The doping of semiconductor materials through some facile and appropriate methods holds significant promise in enhancing the catalytic performance of catalysts. Herein, NiCo2O4/g-C3N4 composite catalysts were synthesized via a high-energy ball milling method. The microstructure and physicochemical characterization of the as-prepared composites confirmed the successful loading of NiCo2O4 nanoparticles onto the g-C3N4 nanosheets. The NiCo2O4/g-C3N4 composites showed excellent catalytic effect under visible light/ultrasonic irradiation, and the efficiency of tetracycline hydrochloride (TCH) degradation reached 90% within 15 min. The optical properties of g-C3N4 nanosheets were improved by doping, and the diffusion of active materials and carrier migration rate were improved by ultrasonic assistance. Possible catalytic mechanisms and potential pathways of the NiCo2O4/g-C3N4 composites for the degradation of TCH triggered by visible light/ultrasonic irradiation were proposed. This study provides a new strategy for energy-assisted photocatalytic degradation of organic pollutants.
Read full abstract