Anticorrosion Properties Research Articles

Improvement of tribological and anti-corrosive performance of MXene nanosheets by grafting polymer brush

Herein, the anti-corrosive polymer brush functionalized MXene (P-MBTS2MA@MXene) was successfully prepared via surface-initiated polymerization. First, the dopamine initiator (DA-Br) can self-assemble onto MXene nanosheets formation of initiator modified MXene (PDA-Br@MXene) via spontaneous oxidative polymerization, then the corrosion inhibitor MBT derivative MBTS2MA monomer was grafted onto MXene nanosheets through surface-initiated atom transfer radical polymerization (SI-ATRP) to obtain polymer brush P-MBTS2MA functionalized MXene (P-MBTS2MA@MXene). The prepared P-MBTS2MA@MXene served as lubricant additive, manifesting good tribological properties with a low COF of 0.098 % and 94.8 % wear-reduction, which is attributed to the shielding effect and protective film formed by P-MBTS2MA@MXene. Additionally, the grafting P-MBTS2MA endows MXene nanosheets with improved anti-corrosion property, which prevents further corrosion of the metal surface via releasing corrosion resistance molecule MBT.

Eco-Friendly Waterborne Polyurethane Coating Modified with Ethylenediamine-Functionalized Graphene Oxide for Enhanced Anticorrosion Performance.

This study explores the potential of graphene oxide (GO) as an additive in waterborne polyurethane (WPU) resins to create eco-friendly coatings with enhanced anticorrosive properties. Traditionally, WPU's hydrophilic nature has limited its use in corrosion-resistant coatings. We investigate the impact of incorporating various GO concentrations (0.01, 0.1, and 1.3 wt%) and functionalizing GO with ethylenediamine (EDA) on the development of anticorrosive coatings for carbon steel. It was observed, by potentiodynamic polarization analysis in a 3.5% NaCl solution, that the low GO content in the WPU matrix significantly improved anticorrosion properties, with the 0.01 wt% GO-EDA formulation showing exceptional performance, high Ecorr (-117.82 mV), low icorr (3.70 × 10-9 A cm-2), and an inhibition corrosion efficiency (η) of 99.60%. Raman imaging mappings revealed that excessive GO content led to agglomeration, creating pathways for corrosive species. In UV/condensation tests, the 0.01 wt% GO-EDA coating exhibited the most promising results, with minimal corrosion products compared to pristine WPU. The large lateral dimensions of GO sheets and the cross-linking facilitated by EDA enhanced the interfacial properties and dispersion within the WPU matrix, resulting in superior barrier properties and anticorrosion performance. This advancement underscores the potential of GO-based coatings for environmentally friendly corrosion protection.

Enhanced Anti-corrosion and Anti-fouling Properties of Galvanized Iron Using Nanocomposite Hydrophobic Coatings

Enhanced Anti-corrosion and Anti-fouling Properties of Galvanized Iron Using Nanocomposite Hydrophobic Coatings

Preparation and anticorrosion properties of Co-Ti-Zr composite conversion coating on 6061 aluminium alloy of the scooter profile

The traditional Cr conversion process is limited in industrial application due to environmental protection issues. The relationship between the morphology, composition and corrosion resistance of the Co-Ti-Zr composite conversion coating was systematically studied by dropping test, electrochemical test, SEM, EDX and XPS. The results show that the best conversion temperature and conversion time of CoTiZrCC is 40 ℃ and 18 min, respectively. The CoTiZrCC formed under the optimal conversion parameters is continuous and compact with the main elements of Co, Ti, Zr and Al on the surface, and its main phases are TiO2, ZrO2, Al2O3 and a small amount of fluoride. Additionally, the CoTiZrCC has lower self-corrosion current and higher film resistance, thereby greatly improving the corrosion resistance of the aluminum alloy substrate.

Fabrication and Properties of Superhydrophobic Colored Stainless Steel Surface for Decoration and Anti-Corrosion

A colored superhydrophobic surface on a stainless steel substrate was achieved by means of high temperature oxidation combined with subsequent spraying modification by superhydrophobic nano-silica film. Comprehensive characterizations of the surface were performed in terms of color, morphology, composition, wettability, and corrosion resistance by optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), contact angle, potentiodynamic polarization, and electrochemical impedance spectroscopy measurement. At 400 °C, the surface was pale yellow, gradually turning yellow and then red as the temperature increased. At 700 °C and 800 °C, the surface colors were blue and dark brown, respectively. The samples with oxide films demonstrated lower contact angles, specifically 80.5° ± 2.5 at 400 °C, 79.1° ± 2.8 at 500 °C, and 75.6° ± 3.4 at 600 °C. The polarization resistance measured on the oxidized film formed at 600 °C exceeded 7.93 × 104 Ω·cm2. After spraying the treatment, these colorful surfaces exhibited superhydrophobicity, they were self-cleaning, and they satisfied anti-corrosion properties. The treatment performs as an excellent barrier and exhibits a high corrosion resistance of 4.68 × 106 Ω·cm2. The successful preparation of superhydrophobic colored surfaces offers the possibility of providing stainless steel with both decoration value and self-cleaning function simultaneously by our proposed chromium-free fabrication process.

Physicochemical, Morphological and Anticorrosive Properties of Electrodeposited ZnNi Alloy Coating

Corrosion in its many forms is a major problem for many types of materials, extending from machining to manufacturing and daily use. In fact, it affects practically all engineering projects, from the biggest to the smallest: energy production, construction, transport, medical sector, electronics, etc. Consequently, corrosion generates both economic and environmental problems. To prevent corrosion and preserve materials' durability, several protection methods can be applied. These included protection by applying a coating on the metal surface. In this context, Zinc based alloy coatings have attracted much interesting scientific community because of their excellent mechanical and anti-corrosive properties. In the present work, ZnNi coatings were electrodeposited on steel substrates using a chloride bath containing ammonium salts. The effect of some experimental parameters, namely, potential and metal ion concentration ratio on the deposition kinetics of ZnNi system as well as on its physicochemical, morphological and anticorrosive properties has been investigated. For this purpose, an appropriate experimental work was performed by using both electrochemical (cyclic voltammetry, chronoamperometry, open circuit potential, potentiodynamic polarization) and nonelectrochemical (SEM-EDX) analysis methods. Based on the obtained results, it has been revealed that simultaneous codeposition of both elements Zn and Ni is possible in our experimental conditions. However, deposition kinetics exhibited a strong dependence on explored parameters. Also, morphological aspect and chemical composition of deposits are strongly influenced by metal ion concentration ratio. Investigation of corrosion behaviour confirms the protective effect of coatings acted as a sacrificial anode. Furthermore, increasing Ni content in the deposits induces a significant enhancement in corrosion resistance. Thus, Zn-Ni alloy coatings prepared from the Ni(II)-rich bath exhibited better corrosion resistance.

Electrolyte Formulation with Improved Ion Desolvation and Diffusion Kinetics, and Superior Anti-Corrosion Properties for Ultrawide-Temperature Supercapacitors (–70∼100°C)

Electrochemical energy storage (EES) devices operating over a wide temperature range are crucial for extreme applications like near-space exploration (–70 °C) and desert exploitation (80 °C). However, their electrochemical performance is still hindered by the high-energy-barrier desolvation process at low temperature and the parasitic redox corrosion reactions at high temperature. In this work, an ultrawide-operating-temperature-window supercapacitor is proposed by simultaneously regulating ion kinetics of electrolyte and modulating anti-corrosion property of current collector. The optimized kinetics at low temperatures (–70 °C) refer to the enhanced ion dissociation and accelerated desolvation process, which is precisely regulated by the medium dielectric constant and low donor number of both methyl propyl ketone (MPK) and methyl ethyl ketone (MEK) cosolvents. Meanwhile, the remarkable cycling stability at high temperatures (100 °C) is realized by the strengthened corrosion resistance of carbon cloth current collector. The combination of MEK/MPK based electrolyte and carbon cloth current collector enables the supercapacitor to achieve a superior low-temperature capacitance retention (91.13 % @ –60 °C and 75.4 % @ –70 °C), extended high-temperature cycling stability (69.2 % @ 100 °C, 10,000 cycles) and excellent power and energy densities (13,820 W kg–1 @ 20.68 W h kg–1). This research is expected to provide valuable references for the advanced design of EES devices with wide-operating-temperature range in future studies.

Mechanical and anti-icing performance of superhydrophobic aluminum conductor by anodized oxide technique

Abstract Anodized oxide technology is a traditional surface treatment method used in the material engineering field to enhance the friction, anti-icing, anti-corrosion, and insulation properties of Al-based samples. Considering the anti-icing and insulation performance, anodized oxide technology has great application prospects in overhead transmission lines. In this study, the preparation process of Aluminum (Al) flat plates and Aluminum Cable Steel-Reinforce (ACSR) was explored by using anodizing technology to obtain superhydrophobic properties. Moreover, as the significant performance in the application of transmission lines, the mechanical performance (tensile strength) of Al conductors was evaluated to study the impact of anodized oxidation technology. The results show that anodized oxide technology can improve the tensile strength of aluminum clad steel bars and aluminum-stranded wires in ACSRs. In addition, the hydrophobicity and anti-icing performance of anodized wires can demonstrate potential application prospects in the field of anti-icing.

The effect of polylactic acid ordering on the long-term corrosion protection capacity of biodegradable magnesium alloys

The polylactic acid (PLA) coatings of different crystallinity were prepared on biodegradable Mg-2.2Zn-0.3Ca alloy wires to improve the long-term anti-corrosion properties. The composition characteristics and microstructure of the samples were investigated by differential scanning calorimetry (DSC), Fourier transform infrared spectroscope (FTIR), wide angle X-ray diffraction (WAXD) and scanning electron microscope (SEM). The corrosion resistance of all samples was investigated by immersion tests and electrochemical techniques in vitro simulated body fluid (SBF). The results indicated heat treatment improved the crystallinity of PLA coating and heated-coating performed protective behaviors in the short and long-term immersion. The corrosion rate of heated samples was lower than that of unheated samples and exhibited superior long term protective effect for Mg alloy wires. The lifetime of heated sample (H2) increased significantly from 33 to 55 days. The initial electrochemical performance of unheated coating was better than heated coating, but it declined more rapidly during the long-term immersion. These results indicated that PLA coating could not ignore the effect of its crystallinity to anti-corrosion ability, and only the suit heat treatment makes PLA coating more ordering and achieves higher corrosion resistance in vitro immersion. Therefore, it has promising potential by controlling effectively the PLA ordering for surgical implant applications.

Anti-corrosive properties of vermiculite-enhanced waterborne epoxy resins with two-dimensional exfoliation

Abstract Although waterborne epoxy resin coatings are widely used in the field of anti-corrosion, micropores and micro defects in their coatings are the key factors restricting their further development. The exfoliated vermiculite was stripped by a physical one-step stripping method, with good water dispersion and dense lamellar structure. As the nano-filler, it can effectively fill the micro defects in the coating, make the coating structure more compact, and effectively prevent the intrusion of corrosive media. When exfoliated vermiculite was added at 1%, two orders of magnitude increased the electrochemical impedance modulus to 2.276×106 Ω cm2 and the corrosion current was correspondingly reduced to 1.186×10−8 A cm−2, showing excellent corrosion resistance. Adding 1% exfoliated vermiculite creates a “labyrinth effect” in the coating that extends the penetration path of the corrosion particles, thus effectively preventing corrosion of the underlying metal substrate. This enables the coating to better cope with harsh corrosive environments and provides a viable idea for coating protection.

Corrosion protection performance of stretched graphene-modified cold-sprayed zinc coating for steel rebar

The cold-sprayed zinc technology exhibits unique advantages in the field of metal corrosion prevention due to its environmental friendliness and convenient construction. However, compared to hot-dip galvanizing, there is still a necessity to improve its corrosion resistance. Graphene as a filler material, effectively strengthens the anticorrosive properties of the coating. Nevertheless, the resistance of graphene-modified cold-sprayed zinc coating to chloride ion induced metal corrosion remains unknown. In this study, cold-sprayed zinc coating and graphene-modified zinc coating were employed to steel rebar that was subjected to different levels of tensile stress. The passivation and de-passivation process of the stretched zinc-coated rebar in the simulated concrete pore solution were investigated with electrochemical tests and microscopic analyses. The research findings reveal that compared with ordinary cold-sprayed zinc coating, graphene-modified coating can significantly improve the coating resistance and reduce the corrosion rate of rebar under different levels of tensile stress attributed to the high surface area of graphene. However, due to the discontinuity between zinc powders induced by graphene, a complete passivation film cannot form on the surface of graphene-modified zinc coating, which resulted in a lower resistance against chloride ion induced de-passivation. This study indicates that graphene-modified cold-sprayed zinc-coating is not fit for marine environment.

Exploring tribological and corrosion properties of Al-5052/SiC+CeO2 hybrid surface composites fabricated using friction stir processing

In this study, advanced aluminium metal matrix hybrid surface composites were synthesized using the five-pass friction stir processing (FSP) technique. A blend of Hybrid reinforcement particles, silicon carbide and cerium oxide, were incorporated into the Al-5052 matrix at varying SiC: CeO2 ratios of 100:0, 75:25, 50:50, 25:75, and 0:100. The multi-pass FSP methodology ensured thorough mixing and uniform nanoparticle distribution, resulting in tailored microstructures. The optimal 75:25 SiC: CeO2 ratio exhibited superior microstructural, anti-corrosion, and tribological properties, with the lowest wear rates of 8.3 × 10−9 and 8.8 × 10−9 mm3/m at 15 N and 25 N loads, respectively, and the lowest corrosion rate of 8.06 mm per year compared to other hybrid blends.

ФИЗИКО-ХИМИЧЕСКИЕ СВОЙСТВА МОДИФИЦИРОВАННЫХ БИТУМНЫХ ПРАЙМЕРОВ ДЛЯ ПРОТИВОКОРРОЗИОННОЙ ЗАЩИТЫ СЕЛЬСКОХОЗЯЙСТВЕННОЙ ТЕХНИКИ И ОБОРУДОВАНИЯ

Compositions based on bitumen primers can be used for anti-corrosion protection of agricultural machinery and equipment. Their physicochemical properties were studied. It has been shown that the thickness of coatings, which is responsible for the effectiveness of barrier protection, increases as expected with an increase in the number of applied coating layers, and decreases even with a slight increase in temperature and with an increase in the amount of solvent in the case of coating by dipping. Increasing the amount of solvent added to the bitumen primer from 40 wt. % up to 67 wt. % leads to a reduction in coating thickness by 55 times. Brush application produces thinner finishes than dip application. Moisture absorption for modified BP with 67 wt. % solvent is 1-2 orders of magnitude higher than that of BP with 40 wt. % white spirit, therefore, a decrease in protective effectiveness can be expected for these materials. According to experimental studies, the contact angles for the original BP exceed 900C, which indicates the presence of hydrophobic properties. The type and concentration of additives affect the contact angles. Introduction 5 wt. % of modifying additives, paraffin P2 and Emulgin, reduces the contact angle of BP, the addition of KO-SZhK, on the contrary, increases it, improving hydrophobic properties. BP with 40 wt. % white spirit, including those with additives, shows good adhesion to carbon steel 0.8 kp. At 67 wt. % solvent in the presence of drying oil and unrefined sunflower oil additives, adhesion worsens. Viscosity-temperature dependences in semi-logarithmic coordinates for modified BP are close to linear in the temperature range 20 -60 0C with a high approximation reliability index R2 = 0.9543 - 0.9833. Based on the physicochemical properties, high anti-corrosion properties can be assumed.

Exfoliated MoS2 with tunable size effect towards anticorrosion application

MoS2 sheets are becoming more and more active in the field of anticorrosion coatings. In this work, different size of MoS2 were fabricated by a simple gradient centrifugation approach then introduced into epoxy coatings (EP). Composite coatings with smaller size and larger size of MoS2 were also prepared for comparison. Anticorrosion properties of the coatings were evaluated via electrochemical spectroscopy, salt spray tests and theoretical calculation in detail. The impedance arc of doping the 1.4±0.1 μm of EM2000 for EP was 4.8×107 Ω cm2 after 7d immersing, which is much higher than that of EM800/EP, EM1000/EP and EM3000/EP. Salt spray test and corrosion products analysis have also proved the proposed protection mechanism of EM2000/EP coating. Doping the optimized size of EM2000 could form nano-network covering the microcracks to impede the diffusion of corrosive medium. In addition, the theoretical calculation showed that the body-center adsorption of O2 show the weaker physisorption with adsorption energies of ∼ −0.64 eV and −0.14 eV for H2O and O2. Excellent barrier ability and enhanced dispersion of the optimized size of MoS2 sheets were responsible for the superior enhancement of the anticorrosion performance of EP coating.

Construction of chromium-free passivation film of pomelo peel extract on the surface of lithium-ion battery copper foil and study on anti-corrosion mechanism

Passivation treatment is the last key process to ensure the service life of copper foil for lithium-ion batteries. Although chromic anhydride commonly used in industry has an efficient passivation effect, it can threat human health and the environment. Herein, an environmentally friendly passivator is prepared from pomelo peel by a simple and economical solution extraction method, which makes copper foil have good anti-corrosion properties in air, chlorine-containing solution, and organic electrolyte. Electrochemical methods and X-ray photoelectron spectroscopy (XPS) confirm the potential of pomelo peel extractant (PP) to replace chromic anhydride as a passivating agent for copper foil. The interaction mechanism between PP and copper foil is analyzed by adsorption models, and the efficient passivation behavior of PP for copper foil is consistent with the Langmuir model. Density Functional Theory (DFT) calculations of the naringin (main component of PP) is performed to further reveal the protection mechanism of PP on copper foil. In addition, the copper foil treated by PP still has excellent electrochemical performance as lithium-ion battery current collector, indicating that the presence of PP not only protects the copper foil from corrosion, but also does not affect the conductivity of the copper foil. This research provides a new insight into the chrome-free passivation of copper foils, which is in line with the development concept of green production.

Machine learning models and computational simulation techniques for prediction of anti-corrosion properties of novel benzimidazole derivatives

The present paper delves into the development of predictive models for the optimum prediction of inhibition efficiencies and anti-corrosion properties of newly designed benzimidazole compounds in an HCl medium. Density functional theory (DFT) was used to obtain the molecular descriptors. 17 descriptors considered as input variables were reduced to 9 after redundant variables were eliminated using the variance inflation factor (VIF). Machine learning models such as random forest regression (Rf), K-nearest neighbor (KNN), and gradient boosting (GB) were used to develop a predictive model using data from 50 benzimidazole derivatives whose inhibition efficiencies for steel alloy in HCl medium have been determined experimentally and are available in the literature. The cross-validation (CV) technique was used to evaluate the predictive capability of the models. KNN gave the best result with a coefficient of correlation (R2) of 0.654, compared to GB (0.591) and RF (0.512). Subsequently, the three models were used to predict the inhibition efficiencies of three novel benzimidazole compounds. The corrosion inhibition efficiency of three newly developed benzimidazole compounds was 91 % - 98.5 % when assessed with the best-performing model, K-nearest neighbor (KNN) with MSBAH recording the highest value of 98.5 %. Fukui indices parameters fk+k,fk−k,andf2(r) showed that both the electrophilic and nucleophilic sites are concentrated around specific atoms most of whom are heteroatoms that participate actively in electron-donor and acceptor interaction with the metal atom leading to the formation of coordinate covalent bonds. The results of electron distribution and Fukui dual descriptors support the results of the predictive model. The study also revealed that machine learning algorithms in conjunction with DFT and MD simulation is an innovative technique for the prediction of anti-corrosion properties of newly designed molecules such as corrosion inhibition efficiencies, and mechanism of inhibitor adsorption on metal/alloy surfaces exposed to an aggressive environment. This technique can be harnessed in proffering solutions to acid corrosion especially those that occur during descaling operation.

Anticorrosion properties of flavonoids for rust-free building materials: a review

Abstract Rust-free building materials are crucial for ensuring the durability and structural stability of constructions. Corrosion, a widespread issue affecting metals like steel, copper, and concrete, can be effectively managed with the help of corrosion inhibitors. One effective method for corrosion inhibition involves the application of corrosion-inhibiting coatings, which form resilient and tightly adherent films on metal surfaces. Flavonoids, renowned for their diverse biological activities, demonstrate significant anticorrosive properties. They contain beneficial compounds such as antioxidants and chelating agents. The efficacy of plant extracts as corrosion inhibitors is influenced by their organic constituents, particularly phenols and flavonoids. Flavonoids act by creating a protective film that serves as a barrier, shielding the metal surface from corrosive agents and limiting their access to the metal. This contributes to the prevention of corrosion. The integration of flavonoids into building materials has the potential to transform corrosion prevention practices, leading to improved durability, reduced maintenance costs, and a more environmentally friendly built environment. This article explores the promising prospects of flavonoids as an innovative and sustainable approach to corrosion prevention in building materials. Additionally, it aims to stimulate further research endeavors, fostering the development of effective and eco-friendly corrosion protection strategies for the construction industry.

The Anti-corrosion Property of 6061 Aluminum Alloy Subjected to Direct Current Interference in Marine Environment

The Anti-corrosion Property of 6061 Aluminum Alloy Subjected to Direct Current Interference in Marine Environment

A novel UV-curable composite coating with superior anti-corrosion and mechanical properties

The UV curing method is free from volatile organic compounds (VOC) and exhibits high curing efficiency. However, pore flaws and inadequate mechanical qualities after cure greatly hinder their utilization in metal anti-corrosion. Herein, layered double hydroxides (LDH) supported by molybdic acid and cerium ions were synthesized in situ on the sericite (SC) surface, enhancing the shielding, corrosion inhibition, resin compatibility, and cross-linking density of the coating. Compared with carbon steel immersed in a 3.5 wt% NaCl solution, the incorporation of SC/KH560@LDH reduced the corrosion current density (Icorr) from 2.001 × 10−5 A/cm2 to 7.883 × 10−6 A/cm2. Moreover, the low-frequency impedance of the UV-SC/KH560@LDH coating remained high at 1.939 × 1010 Ω·cm2 after 70 days of immersion in a 3.5 wt% NaCl solution. The excellent corrosion resistance of UV-SC/KH560@LDH can be attributed to the barrier properties of the filler, the chloride ion trapping, and the passivation effect. Furthermore, the UV-curable alkyd resin used in this work formed a chemical bond with the metal substrate, enhancing the mechanical properties of the coating. The adhesion strength of the UV-SC/KH560@LDH was measured at 11.50 MPa. The thickness loss (21.3 μm) of the UV-SC/KH560@LDH were minimal after 5000 cycles of wear. A new research concept for preparing the UV-SC/KH560@LDH with superior anti-corrosion and mechanical properties for carbon steel plate surfaces has been proposed to meet the demands of practical applications.

The effect of clay reinforcement of pine pollen grains on the mechanical, anti-corrosion and anti-microbial properties of an epoxy coating

Abstract In this work, a new material (PP-Mag) was manufactured using pine pollen (PP) and cetyltrimethylammonium bromide (CTA-Mag). By combining PP and Maghnite with an epoxy resin (EP), innovative nanocomposite materials was developed. With different blend compositions, the effect of EP on the mechanical properties, polarisation tests, salt spray tests and morphological characteristics of the blends was studied. The storage modulus (E′) of EP is 2179 MPa, which increases to 2361 MPa with increasing PP-Mag content. The mechanical properties of the blends containing EP/wt%PP/Mag showed an improved performance due to a better adhesion between the two phases when EP is incorporated. It was shown that the PP/Mag materials present in the matrix improve the corrosion resistance according to the different polarisation tests and the salt spray test.