Anti-corrosion Capability Research Articles

Nanosecond Laser Fabrication of Hydrophobic Stainless Steel Surfaces: The Impact on Microstructure and Corrosion Resistance.

Creation of hydrophobic and superhydrophobic surfaces has attracted broad attention as a promising solution for protection of metal surfaces from corrosive environments. This work investigates the capability of nanosecond fiber laser surface texturing followed by a low energy coating in the fabrication of hydrophobic 17-4 PH stainless steel surfaces as an alternative to the ultrashort lasers previously utilized for hydrophobic surfaces production. Laser texturing of the surface followed by applying the hydrophobic coating resulted in steady-state contact angles of up to 145°, while the non-textured coated base metal exhibited the contact angle of 121°. The microstructure and compositional analysis results confirmed that the laser texturing process neither affects the microstructure of the base metal nor causes elemental loss from the melted regions during the ultrafast melting process. However, the electrochemical measurements demonstrated that the water-repelling property of the surface did not contribute to the anticorrosion capability of the substrate. The resultant higher corrosion current density, lower corrosion potential, and higher corrosion rate of the laser textured surfaces were ascribed to the size of fabricated surface micro-grooves, which cannot retain the entrapped air inside the hierarchical structure when fully immersed in a corrosive medium, thus degrading the material’s corrosion performance.

In Situ Polymerization Approach to Graphene-Oxide-Reinforced Silicone Composites for Superior Anticorrosive Coating.

Novel graphene-oxide-reinforced silicone composites (GOSC) are prepared by in situ polymerization of silanes and low concentrations (<0.15wt%) of silylated GO (SGO). After modification, the distances of the SGO nanosheets are successfully increased from 0.72 to 0.87nm. Compared with GO, the SGO shows better dispersibility in organic solvents as well as remarkably enhanced decomposition temperature (T d improved by 100°C). After covalently grafting onto silicone resins via in situ polymerization, the obtained GOSC exhibits greatly enhanced thermal stability (T d up to 400°C and T g improved by 3-5°C), increased storage modulus, loss modulus, and complex viscosity. The morphology, microstructure, interfacial adhesion of the developed GOSC coatings were carefully investigated. The GOSC coatings on metal exhibit good transparency (up to 90%), hydrophobicity, and excellent anticorrosion capability. This work provides a new strategy for developing high performance graphene-based silicone composite materials.

Comparative corrosion resistance properties between (Cu, Ce)-DLC and Ti co-doped (Cu, Ce)/Ti-DLC films prepared via magnetron sputtering method

Element co-doping is an effective fashion to improve the properties of carbon-based film and amplify its application area. Here, (Cu, Ce)-DLC and (Cu, Ce)/Ti-DLC films were successfully prepared via magnetron sputtering. Evolutions of surface/interface morphology, microstructure and wettability of as-prepared films were investigated systematically to in-depth analysis the relationship between their microstructure and anti-corrosion capability. (Cu, Ce)/Ti-DLC film possessed a thicker thickness compared to (Cu, Ce)-DLC film. Raman spectra of as-prepared films exposed quintessential features of carbon peak. Scanning vibrating electrode technique revealed the local electrochemical corrosion process of films. Particularly, (Cu, Ce)/Ti-DLC film could demonstrate superior anti-corrosion ability.

Calcium hydroxide coating on highly reactive nanoscale zero-valent iron for in situ remediation application

Nano scale zero-valent iron (nZVI), a promising engineering technology for in situ remediation, has been greatly limited by quick self-corrosion and low mobility in porous media. Highly reactive nZVI particles produced from the borohydride reduction method were enclosed in a releasable Ca(OH)2 layer by the chemical deposition method. The amount of Ca(OH)2 coated on nZVI surface were well controlled by the precursor dosage. At moderate Ca(OH)2 dosage (RCa/TFe = 0.25) condition, the increment of Fe0 content for the obtained nZVI/Ca-0.25 sample was observed. The interfacial reactions between the iron oxide shell and the Ca(OH)2 saturated environment were delicately elucidated by the X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) spectrum. And the coverage of Ca(OH)2 shell on spherical nZVI surface was found more complete and uniform for the nZVI/Ca sample obtained from the moderate precursor dosage condition (RCa/TFe = 0.25). The Ca(OH)2 shell before dissolution was demonstrated owning the anti-corrosion capability to slow down the oxidation of Fe0 core in air, during ethanol storage and in aqueous environment. The mechanism of anti-corrosion capability for nZVI/Ca-0.25 particle was interestingly found to be attributed to the Ca(OH)2 shell isolation and also be potentially due to the iron oxide shell phase transformation mediated by the outer Ca(OH)2 shell. An improved trichloroethylene reduction performance was observed for nZVI/Ca-0.25 than bare nZVI. The mobility of nZVI/Ca particles in water-saturated porous media was moderately improved before shell dissolution.

Near-Infrared Light and Solar Light Activated Self-Healing Epoxy Coating having Enhanced Properties Using MXene Flakes as Multifunctional Fillers.

Two issues are required to be solved to bring intrinsically self-healing polymer coatings into real applications: remote activation and satisfied practical properties. Here, we used MXene, a newly reported two-dimensional material, to provide an epoxy coating with light-induced self-healing capabilities and we worked to enhance the properties of that coating. The self-healing coatings had a reversible crosslinking network based on the Diels-Alder reaction among maleimide groups from bis(4-maleimidopheny)methane and dangling furan groups in oligomers that were prepared through the condensation polymerization of diglycidylether of bisphenol A and furfurylamine. The results showed that the delaminated MXene flakes were small in size, around 900 nm, and dispersed well in self-healing coatings. The MXene flakes of only 2.80 wt % improved greatly the pencil hardness of the coating hardness from HB to 5H and the polarization resistance from 4.3 to 428.3 MΩ cm−2. The self-healing behavior, however, was retarded by MXene flakes. Leveling agent acted a key part here to facilitate the gap closure driven by reverse plasticity to compensate for the limitation of macromolecular mobility resulting from the MXene flakes. The self-healing of coatings was achieved in 30 s by thermal treatment at 150 °C. The efficient self-healing was also demonstrated based on the recovery of the anti-corrosion capability. MXene flakes also played an evident photothermal role in generating heat via irradiation of near-infrared light at 808 nm and focused sunlight. The healing can be quickly obtained in 10 s under irradiation of near-infrared light at 808 nm having a power density of 6.28 W cm−2 or in 10 min under irradiation of focused sunlight having a power density of 4.0 W cm−2.

Influence of water adhesion of superhydrophobic surfaces on their anti-corrosive behavior

The water adhesion is important for superhydrophobic materials. Compared with considerable research on metal corrosion protection using superhydrophobic coatings, research involving the different water adhesion of superhydrophobic coating on its anti-corrosive behavior is neglected. Herein, superhydrophobic coatings with controllable water adhesion were successfully fabricated by spraying different percentages of hydrophobic SiO2 nanoparticles (NPs) on the Al substrate, and then the influence of water adhesion of superhydrophobic surfaces on their anti-corrosive behaviour was studied. The electrochemical test was carried out on the superhydrophobic surface with different water adhesion to reveal the influence of water adhesion on anti-corrosion capability. The results showed that the anti-corrosion was markedly influenced by the water adhesion of the superhydrophobic coating, and their corrosion resistance was varied in the order of low-adhesion > medium-adhesion > high-adhesion. Moreover, the superhydrophobic coating with the percentage of OTS-SiO2 = 100 possesses unexpected corrosion protection property with lower corrosion rate (CR) and higher polarization resistance (Rp). The corrosive current reduced and impedance modulus (Rct) increased with the decrease of adhesion. In addition, the anti-corrosion mechanism of superhydrophobic coatings with different adhesion was elaborated.

Electrochemical Behavior of CrN/Cr Bilayer Coating on 316L Stainless Steel in Simulated Cathodic Environment of HT-PEFC

High-temperature polymer electrolyte fuel cells (HT-PEFCs) operate in the range of 120 – 180 °C and currently employ phosphoric acid doped polybenzimidazole membranes. This, in turn, represents a quite aggressive environment for the components of a fuel cell [1]. Due to this reason, bipolar plates are presently made of graphitic composite materials. Indeed, they show long-term stability, but otherwise, they exhibit high mass and volume as well as a high effort of manufacturing. Therefore metallic materials come into play as promising candidates for the bipolar plate [2]. They provide some crucial advantages, like enhanced volumetric and gravimetric power density for stacks, increased ductility, high mechanical stability and the capability of low-cost mass production. Due to the corrosion of the metals, it is not feasible to employ bare commercially available stainless steels or Ni-based alloys as metallic bipolar plates for HT-PEFC application. One possibility to reduce the corrosion rate and to keep the benefits of metals could be applying conductive and inert coatings [2]. For coatings without self-healing ability, localized corrosion should occur at the damaged site and continuous corrode the substrate under the coating. Self-healing ability can be given to the films by introducing a metallic component into the films: The oxidation of the metallic component will heal flaws in the films [3]. According to this idea, CrN/Cr bilayer coating has been studied. Using an electrochemical cell, which was specially designed for HT-PEFC experimental requirements, we analyzed CrN/Cr bilayer coated 316L and bare 316L by means of potentiodynamic, potentiostatic and free corrosion potential monitor tests combined with electrochemical impedance spectroscopy. By purging different gases (nitrogen, oxygen) into the electrolyte, we have also investigated the influence of oxygen on the corrosion resistance ability of CrN/Cr coating under simulated cathodic HT-PEFC environments. Additionally, ex-situ characterizations using SEM+EDX, XPS and ICP-OES were carried out in order to investigate the metallic surface, corrosion production and the corresponding dissolved ion species in the electrolyte. The CrN/Cr bilayer coating shows good anti-corrosion capability in the simulated cathodic environment of HT-PEFC with the existence of oxygen, i.e. no cracks or holes on the surface of the samples after potentiostatic tests at either 0.65 V or free corrosion potential for more than 4 hours at 130 ºC. Cathodic operation conditions including a relatively high potential and the presence of oxygen lead to the oxidation of chromium on the damaged site, therefore healed the damaged site and beneficial for providing sufficient corrosion resistance to the cathodic HT-PEFC environment.

Controlled Release of Nitrate and Molybdate Intercalated in Zn-Al-Layered Double Hydroxide Nanocontainers towards Marine Anticorrosion Applications

Zn-Al layered double hydroxides (LDHs) intercalating with molybdate anions was developed to inhibit the corrosion of mild steel in neutral chloride conditions. The LDH compounds were prepared by a method involving co-precipitation and anion-exchange and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), respectively. The anticorrosion capabilities of the LDHs hybrids were analyzed by using open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curve. A significant reduction of the corrosion rate is observed in the presence of a 2 g/L concentration of the LDHs hybrids in the corrosive media. The mechanism is that the intercalated molybdate anion can slowly diffuse out of the inner structure of LDHs in a controllable way and result in a relatively long-term effect of corrosion inhibition. The result presented here underlines the great potential of the controlled release mechanism for marine anticorrosion applications.

Eminently Enhanced Anticorrosion Performance and Mechanisms of X-ZnO (X = C, N, and P) Solid Solutions.

Nonmetal (C, N, P) doped zinc oxide solid solutions (ZnO SSs) prepared through one-step calcination method exhibited novel anticorrosion capability. The anticorrosion property was identified by electrochemical impedance spectroscopy and polarization curve technique. The maximal impedance belonged to C-ZnO SS, which was 12 times higher than pure ZnO materials. Then, a synergistic anticorrosion mechanism was proposed: the photoelectron flow suppression effect and the self-cohering process formed by doping. The tiny particle size as well as the minor zeta-potential of X-ZnO SSs eminently promoted the intermolecular cohesion and the formation of the compact surface automatically. Moreover, the photocatalytic experiments successfully verified the product and the corrosion inhibition effectiveness of the photoelectrons. Additionally, a positive correlation conclusion between the anticorrosion performance and the photocatalytic performance of the X-ZnO SSs was obtained. Consequently, developing the self-cohering anticorrosion materials is of crucial industrial application prospect and value.

Evolution of microstructure and mechanical properties of SUS430/C11000/SUS430 composites during the laser-forming process

Multilayered sheet metals have been widely used to achieve a wide range of favorable mechanical, physical, thermal and electrical properties. Laser beam irradiation over these materials creates extreme temperature changes that can lead to changes in the microstructural properties. Microstructure plays a very crucial role in determining the mechanical property of the irradiated region, thus determining the optimum laser processing conditions. In this study, metallographic studies, as well as tensile, fatigue and hardness tests, are undertaken on SUS430/C11000/SUS430 laminated composites that have been exposed to laser irradiation with different number of passes. This composite can be used in the microelectronics industry since it has the anti-corrosion and strength capability of stainless steel, and the electrical superiority of copper. Ytterbium fiber laser is used in such a way that the governing mechanism of the process is the temperature gradient mechanism. Evolution of the microstructure is revealed by metallography, and the fracture levels of tension and fatigue test specimens are further evaluated by SEM. This study illustrates the significant effects of successive laser irradiation on the evolution of microstructure and mechanical properties, which lead to some suggestions for improving the properties of laser-formed SUS430/C11000/SUS430 composites.

Adsorption Behavior and Anticorrosion Capability of Antibiotic Drug Nitroxoline on Copper in Nitric Acid Medium

The adsorption performance and anticorrosion activity of nitroxoline (NHQ) on copper were evaluated by gravimetric method in 1.0, 2.0 and 3.0 M nitric acid solutions and by electrochemical techniques namely electrochemical impedance spectroscopy (EIS), Tafel polarization (TP) and linear polarization (LP) in 1.0 M nitric acid solution. In all four methods, it was observed that the percentage of inhibition efficiency increases with increasing inhibitor concentration from 50 to 300 ppm. TP curves indicate that the antibiotic drug NHQ acts as mixed-type inhibitor. EIS studies showed that the charge transfer resistance increases with inhibitor concentration. The thermodynamic parameter \(\Delta G_{\text{ads}}^{0}\) confirmed a physisorption mechanism. The inhibitor adsorption was spontaneous and it obeyed Langmuir adsorption isotherm. The formation of adsorbed layer on the copper metal surface was confirmed by SEM, EDX, FT-IR and AFM techniques.

Novel inorganic solid controlled-release inhibitor for Q235-b anticorrosion treatment in 1 M HCl

Borate was regarded as an interesting material for a broad range of applications. Here, we had prepared a novel borate-based controlled-release inhibitor to improve the anticorrosion performance of Q235-b in 1M HCl. The effective components released by the inhibitor were boron and sodium, and its anticorrosion performance was investigated by various electrochemical methods The potentiodynamic polarization curve results indicated that the borate-based inhibitor showed a clear anodic-type inhibitor characteristic, and a great improvement of the resistance was obtained from the electrochemical impedance spectroscopy, resulting from the formation of a passive film with FeOB structure on the Q235-b surface. The formation process followed the Langmuir isotherm well, and the passive film showed a self-healing capability, which confirmed by the electrochemical noise. Further, the anticorrosion capability of the inhibitor gradually increased with the increasing release time. After 21days of release, the boron concentration reached 125mgL−1, the anticorrosion efficiency was over 97%, and a smooth surface was observed on the Q235-b surface from electron microscopy. According to these results, we believed that the borate-based controlled-release inhibitor displayed a satisfactory capability to suppress corrosion on the Q235-b surface in 1M HCl. The present work provided a novel concept for the development of corrosion inhibitor.

Capability Evaluation of Houttuynia Cordata Leaf Extract As Environmentally Eco-Friendly Inhibitor for Steel Corrosion in HCl 0.1 M

In this study, the anti-corrosion capability of Houttuynia cordata leaf extract (HLE) in HCl 0.1 M on mild steel was investigated by electrochemical testing methods consisting of potentiodynamic polarization (PD), electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR), and surface analysis including scanning electron microscope (SEM), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS). The results showed an increase in corrosion resistance of steel with increasing HLE concentration and suggested that its action as a mixed-type inhibitor, resulting in excellent inhibition efficient of HLE on steel surface and lower corrosion rate. Surface analysis exhibited profoundly influential impact of HSL components for improving steel surface protection by protective film formation via adsorption process of HLE components. The steel surface protection mechanism was also provided and discussed in detail.

Enhancing the rate and cycling performance of spherical ZnO anode material for advanced zinc-nickel secondary batteries by combined in-situ doping and coating with carbon

High-performance ZnO microspheres doped and coated with carbon has been successfully fabricated by a facile three-step process using trisodium citrate as doping carbon source and glucose as coating carbon source. Compared with carbon free ZnO precursor, the resulting ZnO-N2@Cmicrospheresexhibitsuperiorrateperformanceandenhancedcyclingstability.(*) At a rate of 10C (5000mAg−1), the ZnO-N2@C exhibits specific discharge capacity and volumetric capacities of 283.4mAhg−1 and 858.7mAhcm−3, respectively, while the values for the carbon free ZnO precursor are only 140.2mAhg−1 and 423.4mAhcm−3. After cycling 200 times at 500mAg−1, the obtained ZnO-N2@C can maintain a satisfying capacity of 508.2mAhg−1, corresponding to a superior capacity retention (94.7%). In contrast, carbon free ZnO can only deliver the capacity of 109.4mAhg−1 and a capacity retention of 24.7% after 200 cycles. This outstanding improvement is attributed to the synergistic effect of the combined in-situ doping and coating carbon, including reduced charge-transfer resistance, enhanced electrochemical reversibility, and better anti-corrosion capabilities. As a result, it is believed that ZnO-N2@C should be an attractive and promising anode material for high power Zinc-Nickel batteries.

Microstructural Modeling of Pitting Corrosion in Steels Using an Arbitrary Lagrangian–Eulerian Method

Two microscale numerical models are developed in this work using a moving-mesh approach to investigate the growth process of pitting in different iron phases and the corrosion prevention capability of polyaniline (PANi) on steels. The distributions of corrosion potential and current in the electrolyte-coating-steel system are computed to evaluate the anti-corrosion ability of PANi. The arbitrary Lagrangian–Eulerian approach was used to accomplish the continuous remesh process as was needed to simulate the dynamic growing forefront of the modeled pitting domain. Experimental validation of the numerical models was conducted using the technique of scanning kelvin probe force microscopy (SKPFM). The SKPFM-scanned surface topography and Volta potential difference exhibit comparable results to and thereby prove the numerical results. The potential distribution in the electrolyte phase of the validated models shows that the corrosion pit grows faster in the epoxy-only-coated steel than that in the PANi-primer-coated steel over the simulation time; also, the corrosion pit grows faster in the ferrite phase than in the cementite phase. The simulation results indicate that the epoxy-only coating lost its anti-corrosion capability as the coating was penetrated by electrolyte, while the PANi-based coating can still protect the steel from corrosion after the electrolyte penetration. The models developed in this work can be used to study the mechanisms of pitting corrosion as well as develop more effective corrosion prevention strategies for general metallic materials.

Fabrication of FDTS-modified PDMS-ZnO nanocomposite hydrophobic coating with anti-fouling capability for corrosion protection of Q235 steel

Perfluorodecyltrichlorosilane-based poly(dimethylsiloxane)-ZnO (FDTS-based PDMS-ZnO) nanocomposite coating with anti-corrosion and anti-fouling capabilities has been prepared using a one-step fabrication technique. XPS analysis and contact angle measurements showed the fluorine content to increase, while the hydrophobicity of the coatings decreased with addition of FDTS. XRD analysis revealed existence of ZnO nanoparticles of dimensions ranging from 11.45 to 93.01nm on the surface of coatings, with the mean particle size decreasing with FDTS addition, and was confirmed by SEM and TEM observations. Interestingly, the anti-corrosion performance and mechanical properties of the coatings increased remarkably on addition of FDTS. Indeed, the observed low adhesion strength, surface energies and the outstanding anti-corrosive properties imply that the obtained coating would be useful in anti-fouling applications.

The high-temperature performance of low-cost La[sbnd]Ni[sbnd]Fe based hydrogen storage alloys with Si substituting

Various properties of La0.78Ce0.22Ni3.73Co0.30Mn0.30Al0.17Fe0.5−xSix (x = 0, 0.05, 0.075 and 0.1) hydrogen storage alloys at 20–80 °C have been investigated systematically. With the increase of Si content, the hydrogen storage capacity increases and the equilibrium pressure decreases, thus the improved thermodynamic stability of the metal hydrides makes the Si-containing alloys more suitable for working at higher temperatures. Appropriate addition of Si (x = 0–0.075) improves the anti-corrosion capability of the alloy, as a result, the temperature insensitivity, high-temperature dischargeability and high-temperature recoverability increase accordingly, particularly the cycling stability (S150) increases from 43.7% to 71.8%. In addition, the charge-transfer process is suppressed gradually by Si substituting (x = 0–0.075) at 20 °C, but gets promoted due to the improved surface catalytic ability when that at 60 °C, consequently the high-rate dischargeability and high-power delivery deteriorate at room temperature, but increase gradually at higher temperature. Therefore, an optimum alloy electrode is got when x = 0.075, the deterioration of x = 0.1 alloy on high-temperature performance is attributed to the appearance of the second A2B7 phase.

Laser bendability of SUS430/C11000/SUS430 laminated composite and its constituent layers

Laminated composites are of great interest in different industries while having the advantages of all base metals. In this research, the laser bending of a three-layered SUS430/C11000/SUS430 laminated composite is characterized both experimentally and numerically. This composite can be used in the microelectronics industry since it has the anti-corrosion and strength capability of stainless steel, and the electrical superiority of copper. The specimens are bent using a Ytterbium fiber laser irradiated on a straight path along the sheet width. The effects of bending parameters including the number of passes, scanning velocity, beam diameter, laser power and delay time between passes are examined for a three-layered laminated sheet, and compared with its constituent steel and copper layers. It is found that the thin copper mid-layer strongly affects the rate of bending per pass. Heat distribution and plastic strain along the thickness during the process are characterized by using the finite element method. The Cu mid-layer decreases the bending angle, but also postpones the onset of melting, and thus can be compensated by the application of higher laser powers. It is shown that the bending angle increases with an increase in laser power and delay time, and a decrease in laser velocity and beam diameter.

The mechanism of suppressing capacity degradation of high-Al AB5-type hydrogen storage alloys at 60 °C

Excellent high-temperature cycling stability and storage property are obtained by partially substituting Al for Ni in La0.78Ce0.22Ni3.95-xCo0.65Mn0.3Si0.1Alx (x = 0–0.4) alloys, especially at 60 °C. Potentiodynamic polarization, electrochemical impedance spectrum (EIS), inductively coupled plasma-atomic emission spectroscopy and scanning electron microscope analyses are employed to reveal the mechanism of suppressing capacity loss of the alloy. The results demonstrate that partially Al substituting suppresses the pulverization and corrosion tendency of the alloys. Al-containing alloys show improved anti-corrosion capability, and the dissolution of La, Ce, Ni, Co, Mn and Si can be restrained remarkably by sacrificing Al content, thus excellent cycling stability and storage property are obtained. In addition, at higher temperature, the dissolution of Al is the dominant factor that influences the electrochemical properties at the early stage of cycles, promoting the surface catalytic ability. Subsequently, the gradual accumulation of metal hydroxide on the electrode alloy surface protects active metal from further oxidation and corrosion. Novel EIS mode in metal hydride electrode is proposed to study surface corrosion and dissolution behavior at higher temperature.

Low-cost mussel inspired poly(catechol/polyamine) coating with superior anti-corrosion capability on copper

A low-cost mussel inspired approach was developed to produce anti-corrosion coating on copper substrate. Catechol (CA) and polyamine (PA) were spontaneously polymerized to form adhesive coating of poly(cetechol/polyamine) (P(CA/PA)) onto copper surface and then P(CA/PA) was grafted by 1-dodecanethiol. The SEM, contact angle, XPS, FTIR and TG results demonstrated the formation of uniform, compact and thermal stable coatings through multiple interactions and chemically grafting. Electrochemical tests indicated of Cu-P(CA/PA)-SH possessed a highest corrosion potential of −81mV, a lowest corrosion current density of 0.15μA/cm2, and a highest coating resistance of 57.19kΩcm2, and also exhibit great long-term stability whether in solution immersion or salt spray tests. The remarkable anti-corrosion capability of Cu-P(CA/PA)-SH could be ascribed to the synergistic effect of the hydrophobicity, good stability, and strong wet adhesion of the mussel-inspired coating. This study provides an effective and cheap way for material protection and may give inspiration in the fields of material, biology and medicine relating to surface and interface engineering.