Argon Research Articles

Role of growth temperature on microstructural and electronic properties of rapid thermally grown MoTe2 thin film for infrared detection

In the field of electronic and optoelectronic applications, two-dimensional materials are found to be promising candidates for futuristic devices. For the detection of infrared (IR) light, MoTe2possesses an appropriate bandgap for which p-MoTe2/n-Si heterojunctions are well suited for photodetectors. In this study, a rapid thermal technique is used to grow MoTe2thin films on silicon (Si) substrates. Molybdenum (Mo) thin films are deposited using a sputtering system on the Si substrate and tellurium (Te) film is deposited on the Mo film by a thermal evaporation technique. The substrates with Mo/Te thin films are kept in a face-to-face manner inside the rapid thermal-processing furnace. The growth is carried out at a base pressure of 2 torr with a flow of 160 sccm of argon gas at different temperatures ranging from 400 °C to 700 °C. The x-ray diffraction peaks appear around 2θ= 12.8°, 25.5°, 39.2°, and 53.2° corresponding to (002), (004), (006), and (008) orientation of a hexagonal 2H-MoTe2structure. The characteristic Raman peaks of MoTe2, observed at ∼119 cm-1and ∼172 cm-1, correspond to the in-plane E1gand out-of-plane A1gmodes of MoTe2, whereas the prominent peaks of the in-plane E12gmode at ∼234 cm-1and the out-of-plane B12gmode at ∼289 cm-1are also observed. Root mean square (RMS) roughness is found to increase with increasing growth temperature. The bandgap of MoTe2is calculated using a Tauc plot and is found to be 0.90 eV. Electrical characterizations are carried out using current-voltage and current-time measurement, where the maximum responsivity and detectivity are found to be 127.37 mA W-1and 85.21 × 107Jones for a growth temperature of 600 °C and an IR wavelength illumination of 1060 nm.

Thermal properties and decomposition of perovskite energetic materials (C6H14N2) NH4 (ClO4)3

(C6N2H14) NH4 (ClO4)3 (DAP-4) have attracted an increasing focus recently as an ammoniumperchlorate-based molecular perovskite energetic material with outstanding features. Microscopy, variable temperature X-ray diffraction, in situ infrared spectroscopy, differential scanning calorimetry-thermogravimetry simultaneous thermal analysis coupled with infrared spectroscopy and mass spectrometry (DSC-TG/FTIR/MS) techniques were used to systematically investigate DAP-4 thermal properties from -40 °C to 550 °C. The results revealed that DAP-4 have two solid-solid crystallization phase transitions with a non-characteristic melting process. The generated activation energies of HCN, CO, CH2NH2, CO2 and NO2 gas products are all lower than the macroscopic decomposition's of DAP-4. This finding strongly proves that DAP-4 is easy to form these gas products during thermal stimulus. The two stages decomposition mechanism accompanying a large of CH2NH2 and NH2C2H4 gases and kinetic model of DAP-4 were proposed under the condition of high-purity argon gas. This study provides new insight into the in-depth and accurate description thermal decomposition mechanism of DAP-4 as a potential energetic material.

The experimental investigation of performance behaviors of a beta-type Stirling engine with bell-crank motion mechanism

The current study aims to develop a novel power generation system that is capable of working with a Stirling engine. Within this context, a β-type Stirling engine design has been created with a bell-crank motion mechanism and a 365 cm3 swept volume. The engine has been manufactured, and then a detailed assessment has been conducted to determine the impact of the motion mechanism on engine performance characteristics. The designed and manufactured engine has been tested using a range of working fluids, such as air, argon, carbon dioxide, helium, and nitrogen gases. The performance tests of this engine have been carried out at 1000 K (±10) heater and 300 K (±5) coolant temperatures. Based on the outcomes of the experimental studies, the highest engine power and torque values have been obtained at a charge pressure of 4 bar using helium gas, with 143.5 W at 267 rpm and 7.75 Nm at 100 rpm, respectively. Moreover, the maximum engine power values obtained from other tests with nitrogen, air, carbon dioxide and argon gases have been compared with helium gas. Helium gas has been found to outperform nitrogen, air, carbon dioxide, and argon gases in tests by 67.3%, 73.9%, 197.1%, and 200.2%, respectively. Finally, the highest thermal efficiency value has been obtained with helium gas as 48.7% at a charge pressure of 4 bar.

Preparation and Characterization of Carbon/Si Nanocomposites Synthesized by Chemical Vapor Deposition (CVD) Using SiC and SiO2

Carbon-based nanocomposite materials have attracted the attention of researchers in the last decade due to their unique properties applicable in wide applications. This study aims to synthesize and study the characteristics of the carbon-based nanocomposite material produced using the chemical vapor deposition (CVD) method with SiC and SiO<sub>2</sub>. The CVD process was carried out at 900 ℃ in a vacuum with flowing argon, hydrogen, and acetylene gases. The CVD process produced nanocomposites with more sp<sup>3</sup> hybridized carbon atoms, as indicated by the D peak in the Raman spectra. The diffraction pattern analyses show that the resulting carbon powder nanocomposite growth with SiC powder (CSiC) reveals a carbon diffraction peak C(002) and has an elongated form confirmed by an electron microscope. In comparison, the resulting carbon powder nanocomposite growth with SiO<sub>2</sub> powder (C<sub>SiO2</sub>) has a spherical form and presents a carbon diffraction peak C(002). C<sub>SiC</sub> nanocomposites showed both symmetric and asymmetric C‒H stretching. In FTIR data, C<sub>SiO2</sub> nanocomposites show more intense O‒H group peaks but lower-intensity C‒H group vibrations.

Operating Characteristics of a Wave-Driven Plasma Thruster for Cutting-Edge Low Earth Orbit Constellations

This paper outlines the development phases of a wave-driven Helicon Plasma Thruster for cutting-edge Low Earth Orbit (LEO) constellations. The two-stage ambipolar electric propulsion (EP) system combines the efficient ionization of an ultra-compact helicon reactor with plasma acceleration based on an ambipolar electric field provided by a magnetic nozzle. This paper reveals maturation challenges associated with an emerging EP system in the hundreds-watt class, followed by outlook strategies. A 3 cm diameter helicon reactor was operated using argon gas under a time-modulated RF power envelope ranging from 250 W to 500 W with a fixed magnetic field strength of 400 G. Magnetically enhanced inductively coupled plasma reactor characteristics based on half-wavelength right helical and Nagoya Type III antennas under capacitive (E-mode), inductive (W-mode), and wave coupling (W-mode) were systematically investigated based on Optical Emission Spectroscopy. The operation characteristics of a wave-heated reactor based on helicon configuration were investigated as a function of different operating parameters. This work demonstrates the ability of two-stage HPT using a compact helicon reactor and a cusped magnetic field to outperform today’s LEO spacecraft propulsion.

Influence of carbon ionization increment by adding ne on the bonding, electrical, and tribological properties of carbon thin films deposited by HiPIMS

In this work, we use mass quadrupole spectroscopy to analyze the ion energy distribution function for C+ ions from different gas composition discharges (20, 40, 60, 80, and 90% Ne) + Ar in a plasma sputtering process. Carbon films were obtained for each gas composition discharge. The carbon bonding structure of films was analyzed by Raman spectroscopy using deconvolution fitting of the G and D Raman peaks. The C-sp3 content was correlated with the electrical and tribological properties of the carbon films. Our results further corroborate the enhancement of carbon ionization in HiPIMS processes by adding neon in conventional argon gas during the deposition process. Furthermore, we found that excessive levels of carbon ionization were detrimental in the formation of C-sp3 decreasing the resistivity, and indicating the decrement of the elastic modulus of the samples. In addition, the use of neon in the gas working mixture increased the deposition rate significantly compared to argon-only processes from 1.7 to 3.22 nm/min for the highest deposition rate cases. Tribology showed that an intermediate C-sp3 content in the carbon films developed desirable tribological behaviors with lower friction coefficients and wear rates, revealing that higher values of C-sp3 content are not necessarily for robust solid lubricious and wear resistance.

Process for the Recovery of Actinide and Lanthanide Oxides via Thermal Decomposition and Calcination of Loaded Diglycolamide Resin

Diglycolamide (DGA) resin, a product produced by Eichrom Technologies, Inc. employs TODGA (N,N,N′,N′-tetraoctyldiglycolamide) as the active extractant, which will be used by Savannah River National Laboratory to extract trivalent actinides and lanthanides from dissolved irradiated Mark-18A targets. The final form of the extracted material will be an oxide suitable for shipment. A two-step process was developed and validated for the direct recovery of actinides and lanthanides loaded on I-grade DGA resin as nitrates by thermally drying and decomposing resin loaded with Nd(III), a surrogate for trivalent actinides and lanthanides, under inert conditions followed by calcining the resultant residue in air to provide an oxide product. A stepwise heating profile up to 385°C under argon gas flow resulted in 85% to 89% mass loss during the resin drying and decomposition step, and calcination of the resultant Nd-loaded resin residue provided an overall material mass loss of ≥ 98%. Recoveries from resin saturated with Nd(III) from 7 M and 0.35 M nitric acid subjected to this process were 30.7 mg and 27.6 mg Nd/g dry resin, respectively, representing an average of 96.1% of Nd retained in the resin bed.

Comparison of high-temperature friction and wear behaviours of Ti6Al4V produced by additive manufacturing and casting

Additive manufacturing (AM) methods, especially selective laser melting (SLM), have recently attracted attention because they enable the quick and easy production of complex parts that cannot be produced with traditional manufacturing methods. However, residual stresses in the fabricated components impact their mechanical characteristics and may necessitate additional heat treatments. In this study, SLM-produced Ti6Al4V parts were subjected to a stress relief treatment under argon gas at 790°C for 2 h. The microstructure, microhardness and high-temperature tribological properties were examined comparatively with the traditional casting method. Dry sliding tribological experiments were carried out at different temperatures up to 600°C to compare high-temperature performance. It has been determined that the microstructure of samples produced by casting and SLM comprised β and α phases. The casting sample had 66.02% α grains, whereas the SLM sample had 59.02% α grains. The average microhardness in the SLM sample was marginally higher than that in the casting due to the formation of martensitic α. The results showed that wear rates increased with temperature for each sample. SLM samples exhibited slightly higher wear rates at each test temperature compared to the casting sample, which is attributed to the oxidative wear mechanism. The higher percentage of oxygen in the triboxide layers in the casting sample increased the wear resistance. When examining friction coefficients, an increase in average friction coefficients was observed at a test temperature of 300°C, while a decrease was observed at a test temperature of 600°C.

Temperature-controlled synthesis of novel boron nanofibers by laser ablation technique

The synthesis of boron nanofibers (BNFs) at different temperatures using the double-pulsed laser ablation (DPLA) technique were reported. Q-switched Nd: YAG laser with 532 and 1064 nm dual beam wavelengths of laser used to ablate a solid boron target. A vapor–solid process at a furnace temperature and pressure supported boron 'nanofibers' growth with the active metal catalysts of 1 % Ni and 1 % Co in a quartz tube furnace in flowing argon (Ar) gas. The crystalline phase purity of the synthesized BNFs at 950, 1050, and 1150 °C were determined by X-ray diffraction (XRD), and the results from XRD confirm that each BNF is preferentially grown in the c-axis (100) direction of alpha boron (α-B). Electron microscopy revealed that each BNF exhibit a length of 1–5 μm and a diameter width of 5–100 nm, while the elemental chemical compositional nature of the BNFs is identified from energy dispersive X–ray spectroscopy (EDX). Image analysis shows the average diameter of each BNF synthesized to be 23.10, 19.13, and 16.09 nm. The lattice distance of each BNF is found to be 0.40, 0.39, and 0.38 nm, respectively. Fingerprint Raman spectroscopy revealed the fundamental vibrational modes of BNFs at Eg and A1g.

Thermal hysteresis in wettability and the Leidenfrost phenomenon

The Leidenfrost temperature (TL), at which the liquid drop lifetime peaks on a superheated surface, is believed to be wettability dependent. Here, we show that the wettability effect on TL is subject to the history of the surface temperature. Observing a water drop evaporating on a polished stainless-steel surface heated from 100 to 400∘C in argon gas, we find TL≈265∘C. We then repeat the experiment along decreasing temperature and find a TL increase by 10 K, i.e., TL≈275∘C. This thermal hysteresis is due to a reduced contact angle during heating. Once hydrophilized, the hysteresis disappears until the contact angle recovers. Similar observations are made in the air where oxidation is possible. Published by the American Physical Society 2024

Investigation of Microstructure and Interfacial Reactions of Diffusion Bonding of Ni-Ti6Al4V Materials Joined by Using Ag Interlayer.

Due to its super plasticity, low weight, and high mechanical resistance properties, generally, Ti6Al4V is used for aeronautical applications. However, it has low resistance to plastic shearing. In addition, it has poor wear resistance. For these reasons, a lot of techniques have been developed to improve its wear resistance. Investigations of microstructure and interfacial reactions of diffusion bonding of Ni and Ti6Al4V materials have been performed experimentally. Ni samples were prepared with 50 ± 5 µm Ni powders in cylindrical shape. For diffusion bonding, Ag foil was used for improving the interlayer and connection quality. Nickel and its alloys can be joined by using some different processes, and the use of an interlayer can further facilitate the joining process and improve the joint quality. The experiments were carried out under the protected atmosphere. Argon gas was used for protection. The experiments were performed under 5 MPa pressure for 60 min duration at 850 °C, 900 °C, and 950 °C thermal conditions. Investigations of metallurgical structure occurring in the interface areas were examined by optic analysis of EDS, SEM, and X-ray. The strength of the joints was tested by lap-shear tests. From observations, the best quality of the coalescence at interfaces was indicated at elevated temperatures.

Effect of laser chirping on third harmonic generation in anharmonic clusters with ripple on cluster density

A proposed model delves into the resonant enhancement of third harmonic generation (THG) by a short-pulse laser inside nanoclustered plasma under the influence of density ripple. An intense chirped laser pulse incident on a clustered plasma of argon gas displaces the electrons of the medium and produces a restoring force. This force is considered to vary nonlinearly with electron displacement, leading to the anharmonic response of the electron clouds of the cluster. The nonlinear current at the third harmonic frequency arises from the perturbation of the electron density of the cluster by the ponderomotive force exerted on them by the incident laser pulse. Applying ripple in cluster density and electron density of surrounding plasma enables the phase-matching criteria for THG to be satisfied, which leads to enhanced harmonic output. An anharmonic structure of clusters exhibits strong optical nonlinearities, resulting in the plasmon resonance broadening and producing harmonics with greater efficiency. Numerical analysis shows that the chirp parameter of the laser pulse and ripple on cluster density enhance system nonlinearity causing the generation of a third harmonic of enhanced amplitude. The study explores how different factors such as laser intensity, cluster size, ripple parameter, chirp parameter, and electron excursion influence the efficiency of THG.

Pretreatment method for oxygen stable isotope ratio analysis of the sugar-rich fraction in fruit juice via isotope ratio mass spectrometry.

The oxygen stable isotope ratio (δ18O) of the sugar-rich fraction of fruit juice is important as a tracer of the geographical origin of raw material. This study sought to minimize the inter-day variation of δ18O attributable to the influence of water to accurately monitor geographical origin labeling. Two drying devices (freeze dryer and vacuum oven) were compared. Then, two humidity levels (normal and low humidity) at which the samples were placed after drying were compared. The low-humidity environment was constructed using a glove bag and pure argon gas. δ18O was measured using thermal conversion elemental analyzer/isotope ratio mass spectrometry. Improvements were made to the measurement method based on aforementioned analyses results, and the performance of the initial and improved methods was compared. δ18O of juice dried in a vacuum oven was 3.30‰ lower than that of juice dried in a freeze dryer. Moreover, δ18O of juice samples exposed to normal humidity was 3.74‰ lower than that of samples exposed to low humidity. The combined inter-day and intra-day standard deviation was reduced from 1.20‰ in the initial method to 0.42‰ in the improved method. This study describes a pretreatment method for δ18O measurement in the sugar-rich fraction of fruit juice with less inter-day variation, and it will be useful for monitoring geographical origin labeling.

Effect of gas injection pattern on magnetically expanding rf plasma source

Abstract Argon gas is injected from a back plate having either a radial center hole or shower-patterned eight holes into a 13.3-cm-diameter and 25-cm-long radio frequency (rf) plasma source attached to a 43.7-cm-diameter and 65cm-long diffusion chamber under an expanding magnetic field, which resembles the magnetic nozzle rf plasma thruster. The source has a double-turn loop antenna powered by a 13.56 MHz rf generator at a maximum power level of ~2.8 kW in low-pressure argon, providing a plasma density of about 1018 m−3 in the source. A high plasma density and a slightly low electron temperature are obtained for the shower-pattered case in both the source tube and the diffusion chamber, compared with the center hole case, suggesting that the neutral density profile significantly affects the plasma density profile. This result will provide an improvement in the thruster performance by the gas injection pattern.

Oxidation kinetics of Ti6Al4V alloy deposited by wire arc additive manufacturing using argon gas as processing atmosphere

Ti6Al4V alloy is currently the most common metal alloy of the α+β phase type, its application is increasing as it has excellent properties at elevated temperatures. The main users of Ti6Al4V alloy are industries like of aerospace, naval, and biomedical; therefore, Ti6Al4V alloys one of the most studied material worldwide. One of the great advantages that Ti6Al4V alloy offers is the possibility of manufacturing components in situ by means of additive technologies.. Similar studies, in additive manufacturing, have reported the formation of titanium oxide on the surface of the material, followed by an oxygen-enriched region called "α-case". By means of thermogravimetric analysis, the oxidation effect on the surface of Ti6Al4V samples, obtained by wire arc additive manufacturing as well as samples from conventional manufacture, were studied. Argon gas, with an oxygen partial pressure of 1x10-5 atm, was used as the oxidation atmosphere within a range of 550°C to 950°C and oxidatión times of 60 min and 180 min. For the oxidation reaction, the kinetic analyses led to calculate the activation energy as 250 kJ/mol and 166 kJ/mol for the Ti6Al4V alloy processed by conventinal and additive manufacturing, respectively. The results of the of thermogravimetric analysis were fitted to a parabolic-type kinetic model. Furthemore, a mathematical model was proposed to predict the oxidation kinetics. The experimental data were fitted to the mathematical model in the range of 750 - 950°C for Ti6Al4V alloy by wire arc additive manufacturing. The oxidized microstructures were analized by optical and electronic microscopy finding α-case on the surface of the samples.

The incident photons cut-off energy, the optical linear equations and the electron phonon interactions in ZnO thin films annealed at different temperatures

The using RF-magnetron sputtering, the ZnO thin films were deposited on glass substrates at room temperature. Then using an electrical furnace in the presence of argon gas, they were annealed at different temperatures (400–600 °C). It was found that with taking Nc = 4, Za = 2, Ne = 8 for ZnO films for covalently bonded crystalline and amorphous chalcogenides, the constant β has values of about 0.37 ± 0.04 and for halides and most oxides that have ionic structure the constant β has values of about 0.26 ± 0.04 eV. It can be seen that with increasing annealing temperature absorption edge these films have a shifting behavior towards larger wavelength. Due to shifting behavior of defects distribution of atoms into films, the values of the cut-off energy, E cut-off and the λ cut-off of these films were about 3.48 eV and 355 nm, respectively. The ZnO films annealed at 500 °C specially above 3 eV have maximum value of optical density. The different linears fitting of ln (⍺) for films were obtained as y = Ex + F where 10<E < 12.5 and 14<F < 16. The ZnO films annealed at 600 °C have minimum value of electron phonon interaction (Ee-p) in a bout of 0.858 eV. The optical band gap and disordering energy plots of these films can be fitted by linear relationship EU and Eg = 0.0989–0.148 EU. We found that as deposited ZnO films have minimum value of steepness parameter σ in about of 30.93 × 10 −2eV.

Influence of Applied Discharge Voltage and Gas Flow Rate on Nickel Plasma Jet Parameters Diagnosed by Optical Emission Spectroscopic Technique

Abstract: In this work, we measure the plasma parameters by using an AC high-voltage power supply that generates a non-thermal plasma jet system at atmospheric pressure. A nickel (Ni) metal strip, with dimensions of 1.5 × 10 cm2, was connected to the anode electrode of the AC power supply. This nickel strip was immersed in a flask with a small amount of distilled water positioned below the plasma plume nozzle. Optical emission spectroscopy (OES) was used to diagnose the plasma system at different argon gas flow rates (1-5 L/min) and varying applied voltage values (11-15 kV). It is significant to know the processes accompanying plasma generation to measure their parameters which include the electron temperature (Te), electron number density (ne) of the plasma, Debye length (λD), and plasma frequency (fp). Our results showed an increase in the intensity of spectral lines with the increase in applied discharge voltage (11-15 kV). The maximum peak for ArI was observed at a wavelength of 811.531 nm, and the maximum peaks for nickel (Ni) were observed at wavelengths of 285.21 and 519.70 nm. Also, the results indicated a gradual increase in electron temperature (Te) and electron density (ne) values at the applied voltage of 0.403-0.468 eV. Likewise, the electron density (ne) was in the range of (11.486-13.851) × 1017 cm-3. Keywords: Atmospheric plasma jet, Nickel (Ni) plasma parameters, Electron temperature, Spectroscopic optical emission (OES).

Ab initio chemical kinetics and shock-tube experimental study on nitrocyclohexane pyrolysis and combustion

Nitrocyclohexane (NCH) is a model nitroalkane compound with naphthenic structural groups for studying the combustion properties of nitro-based energetic fuels, and also demonstrates significant potential applications for advanced engines. However, accurate description of the detailed kinetic mechanisms for pyrolysis and combustion of NCH receives little attentions. Herein, the detailed pyrolysis and oxidation mechanism of NCH is studied by using quantum chemistry calculations and chemical kinetic theory. The potential energy surfaces of the CN bond dissociation reaction, HONO elimination reaction, abstraction reactions of NCH as well as the subsequent β-scission reactions are calculated using G4//M06–2X/6–311++G(d, p) method, which are subsequently employed for reaction rate constant computations via transition state theory (TST) and RRKM/master-equation (RRKM/ME) method. The ab initio chemical kinetic study results are used to develop a detailed kinetic mechanism to predict the pyrolysis experimental results of NCH, which are performed using a single-pulse shock tube (SPST). The SPST experiment is performed at pressure of 10 bar, temperature ranging from 1070 to 1560 K, reaction time of around 1.77 microsecond with fuel concentrations of 0.5 % diluted by Argon gas. The developed detailed kinetic mechanism exhibits reasonable prediction results of the pyrolysis product distributions together with literature ignition delay times across a wide range of temperature, pressure, and equivalence ratio conditions. Rate-of-production analysis is conducted to gain insight into the pyrolysis chemical kinetics of NCH. The present work should be valuable for the study of the combustion chemistry of nitro-alkane energetic fuels.

Strength-ductility synergy in a non-equiatomic Co–Cr–Ni medium entropy alloy wall structure deposited using twin-wire arc additive manufacturing

An innovative twin-wire arc additive manufacturing (T-WAAM) has been deployed to fabricate a Co-rich non-equiatomic Co–Cr–Ni medium entropy alloy. The TWAAM-built single-wall structures of Co50Cr10Ni40 alloy were fabricated under argon gas shielding using dual gas metal arc welding sources. The microstructure studies revealed a single-phase FCC crystal structure and defect-free deposition. The slender columnar substructure and cellular substructure are formed along the build direction (BD) and scan direction (SD) respectively, which are commonly observed in the wall structures of other conventional FCC alloys. The tensile coupon SD and BD displayed a superior high strength and ductility combination. The T-WAAM-fabricated Co50Cr10Ni40 alloy showed both strength and elongation 1.4 times greater than that of the laser additive manufactured equiatomic CoCrNi wall structure. Thus, the study opens up a new avenue to tailor the mechanical properties of CoCrNi MEA by composition variation, with an added advantage of higher deposition rates of TWAAM.

In-situ laser surface remelting of laser powder bed fused AlSi10Mg alloy at argon and nitrogen protective gases: Multiscale analysis

In the recent decades, laser powder bed fusion (LPBF) of aluminum alloy has been widely used in many fields. However, the poor surface quality, inevitable defects, and limited mechanical performance are obvious obstacles. In-situ laser surface remelting (LSR) is a promising method to give a second opportunity for the defect elimination. In this work, the LSR protective gas (argon and nitrogen) on the surface roughness, porosity, and microstructure of LPBF-fabricated AlSi10Mg alloy are experimentally compared. The nitrogen shows significant superiority in the surface flatness and densification enhancement compared with argon gas. After LSR at nitrogen gas, the average grain size reduces by 8.7 % and the low-angle grain boundaries increases from 70.9 % to 99.7 %. Moreover, a two-dimension mesoscale FEM (Finite Element Method, FEM) model is established to investigate the movement of multi pores inside the molten pool. Attributed to the lower density and dynamic viscosity and larger thermal conductivity, the combination of multi pores is significantly drastic with obvious surface fluctuation during LSR at nitrogen gas. According to the density functional theory (DFT) calculation, the absolute adsorption energies of nitrogen on Al (100) and Al (110) surfaces are generally larger, revealing that the argon gas is easier to be adsorbed on the processing aluminum layer during LSR treatment. Furthermore, the vacancy defects in the aluminum layer play positive roles in the adsorption of gas. This work establishes the importance of the protective gas on the LSR treatment, and provides a multiscale analysis method for the pore evolution.