Petrological and mineralogical constraints on the formation of Neoproterozoic calc-alkaline continental crust: The example of the Luding Intrusive complex, western Yangtze Block, South China

Abstract

Decoding the trans-crustal magmatic evolution processes from exposed paleo-depth that are otherwise inaccessible above continental arc zone is instructive to understand the geochemical fractionation of arc magmatism and geochemical stratification of continental crust. To unravel trans-crustal magmatic processes leading to the formation of Neoproterozoic continental arc, we combined a comprehensive dataset of petrography, zircon UPb geochronology, whole-rock major and trace elements, and SrNd isotopes as well as zircon LuHf isotopes for the Neoproterozoic calc-alkaline Luding Intrusive Complex (LIC) in the western Yangtze Block, South China. The LIC is composed of monzodiorites, gabbro-diorites, diorites, and granodiorites that formed at ca. 783–779 Ma. The LIC lithologies are calc-alkaline with highly variable Mg# values (40.8–70.6) and subduction-related trace elemental patterns. In combination with predominantly depleted and comparable whole-rock SrNd (initial 87Sr/86Sr = 0.703244–0.704248 and εNd(t) = +2.35 ∼ +5.10) and zircon Hf isotopes (εHf(t) = +4.47 ∼ +9.99), the LIC originated from a common subduction fluids-metasomatized mantle source. The hornblende geothermobarometry and whole-rock normative mineral trajectories as well as previously experimental results collectively suggest that the crystallization of LIC occurred within the middle crustal level (11.4–20.9 km) at various temperatures (776–875 °C) and pressures (2.50–5.50 kbar), and underwent different degrees of fractional crystallization of predominant hornblende and plagioclase phases during the assemblage and solidification of cogenetic and multiple batches magmatic pluming. The diorites-granodiorites result from fractionation of early olivine + clinopyroxene phases followed by subsequent amphibole + plagioclase phases, and the monzodiorites mainly represent accumulation residues of dominant hornblende + plagioclase phases from more fractionated melts, while the gabbro-diorites underwent the fractionation from an isotopically homogeneous mantle source, but differ in their elemental compositions. The LIC from Neoproterozoic continental arc suggests that the cogenetic fractional crystallization of mantle-derived melts in intra-crustal magmatic system can account for the petrochemical diversities of arc magmatic rocks during the construction of the Neoproterozoic continental arc crust in the western Yangzte Block, South China.