Using an arc heat source, the filling ratio of Ti6Al4V and Inconel 625 wires was controlled to manufacture a TiNi gradient material using wire arc additive manufacturing (WAAM). The effects of wire filling ratio on the microstructure of the deposition layer were studied through X-ray diffraction (XRD), scanning electron microscope (SEM), and differential scanning colorimetry (DSC). The mechanical performance was evaluated using compression, Vickers hardness, and surface wear testing. The results show that increasing the ratio of Inconel 625 filling wire can form Ti 2 Ni and TiNi strengthening phases in the deposition layer. The Ti 2 Ni and TiNi phases are evenly distributed over the region owing to the stirring of the molten pool by the arc, which improves the compression and surface wear performance of the WAAM parts. When the Inconel 625 wire filling ratio is 35%, the Vickers hardness reaches 600 HV and the compression strength increases to 2.15 GPa. However, excessive Ti 2 Ni phase will reduce toughness. As an Inconel 625 wire filling ratio lower than 35% can achieve a well-performing structure, five kinds of wire filling ratios were chosen to fabricate different gradient materials, and the microstructure, elemental distribution, phase composition, and mechanical properties were analyzed thoroughly. • We propose a new AC-WAAM method to manufacture Ni-Ti alloy Graded Materials. • By adding lnconel625 filling wire and titanium alloy filling wire at the same time. • Changing alloy compound by adjusted the speed rate of lnconel625 and TC4 filling wire. • The effects of wire feeding rate on the microstructure and mechanic were analyzed.