Quartz-Based Photo-Mobile Polymer Film for Controlled Motion Triggered by Light or Heat.

We have developed a photo-mobile polymer film, that combines organic and inorganic materials, to allow for controlled motion that can be triggered by light or heat. Our film is made using recycled quartz and consists of two layers: a multi-acrylate polymer layer and a layer containing oxidized 4-amino-phenol and N-Vinyl-1-Pyrrolidinone. The use of quartz in our film also gives it a high temperature resistance of at least 350 °C. When exposed to heat, the film moves in a direction that is independent of the heat source, due to its asymmetrical design. Once the heat source is removed, the film returns to its original position. ATR-FTIR measurements confirm this asymmetrical configuration. This technology may have potential applications in energy harvesting, due to the piezoelectric properties of quartz.

Microfluidic Bi-Layer Platform to Study Functional Interaction between Co-Cultured Neural Networks with Unidirectional Synaptic Connectivity

The complex synaptic connectivity architecture of neuronal networks underlies cognition and brain function. However, studying the spiking activity propagation and processing in heterogeneous networks in vivo poses significant challenges. In this study, we present a novel two-layer PDMS chip that facilitates the culturing and examination of the functional interaction of two interconnected neural networks. We utilized cultures of hippocampal neurons grown in a two-chamber microfluidic chip combined with a microelectrode array. The asymmetric configuration of the microchannels between the chambers ensured the growth of axons predominantly in one direction from the Source chamber to the Target chamber, forming two neuronal networks with unidirectional synaptic connectivity. We showed that the local application of tetrodotoxin (TTX) to the Source network did not alter the spiking rate in the Target network. The results indicate that stable network activity in the Target network was maintained for at least 1–3 h after TTX application, demonstrating the feasibility of local chemical activity modulation and the influence of electrical activity from one network on the other. Additionally, suppression of synaptic activity in the Source network by the application of CPP and CNQX reorganized spatio-temporal characteristics of spontaneous and stimulus-evoked spiking activity in the Target network. The proposed methodology and results provide a more in-depth examination of the network-level functional interaction between neural circuits with heterogeneous synaptic connectivity.

Application of asymmetrical configuration in electrochemical noise to investigate corrosion inhibition of aluminum alloy by Ranunculus Arvensis/silver nanoparticles

Asymmetric Configuration (As-Co) in the electrochemical noise (EN) was used to evaluate Ranunculus Arvensis / silver nanoparticles (RA/Ag NPs) as corrosion inhibitor for aluminum alloy (AA 2030) when gets exposed to 3.5% NaCl media. The ECN results of Asymmetric Configuration (As-Co) and Symmetric Configuration (Sy-Co) were interpreted using wavelet and statistical methods. The standard deviation of partial signal (SDPS) plots derived using of wavelet. The SDPS plot of As-Co demonstrated that the quantity of electric charge (Q) decreased with the addition of the inhibitor up to the optimum amount (200 ppm) due to the decreased corrosion rate. Moreover, the use of As- Co leads to record signal of one electrode and prevent recording extra signals arising from two identical electrodes which confirmed by the statistical parameters. The As-Co made of Al alloys were more satisfactory for estimating inhibiting effect of RA/Ag NPs compared to Sy-Co. Besides, aqueous extract of Ranunculus Arvensis (RA) plant as reducing agent mediates the synthesis of silver nanoparticles (RA/Ag NPs). The prepared NPs have been elaborately characterized using Field-Emission Scanning Electron Microscopy (FESEM), X-Ray Diffraction (XRD) analysis, and Fourier-Transform Infrared Spectroscopy (FT-IR) that revealed suitable synthesize of the RA/Ag NPs.

Analysis of Homogeneous/Heterogeneous Reactions in an Electrohydrodynamic Environment Utilizing the Second Law.

In this study, we investigate what happens to entropy in the presence of electrokinetic phenomena. It is speculated that the microchannel has an asymmetrical and slanted configuration. The presence of fluid friction, mixed convection, Joule heating, presence and absence of homogeneity, and a magnetic field are modelled mathematically. It is also emphasized that the diffusion factors of the autocatalyst and the reactants are equal. The governing flow equations are linearized using the Debye-Huckel and lubrication assumptions. The resulting nonlinear couple differential equations are solved using the program's integrated numerical solver, Mathematica. We take a graphical look at the results of homogeneous and heterogeneous reactions and talk about what we see. It has been demonstrated that homogeneous and heterogeneous reaction parameters affect concentration distribution f in different ways. The Eyring-Powell fluid parameters B1 and B2 display an opposite relation with the velocity, temperature, entropy generation number, and Bejan number. The mass Grashof number, the Joule heating parameter, and the viscous dissipation parameter all contribute to the overall increase in fluid temperature and entropy.

Symmetric and Asymmetric Strengthening of Two-Span RC Beams Using FRCM Systems

This paper reports on the feasibility of using fabric-reinforced cementitious matrix (FRCM) systems to strengthen two-span reinforced concrete (RC) beams that are structurally deficient in their sagging regions. In addition to one unstrengthened control beam, nine beams strengthened either symmetrically or asymmetrically with polyparaphenylene benzobisoxazole (PBOFRCM), carbon (CFRCM), and carbon fiber–reinforced polymer (CFRP) sheets were tested under a five-point load configuration. Test results showed that increasing the strengthening ratio resulted in significant increases in the yielding and load-carrying capacity of the beams. Beams symmetrically strengthened with PBOFRCM showed high ductility indices ranging between 100% and 121% of that of the control beam, whereas those strengthened with CFRCM and CFRP showed ductility indices of 45% and 34% of that of the control beam, respectively. Moreover, beams symmetrically strengthened with PBOFRCM systems encountered moment redistribution ratios between 42% and 82% of that of the control beam compared with 10% and 9% only for those strengthened with CFRCM and CFRP systems, respectively. The asymmetric strengthening configuration in which FRCM systems were used along with CFRP sheets proved to be an efficient method to enhance the ductility and moment redistribution capacity of the strengthened beams. Analytically, the rigid-body-rotation approach was modified to predict the moments and curvatures at the plastic hinges of the strengthened sections. The predicted moments and curvatures showed a notable agreement with the experimental values.

The Asymmetric Total Synthesis and Configuration Confirmation of Aplysiaenal and Nhatrangin A, Truncated Derivatives of Aplysiatoxin and Oscillatoxin.

Asymmetric total syntheses of aplysiaenal (1) and nhatrangin A (2), truncated derivatives of the aplysiatoxin/oscillatoxin family of marine natural products, from configurationally defined intermediates are described. NMR spectra of our synthesized nhatrangin A did not match with either those obtained from authentic samples of the natural product or material obtained via two other total syntheses, but were similar to that obtained from a sample obtained in a third total synthesis. By independently synthesizing the fragments used in its total syntheses, we were able to confirm the configuration of nhatrangin A and clarified that the discrepancy in the spectroscopic data is due to salt formation of the carboxylic acid moiety.

The Spatial Analysis of Vegetation Cover and Permafrost Degradation for a Subarctic Palsa Mire Based on UAS Photogrammetry and GPR Data in the Kola Peninsula

Subarctic palsa mires undergo substantial transformation under climate impacts, and today a reliable marker of their degradation is the vegetation cover. We studied the correspondence between the surface traits of palsa degradation, as expressed in the vegetation composition, and the interior condition of permafrost within subarctic palsa mires in the central part of the Kola Peninsula. We have employed a set of methods to collect the data, including geobotanical relevés, unmanned aerial system (UAS) photogrammetry, and ground-penetrating radar (GPR) survey. Based on RGB orthophoto values and morphometric variables, we produced a land cover classification (LCC) consistent with the vegetation classes identified during field measurements. The outcome proves that the additional morphometric predictors improve the accuracy of classification algorithms. We identified three major patterns in GPR cross-sections defining (i) permafrost in palsas, (ii) water saturated peat, and (iii) the regular peat layer. As a result, our GPR data demonstrated a high correlation with land cover classes and pointed to some vegetation features controlled by the peat deposit inner structure. Under our results, palsas with thawing permafrost can be appraised using sequences of LCC. This is primarily the lichen hummock—tall shrub—carpet vegetation (LH–TSh–C) sequence from palsa top to foot. We have also detected an asymmetric configuration of permafrost in some palsas in the west-to-east direction and hypothesized that it can relate to the wind regime of the area and snow accumulation on the eastern slopes. Our results highlight that the combined application of the remote UAS photogrammetry and GPR survey enables a more precise delineation of the lateral degradation of palsas.

Enhanced performance with ionic and organic redox-couple electrolytes on MTMO anchored CQD nanocomposites and renewable carbon-based asymmetric flexible supercapacitor

The work utilizes a hybrid approach at electrode and electrolyte systems to fabricate a high-energy density supercapacitor. Hybrid nanocomposite electrodes were fabricated using a facile hydrothermal synthesis. The kinetics were studied by preparing in-situ and ex-situ nanocomposites. The in-situ preparation delivers a homogeneous flower petal-like interconnected porous morphology with an appreciable BET surface area of 97 m2 g−1. The actual electrochemical performance was analyzed by accounting for discharge area instead of discharge time to avoid discrepancies related to hybrid energy storage systems. The three-electrode measurement suggests that the electrode delivers an excellent specific capacitance of 3802 F g−1 at 1 A g−1. In the asymmetric configuration, the device reveals excellent actual specific capacitance of 292 F g−1 at 1 A g−1. However, upon adding 0.02 M KI as redox mediators in a traditional electrolyte (6 M KOH), a ∼37% increase in specific capacitance is achieved without the degradation in the device stability. The nanoarchitecture porous morphology and modification in traditional electrolyte enables a high-performance device having an energy density of 165 Wh kg−1 at a power density of 1000 W kg−1, which retain till 50 Wh kg−1 at 25 kW kg−1. The nanocomposite also shows excellent compatibility in a flexible device assembly, delivering a specific capacitance of 192 mF cm−1 at 1 mA cm−1 without deteriorating its performance upon different bending angles. The study claims the design of a low-cost, environmentally benign, and facile approach for developing a high-performance hybrid supercapacitor.

How does technological innovation drive green growth in China’s complex environments? A configurational approach

This article employs asymmetric configuration theory and methods to investigate how technological innovation drives regional green growth in China’s complex environment. Specifically, the pooled QCA method is employed to identify multiple driving paths for technological innovation-driven regional green growth. Three configurations for high green growth have been identified: (1) a configuration with high IRD (internal R&D), non-high GS (government support), non-high TM (technology market), and non-high ER (environmental regulation) as core conditions; (2) a configuration with high IRD, non-high NRD (non-R&D) and non-high ER as core conditions complemented by high TM; and (3) a configuration with high levels of IRD, ERD (external R&D) and TM, and non-high ER as core conditions. Furthermore, high IRD is essential for green growth, while strict environmental regulations may be detrimental. This article offers a theoretical basis for adjusting innovation strategies or improving relevant policies to promote green growth in China.

A Solid-State Wire-Shaped Supercapacitor Based on Nylon/Ag/Polypyrrole and Nylon/Ag/MnO2 Electrodes.

In this work, a novel wire-shaped supercapacitor based on nylon yarn with a high specific capacitance and energy density was developed by designing an asymmetric configuration and integrating pseudocapacitive materials for both electrodes. The nylon/Ag/MnO2 yarn was prepared as a positive electrode by electrochemically depositing MnO2 on a silver-paste-coated nylon yarn. Additionally, PPy was prepared on nylon/Ag yarn by chemical polymerization firstly to enlarge the surface roughness of nylon/Ag, and then the PPy could be easily coated on the chemically polymerized nylon/Ag/PPy by electrochemical polymerization to obtain a nylon/Ag/PPy yarn-shaped negative electrode. The wire-shaped asymmetric supercapacitor (WASC) was fabricated by assembling the nylon/Ag/MnO2 electrode, nylon/Ag/PPy electrode and PAANa/Na2SO4 gel electrolyte. This WASC showed a wide potential window of 1.6 V and a high energy density varying from 13.9 to 4.2 μWh cm-2 with the corresponding power density changing from 290 to 2902 μW cm-2. Meanwhile, because of the high flexibility of the nylon substrate and superior adhesion of active materials, the WASC showed a good electrochemical performance stability under different bending conditions, suggesting its good flexibility. The promising performance of this novel WASC is of great potential for wearable/portable devices in the future.

Effect of Asymmetric Fins on Thermal Performance of Phase Change Material-Based Thermal Energy Storage Unit.

Phase change material (PCM)-based thermal energy storage units (TESU) have very low thermal conductivity that compromise their charging and discharging rate. The present study focuses on an enhancement in charging rate as well as an increase in the uniformity of the melting rate. A rectangular cavity consisting of two horizontal partial fins is studied. The horizontal partial fins are placed symmetrically in a PCM-based TESU. In the current work, the melting rate of PCM was enhanced using asymmetric arrangement while keeping all other parameters the same, thus showing the positive effect of asymmetric configuration in such storage systems. The position and the pitch of each fin is optimized to improve heat transfer characteristics of the TESU. The numerical investigation of the problem is performed. TESU with asymmetrically placed fins show better performance in terms of higher charging rate as well as uniformity of the charging rate. The asymmetric placement of the fins suggested by present study increased the charging rate by 74.3% on average as compared to the symmetrically placed fins in the storage system. The charging rate uniformity is improved by 43.7%. The asymmetric fin's placement conserved the convection strength for a longer melting duration and so increased the Nusselt number by 80.2% as compared to the symmetrically placed fins. Thus, it can be concluded that the performance of asymmetric fins is better in the charging of PCMs than the symmetrically placed fins in a PCM-based TESU.

Multiferroic properties in Fe-site engineered PbFe1/2Nb1/2O3 with distinct antisymmetric spin interaction

Multiferroic Fe-site engineered lead iron niobate [Pb(Fe1/2Nb1/2)O3, PFN] was prepared by partially substituting Fe with Ni, Co, and Cr, which comprise distinct Bohr magnetons, to investigate the effect of the variation in spin configurations on magnetic and multiferroic properties. All the studied compositions exhibited a single-phase perovskite structure, wherein the lattice constant decreased with increasing substitutions. The inherent ferroelectric order was preserved when Ni or Co ions were introduced, while the introduction of Cr made the samples too lossy, which prevented the verification of the possible ferroelectricity. Substitution of Fe with different transition metals in PFN, which is originally paramagnetic at room temperature, resulted in oriented spin configurations that led to distinct magnetic orders: soft ferromagnetic, hard ferromagnetic, and antiferromagnetic orders for Ni, Co, and Cr, respectively. This distinction mainly stems from the interspin distance and the spin moment, both of which are important factors during the spin exchange interaction. The interspin distance of pristine and Cr-substituted PFN is too long and short, respectively, to induce ferromagnetic properties. Moreover, at room temperature, magnetic-field-dependent magnetoelectric coupling was observed only for the Ni- and Co-substituted PFN owing to their asymmetric spin configuration. This research could lead to a general method for modulating the magnetic properties of multiferroic perovskite oxides.

Seismic Behavior of Multi-Storey Structure Using Different Energy Dissipation Devices A-review

Earthquake is a most disaster event, responsible a lot of structural damage and casualties worldwide on the earth’s surface without any early warning. The trends in using dampers in buildings and tall buildings, increasing yearly based on their outstanding feature during an earthquake event. Typically, there are four types of energy dissipation device system such as friction damper, viscous damper, viscoelastic damper and metallic damper. The theoretical and experimental study results indicate that all fourth types of dampers can be able to minimize the structural damages and cracking during an earthquake occurrence event. But only viscous damper device has an acceptable feature against of earthquake forces as compare to other kinds of damper devices in symmetric and asymmetric building plan configurations as well. Based on the reviews, a viscous damper device system plays major role in reducing the lateral displacement of buildings about 30% to 85%, inter-storey drift of building about 60% to 80% and 1487.82KN drop in base shear of structural components in symmetric and asymmetric building plan configurations upward as compared to friction dampers, viscoelastic dampers and metallic dampers. Contradictory, dampers can decrease the construction cost limitation of multi-storey structures economically rather than conventional buildings.

Effect of Sac Asymmetry, Neck and Iliac Angle on the Hemodynamic Behavior of Idealized Abdominal Aortic Aneurysm Geometries

Abdominal Aortic Aneurysms (AAAs) are currently treated based on the universal maximum diameter criterion, but other geometric variables may play a role in the risk of rupture. The hemodynamic environment inside the AAA sac has been shown to interact with several biologic processes which can affect prognosis. AAA geometric configuration has a significant impact in the hemodynamic conditions that develop, which has only been recently realized, with implications for rupture risk estimations. We aim to perform a parametric study to evaluate the effect of aortic neck angulation, angle between the iliac arteries and sac asymmetry on the hemodynamic variables of AAAs. This study uses idealized AAA models and it is parametrized in terms of three quantities: the neck angle, φ(o), iliac angle, θ(o), and sac asymmetry, SA(%), each of which accepts three different values, specifically φ=(0o,30o,60o),θ=(40o,60o,80o), and SA=(S,SS,OS) where the sac asymmetry can either be on the same side with respect to neck (SS) or on the opposite side (OS). Time Average Wall Shear Stress (TAWSS), Oscillatory Shear Index (OSI), Relative Residence Time (RRT) and the velocity profile are calculated for different geometric configurations while the percentage of the total surface area under thrombogenic conditions, using thresholds previously reported in the literature, is also recorded. In case of an angulated neck and a higher angle between iliac arteries, favorable hemodynamic conditions are predicted with higher TAWSS and lower OSI and RRT values. The area under thrombogenic conditions reduces by 16%-46% as the neck angle increases from 0o to 60o, depending on the hemodynamic variable under consideration. The effect of iliac angulation is present but less pronounced with 2.5%-7.5% change between the lower and the higher angle. The effect of sac asymmetry seems to be significant for OSI with a non-symmetrical configuration being hemodynamically favorable, which in the presence of an angulated neck is more pronounced for the OS outline. Favorable hemodynamic conditions develop inside the sac of idealized AAAs with increasing neck and iliac angles. Regarding the sac asymmetry parameter, asymmetrical configurations most often appear advantageous. Concerning the velocity profile the triplet (φ,θ,SA) may affect outcomes under certain conditions and thus should be taken into account when parametrizing the geometric characteristics of AAAs.

Advances on Microsupercapacitors: Real Fast Miniaturized Devices toward Technological Dreams for Powering Embedded Electronics?

Microsupercapacitors (MSCs) have emerged as the next generation of electrochemical energy storage sources for powering miniaturized embedded electronic and Internet of Things devices. Despite many advantages such as high-power density, long cycle life, fast charge/discharge rate, and moderate energy density, MSCs are not at the industrial level in 2022, while the first MSC was published more than 20 years ago. MSC performance is strongly correlated to electrode material, device configuration, and the used electrolyte. There are therefore many questions and scientific/technological locks to be overcome in order to raise the technological readiness level of this technology to an industrial stage: the type of electrode material, device topology/configuration, and use of a solid electrolyte with high ionic conductivity and photopatternable capabilities are key parameters that we have to optimize in order to fulfill the requirements. Carbon-based, pseudocapacitive materials such as transition metal oxide, transition metal nitride, and MXene used in symmetric or asymmetric configurations are extensively investigated. In this Review, the current progress toward the fabrication of MSCs is summarized. Challenges and prospectives to improve the performance of MSCs are discussed.

Resonator-like behavior of a wall-bounded precessing vortex core in a diffuser with wall asymmetries

This paper reports a detailed investigation of the interaction between a wall-bounded precessing vortex core (PVC) occurring in swirling flows after vortex breakdown and a wall asymmetry. Experiments are carried out in an axisymmetric diffuser downstream of an axial swirl generator inducing a swirling flow with a swirl number of S = 1.1. Wall pressure measurements and two-component particle image velocimetry (PIV) are conducted for Reynolds numbers (Re) ranging from 20 000 to 76 000 in the initial axisymmetric configuration and several asymmetric configurations, with an additional cylindrical protrusion placed on the diffuser wall at different streamwise and circumferential positions. It is first confirmed that synchronous pressure fluctuations at the PVC frequency are only produced in asymmetric configurations. Furthermore, the analysis of the pressure data in several asymmetric configurations revealed for the first time a resonator-like behavior of a wall-bounded PVC. While a change of the protrusion circumferential position in a given cross section of the diffuser only affects the phase of the synchronous pressure fluctuations, the amplitude of the latter features successive minima (pressure node) and maxima (pressure anti-node) as the protrusion is moved along the diffuser in the streamwise direction. In addition, as the protrusion is moved closer to a pressure node, the phase of the synchronous pressure fluctuations exhibits a sudden variation of ±π. Similar results are observed for all tested values of Reynolds number, whereas the PVC frequency linearly increases with Re. A reconstruction of the PVC helical structure based on PIV measurements showed that these consecutive pressure nodes are spaced by a distance equal to approximately one third of the PVC helical pitch. Finally, it also revealed that two different states are observed, depending on the position of the protrusion along the diffuser: the synchronous pressure component reaches its maximum value as the PVC center is approaching either its closest or farthest angular position with respect to the protrusion. The transition from one state to another one depends on the streamwise position of the protrusion with respect to the pressure nodes. These unprecedented experimental observations pave the way to novel theoretical developments for a better understanding and modeling of synchronous pressure fluctuations induced by wall-bounded PVC in asymmetric geometries.

Hardware Design and Implementation of FPGA Controlled Seven-Level Reduced Switch MLI

The paper proposes the design of a seven-level reduced switch multi-level inverter (7LRS-MLI) topology. The design produces a seven-level staircase output waveform with fewer components (seven power switches), thus reducing the cost and area and improving the performance of the design, i.e. increasing efficiency and reducing switching loss effectively. Both symmetric and asymmetric configurations have been implemented and the results are discussed in the paper. A comparison of the proposed structure with other recent seven-level structures has been illustrated. The simulation (using MATLAB/SIMULINK software) and experimental validation of 7LRS-MLI also have been performed for R, RL load, change in load and change in a modulation index (MI). Field programmable gate arrays (FPGA) have been used for digital implementation of the switching waveforms which reduces design time and improves flexibility. For switching devices, the alternative phase opposite disposition pulse width modulation (APOD-PWM) technique is used at 500 Hz and 5 kHz. The voltage and current total harmonic distortion (THD) profiles are also computed during the simulation and experimental validation.

Advancing insights towards electrocatalytic activity of La/Ba-Sr-Co-Fe-O-based perovskites for oxygen reduction & evolution process in reversible solid oxide cell

Electrocatalytic activity of La/Ba-Sr-Co-Fe-O-based mixed ionic and electronically conducting (MIEC) perovskites has been studied for selective oxygen reduction (ORR) and evolution (OER) processes applicable in Reversible Solid Oxide Cell (R-SOC). XPS study establishes scavenging of oxygen vacancy in LSCF and generation of the same in BSCF. BSCF enables faster oxygen ion transport and is correlated with lower frontier molecular orbital (FMO) energy gap of 1.18 eV derived from density functional theory (DFT). Relatively higher ΔEFMO(Absolute) 1.75 eV in LSCF accounts for higher charge transfer. Amperometric measurements @800℃ in asymmetric cell configuration exhibit lowest time-dependent current loss of 0.019 mA.h-1 & 0.035 mA.h-1 for BSCF & LSCF under applied anodic (+0.8 V) and cathodic potentials (-0.8 V) for 200 h with respective surface resistances (Rs) of 0.19 Ω.cm2 and 0.081 Ω.cm2. H2 flux of 0.4Nl.h-1.cm-2 obtained with BSCF, establishes its effectivity as OER whereas LSCF is found to be more selective in ORR.