Amorphous Research Articles

New zeolite-based composite pads with high-volume blood absorption for early warning of postpartum hemorrhage

Medical treatment of severe blood loss during labor is crucial, and the early warning indicator of postpartum hemorrhage (PPH) is essential for labor medical treatment. Measurement of blood loss conventionally looks dirty, reluctant, and less hygienic since some of the blood might be spilled out in the maternity bed, while commercially existing pads have low blood absorption capacity. A new design composite pad composed of absorbent materials including cellulose rayon, super absorbent polymer (SAP), and zeolite was fabricated and characterized. The SAP and zeolite show properties as crystalline and amorphous materials, respectively. The surface area of natural zeolite was 19.79 (m2/g). The newly fabricated composite pad showed a high blood absorption capacity (>500–600 mL) with a blood absorption rate of 55.56–85.84 mL/min (depending on the blood volume), showing better performance as compared to the commercial pads. These characteristics suggest that the new composite pad could function not only as a sanitary pad but also as an early warning indicator for PPH if the rate and blood volume reach the dangerous category (≥600 mL or at ≥13 mL/min rate).

Challenging POPular opinion: Porous organic polymers for atmospheric water harvesting

As humanity faces growing water scarcity in many parts of the world, innovative solutions are imperative to achieve equitable access to safe drinking water for all. Atmospheric water harvesting (AWH) is a highly promising solution to water scarcity, comprising water adsorption directly from air using hydrophilic adsorbents, followed by collection upon desorption. Porous organic polymers exhibit distinct advantages for AWH, including broad tailorability, desirable porous properties, and outstanding chemical and thermal stability. This perspective outlines the current state-of-the-art in porous organic materials for AWH, distinguishing between reticular and amorphous materials, to discern key properties and outline future design principles. We also outline key performance metrics and provide a guide for the characterisation of such porous organic materials for those seeking to enter the field of AWH.

Magnetic Hardening: Unveiling Magnetization Dynamics in Soft Magnetic Fe-Ni-B-Nb Thin Films at Cryogenic Temperatures.

Recent advancements in amorphous materials have opened new avenues for exploring unusual magnetic phenomena at the sub-nanometer scale. We investigate the phenomenon of low-temperature "magnetic hardening" in heterogeneous amorphous Fe-Ni-B-Nb thin films, revealing a complex interplay between microstructure and magnetism. Magnetization hysteresis measurements at cryogenic temperatures show a significant increase in coercivity (HC) below 25 K, challenging the conventional Random Anisotropy Model (RAM) in predicting magnetic responses at cryogenic temperatures. Heterogeneous films demonstrate a distinct behavior in field-cooled and zero-field-cooled temperature-dependent magnetizations at low temperatures, characterized by strong irreversibility. This suggests spin-glass-like features at low temperatures, which are attributed to exchange frustration in disordered interfacial regions. These regions hinder direct exchange coupling between magnetic entities, leading to magnetic hardening. This study enhances the understanding of how microstructural intricacies impact magnetic dynamics in heterogeneous amorphous thin films at cryogenic temperatures.

Caseous Calcification of the Mitral Annulus: Calcified Toothpaste of the Heart.

Caseous calcification of the mitral annulus (CCMA) is a rare variant of mitral annular calcification (MAC) usually described as an antemortem finding. We report a case of sudden cardiac arrest in a 39-year-old male with end-stage renal disease undergoing hemodialysis with a history of Fabry disease by kidney biopsy. Autopsy revealed significant circumferential annular calcification in both mitral and aortic valves with a caseous gross appearance. Histologically, these areas consisted of amorphous basophilic material accompanied by a surrounding granulomatous-appearing infiltrate. Von Kossa staining on non-decalcified tissue revealed strong positive staining, confirming CCMA diagnosis. While identifiable, the atrioventricular node was displaced and distorted by caseous deposits. Toluidine blue staining of myocardium showed osmophilic accumulations, and electron microscopy (EM) showed myeloid/zebra bodies, consistent with Fabry disease. We posit that Fabry disease leads to end-stage kidney disease, altering calcium phosphate metabolism, a proposed mechanism for CCMA. This case highlights the multifactorial nature of sudden cardiac death in decedents with various structural cardiac changes and potential renal-disease-induced electrolyte imbalances. We aim to bring awareness to this rare entity, its potential role in a sudden cardiac death, and to highlight the need to use non-decalcified tissue when staining for calcium to establish the diagnosis.

Posaconazole-hemp seed oil loaded nanomicelles for invasive fungal disease

Invasive fungal infections (IFI) pose a significant health burden, leading to high morbidity, mortality, and treatment costs. This study aims to develop and characterize nanomicelles for the codelivery of posaconazole and hemp seed oil for IFI via the oral route. The nanomicelles were prepared using a nanoprecipitation method and optimized through the Box Behnken design. The optimized nanomicelles resulted in satisfactory results for zeta potential, size, PDI, entrapment efficiency, TEM, and stability studies. FTIR and DSC results confirm the compatibility and amorphous state of the prepared nanomicelles. Confocal laser scanning microscopy showed that the optimized nanomicelles penetrated the tissue more deeply (44.9µm) than the suspension (25µm). The drug-loaded nanomicelles exhibited sustained cumulative drug release of 95.48 ± 3.27% for 24 h. The nanomicelles showed significant inhibition against Aspergillus niger and Candida albicans (22.4 ± 0.21 and 32.2 ± 0.46 mm, respectively). The pharmacokinetic study on Wistar rats exhibited a 1.8-fold increase in relative bioavailability for the nanomicelles compared to the suspension. These results confirm their therapeutic efficacy and lay the groundwork for future research and clinical applications, providing a promising synergistic antifungal nanomicelles approach for treating IFIs.

Enhanced mechanical and thermophysical properties of Mg2Ca, Al2Ca, and Al4Ca bulk metallic glasses in comparison to crystalline alloys for bone grafting applications: A molecular dynamics investigation

We investigate the glassy-state properties of Mg2Ca, Al2Ca, and Al4Ca from the grafting application viewpoint. We employed classical molecular dynamics to examine the phase transition, structural, thermodynamic, transport, and mechanical properties in the amorphous state. All properties suggest successful simulations of the glass phase at and below the glass transition temperature, ranging between 550 and 689 K for Mg2Ca, Al2Ca, and Al4Ca. Computed results are compared and discussed with the reported findings and known mechanical and thermal properties of the various parts of the human bones and biocomposites. The comparison establishes that the mechanical, thermal, and transport properties significantly improve in the glass phase compared to its crystalline alloy form. At 300 K, studied glasses have densities in close agreement with human bone density. Structural analysis and heat capacity show the second-order phase transition, verifying the formation of the glass structure. The targeted glasses exhibit excellent thermal conductivity and thermal diffusivity compared to other commonly used biocomposites for bone grafting. Furthermore, the simulated elastic properties, viz., the Poisson ratio, G/B ratio, Cauchy's pressure, and yield strength, are in close agreement with the mechanical properties of various parts of human bone. The predicted ductility nature, contrary to the brittle character of Mg2Ca, Al2Ca, and Al4Ca crystalline alloys, proves the superiority of the glassy form for the implant's functioning. The minimum enthalpy of formation and thermodynamic stability of studied compounds benefit the synthesis process; hence, we propose that the studied glasses are persuasive materials for experimental synthesis aimed at bone grating applications.

Novel Solid‐State Fluorophores, a Series of Cyanostilbene‐Based Amorphous Molecular Materials

AbstractWe have designed and synthesized a novel series of cyanostilbene‐based amorphous molecular materials with different methylene chain lengths, BMAC‐n (n=3,4,5,6), and investigated their emitting properties in solution and various solid states. All BMAC‐n molecules showed solvatochromic fluorescence in solutions. Emission spectra of BMAC‐n molecules in the same solution were identical to one another irrespective of the methylene chain length while the spectra in crystalline states depended on their methylene chain length. As in solutions, emission spectra of their spin‐coated amorphous films were identical to each other irrespective of the methylene chain length. Emission spectra of rubbed amorphous films prepared by grinding their crystals were identical to those for spin‐coated amorphous films; however, comparative studies between spin‐coated and rubbed amorphous films indicated that fluorescence quantum yields and photochemical reactivity depend on the preparation method.

Effect of Aerosol Size on Glass Transition Temperature.

The amorphous phase state of suspended nanoparticles affects their atmospheric lifetimes and environmental impact. Influence of relative humidity and chemical composition on the glass-to-liquid transition is well-known. However, the influence of the particle size on the phase transition remains uncertain. Here we show experimental data that probe the amorphous phase transition of suspended sucrose particles as a function of particle size. The depression in glass-transition temperature follows the Gibbs-Thomson or Keesom-Laplace predicted proportionality of ΔTg ∝ D-1 for particles 100-700 nm in diameter, but the proportionality changes to ΔTg ∝ D-1/2 for smaller sizes. Literature data for glass-transition temperature depression in thin films and nanoconfined compounds show similar and strong deviations from the expected D-1 behavior. While the observed proportionalities remain incompletely understood, the results here provide evidence that the deviation from ΔTg ∝ D-1 is not attributable to substrate effects.

Femtosecond nonlinear optical properties of Ti-doped In2Te3 thin films grown by magnetron co-sputtering

Herein, we successfully prepared Ti-doped In2Te3 and pure In2Te3 films by magnetron co-sputtering at room temperature. The film structure was measured using x-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with energy dispersive x-ray spectroscopy (EDS), and x-ray photoelectron spectroscopy (XPS), while the linear optical constant of the films was measured using a spectroscopic ellipsometer (SE). The nonlinear optical properties of the films were examined using the Z-scan technique, wherein the samples were irradiated with 140 fs laser pulses at a wavelength of 800 nm and a repetition rate of 80 MHz, with an input intensity of 1.2GW/cm2. Ti incorporation led to decreased crystallinity and a reduction (redshift) in the optical bandgap (E g ). All films exhibit reverse saturation absorption (RSA) and self-focusing effect. A ninefold increase in the nonlinear refractive index (n2) and a fourfold increase in the nonlinear absorption coefficient (β) were observed for the Ti-doped S40 sample in comparison to the pure S0 sample. Adjusting the phase transition between amorphous and crystalline states in Ti-doped In2Te3 films further modulated their nonlinear optical properties. The optical limiting (OL) behavior of pure In2Te3 and Ti-doped In2Te3 thin films was investigated, and the results demonstrated that Ti-doped In2Te3 films show great promise as optical limiter devices in nonlinear photonics.

Volcanic Eruption in the Nanoworld: Efficient Oxygen Exchange at the Si/SnO2 Interface.

Here, a phenomenon of efficient oxygen exchange between a silicon surface and a thin layer of tin dioxide during chemical vapor deposition is presented, which leads to a unique Sn:SiO2 layer. Under thermodynamic conditions in the temperature range of 725-735°C, the formation of nanostructures with volcano-like shapes in "active" and "dormant" states are observed. Extensive characterization techniques, such as electron microscopy, X-ray diffraction, synchrotron radiation-based X-ray photoelectron, and X-ray absorption near-edge structure spectroscopy, are applied to study the formation. The mechanism is related to the oxygen retraction between tin(IV) oxide and silicon surface, leading to the thermodynamically unstable tin(II)oxide, which is immediately disproportionate to metallic Sn and SnO2 localized in the SiO2 matrix. The diffusion of metallic tin in the amorphous silicon oxide matrix leads to larger agglomerates of nanoparticles, which is similar to the formation of a magma chamber during the natural volcanic processes followed by magma eruption, which here is associated with the formation of depressions on the surface filled with metallic tin particles. This new effect contributes a new approach to the formation of functional composites but also inspires the development of unique Sn:SiO2 nanostructures for diverse application scenarios, such as thermal energy storage.

Mechanical-robust and polymer-based superhydrophobic coating toward self-cleaning and anti-corrosion

The corrosion of reinforced concrete materials severely threatens cross-sea bridges, buildings and marine ships. The unique air layer on the superhydrophobic coating surface can effectively minimize the reinforced concrete corrosion, which not only extends the long-term usability of concrete but also reduces economic losses and environmental pollution. It is necessary to design a superhydrophobic coating on substrate surfaces to accommodate the requirement for corrosion prevention due to their anti-corrosion and self-cleaning properties. Despite gradually developing superhydrophobic coatings to meet diverse needs, they still encounter limitations in engineering preparation and applications. For example, the rough micro-/nano structure of the superhydrophobic surface is easily damaged by mechanical impact or physicochemical damage, which could affect the antiseptic properties. Moreover, designing and preparing all polymer-based superhydrophobic micro-/nano structures using amorphous elastomer materials is vital for enduringly industrial applications, yet it remains a challenge. Here, we design and fabricate a mechanical-robust superhydrophobic coating composed of amorphous polyurethane (PU) and epoxy resin modified with amino-terminated polysiloxane (APT-PDMS) via a scalable atomization spraying method. A quartz sands impact abrasion test evaluates the mechanical durability of the PU superhydrophobic coating (PU-SC). The superficial PU particles can form elastic micro-protuberances, absorbing impact and preventing fracture through elastic deformation during friction. Furthermore, the as-prepared PU-SC can also resist some chemical mechanical damage, including acids/bases/salts solution corrosion, UV radiation, knife scraping treatment, 3M tape-stripping, water flow impact, outside sunlight shining treatment and temperature treatment. Notably, the robust PU-SC can be efficiently produced on a large scale and applied to prevent electrochemical corrosion in a simulated seawater environment. The corrosion protection efficiency (PE) can reach 98.1%. We believe that the design and development of a mechanical-robust and polymer-based superhydrophobic coating has the prospect of actual application on marine corrosion.

Unifying the temperature dependent dynamics of glass formers.

Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, Tg, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for these macroscopic changes in properties. Using transition state theory (TST), we delve into the atomic/molecular level picture of how microscopic localized unit relaxations, or "cage rattles," evolve to macroscopic structural relaxations above Tg. Unit motion is broken down into two populations: (1) simultaneous rearrangement occurs among a critical number of units, nα, which ranges from 1 to 4, allowing a systematic classification of glass formers, GFs, that is compared to fragility; and (2) near Tg, adjacent units provide additional free volume for rearrangement, not simultaneously, but within the "primitive" lifetime, τ1, of one unit rattling in its cage. Relaxation maps illustrate how Johari-Goldstein β-relaxations stem from the rattle of nα units. We analyzed a wide variety of glassy materials and materials with a glassy response using literature data. Our four-parameter equation fits "strong" and "weak" GFs over the entire range of temperatures and also extends to other glassy systems, such as ion-transporting polymers and ferroelectric relaxors. The role of activation entropy in boosting preexponential factors to high "unphysical" apparent frequencies is discussed. Enthalpy-entropy compensation is clearly illustrated using the TST approach.

Robust Electrothermal Switching of Optical Phase‐Change Materials through Computer‐Aided Adaptive Pulse Optimization

Electrically tunable optical devices present diverse functionalities for manipulating electromagnetic waves by leveraging elements capable of reversibly switching between different optical states. This adaptability in adjusting their responses to electromagnetic waves after fabrication is crucial for developing more efficient and compact optical systems for a broad range of applications, including sensing, imaging, telecommunications, and data storage. Chalcogenide‐based phase‐change materials (PCMs) have shown great promise due to their stable, nonvolatile phase transition between amorphous and crystalline states. Nonetheless, optimizing the switching parameters of PCM devices and maintaining their stable operation over thousands of cycles with minimal variation can be challenging. Herein, the critical role of PCM pattern as well as electrical pulse form in achieving reliable and stable switching is reported on, extending the operational lifetime of the device beyond 13000 switching events. To achieve this, a computer‐aided algorithm that monitors optical changes in the device and adjusts the applied voltage in accordance with the phase transformation process is developed, thereby significantly enhancing the lifetime of these reconfigurable devices. The findings reveal that patterned PCM structures show significantly higher endurance compared to blanket PCM thin films.

Low-temperature co-fired PNN-PZT-based multilayer piezoelectric actuator with low cost and high reliability

Developing low-temperature co-fired MLAs for the commercial application of micro-nano actuation and manipulation has recently become a research highlight. To simultaneously achieve high piezoelectric response and low co-firing temperature below 960 °C, a PNN-PZT-0.02 Sr piezoceramic incorporated with Li2O-Bi2O3-CuO sintering additives and its MLA with the dimension of 7×7×3 mm3 were prepared using tape-casting and subsequent co-firing methods. The piezoceramic mainly composed of a triple phase (M, R, and T) co-existence shows a dense microstructure, indicating a good sintering-assistance effect. Even sintering at 920 °C, the piezoceramic possesses d33 ∼ 683 pC/N and kp ∼ 0.64, possibly surpassing most reported PZT-based piezoceramics. The MLA co-fired at 940 °C possesses a good Ag-ceramic interface without holes, aggregation or delamination. Also, it shows high maximum displacement (≥ 20 μm), high stiffness (118.5 N/μm @ 150 V), excellent thermal stability and 109-cycle reliability. A flat and defect-free electrode morphology is conducive to decreased leakage current. However, high tanδ primarily induced by the residual glassy phase and (Pb, Bi) oxides is the drawback. These findings give a novel paradigm for low-cost and high-reliability MLAs using pure Ag as inner electrodes by triple-phase controlling and nano-heterogeneity.

Evidence of intrinsic structural heterogeneity by monatomic metallic glass

Structural heterogeneity is generally considered to be an intrinsic feature of metallic glasses (MGs), playing a crucial role in their numerous exceptional properties. Prior studies on the structural and dynamic heterogeneities of MGs mainly focused on multi-element systems, which were possibly caused by chemical variations, challenging to exclude. This study employed a monatomic MG, as an ideal system, to investigate structural heterogeneities despite chemical factors using atomic force microscopy. Our results confirm the persistence of markedly structural heterogeneities in monatomic MGs, which cannot be entirely eliminated through annealing, thereby solidifying the intrinsic nature of structural heterogeneity in amorphous solids. Furthermore, we discover that tuning heterogeneity allows for tailoring the properties of monatomic MGs. This work provides conclusive evidence of the intrinsic property of heterogeneity in amorphous solids, reveals the hidden the complexity which covered by the chemical factors, and could advance the current understanding of the nature of glasses.

Design of Experiments-Driven Optimization of Spray Drying for Amorphous Clotrimazole Nanosuspension.

This study employed a Quality by Design (QbD) approach to spray dry amorphousclotrimazole nanosuspension (CLT-NS) consisting of Soluplus® and microcrystallinecellulose. Using the Box-Behnken Design, a systematic evaluation was conducted toanalyze the impact of inlet temperature, % aspiration, and feed rate on the criticalquality attributes (CQAs) of the clotrimazole spray-dried nanosuspension (CLT-SDNS). In this study, regression analysis and ANOVA were employed to detect significantfactors and interactions, enabling the development of a predictive model for the spraydrying process. Following optimization, the CLT-SD-NS underwent analysis using Xraypowder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR), Dynamic Scanning Calorimetry (DSC), and in vitro dissolution studies. The resultsshowed significant variables, including inlet temperature, feed rate, and aspiration rate,affecting yield, redispersibility index (RDI), and moisture content of the final product. The models created for critical quality attributes (CQAs) showed statistical significanceat a p-value of 0.05. XRPD and DSC confirmed the amorphous state of CLT in theCLT-SD-NS, and FTIR indicated no interactions between CLT and excipients. In vitrodissolution studies showed improved dissolution rates for the CLT-SD-NS (3.12-foldincrease in DI water and 5.88-fold increase at pH 7.2 dissolution media), attributed torapidly redispersing nanosized amorphous CLT particles. The well-designed studyutilizing the Design of Experiments (DoE) methodology.

An Artificial Intelligence Constitutive Model for Amorphous Solids Utilizing Graph Neural Networks

An Artificial Intelligence Constitutive Model for Amorphous Solids Utilizing Graph Neural Networks

Karanjin-loaded soya lecithin-based ethosomal nanogel for the therapeutic intervention of psoriasis: formulation development, factorial design based-optimization, in vitro and in vivo assessment

This study aimed to develop and optimize karanjin-loaded ethosomal nanogel formulation and evaluate its efficacy in alleviating symptoms of psoriasis in an animal model induced by imiquimod. These karanjin-loaded ethosomal nanogel, were formulated to enhance drug penetration into the skin and its epidermal retention. Karanjin was taken to formulate ethosomes due to its potential ani-psoriatic activity. Ethosomes were formulated using the cold method using 32 full factorial designs to optimize the formulation components. 9 batches were prepared using two independent variables X 1: concentration of ethanol and X 2: concentration of phospholipid whereas vesicle size (Y 1) and percentage entrapment efficiency (Y 2) were selected as dependent variables. All the dependent variables were found to be statistically significant. The optimized ethosomal suspension (B3) exhibited a vesicle size of 334 ± 2.89 nm with an entrapment efficiency of 94.88 ± 1.24% and showed good stability. The morphology of vesicles appeared spherical with smooth surfaces through transmission electron microscopy analysis. X-ray diffraction analysis confirmed that the drug existed in an amorphous state within the ethosomal formulation. The optimized ethosome was incorporated into carbopol 934 to develop nanogel for easy application on the skin. The nanogel underwent characterization for various parameters including spreadability, viscosity, pH, extrudability, and percentage drug content. The ethosomal formulation remarkably enhanced the skin permeation of karanjin and increased epidermal retention of the drug in psoriatic skin compared to marketed preparation and pure drug. A skin retention study showed that ethosomal nanogel formulation has 48.33% epidermal retention in 6 h. In vivo, the anti-psoriatic activity of karanjin ethosomal nanogel demonstrated significant improvement in psoriasis, indicated by a gradual decrease in skin thickness and scaling as reflected in the Psoriasis Severity Index grading. Therefore, the prepared ethosomal nanogel is a potential vehicle for improved topical delivery of karanjin for better treatment of psoriasis.

The influence of temperature (up to 120 °C) on the thermal conductivity of variably porous andesite

The thermal conductivity of volcanic rock is an essential input parameter in a wide range of models designed to better understand volcanic and geothermal processes. However, although volcanoes and geothermal reservoirs are often characterised by temperatures above ambient, laboratory thermal conductivity measurements are often performed at ambient temperature. In addition, there are currently few data on the temperature dependence of thermal conductivity for andesite, a common volcanic rock. Here, we provide elevated-temperature (up to 120 °C) laboratory measurements of thermal conductivity for variably porous (∼0.05 to ∼0.6) and variably glassy andesites from Mt. Ruapheu (New Zealand) using the transient hot-strip method. Our data show that (1) the thermal conductivity of these andesites has little to no temperature dependence and, therefore, (2) there is also no influence of porosity on the temperature dependence of thermal conductivity. We compare our new data with compiled published data to show that the thermal conductivity of volcanic rocks may decrease, remain constant, or increase as a function of temperature. We show that the thermal conductivity of amorphous glass and crystalline material increase and decrease, respectively, as temperature increases. We therefore interpret the temperature dependence of the thermal conductivity of volcanic rock to be dependent on glass content. The thermal conductivity of the studied andesites, the microstructure of which can be characterised by phenocrysts within a variably glassy groundmass, has little to no temperature dependence because the decrease in the thermal conductivity of the crystalline materials, due to decreases in lattice thermal conductivity, is offset by the increase in the thermal conductivity of the amorphous glass. A simple modelling approach, using the temperature dependence of the thermal conductivity of glass and crystalline material, provides a crystal content of 0.26 for a thermal conductivity independent of temperature, a common crystal content for andesite dome rock. Our findings imply that calculations of heat transfer through partially glassy volcanic rocks need not consider a temperature-dependent thermal conductivity, but that decreases and increases in thermal conductivity with temperature should be expected for fully crystallised or devitrified volcanic rocks and completely glassy volcanic rocks, respectively. We highlight that more experimental studies are now required to assess the evolution of thermal conductivity as a function of temperature in a wide range of volcanic rocks with different crystallinities.

Nonstoichiometry Induced Amorphous Grain Boundary of Na5SmSi4O12 Solid-State Electrolyte for Long-Life Dendrite-Free Sodium Metal Battery.

Oxide ceramics are considered promising candidates as solid electrolytes (SEs) for sodium metal batteries. However, the high sintering temperature induced boundaries and pores between angular grains lead to high grain boundary resistance and pathways for dendrite growth. Herein, we report a grain boundary modification strategy, which in situ generates an amorphous matrix among Na5SmSi4O12 oxide grains via tuning the chemical composition. The mechanical properties as well as electron mitigating capability of modified SE have been significantly enhanced. As a result, the SE achieves a room-temperature total ionic conductivity of 5.61 mS cm-1, the highest value for sodium-based oxide SEs. The Na|SE|Na symmetric cell achieves a high critical current density of 2.5 mA cm-2 and excellent cycle life over more than 2800 h at 0.15 mA cm-2 without dendrite formation. The full cell with Na3V2(PO4)3 as the cathode demonstrates impressive cycling performance, maintaining stability over 3000 cycles at 5C without observable loss of capacity.