In this study, the acoustic behavior and gas flow noise in a Helmholtz photoacoustic cell were simulated and optimized to study the influence of the cell dimensions and buffer structure. Numerical analysis using finite element analysis and experimental validation were performed in this study. A spindle-type photoacoustic cell with a resonator volume of 0.5 mL and buffer volume of 0.4 mL was selected for CH4 detection. Besides its strong photoacoustic enhancement, the spindle-type buffer structure has the best ability to eliminate flow noise compared to the other buffer structures. A linearity of 0.9992 was achieved over a wide concentration range of 0–10000 ppm in the CH4 measurement experiment. The 1σ equivalent detection limit for a response time of 10 s was measured to be 0.49 ppm. Allan deviation analysis indicated that a minimum detection limit of 17.9 ppb can be achieved by extending the integration time to 4760 s.
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