FESEM Analysis Research Articles

LaFeO3 supported by ionic liquid on Bi7O9I3 for the degradation of ciprofloxacin and tetracycline

The introduction of LaFeO3 nanoparticles into the nanospaces of the Bi7O9I3 filamentary structure was achieved through the utilization of an ionic liquid (IL). The juxtaposition of these two types of nanoparticles resulted in the formation of a bifunctional nanocatalyst known as Bi7O9I3/IL/LaFeO3 NFs. The contamination of antibiotics presents serious ecological and human health risks. Therefore, the development of innovative approaches is imperative to effectively eliminate these harmful contaminants. To mitigate these adverse effects, a cost-effective and innovative three-dimensional (3D) heterogeneous material, namely Bi7O9I3 modified IL/LaFeO3 (Bi7O9I3/IL/LaFeO3), was successfully synthesized. The analyses of FESEM, BET, TEM, XRD, XPS, TGA, and FTIR are used for characterizing the catalyst. This material exhibited enhanced catalytic performance in the degradation of ciprofloxacin (CIP) and tetracycline (TC) under exposure to light. Remarkably, this entire process is carried out at short time and minimal amount of catalyst and at low temperatures, ensuring energy conservation and minimizing any potential adverse effects.

Sustainable green synthesis and characterization of nanocomposites for synergistic photocatalytic degradation of Reactive Orange 16 in textile wastewater using CuO@A-TiO2/Ro-TiO2

This paper explores the photocatalytic degradation of Reactive Orange 16 (RO16) dye in textile wastewater employing a novel CuO@A-TiO2/Ro-TiO2 nanocomposite. The nanocomposite was synthesized via a hydrothermal technique, resulting in a monoclinic phase of leaf-shaped CuO loaded on a hexagonal wurtzite structure of rod-shaped ZnO, as confirmed by FE-SEM and XRD analyses. Optical experiments revealed band gap energies of 1.99 eV for CuO, 2.19 eV for ZnO, and 3.34 eV for the CuO@A-TiO2/Ro-TiO2 nanocomposite. Photocatalytic degradation experiments showcased complete elimination of a 100 mg/L RO16 solution (150 mL) after 120 min of UV light illumination and 100 min of sunlight illumination, emphasizing the nanocomposite's efficiency under both light sources. The study further delves into the application of the CuO@A-TiO2/Ro-TiO2 nanocomposite for the degradation of actual textile wastewater samples under sunlight irradiation. The results underscore the nanocomposite's remarkable efficacy in treating RO16 in textile wastewater, positioning it as a promising candidate for sustainable and efficient wastewater treatment applications. This research contributes valuable insights into the development of advanced photocatalytic materials for textile dye degradation in wastewater treatment.

Efficient synthesis of some [1,3]-oxazine derivatives in the presence of solid acid nano catalyst based on ferrierite and study on their activity against breast cancer through molecular docking calculation

In this research, the magnetic solid acid nanocatalyst based on ferrierite has been prepared and used as catalyst for the green synthesis of some [1,3]-oxazine derivatives in water at room temperature. The synthesized compounds were obtained in high to excellent yields after short reaction times and the structure of synthesized products were investigated by spectroscopic methods such as: FT-IR, 1H NMR and 13C NMR. The prepared magnetic solid acid catalyst was characterized using XRD, FT-IR, FE-SEM, EDX, elemental mapping, TGA and VSM analysis methods. Magnetic catalyst has easy separation ability, which leads to better and easier recycling. The preparation and synthesis of [1,3]-oxazine derivatives were carried out at room temperature in the presence of M-FER/TEPA/SO3H. Easy workup, green solvent (water) and also short reaction times with high to excellent yield of products, are some of advantageous of presented method. Docking calculations on the structure of the synthesized compounds proved their medicinal properties against breast cancer cells.

Evaluating the impact of ZnO doping on electrical and thermal properties of calcium-aluminosilicate oxynitride glass-ceramics

This study aimed to investigate the impact of ZnO content on the structure, thermal, and electrical properties of oxynitride glass-ceramic(s) within the Ca–Al–Si–O–N (CASON) system. The base glass had the composition of Ca7Al14Si17O52N7, with ZnO additions ranging from 3 to 15 % by weight. A pristine Ca7Al14Si17O52N7 glass was successfully prepared by melt-quenching technique followed by converted into glass-ceramic by incorporating various amounts of ZnO using the field-assisted sintering technique. XRD and FESEM analysis confirmed that increasing the amount of Zn increases the crystallinity in the glass matrix. The observed crystalline phases were formed mostly from ZnO and showed higher conductivity than the remaining dielectric matrix. IR spectra confirmed the presence of bands correlated with the presence of Zn and suggested the progressive depolymerization of the silicate-aluminate network as a consequence of increasing Zn content. Density values varied between 2.75 and 2.94 gcm−3 and increased with increasing the Zn content in the glass-ceramic. The thermal expansion and thermal conductivity values increased and decreased, respectively, with the increase of Zn content in the matrix. The electrical properties of the samples were investigated using impedance spectroscopy over a wide range of frequencies (10 mHz to 1 MHz) and temperatures (153 K–623 K). The results showed that in the glass without ZnO and glass-ceramic(s) with a small addition of ZnO, the conductivity is mainly dominated by the transfer of oxygen ions and, to a small extent, by the presence of electronic conductivity. As the ZnO content increases, continuous conduction paths are formed between the ZnO crystallites, and the electrical conductivity increases rapidly and becomes dominated by electron transfer.

Antimicrobial and Wound Healing Performance of Polycaprolactone Electrospun-Based Nanofibers Incorporating Propolis and Quercus Infectoria Gall Extracts

Background: A highly effective antibacterial wound dressing was developed in this investigation by developing a novel bioactive functional nanostructure. Methods: Ethanolic extracts of propolis (EEP) and Q.infectoria galls (QIG) were processed to obtain their respective extracts. The antibacterial properties of the individual EEP and QIG extracts and their combined effects were investigated. Based on the antibacterial test results, solutions containing polycaprolactone (PCL), PCL/EEP, PCL/QIG and PCL/EEP/QIG were prepared. These solutions were then used to fabricate nanobased mats through electrospinning. The resulting nanofibers were examined in terms of their physical, chemical and biological traits. In order to assess the wound healing capabilities, in vivo experiments were conducted, wherein the efficacy of the scaffolds in combating Staphylococcus aureus (MRSA) infections on wounds was evaluated. Results: The nanoscale structure of the electrospun nanofibers was confirmed through FESEM analysis, while the successful integration of EEP and QIG in the PCL-based electrospun nanofiber was validated using FTIR. By including both EEP and QIG bioactive extracts in the nanofiber, improved antibacterial and antioxidant activities were achieved without compromising the viability of human fibroblast cells. The use of PCL/EEP/QIG dressings led to wound closure rates of 85% and 100% on the 5th and 15th day of treatment, respectively, demonstrating the effectiveness of the combination of EEP and QIG extracts. Conclusions: The remarkable outcomes have presented encouraging prospects for using PCL/EEP/QIG as a highly effective wound dressing with antibacterial properties in clinical trials.

Comparative performance analysis of mussel-inspired polydopamine, polynorepinephrine, and poly-α-methyl norepinephrine in electrochemical biosensors.

Polydopamine (PDA) has garnered significant interest for applications in biosensors, drug delivery, and tissue engineering. However, similar polycatecholamines like polynorepinephrine (PNE) with additional hydroxyl groups and poly-α-methylnorepinephrine (PAMN) with additional hydroxyl and methyl groups remain unexplored in the biosensing domain. This research introduces three innovative biosensing platforms composed of ternary nanocomposite based on reduced graphene oxide (RGO), gold nanoparticles(Au NPs), and three sister polycatecholamine compounds (PDA, PNE, and PAMN). The study compares and evaluates the performance of the three biosensing systems for the ultrasensitive detection of Mycobacterium tuberculosis (MTB). The formation of the nanocomposites was meticulously examined through UV-Visible, Raman, XRD, and FT-IR studies with FE-SEM and HR-TEM analysis. Cyclic voltammetry and differential pulse voltammetry measurements were also performed to determine the electrochemical characteristics of the modified electrodes. Electrochemical biosensing experiments reveal that the RGO-PDA-Au, RGO-PNE-Au, and RGO-PAMN-Au-based biosensors detected target DNA up to a broad detection range of 0.1 × 10-8 to 0.1 × 10-18M, with a low detection limit (LOD) of 0.1 × 10-18, 0.1 × 10-16, and 0.1 × 10-17M, respectively. The bioelectrodes were proved to be highly selective with excellent sensitivities of 3.62 × 10-4mAM-1 (PDA), 7.08 × 10-4mAM-1 (PNE), and 6.03 × 10-4mAM-1 (PAMN). This study pioneers the exploration of two novel mussel-inspired polycatecholamines in biosensors, opening avenues for functional nanocoatings that could drive further advancements in this field.

Sensitive determination of quercetin in food samples implementing magnetic dispersive solid phase extraction coupled with ion mobility spectrometry

Quercetin (QUR) is a vital flavonoid, which is found in dietary human. The quick analysis of QUR is difficult on account of utilizing complicated methods. Hence, we developed a proposed method based on ion mobility spectrometry (IMS) to evaluate the fast analysis of QUR in food samples. This analytical method combined the benefit of polypyrrole-coated magnetic dispersive solid phase extraction (MDSPE) as a sorbent phase for the QUR extraction, and also the strength of IMS for the rapid detection. Nanoparticle (NP) characterization was investigated through VSM, FT-IR, XRD, BET, and as well as FE-SEM analysis. Sample pH, amount of nanoparticles, type and volume of desorption solvent, extraction time, and desorption time as impressive parameters in MDSPE method were investigated and optimized. The calibration curve was linear in the range of 1.0–90.0 ng mL−1, with a determination coefficient (R2) of 0.9954. The limit of detection (LOD) and the limit of quantification (LOQ) for QUR were 0.31 and 1.02 ng mL−1, respectively. The RSD% of QUR through seven parallel analyses was 4.44. This analytical work was executed to quantify QUR in honey and tea samples without any derivation procedure needed. The recovery values for QUR were estimated in the range of 92.5–96.7 % using the proposed method. Also, according to the attained results from HPLC analyses, the applicability, and susceptibility of the current method was verified.

Ionic liquid based surfactant-free microemulsion as a new protocol for preparation of visible light active poly(methyl methacrylate)/TiO2 nanocomposite

The practical application of sensitized TiO2 nanocomposites is very satisfying due to their high photon utilization in visible light, simple recovery without affecting the photocatalytic performance, high energy efficiency, low potential environmental risk, and low operational costs. The objective of this study is developing the ionic liquid (IL)-based surfactant-free microemulsion, as a soft template, for preparation of a novel type of sensitized poly(methyl methacrylate)/TiO2 nanocomposite (PMMA/TiO2/IL). For this purpose, a series of visible light-responsive PMMA/TiO2/IL transparent nanocomposites were prepared in microemulsion composed of methyl methacrylate monomer, 1-buthyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), and 1-buthanol as amphi-solvent. Techniques such as diffuse reflectance spectroscopy (DRS)), attenuated total reflectance-fourier transform infrared (ATR-FTIR) spectroscopy, atomic force microscopy (AFM), field emission scanning electron microscopy (FE-SEM), and energy dispersive X-ray analysis (EDX) were used to characterize prepared nanocomposites. Photocatalytic degradation of methyl orange dye under visible light illumination, as an application in wastewater treatment, with the investigation of the influence of TiO2 content in the nanocomposite, pH, and nanocomposite reusability on photodegradation efficiency was studied and maximum value of 93.9% obtained at optimum conditions. The FESEM analysis indicated that the utilization of a relatively low amount of ionic liquid and also in absence of the surfactant ensures the monodispersity of the visible light sensitized TiO2 nanoparticles in the polymer matrix.

Unlocking Cd(II) biosorption potential of Candida tropicalis XTA 1874 for sustainable wastewater treatment

Cd(II) is a potentially toxic heavy metal having carcinogenic activity. It is becoming widespread in the soil and groundwater by various natural and anthropological activities. This is inviting its immediate removal. The present study is aimed at developing a Cd(II) resistant strain isolated from contaminated water body and testing its potency in biological remediation of Cd(II) from aqueous environment. The developed resistant strain was characterized by SEM, FESEM, TEM, EDAX, FT-IR, Raman Spectral, XRD and XPS analysis. The results depict considerable morphological changes had taken place on the cell surface and interaction of Cd(II) with the surface exposed functional groups along with intracellular accumulation. Molecular contribution of critical cell wall component has been evaluated. The developed resistant strain had undergone Cd(II) biosorption study by employing adsorption isotherms and kinetic modeling. Langmuir model best fitted the Cd(II) biosorption data compared to the Freundlich one. Cd(II) biosorption by the strain followed a pseudo second order kinetics. The physical parameters affecting biosorption were also optimized by employing response surface methodology using central composite design. The results depict remarkable removal capacity 75.682 ± 0.002% of Cd(II) by the developed resistant strain from contaminated aqueous medium using 500 ppm of Cd(II). Quantitatively, biosorption for Cd(II) by the newly developed resistant strain has been increased significantly (p < 0.0001) from 4.36 ppm (non-resistant strain) to 378.41 ppm (resistant strain). It has also shown quite effective desorption capacity 87.527 ± 0.023% at the first desorption cycle and can be reused effectively as a successful Cd(II) desorbent up to five cycles. The results suggest that the strain has considerable withstanding capacity of Cd(II) stress and can be employed effectively in the Cd(II) bioremediation from wastewater.

Physicochemical and Rheological Properties of Degraded Konjac Gum by Abalone (Haliotis discus hannai) Viscera Enzyme.

In the present study, a new degraded konjac glucomannan (DKGM) was prepared using a crude enzyme from abalone (Haliotis discus hannai) viscera, and its physicochemical properties were investigated. After enzymatic hydrolysis, the viscosity of KGM obviously decreased from 15,500 mPa·s to 398 mPa·s. The rheological properties analysis of KGM and DKGMs revealed that they were pseudoplastic fluids, and pseudoplasticity, viscoelasticity, melting temperature, and gelling temperature significantly decreased after enzymatic hydrolysis, especially for KGM-180 and KGM-240. In addition, the molecular weight of KGM decreased from 1.80 × 106 Da, to 0.45 × 106 Da and the polydispersity index increased from 1.17 to 1.83 after 240 min of degradation time. Compared with natural KGM, the smaller particle size distribution of DKGM further suggests enzyme hydrolysis reduces the aggregation of molecular chains with low molecular weight. FT-IR and FESEM analyses showed that the fragmented KMG chain did not affect the structural characteristics of molecular monomers; however, the dense three-dimensional network microstructure formed by intermolecular interaction changed to fragment microstructure after enzyme hydrolysis. These results revealed that the viscosity and rheological properties of KGM could be controlled and effectively changed using crude enzymes from abalone viscera. This work provides theoretical guidance for the promising application of DKGM in the food industry.

Colorimetric detection of sitagliptin and moxifloxacin using AgNPs modified by 4-mercaptophenylbronic acid

Nowadays, considering the vital role of drugs, identifying and diagnosing them with simple and cost-effective methods and materials is very important. This study explores a colorimetric approach using silver nanoparticles (AgNPs) modified with 4-mercaptophenylboronic acid (MPBA) as a rapid and economical sensor for detecting Sitagliptin (Sit) and Moxifloxacin (Moxi) drugs. The MPBA-AgNPs sensor was synthesized via chemical synthesis of AgNPs followed by surface modification by MPBA. The effect of different parameters on the responsiveness of the MPBA-AgNPs sensor was investigated. The surface morphology, chemical structure, and size of the MPBA-AgNPs sensor in different conditions were examined by FE-SEM, FT-IR, DLS, and TEM analysis. Finally, the results of various investigations showed that the surface of AgNPs successfully modified by MPBA and MPBA-AgNPs as a colorimetric sensor for the detection of Sit and Moxi drugs has excellent detection limits of 16.63 and 0.27 µM. The recovery of the experiment in real samples was obtained in the range of 92.37–105.44 %.

Metal-free Carbon Material Derived from Lantana Camara for the Detection and Removal of Ciprofloxacin.

This work reports the preparation of a metal-free nitrogen and sulphur functionalized graphitic carbon sheets from a unique and less expensive precursor Lantana camara, which is a common hazardous weed in India. The synthesized material NS-CN-180 was successfully tested for the adsorption and removal of fluoroquinolone antibiotics ciprofloxacin. The surface morphology and elemental composition of NS-CN-180 were investigated through FESEM and XPS analyses. The SEM data reveals the graphitic sheets stacked onto each other with cavities in between them. The presence of various functional groups was identified through FT-IR spectroscopy and the degree of graphitization was calculated from XRD pattern. The probable mechanism of interaction for ciprofloxacin molecule with NS-CN-180 was also investigated with the help of FT-IR and zeta potential analyses. The fabricated material was found to be excellent for ciprofloxacin detection with a limit of detection value 16.08nM. Also, the prepared material efficiently removes the 66.2% ciprofloxacin drug in 1h. Adsorption and desorption experiments were performed to demonstrate the reusability of the material.

Elucidation of synergism in Ce-Zr/SBA-15 mesoporous catalysts and the effects on the activity in selective glycerol to lactic acid reaction

The continued conversion of glycerol to value-added chemicals is essential in ensuring the sustainable development of the biodiesel industry. Selective catalytic oxidation of glycerol to lactic acid provides an alternative approach to valorizing glycerol. A mesoporous SBA-15 supported mixed-metallic oxide catalyst is deemed essential to selectively produce lactic acid in this mixed parallel and multi-step reaction. SBA-15-supported bimetallic Ce and Zr oxides were proved to be highly efficient catalysts for the selective glycerol oxidation into lactic acid in base-free media. The synergism between Ce and Zr in the bimetallic oxide compounds could enhance the creation of oxygen vacancies in the catalyst via the reduction of Ce4+ to Ce3+. The 2:1CeZr/SBA-15 catalyst exhibited prominent catalytic activity in selectively oxidizing glycerol to lactic acid, with a glycerol conversion of 91.8% and a lactic acid yield of 35.1%. This work achieved superior catalytic performance compared to previously conducted studies, primarily due to the significantly higher initial glycerol concentration employed in this study. To ascertain the intrinsic active sites of the catalyst, the physicochemical properties of the catalyst were thoroughly examined using BET, FTIR, XRD, FESEM, TEM, CO2-TPD, O2-TPD, and H2-TPR analysis. This work concluded that the synergistic interaction of the active sites, which led to the formation of active oxygen species, facilitated primary dehydrogenation of the terminal -OH bond in glycerol. Hence, in this work, a plausible glycerol conversion mechanism over the 2:1CeZr/SBA-15 catalyst was also proposed.

Effect of patterns on Polyacrylamide hydrogel surface towards enhancement of water retention

Polyacrylamide hydrogel was investigated to improve its water retention capacity. Among the several hydrogel samples prepared, a sample with ∼0.55 % cross-linker was found sufficiently rigid with high water content. The drying and rehydration cycles induced the appearance and disappearance of cracks respectively within the hydrogel and were confirmed by FESEM analysis. The effect of mili-patterns on hydrogel surface was studied and was found that the patterns enhanced the duration of water retention by ∼60 %. Even after 100 h of drying of a swelled hydrogel, the one with the pattern retained sufficient water so that its length remained ∼35 % longer compared to a non-patterned flat hydrogel. These findings were discussed in light of the Kelvin equation and were supported by the time-resolved Raman spectra that ensured the presence of the bound water for a longer duration. Based on the intensity of O–H stretching, it was inferred that patterned hydrogel exhibited water retention efficiency (RE) of ∼97 %, whereas, a flat non-patterned hydrogel had RE merely of ∼70 % after 3 cycles of drying and rehydration.

Effective adsorptive removal of Pb2+ ions from aqueous solution using functionalized agri-waste biosorbent: New green mediation via Seidlitzia rosmarinus extract

Currently, the use of natural adsorbent for the elimination of pollutants, such as heavy metals, from water has been extensively investigated. However, the low adsorption capacity of these natural adsorbents has led researchers towards the use of synthetic surfactants, which themselves can become environmental pollutants. In this research, an investigation was conducted to examine the impact of a surfactant obtained from the Seidlitzia rosmarinus plant on the adsorption properties of Pumpkin seed shell (PSS), a natural adsorbent. As a result, a modified version of PSS, known as functionalized Pumpkin seed shell (FPSS), was developed, and the effect of these two adsorbents on the elimination of Pb2+ has been investigated. FESEM, EDS, FTIR, and BET analyses were conducted to get detailed information of the adsorbent. Additionally, the effects of contact time, dosage of the adsorbent, pH of the solution, and temperature on the adsorbent were studied. The experimental data was fitted using Langmuir, Freundlich, Temkin, and Jovanovic isotherms. The PSS adsorbent was fitted best with the Langmuir isotherm, showing an adsorption capacity of 160.80 mg g−1, while the FPSS adsorbent was fitted with the Jovanovic isotherm, exhibiting an adsorption capacity of 553.57 mg g−1. Furthermore, kinetic modeling results indicated that the data for these adsorbents follow pseudo-second-order kinetic. Finally, the impact of coexisting ions and reusability was examined, with the FPSS adsorbent outperforming PSS. Therefore, the investigation of all these aspects demonstrated that the use of this natural surfactant significantly improves the performance of the adsorbent.

Mesoporous manganese oxide/multiwalled carbon nanotubes as a base material for the 99mTc/99Mo generator: Development, characterization, and implementation study

The uptake capacity of Mo on the active MnO2 nanoparticles was determined in a previous study, and it was found to be 7 mg/g. This value is appropriate for 99Mo, which is more complex to separate due to its production using the 235U fission reaction with a high specific activity. Currently, multiwall carbon nanotubes (MWCNTs) linked to mesoporous MnO2 are being prepared and studied as a novel sorbent for the 99Mo produced with a low specific activity by thermal neutron activation of natural molybdenum consisting of 92M0, 94Mo, 95Mo, 96Mo, 97Mo, 98Mo, and 100Mo, based on the 98Mo(n,γ) reaction to prepare the 99Mo/99mTc generator with a high uptake capacity for Mo. FTIR spectroscopy, EDX-mapping, XRD, particle size analysis, FESEM, and TEM analysis were used to characterize the novel mesoporous MnO2/MWCNT sorbent with a large total pore area 193.3 m2/g and porosity about 52%. Several factors influencing the sorption of 99Mo and 99mTc onto the mesoporous MnO2/MWCNTs were studied, including the distribution coefficient (Kd), contact time, temperature, and sorbent/solute ratio, etc. The Mo uptake capacities on the novel sorbent were 133 and 115 mg Mo/g, respectively. A preliminary study on the prepared new sorbent for the 99Mo/99mTc generator was performed, and the elution yield of 99mTc was found to be 82.55% with low 99Mo breakthrough. The radiochemical, radionuclide, and chemical purity of the eluted 99mTc were checked to ensure that it was free of impurities.

Enhancement of visible-light photocatalysis of TiO2 via nanocomposite incorporating with Fe(III) species

This paper introduces a novel approach for the synthesis of photocatalytic nanocomposites via a fast reaction occurring at ambient conditions between the strong base NaOH and FeCl3 solution to obtain a fresh precipitate of Fe(OH)3 in the presence of TiO2 nanoparticles. FE-SEM analysis revealed a restructured state of TiO2 particles on the surface of colloidal Fe(OH)3. Solid-phase studies, including XRD and FT-IR, indicated a phase transformation from Fe(OH)3 to γ-Fe2O3 during the formation of the nanocomposite. UV–Vis diffuse reflectance measurements confirmed a significant reduction in the band gap of the synthesized composite, indicating its potentials as a photocatalyst under visible light irradiation. Another advantage of this composite type is its rapid sedimentation ability within minutes, facilitating post-processes such as phase separation and catalyst reuse on a large scale, which are challenging in the case of TiO2 nanoparticles. Inducing photocatalysis under visible light, the efficiency in degrading persistent colorants was demonstrated through a case study of indigo carmine (IC), which exhibited a threefold improvement in degradation efficiency for the case of the nanocomposite compared to the original TiO2. Indeed, the IC degradation process was studied in consideration of various factors such as Fe/Ti ratio in the catalyst, illumination time, colorant concentration, catalyst dosage, and pH of the environment. Additionally, mineralization studies confirmed the oxidation of IC to CO2 rather than the formation of potentially toxic intermediates. Furthermore, the stability of the catalyst was examined through six cycles of reuse.

Enhancing bacterial control and daylight-driven water remediation with chitosan-impregnated MoC nanosheets.

The functionalization of nanoparticles with 2D nanosheets is an effective approach to enhance their functional properties for pollutant removal. This research outlines the synthesis of a 2D-delaminated molybdenum carbide (MXene) chitosan nanocomposite (2D-d-Mo2CTx-Cs NC) with bacterial control and photocatalytic properties for dye adsorption. The nanocomposite includes Tx-surface terminating groups O, OH, and F. In this investigation, the composite was synthesized using the etching method and its formation was confirmed through UV spectra at 288nm. It was characterized through FTIR, XRD, Particle size, Zetapotential, FESEM, HRTEM, EDAX, and XPS analyses. FTIR spectral analysis of NC suggests that amines are formed through a Schiff base reaction between glutaraldehyde and Cs, or through the interaction of terminal aldehydes and carbonyl groups. The XRD analysis confirmed the crystalline structure of the composite. FESEM images revealed irregularly structured nanosheets (NSs) material in the prepared 2D-d-Mo2CTx-Cs NC samples. HRTEM images revealed 2D-d-Mo2CTx NSs impregnated onto Cs with an average size of 50nm, as confirmed by a particle size analyzer, with a zeta potential value of -15mV. Additionally, Mo, C, N, and O are the most significant elements present in the NC, as confirmed by EDAX and XPS analyses. Further, biocompatibility testing of 2D-d-Mo2CTx-Cs NC yielded positive results. Moreover, under sunlight, the composites effectively adsorbed methylene blue with a 90% adsorption capacity, as confirmed by kinetic studies. Furthermore, the synergistic effect of Cs and d-Mo2CTx NSs resulted in significant antibacterial (50-200µl of 1mg/ml) and antibiofilm activity (100µl of 1mg/ml) against pathogenic bacteria. Furthermore, this study represents the first report on the use of 2D-d-Mo2CTx-Cs NC for daylight-influenced photocatalytic applications with a bacteria-controlling effect.

Electro-mechanical analysis of nanostructured polymer matrix composite materials for 3D printing using machine learning

Recently, additive manufacturing (AM) techniques like 3D printing have emerged as a potentially game-changing example of digital manufacturing. However, high entry barriers of a tiny material library, different processing defects, and unpredictable product quality are still holding back its widespread use in the industry. Due to its remarkable success in data tasks like classification, regression, and clustering, machine learning (ML) has recently gained a great deal of interest in the subject of the material library. This paper examines the current state of ML applications in several key areas of AM, including polymer matrix composite materials and machine parameter optimization. Composite filaments have been extruded using Polylactic Acid (PLA) as it is a biodegradable material and shows how High-Density Poly Ethylene (HDPE) enhances physical strength. All the parameters for the filament extruder have been designed by machine learning. Thermal stability is a significant concern for polymers that have been overcome by introducing Titanium Dioxide nanoparticles. The microstructure, surface texture, electro-mechanical behavior, and other general features of extruded filaments made from recycled plastics have been investigated. The extrusion temperature, approximated using ML, is in excellent agreement with the surface texture and microstructure of the polymers, as confirmed by FESEM, EDX, and Particle analysis. Extruded filaments experienced 2500 Vs and confirmed their non-conductivity up to 77.7GΩ. Tensile strength and elongation at break, two measures of mechanical properties, have been examined. Incorporation of Titanium Dioxide Nanoparticles improved mechanical properties significantly. When it comes to 3D printing, the physical properties and potential uses of each composite material are different.

Bio-inspired magnetic chitosan/Iron oxide macromolecules for multiple anionic dyes adsorption from aqueous media

Organic anionic dyes are major water pollutants due to their low degradability caused by complex aromatic structures. Not only do they exert toxic, mutagenic, teratogenic, tumorigenic, and genotoxic effects, but they also decrease fertility and cause irritation to the skin and respiratory system in humans. This long-term toxicity has detrimental effects on aquatic organisms and their surroundings, resulting in an imbalanced ecosystem. In this study, a Cs@Fe3O4 magnetic biosorbent was synthesised to uptake three anionic dyes and characterised for FTIR, BET/BJH, XRD, TGA, VSM, and FESEM analyses. The biosorbent average surface area was confirmed to be 52.6524 m2/g, with average pore sizes of 7.3606 nm and 6.9823 nm for adsorption-desorption processes, respectively. Batch adsorption studies pH values, contact times, temperature, initial dye concentrations, and adsorbent dosages were examined. Several isotherm and kinetic models were studied to determine the adsorption mechanism. The adsorption data of these dyes at equilibrium was observed to match Langmuir's isotherm and pseudo-second-order kinetic models. The thermodynamic study revealed that the adsorption process for these dyes was an exothermic reaction. Maximum adsorption capacities for congo red, methyl orange, and metanil yellow were 117.77 mg/g, 137.77 mg/g, and 155.57 mg/g, respectively. The reusability of recovered Cs@Fe3O4 after dye adsorption was evaluated up to five continuous adsorption-desorption cycles for its possible industrial applications.