The ion behavior phenomenon associated with transitions of the anode discharge mode to the anode-spot mode is studied by measuring the wall ion current and by spectroscopic observation in vacuum arcs. The anode mode transfers when the wall ion current attains a certain magnitude that is independent of the cathode, but dependent on the anode. The ion-current function to the arc current increases when the arc current increases in the diffuse arc. Spectral-line intensity of Cu III emitted from the plasma in the anode region increases with an instantaneous arc current of a 5-kA peak (kAp) sinusoidal half-wave. These findings suggest an idea for the mode transition, that an ion generation region appears, and that an increase in the ion density produces a positive potential hump near the anode, which results in the negative anode voltage drop triggering the mode transition. After the mode transition, an arc current is found to reduce the ion current near the crest of a sinusoidal current in a copper arc. This appears to be significant for the arc on a small anode. The decrease in the ion current is attributed to the recombination of ions decelerated by anode vapor with electrons emitted from the hot spot on the anode. >