Arc Magmatic Rocks Research Articles

Land plants, sediment composition, granitic magma compositions and environments of formation

Earth’s biosphere and lithosphere continually interact, and life’s metabolic processes influence atmospheric composition, the weathering of rocks and how rivers deliver sediments to ocean and intracontinental basins. Recently, other authors noted a correlation between the oxygen isotopic compositions and crustal residencies of arc magmatic rocks. This correlation appeared at about 430 Ma and is attributed to the rise of deep-rooted land plants, which increased clay-mineral production and input to ocean basins, by slowing sediment transfer across continents, stabilising soils, and thereby enhancing weathering time and promoting clay formation. Granites, which form much of the continental crust, contain components derived through partial melting of sediments that can have varying chemical maturity, and the major-element chemical features and isotopic compositions of the granites reflects this. In a global dataset of granite compositions, dating from 500 Ma, major-element markers that reflect original source clay content do not reveal the stepwise increase in sediment clay content inferred for the sources of arc magmas at 430 Ma, and only increase consistently from approximately 200 Ma. This demonstrates that although granite compositions reflect the plant influence, they are not principally formed through subduction processes in magmatic arcs but rather in back-arc environments, and do not receive the immediate transcontinental sediment input that characterises ocean basins. The lag in the granite response occurs because there is commonly a substantial time gap between arc magmatism and granite genesis. This is because a subsequent orogeny is generally required to partially melt older back-arc rocks, including sediments, to produce granitic magmas.

The Petrogenesis of Devonian Volcanism and Its Tectonic Significance in the Kalatag Area, Eastern Tianshan, Xinjiang, China

The Kalatag mineralization belt is an important metallogenic belt of polymetallic mineral deposits in the northern part of eastern Tianshan, and its age and tectonic setting are still controversial. We identified a set of Devonian volcanic rocks hosted in the Early Palaeozoic package of dominantly marine sediments with a small amount of terrestrial rocks. This study presents petrological, U–Pb geochronology, and geochemical data for the volcanic rocks. The ages of the rhyolite (407.2 ± 1.9 Ma) and basaltic andesite (380.4 ± 2.8 Ma) suggests that the Kalatag belt is a Devonian volcanic succession. These rocks consist mainly of marine calc–alkaline lava, tuff, pyroclastic rocks, and minor terrestrial basaltic andesite. The lavas are characterized by the enrichment of light rare earth elements and strongly depleted in Nb and Ta, typical of island arc magmatic rocks. The volcanic rocks probably originated from the partial melting of the mafic lower crust which was modified by subducted slab-related fluids. During their ascent through the crust, these volcanic rocks underwent variable extents of fractional crystallization (rhyolites) and crustal contamination (basaltic andesites). Combined with the results of previous studies, we suggest that the Devonian rocks formed in an island arc related to the northward subduction of the Northern Tianshan Ocean with a crustal thickness of ~35–40 km.

Temporal covariation of island arc Sr isotopes and seawater chemistry over the past 2 billion years

The chemical compositions of island arc basalts (IAB) reflect contributions from the mantle as well as fluids and melts from the subducting slab. Addition of radiogenic seawater Sr to oceanic crust through hydrothermal alteration and subsequent subduction is often invoked to explain elevated 87Sr/86Sr signatures in modern IAB. However, changes in the 87Sr/86Sr of island arc magmatic rocks through time has not been investigated, limiting our understanding of the factors influencing the Sr budgets of arcs throughout Earth's history. To address this, we compiled 87Sr/86Sr values from island arc magmatic rocks ranging in age from modern to Paleoproterozoic, only including data from island arc localities that best preserve initial magmatic 87Sr/86Sr. Median initial 87Sr/86Sr values are consistently elevated compared to depleted mantle 87Sr/86Sr over this period, indicating persistent enrichment in radiogenic Sr in island arcs. Moreover, the elevation in island arc 87Sr/86Sr relative to the depleted mantle is variable. A notable rise in island arc 87Sr/86Sr during the late Neoproterozoic coincides with a steep increase in seawater 87Sr/86Sr and Sr concentration. To investigate this potential connectivity, we modeled the 87Sr/86Sr of island arc magmas between 0 and 830 Ma with inputs of depleted mantle 87Sr/86Sr, seawater 87Sr/86Sr, and seawater Sr concentration. The model reproduces the overall trajectory of the compiled data. We interpret the observed temporal variation in island arc 87Sr/86Sr values and its close association with fluctuations in seawater chemistry as evidence that changes in marine geochemistry have strongly influenced the Sr isotopic record of island arc magmas over time.

Ca–Zn isotope fractionation during fluid–rock interaction in subduction zones and its implication for deep carbon cycle

Subducting slabs transport Earth's surface carbon into the deep mantle, with a portion of this carbon potentially recycled through volcanic eruptions at mid-ocean ridges or ocean islands. Non-traditional stable isotopes such as calcium (Ca) and zinc (Zn) are increasingly used to trace this deep carbon cycle. However, the potential for Ca and Zn isotope fractionation in the subduction zone, critical for the successful application of these tracers, remains insufficiently explored. In this study, we investigate high-pressure carbonated metamafic rocks and enclosed vein systems from a Paleo-oceanic subduction complex (SW Tianshan) to explore the possible fractionation of Ca and Zn isotope during subduction-related metamorphism and fluid–rock interaction. The δ44/40Ca (0.77 ‰–0.90 ‰) and δ66Zn isotope compositions (0.20 ‰–0.39 ‰) of greenschist-, blueschist- and eclogite-facies metabasites are consistent with their protoliths (OIBs and MORBs). We observe no systematic fractionation of either Ca and Zn isotopes across prograde metamorphism and associated dehydration. However, the precipitation of carbonate in surrounding rock along fluid pathways leads to an increase in the δ44/40Ca of residual fluids (>0.90 ‰). More significantly, we find detectable Zn isotope fractionation (ΔA-H = ẟ66Znaltered - ẟ66Znhost of 0.06–0.10 ‰) during fluid-mediated metasomatism of some blueschists/eclogites. Light Zn isotopes are preferentially released into the infiltrating fluid, resulting in an elevated δ66Zn isotope composition in the immediate carbonated eclogites along the vein. The modified slab fluids during migration are likely charactered by heavy δ44/40Ca and light δ66Zn compositions, which may play a crucial role in determining the low δ66Zn values found in some arc lavas. However, the MORB-like δ44/40Ca compositions observed in global arc magmatic rocks suggest that the slab-released Ca (possibly along with some carbon) is probably sequestered and stored along the migration path of the fluid, thereby hindering the slab–arc carbon recycling. Our study emphasizes that intraslab fluid–rock interaction results in similar δ44/40Ca and δ66Zn signature in carbonate-bearing eclogites compared to sedimentary carbonates. Consequently, deeply subducted carbonate-bearing eclogites –not necessarily sedimentary carbonates– might carry light δ44/40Ca and heavy δ66Zn signatures into the deep mantle, potentially influencing the corresponding Ca-Zn isotope compositions of some mantle-derived basalts.

Configuration of the early-mid Cenozoic extensional arc volcanism of the North Patagonian and the Southern Central Andes (33–44°S)

The late Eocene to earliest Miocene volcanic arc of the Southern Central Andes (33–40°S) and North Patagonian Andes (40–44°S) exhibits distinctive features that shed light on the dynamics of subduction-related volcanic activity in extensional tectonic settings. This period is particularly significant in the Andes, as it records the opening of forearc, intra-arc, and retroarc extensional basins, accompanied by high-volume volcanism, preceding the middle-late Miocene final major uplift phase of the Andes. This extensional event occurred in two phases, associated with changes in the geometry and dynamics of the subduction system: from oblique convergence at low rates during the late Eocene-early Oligocene to an orthogonal convergence at high rates during the late Oligocene-early Miocene. This study presents a compilation of field, petrographic, geochemical, and isotopic data from volcanic sequences in the North Patagonian Andes and the Southern Central Andes, aiming to analyze petrogenetic processes at different stages of arc evolution.During the late Eocene to early Oligocene, subduction-related volcanism occurred in a wide area from 100 to 300 km from the trench. In this period, magmatic arc rocks exhibit intermediate composition and a relatively homogeneous geochemical signature, transitional between tholeiitic and calc-alkaline series, with a marked subduction-related signature. These magmas originated from depleted mantle sources with high slab-derived fluid and sediment contributions and limited crustal interactions. In contrast, the late Oligocene to earliest Miocene volcanic activity, at the peak of the extensional regime, displays significant geochemical differences along the Andes. In the Southern Central Andes (33–40°S), volcanism displays compositions similar to those of the previous stage with varying influence from the subducting slab. In some sectors, magmas register the climax of the extensional conditions, whereas the youngest volcanic rocks towards the north (33–34°S) present evidence of the onset of contractional tectonics, demonstrated by the increased interaction of the magmas with a progressively thickened crust. In the North Patagonian Andes (40–44°S), subaerial and subaqueous arc-related lava flows are interbedded with marine deposits, indicating a rapid subsidence regime. These rocks exhibit geochemical features transitional from arc to E-MORB and even OIB compositions, which suggest a genesis primarily dominated by decompression melting of a heterogeneous mantle source. Above all, the contrasting nature of late Eocene-early Miocene arc products in the Southern Central and Patagonian Andes highlights that no single process can explain the changes in composition, distribution, and evolution of arc magmatism; rather, it is a combination of factors, including variations in subduction zone configuration and mantle dynamics and composition.

Post-collisional reworking of juvenile mafic lower crust for the petrogenesis of late Triassic adakitic rocks in the East Kunlun Orogen

The East Kunlun Orogen (EKO), a major component of the Greater Tibetan Plateau, provides an excellent natural laboratory to investigate the tectonic evolution of the Paleo-Tethys Ocean (also known as the A'nyemaqen Ocean in the EKO). We present a combined study of in situ zircon UPb ages and LuHf isotopic compositions, and whole-rock major and trace element and Sr–Nd–Hf isotopic compositions of the post-collisional Xiangjia granodiorite at the eastern end of the EKO. Zircon UPb dating indicates that the Xiangjia granodiorites were emplaced at 225.0–217.1 Ma. Relict zircon cores yield ages of 267.5–239.5 Ma. These granodiorites are calc-alkaline to high-K calc-alkaline and metaluminous to weakly peraluminous, enriched in large-ion lithophile elements and light rare earth elements, and depleted in high field strength elements (e.g., Nb and Ta) and heavy rare earth elements. They yield trace element characteristics that are typical of adakitic rocks, including high Sr (493–590 ppm) and low Yb (0.74–1.12 ppm) and Y (8.83–12.24 ppm) contents, high Sr/Y (40.47–63.64) and (La/Yb)N (11.81–30.91) ratios, and positive Eu anomalies. The UPb ages and Hf isotopic compositions of the relict zircon cores and whole-rock SrNd isotopic compositions of the Xiangjia adakitic rocks are similar to those of the mafic arc magmatic rocks formed during the subduction of the Paleo-Tethys Ocean, suggesting they originated from the reworking of juvenile mafic lower crust. Phase equilibrium modelling suggests that the contemporaneous adakitic rocks from Xiangjia and other areas in the EKO are likely the products of partial melting of the juvenile mafic arc rocks under granulite-facies conditions at 10–11 kbar and 934–951 °C, possibly related to slab break-off in a post-collisional setting.

Petrogenesis and tectonic setting of the Neoproterozoic Douling dioritic–granodioritic–granitic intrusion in the northern Yangtze Block, Central China

Voluminous Neoproterozoic intermediate to felsic rocks intruded the Neoarchean Douling Complex in the South Qinling Belt of Central China, which may provide new constraints on the controversial issue about the nature of the continental margin of the Yangtze Block during the Neoproterozoic. This study presents zircon U–Pb geochronology, whole‐rock geochemistry and Sr–Nd isotope of the Douling dioritic–granodioritic–granitic intrusion, aiming to clarify its petrogenesis and tectonic significance. The dioritic–granodioritic–granitic rocks yield similar zircon U–Pb ages ranging from 735 to 705 Ma. The enrichment of light rare earth elements (LREEs) and large‐ion lithophile elements (LILEs), and depletion of high‐ field‐strength elements (HFSEs) (e.g., Nb, Ta) are typical features of arc magmatic rocks. The whole‐rock Sr–Nd isotopic compositions show initial 87Sr/86Sr ratios ranging from 0.7034 to 0.7059, and εNd(t) values from −7.3 to −1.4. Elemental and isotopic data suggest that the Neoproterozoic dioritic–granodioritic–granitic rocks were co‐genetic and were generated by partial melting of lower crust materials combined with mantle‐derived melts. The granites were the derivative product of dioritic rocks by fractional crystallization of amphibolite, plagioclase, mica and zircon. Combined with literature data, we infer a subduction‐related setting for the northern margin of the Yangtze Block during the Middle Neoproterozoic, and a tectonic model of accretion along an Andean‐type active continental margin after the collision of the Douling micro‐block with the northern Yangtze Block is further proposed.

Detrital zircon U–Pb geochronology and geochemistry of sandstones in the Siziwang Banner, Central Inner Mongolia: Implication for tectonic evolution

The central Inner Mongolia, located at the intersection of the northern margin of the North China Craton (NCC) and the Central Asian Orogenic Belt, is crucial for deciphering the Late Palaeozoic tectonic evolution associated with the subduction and closure of the Palaeo‐Asian Ocean (PAO). Our study focused on petrology, detrital zircon LA–ICP–MS U–Pb geochronology and whole‐rock geochemistry for the Late Carboniferous to Permian sandstones within the Shuanmazhuang, Dahongshan, Naobaogou, and Laowopu formations in Siziwang Banner, central Inner Mongolia. This comprehensive analysis shed light on the dynamic interplay between the NCC and the South Mongolia Block. Detrital zircon U–Pb ages in investigated samples mainly cluster between 250 and 2650 Ma, with significant peaks at 2.4–2.5 Ga, 1.8–2.0 Ga, 400–430 Ma, and 250–320 Ma, respectively. The geochemistry data are characterized by SiO2 contents (56.29–77.95 wt. %), Na2O / K2O ratios (0.45–1.58) and SiO2/Al2O3 ratios between 4.33 and 7.44. Moreover, they exhibit the slight enrichment in large ion lithophile elements (Rb and Ba) and the depletion in high field strength elements (Nb, Ta, Th, and U). These facts indicate that the sedimentary detritus predominantly originates from felsic sources, probably deriving from the Late Carboniferous–Permian continental island arc‐related intermediate‐acid igneous rocks, the Late Ordovician‐Silurian magmatic rocks in the Bainaimiao arc and the basements of the NCC. Furthermore, our present results also suggest that during the Early–Middle Permian, accelerating oceanic crust subduction triggered significant magmatic events in Siziwang Banner, leading to rapid uplift and the erosion of arc magmatic rocks, as well as the abundant corresponding sediments. Subsequently, the gradual convergence and eventual collision between the NCC and the Southern Mongolian Block took place at the end of the Permian, representing final closure of the PAO.

Early Cretaceous continental arc magmatism in the Wakhan Corridor, South Pamir: Mantle evolution and geodynamic processes during flat subduction of the Neo-Tethyan oceanic slab

The petrogenesis of continental arc magmas provides critical insights into thermal evolution and geodynamics of the continental lithosphere, crust-mantle interaction, and deep dynamic processes. In this study, we report new zircon U-Pb ages along with isotopic and elemental whole-rock geochemistry, mineral chemistry, and Hf-O isotope data for the Kalaqigu diorites and monzogranites of the Chinese Wakhan Corridor, South Pamir. Zircon U-Pb dating indicates that the Kalaqigu pluton was emplaced in the Early Cretaceous (ca. 108−106 Ma). The diorites are geochemically characterized by low SiO2 (51.9−54.5 wt%) and CaO (7.7−9.4 wt%) contents, but high MgO (5.3−8.3 wt%), Al2O3 (12.8−16.8 wt%), and TiO2 (0.6−1.1 wt%) contents as well as high Mg# (56−65) values. Thus, they are similar to high-Mg diorites: enriched in large ion lithophile elements (e.g., K, Sr, and Ba) and light rare earth elements, while depleted in high field strength elements (i.e., Nb, Ta, Zr, and Hf). Combined with negative εNd(t) (−6.9 to −14.0) and εHf(t) (−9.9 to −12.2), and high (87Sr/86Sr)i (0.7075−0.7086) ratios, these observations indicate that they originated from an enriched lithospheric mantle source. High δ18Ozrn (7.49‰−9.01‰) values, in conjunction with relatively high 207Pb/206Pb and 208Pb/206Pb ratios, suggest that the source was modified by subducted sediment-derived melts. Variable Cr contents (54−117 ppm) are likely controlled by minor fractionation of olivine and orthopyroxene. The monzogranites show high SiO2 contents (69.2−72.0 wt%), and low Rb/Sr (0.4−0.6), (K2O + Na2O)/CaO (2.6−4.8), and FeOT/MgO ratios (2.6−3.2). They contain diagnostic cordierite and show strongly peraluminous characteristics (A/CNK > 1.1) with high δ18Ozrn (7.82‰−8.85‰) values that are compatible with those of typical S-type granites. Their abundant inherited zircons, with age populations similar to those of detrital zircons from regional early Paleozoic metasedimentary rocks, indicate that they were derived from partial melting of ancient metasedimentary rocks. Phase equilibrium modeling is consistent with biotite-dehydration melting of metagreywacke, probably at ∼750 °C and ∼6.0 kbar, as indicated by the biotite chemistry. Based on regional geochronology, a south-to-north magmatic migration suggests that northward flat-slab subduction of the Neo-Tethyan oceanic slab played an important role in the generation of these widespread Early Cretaceous continental arc magmatic rocks. However, the granitoids were generated earlier than the mantle-derived mafic rocks, which suggests that crustal melting occurred during the early stage of subduction. The continuous flat-subduction resulted in partial melting of subducted sediments, which metasomatized the mantle wedge. Contemporaneous regional compression primarily occurred far north of the subduction zone (i.e., North and Central Pamir), inducing deformation as well as crustal shortening. With the flare-up of continental arc magmatism in South Pamir, crustal shortening moved southward. These processes, combined with the addition of voluminous, mantle-derived magmas, played an important role in crustal thickening in Pamir during the Early Cretaceous.

Middle–Late Jurassic subduction erosion caused by intra-oceanic arc subduction in central Tibet

Abstract Subduction erosion is crucial in crustal material recycling. However, subduction erosion caused by intra-oceanic arc subduction has not been sufficiently investigated. In this study, we provide new geological, geochronological, geochemical, and isotopic data from Dongco granodiorites in the central Bangong–Nujiang suture zone of central Tibet to explore subduction erosion caused by intra-oceanic arc subduction. Analysis shows that the ca. 158–155 Ma Dongco granodiorites originated from the subducted oceanic plate, and they were contaminated with accretionary wedge when they intruded the Dongco ophiolite. This suggests that the Dongco ophiolite was emplaced in the subducted accretionary wedge before the Late Jurassic. Based on the intra-oceanic arc affinity and lack of volcanic rocks of Middle Jurassic Dongco ophiolite and other regional data, we believe that the main body of the central intra-oceanic arcs and a portion of the western intra-oceanic arcs in the Meso-Tethys Ocean subducted beneath the southern Qiangtang terrane during the Middle–Late Jurassic. In addition, the different degree absence of the Jurassic accretionary wedge, forearc region, and arc magmatic rocks in the southern Qiangtang terrane indicate that the central and western parts of the southern Qiangtang terrane experienced both vigorous and relatively weak subduction erosion during the Middle–Late Jurassic, respectively. Thus, there is a significant spatiotemporal coupling between subduction erosion of the southern Qiangtang terrane and intra-oceanic arc subduction. Based on these studies and the research on subduction erosion, we suggest that subduction of the main body of the central intra-oceanic arcs and partial subduction of the western intra-oceanic arcs in the Meso-Tethys Ocean caused both vigorous and relatively weak subduction erosion of the southern Qiangtang terrane during the Middle–Late Jurassic, respectively. In addition, the increase in subduction rate also promoted Middle–Late Jurassic subduction erosion of the southern Qiangtang terrane.

Subduction erosion revealed by exhumed lower arc crustal rocks in an accretionary complex, northeastern China

Abstract Subduction erosion at convergent margins is a leading mechanism for the destruction (recycling and reworking) of continental crust. But because of the lack of direct evidence, it is not straightforward to identify erosive events and their intensities in fossil subduction zones. The Heilongjiang accretionary complex in northeastern China was formed during the early Mesozoic subduction of the Paleo-Pacific Ocean. We investigated amphibolites from this accretionary complex, whose protoliths (based on whole-rock trace elements and Sr-Nd-Hf isotopes) were mafic continental arc magmatic rocks (255–249 Ma; zircon core U-Pb ages) from the upper plate. Phase equilibria modeling constrained by mineral geochemistry indicates that the amphibolites and their wall rocks were first heated to low granulite facies (750–800 °C, ~7 kbar) at 251–244 Ma (zircon rim U-Pb ages) and then cooled to ~700 °C with increasing pressure (8–9 kbar) before 213–187 Ma (titanite and apatite U-Pb ages). To explain the occurrence of the lower arc crustal lithologies in the accretionary complex and their metamorphic history, we propose that the subducting plate strongly eroded the forearc crust, allowing the plate interface to advance landward and scrape the amphibolites and wall rocks formed under the old arc, which finally were exhumed along the subduction channel and became components of the complex. The case study exemplifies direct petrological evidence of strong subduction erosion occurring in an ancient orogen, thus implying that consumption of the entire forearc crust could occur within only ~50 m.y.

Petrological and mineralogical constraints on the formation of Neoproterozoic calc-alkaline continental crust: The example of the Luding Intrusive complex, western Yangtze Block, South China

Decoding the trans-crustal magmatic evolution processes from exposed paleo-depth that are otherwise inaccessible above continental arc zone is instructive to understand the geochemical fractionation of arc magmatism and geochemical stratification of continental crust. To unravel trans-crustal magmatic processes leading to the formation of Neoproterozoic continental arc, we combined a comprehensive dataset of petrography, zircon UPb geochronology, whole-rock major and trace elements, and SrNd isotopes as well as zircon LuHf isotopes for the Neoproterozoic calc-alkaline Luding Intrusive Complex (LIC) in the western Yangtze Block, South China. The LIC is composed of monzodiorites, gabbro-diorites, diorites, and granodiorites that formed at ca. 783–779 Ma. The LIC lithologies are calc-alkaline with highly variable Mg# values (40.8–70.6) and subduction-related trace elemental patterns. In combination with predominantly depleted and comparable whole-rock SrNd (initial 87Sr/86Sr = 0.703244–0.704248 and εNd(t) = +2.35 ∼ +5.10) and zircon Hf isotopes (εHf(t) = +4.47 ∼ +9.99), the LIC originated from a common subduction fluids-metasomatized mantle source. The hornblende geothermobarometry and whole-rock normative mineral trajectories as well as previously experimental results collectively suggest that the crystallization of LIC occurred within the middle crustal level (11.4–20.9 km) at various temperatures (776–875 °C) and pressures (2.50–5.50 kbar), and underwent different degrees of fractional crystallization of predominant hornblende and plagioclase phases during the assemblage and solidification of cogenetic and multiple batches magmatic pluming. The diorites-granodiorites result from fractionation of early olivine + clinopyroxene phases followed by subsequent amphibole + plagioclase phases, and the monzodiorites mainly represent accumulation residues of dominant hornblende + plagioclase phases from more fractionated melts, while the gabbro-diorites underwent the fractionation from an isotopically homogeneous mantle source, but differ in their elemental compositions. The LIC from Neoproterozoic continental arc suggests that the cogenetic fractional crystallization of mantle-derived melts in intra-crustal magmatic system can account for the petrochemical diversities of arc magmatic rocks during the construction of the Neoproterozoic continental arc crust in the western Yangzte Block, South China.

Detrital zircon U–Pb and Hf analyses of Silurian–Devonian sediments in the Sukhothai Terrane, northern Thailand: implications for the Mid-Paleozoic arc belt

The Sukhothai Terrane in northern Thailand consists of continental basement and a Permo-Triassic magmatic arc related to the subduction of the main Palaeo-Tethys Ocean. The Donchai Group represents the oldest sedimentary sequence of the Sukhothai Terrane and consists mainly of meta-sandstone, quartzo-feldspathic schist, phyllite and silty slate. We present new detrital zircon U–Pb geochronology, Lu–Hf isotope data and geochemical data for the sedimentary rocks of the Donchai Group to elucidate the depositional age, provenance and nature of the group. The youngest detrital zircon ages (433–403 Ma) suggest that the Donchai Group accumulated between 433 and 368 Ma, revealing Silurian–Devonian arc magmatic rocks on the western margin of the Sukhothai Terrane. Sediments of the Donchai Group were sourced from both the continental basement and a Silurian–Early Devonian magmatic arc, suggesting a depositional setting on the continental slope of a back-arc basin along the western flank of the Sukhothai Terrane. The Silurian–Devonian arc belt in SW China probably extends to the Chiang Rai region to the west of the Sukhothai Terrane, northern Thailand, revealing the northwards subduction of the Proto-Tethys Ocean along the western Simao and Sukhothai margin during the mid-Paleozoic. The inferred arc and back-arc configuration of the Proto-Tethys Ocean in northern Thailand is comparable with that recently established in Yunnan, SW China. Supplementary material: Detrital zircon U–Pb ages and trace element analyses, zircon in-situ Lu–Hf isotopic compositions and whole-rock geochemical data are available at https://doi.org/10.6084/m9.figshare.c.6858373

Intraoceanic Subduction System Within the Neo‐Tethys: Evidence From Late Cretaceous Arc Magmatic Rocks of the Eastern Himalaya

AbstractThe tectonic evolution of the Neo‐Tethys Ocean remains highly controversial, with several models existing in the community that conflict with each other. Here, we present new geochronologic and geochemical data for orthogneisses and amphibolites from the Greater Himalayan Sequence, eastern Himalayan orogen, which indicate that these rocks have Cenozoic metamorphic ages (∼52–3 Ma), but were derived from Late Cretaceous (∼89 Ma) magmas with arc‐like and depleted mantle geochemical signatures. Considering that northern India was a passive continental margin during the Mesozoic, and the previously reported Late Cretaceous magmatic rocks in the eastern Himalaya formed in a continental rifting setting, we suggest that the studied Late Cretaceous arc‐type magmatic rocks formed in an intraoceanic arc setting within the Neo‐Tethys, and accreted onto the passive margin of the Indian continent prior to the terminal continental collision. When combined with the existence of Late Mesozoic and intraoceanic arc‐type magmatic rocks in the western Himalaya, we suggest that a huge Late Cretaceous subduction system operated within the eastern Neo‐Tethys Ocean. This study supports two subduction zones having been responsible for the consumption and closure of the Neo‐Tethys basin, and a two‐stage collision history between India, Asia, and the intermediate island arc system. Our data therefore provide important constraints on the evolution of the Neo‐Tethys Ocean and India‐Asia collisional orogeny in southern Tibet.

Tectonics of the Paleoproterozoic Rinkian orogen, central West Greenland

A new tectonic model is presented to explain the tectono-stratigraphic evolution of the Paleoproterozoic Karrat Group in central West Greenland and the polyphase deformation, magmatism, and metamorphism of the Rinkian orogen. Sedimentation of the Karrat Group initiated after ca. 2000 Ma in an intracratonic rift basin with basal quartzites overlying Archean gneisses of the Rae craton. Rift-related alkaline volcanic rocks and synrift siliciclastic sediments were deposited in the north while an evaporite-carbonate platform developed in the south. The rift basin evolved to a back-arc basin, with associated subalkaline volcanic rocks, concomitant with the intrusion of arc-related granitoids of the Prøven igneous complex along the basal contact of the Karrat Group between 1900 Ma and 1850 Ma. The Karrat Group and magmatic arc rocks underwent metamorphism ca. 1830−1800 Ma during the collisional phase of the Rinkian orogeny. The metamorphic grade of the Karrat Group increases from greenschist facies in the south to granulite facies in the north, where it is marked by migmatization and emplacement of S-type leucogranites. Extensive east-southeastward thrust emplacement and fold vergence characterize the Rinkian orogen south of the Prøven igneous complex magmatic arc, where the arc-continent collision is established along a top-to-the-ESE shear zone postdating the Rinkian metamorphism. In summary, the Karrat Basin developed on the upper plate above eastward-dipping subduction and, together with the Rinkian orogen, represents the result of arc-continent collision that initiated the structuring of a back-arc fold-and-thrust system antithetic to the subduction system.

The geochemistry and geochronology of garnet from the Jinchanghe Fe-Cu-Pb-Zn deposit, Baoshan Block, western Yunnan

The Jinchanghe polymetallic Fe-Cu-Pb-Zn deposit is located in the northern region of the Baoshan Block in western Yunnan. Using electron probe micro-analysis and laser ablation inductively coupled plasma mass spectrometry, we analyzed the major, trace, and rare earth elemental contents of garnets from the Jinchanghe deposit. Moreover, U-Pb dating was performed using the laser ablation sector field inductively coupled plasma mass spectrometry (LA-SF-ICP-MS) method to determine the direct mineralization age of the Jinchanghe deposit. Petrographic analyses revealed three garnet generations: early (GrtI), middle (GrtII), and late (GrtIII). GrtI (And55.69-64.47Gro30.28-41.21Ura + Pyr + Spe + Alm2.35-5.49) was characterized by irregular shapes and weak optical properties, and primarily comprised Fe-rich grossular. GrtII (And53.69-96.17Gro2.78-45.07Ura + Pyr + Spe + Alm0.59-2.12) was characterized by andradite, in which GrtIIa was a homogeneous body, whereas GrtIIb shows exhibited oscillatory zoning with abnormal interference colors. Fine-veined andradite aggregates were predominant in GrtIII (And70.51-90.33Gro6.34-27.80Ura + Pyr + Spe + Alm1.03-3.32). The GrtI, GrtIIa, and the rims of GrtIIb were depleted in heavy rare earth elements and enriched in light rare earth elements, with positive Eu anomalies, indicating that these garnets crystallized from mildly acidic magmatic hydrothermal fluids. However, the cores of GrtIIb had negative Eu anomalies and may have crystallized from a relatively neutral Cl-rich fluid. GrtIII was severely depleted in light rare earth elements with positive Eu anomalies, indicating the presence of a weakly acidic environment. Accordingly, owing to a decrease in temperature and an increase in oxygen fugacity, the pH of the Jinchanghe deposit may have transitioned from an early weakly acidic to neutral, then to a late weakly acidic environment. Furthermore, the ages of GrtII and GrtIII ranged from 520 to 496 Ma, which places the formation of the Jinchanghe deposit during the Late Cambrian. The deposit is closely related to the arc magmatic rocks produced by the subduction of the Proto-Tethys Ocean.

Petrogenesis and Geochronology of the Shazuoquan Ophiolite, Beishan Orogenic Belt: Constraints on the Evolution of the Beishan Ocean

The ophiolites in the Beishan Orogenic Belt provide important information about the evolution of the Beishan Ocean in the Paleozoic Era. We studied ophiolite petrology, geochemistry and isotopic chronology. The Shazouquan ophiolites consist of dunites, wehrlites, gabbros and anorthosites. Ophiolitic mélange belts are composed of matrixes and blocks, and different rocks are fault-bounded. Dunites and wehrlites are high in Mg#, Cr# and MgO, low in TiO2, relatively depleted in large-ion lithophile elements (Ti and P) and enriched in high-strength elements (U, Zr and Hf). They have a total REE of 1.25 × 10–6−5.39 × 10−6 and δEu of 1.12–3.54, which are similar to those of SSZ-type ophiolites, indicating that their parent magma source region may be a weakly depleted mantle source region. The anorthosite and gabbro are high in Al2O3, MgO and Mg#, low in TiO2, enriched in large-ion lithophile elements (Rb and Sr), and depleted in high-strength elements (Nb, Ta and Ti), but enriched in Zr and Hf. They have similar geochemical signatures to those of arc magmatic rocks. They are derived from the mantle peridotite formed against the tectonic background of subduction and modified by the fluid materials in the subduction zone. We collected anorthosite and gabbro, which were produced as ophiolite for U-Pb dating. The anorthosite yields a zircon U-Pb, aged 394 ± 11 Ma (MSWD = 0.84), and a gabbro zircon U-Pb, aged 466 ± 12 Ma (MSWD = 3.2), indicating that the Shazouquan ophiolite was formed in the Middle Ordovician–Early Devonian eras. Combining the above evidence, we conclude that the Beishan Ocean was in a subduction tectonic background from the Middle Ordovician to Early Devonian periods.

Continental crustal growth and differentiation in intraoceanic arcs: Insights from plagiogranites in the forearc ophiolite of the southeastern Central Asian Orogenic Belt, China

Oceanic plagiogranites in subduction initiation zones record key information of continental crustal growth and differentiation. However, their petrogenesis remains controversial, due to the lack of complete subduction initiation records in most of ophiolites. In this study, we report a newly recognized plagiogranite suite (including intrusive plagiogranite porphyries and extrusive rhyolites) from the Diyanmiao forearc ophiolite in Inner Mongolia, southeastern section of the Centra Asian Orogenic Belt, where a relatively complete forearc magmatic succession is preserved. In the Diyanmiao suite, the plagiogranite porphyries, occur as small irregular dykes or pods intruding pillowed transitional lavas, and rhyolite lavas within or overlying the upper boninitic lavas, from bottom to top. Zircon UPb dating of two plagiogranite porphyry samples and one rhyolite sample yields mean ages of 322.5 ± 3.6, 319.9 ± 1.9, and 319.6 ± 2.6 Ma respectively. Similar to other oceanic plagiogranites, the plagiogranite porphyries and rhyolites in our study exhibit high SiO2 and Na2O contents and low K2O. They have chondrite-normalized flat to slightly depleted rare earth element patterns, and significantly negative Nb, Ta, and Ti anomalies similar to arc magmatic rocks. They also display high positive εHf(t) values (+12.5 − +18.7) and εNd(t) values (+6.9 − +10.0), comparable to the values of their host rocks. Petrographic characteristics and Rhyolite-MELTS modeling suggest that the plagiogranite porphyries and rhyolites were generated by high degree of crystal fractionation from parent tholeiitic basalt magmas. Our results suggest that melt migration triggered by fractional crystallization of mafic magmas played a vital role in the growth of continental crust in intraoceanic arcs in the southeastern Paleo-Asian Ocean.

Granulite facies metasedimentary rocks: Insight into the formation of the East Kunlun continental arc

The metamorphism and dynamic processes of the Early Paleozoic continental margin arc in the East Kunlun orogen are still unclear. This study investigated the metasedimentary rocks with granulite facies in the Qingshuiquan area in the eastern section of the East Kunlun orogen. The kyanite is not found in the pelitic granulite. The phase equilibrium modeling indicates a middle-pressure type with metamorphic conditions of 0.7 to 0.8 GPa and 800 to 840°Cfor pelitic granulite. UPb dating of zircons from metasedimentary rocks yielded metamorphic ages of 490-480 Ma and detrital zircons ages of 1700-1500 Ma. REE patterns of the metasedimentary rocks are enriched LREEs and distinct negative Eu anomalies, the εNd values vary from −1 to −16. These results imply that the Precambrian supracrustal rocks were buried into the middle-lower crust level and granulite facies metamorphism occurred in Late Cambrian-Early Ordovician.Synchronous (520-480 Ma) magmatic rocks in Qingshuiquan and adjacent areas indicate that subduction of the Proto-Tethyan oceanic crust led to the formation of arc magmatic rocks. Meanwhile, it induced some sedimentary rocks to underthrust or return flows into the middle-lower crust of the upper plate and underwent granulite facies metamorphism.

Tectonic evolution of the Meso-Tethys Ocean in the Jurassic: Birth, growth, and demise of a missing intra-oceanic arc

Reconstructing ophiolite ages and tectonic attributes can elucidate ancient ocean tectonic evolution. We present petrological, chronological, geochemical, and isotopic data for Ritu and Dongco ophiolites (Bangong–Nujiang suture zone, Tibetan Plateau). The ∼171 Ma Ritu and ∼169 Ma Dongco diabase are derived from high-temperature, highly depleted mantle metasomatized by subduction fluids; they are similar to fore-arc basalts. The ∼165 Ma Ritu andesites, from enriched mantle metasomatized by subduction fluids and a small proportion of subduction sediment melts, have affinity with the oceanic plateau. The ∼161 Ma Ritu dacites and Dongco granodiorites arose via interaction between subduction sediment melts and the mantle wedge, and ∼158 Ma Dongco granites were derived from subduction oceanic plate metasomatized by subduction sediment melts; they are all similar to arc magmatic rocks. Their high Na2O and low K2O and Th contents, and depleted zircon εHf(t) values, differ from those of southern Qiangtang terrane continental arc magmatic rocks, indicating intra-oceanic origin. The Middle Jurassic diabase and regional contemporaneous fore-arc basalts and boninites likely formed during intra-oceanic subduction initiation. The Middle–Late Jurassic dacites, granodiorites, granites, and regional contemporaneous high-Mg andesites likely formed in a mature intra-oceanic arc. Therefore, the Meso-Tethys Ocean may contain a ∼1000 km intra-oceanic subduction zone with Middle–Late Jurassic mature intra-oceanic arc. Subduction initiation of the intra-oceanic subduction zone likely arose via subduction transference caused by collage of the oceanic plateau and southern Qiangtang terrane at ∼182–177 Ma. At ∼171–155 Ma, the intra-oceanic arc gradually formed fore-arc basalts, boninites, high-Mg andesites, and tholeiitic/calc-alkaline arc rocks, indicating final maturity. The intra-oceanic arc west section potentially collided with the southern Qiangtang terrane ∼155–145 Ma, while the middle section potentially lasted until Early Cretaceous. Our study constrains Meso-Tethys Ocean evolution, providing an important basis for the study of intra-oceanic arcs in orogenic belts.