The stimulation of shale reservoirs frequently involves significant shear failure, which is crucial for creating fracture networks and enhancing permeability to boost production. As the depth of extraction increases, the impact of elevated temperatures on the anisotropic shear strength and failure mechanisms of shale becomes pronounced, yet there is a notable lack of relevant research. This study conducts, for the first time, direct shear experiment on shales at four different temperatures and seven bedding angles. By employing acoustic emission (AE) and digital image correlation (DIC) techniques, the evolution of damage and the mechanism of crack propagation under anisotropic direct shearing at varying temperatures is revealed. The results indicate that both shear displacement and strength of shale increase with temperature across different bedding angles. Additionally, shale demonstrates distinct brittle failure characteristics under various conditions during direct shearing tests. The types of anisotropic shear failure observed under the influence of temperature include central shearing fracture, central shearing with secondary fracture, and deflected slip along the bedding. Moreover, the temperature effect enhances shear-induced crack propagation along bedding planes. Shear failure in shale predominantly occurs during higher loading stages, which coincide with a substantial amount of AE signals. Finally, the introduction of the anisotropy index and temperature sensitivity coefficient further elucidates the interaction mechanism between thermal effects and anisotropy. This study offers a novel methodology to explore the anisotropic shear failure behavior of shale under elevated temperatures, and also provides crucial theoretical and experimental insights into shear failure behavior relevant to practical shale reservoir stimulation.