Air-soil Exchange Research Articles

Organochlorine pesticides in the soils from Benevento provincial territory, southern Italy: Spatial distribution, air-soil exchange, and implications for environmental health

This study comprehensively interprets the contamination status of organochlorine pesticides (OCPs) in the soils from Benevento provincial territory, southern Italy, and its implications for environmental health by means of a systematic grid sampling method and geostatistics. The total concentrations of OCPs in the soils ranged from 0.058 to 16.9 ng/g, with a geometric mean (GM) of 0.72 ng/g and an arithmetic mean (AM) of 1.71 ng/g. The levels of OCPs were dominated by p,p′-DDE, p,p′-DDD, HCB, contributing together to 73.5% of the total OCPs. The higher levels of HCB, DDTs, and HCHs found in southwestern, central and east Benevento provincial territory, all occurring adjacent to landfill sites. The residues of OCPs in soil are largely ascribed to their historical use. The OCP inventories in soils of Benevento provincial territory ranged from 0.13 to 4.84 metric tons, with GM = 0.42 metric tons and AM = 0.44 metric tons. The soil is likely to be a sink for DDTs under the influence of regional air transport from pollution hotspots and has the potential to release other chemicals with a high vapor pressure, e.g., HCB, HCHs, and α-Endosulfan. And the mean level of the air-soil exchange flux of HCB, HCHs, and DDTs is estimated to be −1.59, −0.72, and 0.10 ng/m2/day respectively. The potential ecological and human health risks caused by OCPs in the soils are deemed essentially negligible in Benevento provincial territory.

Microbial community responses determine how soil–atmosphere exchange of carbonyl sulfide, carbon monoxide, and nitric oxide responds to soil moisture

Abstract. Carbonyl sulfide (OCS) plays an important role in the global sulfur cycle and is relevant for climate change due to its role as a greenhouse gas, in aerosol formation and atmospheric chemistry. The similarities of the carbon dioxide (CO2) and OCS molecules within chemical and plant metabolic pathways have led to the use of OCS as a proxy for global gross CO2 fixation by plants (gross primary production, GPP). However, unknowns such as the OCS exchange from soils, where simultaneous OCS production (POCS) and consumption (UOCS) occur, currently limits the use of OCS as a GPP proxy. We estimated POCS and UOCS by measuring net fluxes of OCS, carbon monoxide (CO), and nitric oxide (NO) in a dynamic chamber system fumigated with air containing different mixing ratios [OCS]. Nine soils with different land use were rewetted and soil–air exchange was monitored as soils dried out to assess responses to changing moisture. A major control of OCS exchange was the total amount of available sulfur in the soil. POCS production rates were highest for soils at WFPS (water-filled pore space) >60 % and rates were negatively related to thiosulfate concentrations. These moist soils switched from a net source to a net sink activity at moderate moisture levels (WFPS 15 % to 37 %). For three soils we measured NO and CO mixing ratios at different mixing ratios of OCS and revealed that NO and potentially CO exchange rates are linked to UOCS at moderate soil moisture. High nitrate concentrations correlated with maximum OCS release rates at high soil moisture. For one of the investigated soils, the moisture and OCS mixing ratio was correlated with different microbial activity (bacterial 16S rRNA, fungal ITS RNA relative abundance) and gene transcripts of red-like cbbL and amoA.

Polychlorinated naphthalene emissions to the atmosphere from typical secondary aluminum smelting plants in southwestern China: concentrations, characterization, and risk evaluation.

Secondary aluminum smelting industry, as an important source of polychlorinated naphthalene (PCN) in environment, has been concerned in recent years. To figure out the emission characteristics of PCNs and the potential influence on surrounding environment, two typical secondary aluminum smelting plants were selected and PCNs were determined in flue gas, fly ash, aluminum slag, soil, and air samples collected at and around the plants by GC-MS coupled with DFS. PCN emission factors from the flue gas of the two plants (mean 0.006ng toxic equivalents/t) were found obviously decreased compared with similar smelting process detected in 2010. The stage of feeding material was still the major PCNs discharge period during the whole smelting process. The total PCN concentrations in air were found to be ranked as following: workshops (290-1917pg/m3), the area near the workshops (62.3-697pg/m3), and the surrounding areas (29.9-164pg/m3, mean 64.5pg/m3). Similar high concentrations of PCNs were found in soil from by the workshop door (983ng/g dry weight). Soil-air exchange calculations indicated that mono-CN to tetra-CN would volatilize but hepta-CN and octa-CN would be deposited to the soil. Exposure of plant workers and local inhabitants to PCNs through inhalation was found to be acceptable but higher (especially for workers in the workshops) than living areas. The workshop and the nearby area are potential PCNs polluted areas and should be paid attention during the practical operation.

Characterization of Tibetan Soil As a Source or Sink of Atmospheric Persistent Organic Pollutants: Seasonal Shift and Impact of Global Warming.

Background soils are reservoirs of persistent organic pollutants (POPs). After decades of reduced primary emissions, it is now possible that the POPs contained in these reservoirs are being remobilized because of climate warming. However, a comprehensive investigation into the remobilization of POPs from background soil on the largest and highest plateau on Earth, the Tibetan Plateau (TP), is lacking. In this study, a sampling campaign was carried out on the TP at three background sites with different land cover types (forest, meadow and desert). Field measurements of the air-soil exchange of POPs showed that previous prediction using empirical models overestimated the values of the soil-air partitioning coefficient ( KSA), especially for chemicals with KOA > 9. The direction of exchange for γ-HCH, HCB, and PCB-28 overlapped with the air-soil equilibrium range, but with a tendency for volatilization. Their emission fluxes were 720, 2935, and 538 pg m-2 day-1, respectively, and were similar in extent to those observed for background Arctic soil in Norway. Nam Co and Ngari are also permafrost regions, and most chemicals at these two sites exhibited volatilization. This is the first result showing that permafrost can also emit POPs. Seasonally, we found that chemicals tended to be re-emitted from soils to the atmosphere in winter and deposited from the air to the soil in summer. This finding is opposite to most previous results, possibly because of the higher air-soil concentration gradient caused by the prevailing transport of POPs in summer. Climate warming exerts a strong influence on air-soil exchange, with an increase of 1 °C in ambient temperature likely leading to an increase of Tibetan atmospheric inventories of POPs by 60-400%.

Concentration, exchange and source identification of polycyclic aromatic hydrocarbons in soil, air and tree bark from the Middle-Lower Yangtze Plain, China

Polycyclic aromatic hydrocarbons (PAHs) were detected in tree bark, soil and air samples of the plain along the Yangtze River (Anhui section) which belongs to the Middle-Lower Yangtze Plain.∑15PAHs in tree bark, soil and air (collected using PUF based passive samplers) ranged from 27 to 1300 ng g −1 dw, 140–5300 ng g−1 dw, and 29–210 ng m−3, respectively. The proportions of 3- and 4- ring PAHs were significantly higher in air and tree bark samples, whereas 5- and 6- ring PAHs were significantly higher in soils. Distribution of PAHs in barks of slow-growing wood (camphor tree) was similar with that in PUFs, and variation of PAHs in tree barks from same species was less than that from different species. Furthermore, all the 4-, 5- and 6- ring PAHs are not in equilibrium between air and bark. Air-soil exchange of 3- and 4- ring PAHs was dominated by net volatilization, while 5- and 6-ring PAHs were mostly reach the equilibrium. For the source identification of air-borne PAHs, diagnostic ratios of PAHs with molecular mass of 202 and 276 may be more appropriate as these ratios are more conservative. Through comprehensive analysis using diagnostic ratios and principal component analysis, combustion of petroleum, coal and biomass were the major sources of PAHs in the environmental compartments of the study area.

Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air

Abstract. Volatile organic compounds (VOCs) play a key role in atmospheric chemistry. Emission and deposition on soil have been suggested as important sources and sinks of atmospheric trace gases. The exchange characteristics and heterogeneous chemistry of VOCs on soil, however, are not well understood. We used a newly designed differential coated-wall flow tube system to investigate the long-term variability of bidirectional air–soil exchange of 13 VOCs under ambient air conditions of an urban background site in Beijing. Sterilized soil was investigated to address physicochemical processes and heterogeneous/multiphase reactions independently from biological activity. Most VOCs revealed net deposition with average uptake coefficients (γ) in the range of 10−7–10−6 (referring to the geometric soil surface area), corresponding to deposition velocities (Vd) of 0.0013–0.01 cm s−1 and soil surface resistances (Rc) of 98–745 s cm−1, respectively. Formic acid, however, was emitted at a long-term average rate of ∼6×10-3 nmol m−2 s−1, suggesting that it was formed and released upon heterogeneous oxidation of other VOCs. The soil–atmosphere exchange of one individual VOC species can be affected by both its surface degradation/depletion caused by surface reactions and by competitive uptake or heterogeneous formation/accommodation of other VOC species. Overall, the results show that physicochemical processing and heterogeneous oxidation on soil and soil-derived dust can act as a sink or as a source of atmospheric VOCs, depending on molecular properties and environmental conditions.

Health risk assessment and source apportionment of polycyclic aromatic hydrocarbons associated with PM10 and road deposited dust in Ahvaz metropolis of Iran.

The objective of this study was to compare the characteristics of polycyclic aromatic hydrocarbons (PAHs) in PM10 and road dust samples, as well as to identify and quantify the contributions of each source profile using the positive matrix factorization (PMF) receptor model. Health risk assessment was carried out using toxic equivalency factors and incremental lifetime cancer risk (ILCR), which quantitatively estimate the exposure risk for age-specific groups. PM10 samples were collected on PTFE filters in the metropolitan area of Ahvaz. Road dust samples were also collected from all over the urban areas with different land uses. Total PAH concentrations in PM10 and road dust samples were 0.5-25.5ng/m3 and 49.3-16,645µg/kg, respectively. Pyrene was the highest PAH in the PM10 profile, whereas fluoranthene became the highest PAH in the road dust. Abundance of benzo[ghi]perylene at PM10 and road dust samples suggested a source indicator for traffic emissions. The results demonstrate that in 36.5% of samples, PM10 concentrations exceed the maximum concentration level recommended by EPA. A multiple linear regression model was used to estimate the influence of meteorological parameters (temperature, wind speed, and relative humidity) on buildup of PAHs. All of PAH species show higher concentrations during the cold and typical days rather than the dust event days and warm periods. PMF analysis showed that vehicular emissions (50.6%) and industrial activities (especially steel industries) (30.4%) were first two sources of PAHs bounded with PM10, followed by diesel emissions (11.6%) and air-soil exchange (7.4%). For road dust samples, three common sources were also identified: vehicular traffic (48%), industrial activities (42.3%), and petrogenic sources (9.7%), in line with that of diagnostic molecular ratios results. According to the results of health risk assessment model, the ILCR of exposure to PAHs associated with PM10 and road-deposited dust was higher than the guidelines of USEPA, indicating high carcinogenic risk.

Agricultural effects on air–soil exchange and slope instability

This study aims to understand in what manner a change from grassland to irrigated apple orchards can produce significant changes on the atmospheric soil–water exchange and in turn on the pore water pressure distribution with depth. Both changes may affect slope stability, as a result of infiltration, a rising water table and modified suction profiles. Pore pressure distributions were determined over an average of a 1-year period. The water balance considers infiltration due to precipitation and irrigation, cleared of run-off losses, and evaporation from soil and induced by plant transpiration. Evaporation and infiltration are related to the climate time history at the ground surface and the suction–saturation response of the soil–vegetation system. Vegetation includes lawn, as the reference condition, and apple trees, new or full-production orchards, under sprinkler or drip irrigation. Slope stability was analysed by neglecting the reinforcing effects of the roots, although this is beneficial for shallow slides, and assuming a planar ground surface.

Revolatilisation of soil-accumulated pollutants triggered by the summer monsoon in India

Abstract. Persistent organic pollutants that have accumulated in soils can be remobilised by volatilisation in response to chemical equilibrium with the atmosphere. Clean air masses from the Indian Ocean, advected with the onset of the summer monsoon, are found to reduce concentrations of hexachlorocyclohexane (HCH), dichlorodiphenyltrichloroethane (DDT) and its derivatives, endosulfan and polychlorinated biphenyls (PCBs) in air at a mountain site (all in the range 5–20 pg m−3) by 77 %, 70 %, 82 % and 45 %, respectively. The analysis of fugacities in soil and air suggest that the arrival of summer monsoon triggers net volatilisation or enhances ongoing revolatilisation of the now-banned chemicals HCH and PCBs from background soils in southern India. The response of the air–soil exchange was modelled using a regional air pollution model, WRF-Chem PAH/POP. The results suggest that the air is increasingly polluted during transport by the south-westerly monsoon winds across the subcontinent. Using a multidecadal multimedia mass balance model, it is found that air–surface exchange of HCH and DDT have declined since the ban of these substances from agriculture, but remobilisation of higher chlorinated PCBs may have reached a historical high, 40 years after peak emission.

Spatio-temporal variations of atmospheric and soil polybrominated diphenyl ethers (PBDEs) in highly industrialized region of Dilovasi

Polybrominated diphenyl ethers (PBDEs) were investigated in ambient air of a highly industrialized region at 23 different sampling sites for 12 months. Total concentrations of 8 PBDE congeners (Σ8PBDE) were found to be between 5.73 and 520 pg m−3 (94.7 ± 78.9; average ± SD) and BDE-209 was the predominant congener, followed by BDE-47 and/or BDE-99. Their contributions to Σ8PBDE were 71 ± 13, 9 ± 4% and 8 ± 4%; respectively. Compared to previous studies around the world, high concentrations detected in Dilovasi demonstrated the severity of atmospheric PBDE pollution in the area. For all sampling sites, average PBDE concentration obtained in summer (118.5 ± 98.7 pg m−3) was higher than one found in winter period (79.7 ± 59.1 pg m−3) and this seasonal difference was more obvious in industrial/urban sites (p < 0.05), probably due to enhanced volatilization from ongoing PBDE sources such as waste incineration and iron-steel plants. The soil-air exchange tendencies of PBDEs did not show substantial differences between the sampling periods with small variations for each congener. All congeners either tend to deposit to soil or to be within the equilibrium range for all seasons. This reflects the impact of local ongoing sources rather than temperature on the direction of soil-air exchange of PBDEs in this region. Specific congener ratios such as BDE-47/-99 and -99/-100 confirmed the impact of local sources rather than long-range transport on PBDE congeners in the study area. According to the Positive Matrix Factorization (PMF) results, the BDE-209 content of the first factor was found to be 91.7% and this factor was attributed to the deca-BDE technical formulations. The second factor was highly rich with both BDE-183 (%61) and BDE-28 (%52) and identified as octa-BDE technical products. The last factor was highly loaded with BDE-99, BDE-47, BDE-100, BDE-154 and BDE-153 and has been determined as the penta-BDE commercial formulations.

Transformation of Polychlorinated dibenzo-p-dioxins and Polychlorinated Dibenzofurans in the Environment

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are toxic, mutagenic and carcinogenic, causing great concern in the public. This review analyzes the properties, toxic effects and sources of PCDD/Fs. The distribution in various environmental compartments, including air, water, soil and sediments, are described. Further, the transformation of PCDD/Fs in the environment was emphatically discussed. The result shows that the fate of PCDD/Fs is mainly controlled by their gasparticle distribution behavior. For gas-phase PCDD/Fs, they are primarily depleted by photolysis and reactions with atmospheric oxidants. For particle-phase PCDD/Fs, dry and wet deposition are the effective removal mode. In the water body, the PCDD/Fs will be inclined to deposit in the sediment. Biodegradation may be a possible environment fate for the PCDD/Fs in sediments. Moreover, PCDD/Fs can enter into the atmosphere in the form of volatilization, especially in the summer. In the soil, the PCDD/Fs can be degraded through anaerobic dechlorination and aerobic dioxygenation, as well as by gas exchange across the air-soil interface. It has a strong net volatilized from the soil into the air for the PCDD/Fs with six or fewer chlorine atoms, while the hepta- and octachloroisomers are approached to the main air-soil exchange balance. Keywords: PCDD/Fs, sources, concentrations, dry and wet deposition, photolysis, oxidation degradation, biodegradation.

Study on the practice and effect of alleviating apple orchard soil compaction in the Weibei plateau

Long-term planting and the application of chemical fertilizer merely have led to soil compaction in the Weibei plateau, which was not conducive to soil water infiltration and air exchange. The aim of this study was to develop knowledge of drilling and backfill materials effect on soil water content and CO2 emissions. Five treatments consisted of control (no drilling) and drilling with vermiculite, slag, lime and backfill soil buried respectively. During the experiment, soil water content and CO2 emissions were determined for each treatment. The results showed that drilling improved the water permeability of the soil without damaging the root system of fruit trees, and promoted the release of soil CO2. The addition of vermiculite and slag had the best effect on soil water content improvement in the apple orchards. Additionally, soil CO2 emission was closely related to soil water content. Both too high and too low soil water content can limit soil CO2 release. The addition of lime can not only absorb the CO2 in soil inside, but also increase soil calcium storage capacity. Therefore, drilling with lime backfilled may be the optimal practice to alleviate soil compaction in apple orchards in the Weibei plateau.

Structural equation modeling of PAHs in ambient air, dust fall, soil, and cabbage in vegetable bases of Northern China

A series of field samples including ambient air (gaseous and particulate phases), dust fall, surface soil, rhizosphere soil and cabbage tissues (leaf, root and core), were collected in vegetable bases near a large coking manufacturer in Shanxi Province, Northern China, during a harvest season. A factor analysis was employed to apportion the emission sources of polycyclic aromatic hydrocarbons (PAHs), and the statistical results indicated coal combustion was the dominant emission source that accounted for different environmental media and cabbage tissues, while road traffic, biomass burning and the coking industry contributed to a lesser extent. A structural equation model was first developed to quantitatively explore the transport pathways of PAHs from surrounding media to cabbage tissues. The modeling results showed that PAHs in ambient air were positively associated with those in dust fall, and a close relationship was also true for PAHs in dust fall and in surface soil due to air-soil exchange process. Furthermore, PAHs in surface soil were correlated with those in rhizosphere soil and in the cabbage leaf with the path coefficients of 0.83 and 0.39, respectively. PAHs in the cabbage leaf may dominantly contribute to the accumulation of PAHs in the edible part of cabbages.

Distribution, sources, and air–soil exchange of OCPs, PCBs and PAHs in urban soils of Nepal

Due to the high temperature and extensive use of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs), tropical cities could act as secondary sources of these pollutants and therefore received global concern. As compared with other tropical cities, studies on the air–soil exchange of OCPs, PCBs and PAHs in tropical Nepali cities remained limited. In the present study, 39 soil samples from Kathmandu (capital of Nepal) and 21 soil samples from Pokhara (second largest city in Nepal) were collected The soil concentrations of the sum of endosulfans (α- and β-endosulfans) ranged from 0.01 to 16.4 ng/g dw. Meanwhile, ∑dichlorodiphenyltrichloroethane (DDTs) ranged from 0.01 to 6.5 ng/g dw; ∑6PCBs from 0.01 to 9.7 ng/g dw; and ∑15PAHs from 17.1 to 6219 ng/g dw. High concentrations of OCPs were found in the soil of commercial land, while, high soil PAH concentrations were found on tourist/religious and commercial land. Combined the published air concentrations, and the soil data of this study, the directions and fluxes of air–soil exchange were estimated using a fugacity model. It is clear that Nepal is a country contributing prominently to secondary emissions of endosulfans, hexachlorobenzene (HCB), and low molecular weight (LMW) PCBs and PAHs. The flux for all the pollutants in Kathmandu, with ∑endosulfans up to 3553; HCB up to 5263; and ∑LMW-PAHs up to 24378 ng m−2 h−1, were higher than those in Pokhara. These high flux values indicated the high strength of Nepali soils to act as a source.

Polychlorinated biphenyls in two typical landforms of Southern Anhui province, China: Sources, air-soil exchange, and risk assessment

Polychlorinated biphenyls (PCBs) were detected in the atmosphere and soil of Southern Anhui, China. The average concentration of ∑26PCBs in the atmosphere along the Yangtze River (YR) was 32 pg m−3, and was higher than that in the HuangShan Mountain (HM) which was 17 pg m−3. The average soil concentrations of ∑26PCBs along the YR and in the HM were 1.6 and 1.3 ng g−1, respectively. The mean percentages of tri-CBs were less than 40% in both air and soil samples. The percentages of penta- and hexa-CBs in air and soil samples were relatively higher than those in Chinese commercial PCBs and unintentionally produced PCBs. These homologue patterns indicated that PCBs in the environmental matrices of Southern Anhui might originate from other distant sources. In southern Anhui, most highly chlorinated congeners presented net gaseous deposition from air to soil, while lower chlorinated congeners preferred net volatilization from soil to air. PCBs in the environmental matrices of the HM were diluted with increasing altitude, suggesting that PCBs in this region might origin from some external sources, and be transported to the HM by atmosphere. Half of the sampling sites along the YR and one site in the HM had the cancer risks for ∑26PCBs through the inhalation exposure higher than acceptable risk level of 10−6. Only one sampling site had the cancer risk for ∑26PCBs through the accidental soil ingestion >10−6.

Environmental concentration and atmospheric deposition of halogenated flame retardants in soil from Nepal: Source apportionment and soil-air partitioning.

While various investigations have been driven on polybrominated diphenyl ethers (PBDEs) and other flame retardants (FRs) in different framework around the world, information about contamination and fate of PBDEs and other FRs in developing countries especially in the Indian subcontinent is uncommon. Nepal being located in the Indian subcontinent, very little is known about contamination level of semi-volatile organic pollutants discharged into the environment. This motivated us to investigate the environmental fate of halogenated flame retardant (HFRs) in Nepalese condition. In this study, we investigated the concentration, fate, and sources of 9 PBDEs, 2 dechlorane plus isomers (DPs), and 6 novel brominated flame retardants (NBFRs). Moreover, air-soil exchange and soil-air partitioning were also evaluated to characterize the pattern of air-soil exchange and environmental fate. In general, the concentrations of NBFRs in soil were more prevalent than PBDEs and DPs, and accounted 95% of ∑HFRs. By and large, the concentrations of NBFRs and DPs were measured high in Kathmandu, while PBDEs level exceeded in Pokhara. Principal component analysis (PCA) study suggested contributions from commercial penta-, octa-, and deca-BDEs products and de-bromination of highly brominated PBDEs as the significant source of PBDEs. Likewise, low fanti ratio suggested DPs in soil might have originated from long-range atmospheric transport from remote areas, while high levels of decabromodiphenyl ethane (DBDPE) in soil were linked with the use of wide varieties of consumer products. The estimated fugacity fraction (ff) for individual HFR was quite lower (<0.05) than equilibrium value, suggesting that deposition and net transport from air to the soil is overwhelming. Soil-air partitioning study revealed neither octanol-air partition coefficient (KOA) nor black carbon partition coefficient (KBC-A) is an appropriate surrogate for soil organic matter (SOM), subsequently, absorption by SOM has no or little role in the partitioning of HFRs.

Factors influencing the diurnal atmospheric concentrations and soil-air exchange of PBDEs at an e-waste recycling site in China

Factors influencing the diurnal atmospheric concentrations and soil-air exchange of polybrominated diphenyl ethers (PBDEs) were investigated at an e-waste recycling site in China during winter and summer. Total PBDE concentrations in winter and summer were 11.0–42.4 and 120–431 pg/m3 in the gaseous phase and 13.3–234 and 69.0–208 pg/m3 in the particulate phase, respectively. Total PBDE concentrations in the e-waste contaminated and nearby soils were 869 and 611 ng/g in winter and 2130 and 31 ng/g in summer, respectively. Concentrations in the gaseous phase were significantly higher in summer than in winter, but concentrations in the particle phase were comparable between winter and summer. Because of the influence of occasional accidental inputs, no apparent diurnal variations were found for PBDEs in either the particle or gaseous phase. Both temperatures and local emissions affected air concentrations of PBDEs in this area. The estimated directions of soil-air exchange of PBDEs suggest that the e-waste contaminated soil generally acted as a secondary source of several low brominated PBDEs, while the nearby soil acted as a secondary source of BDE28. The diurnal variation of atmospheric concentrations of PBDEs is not strong enough to alter the soil-air exchange direction.

Organophosphate ester flame retardants in Nepalese soil: Spatial distribution, source apportionment and air-soil exchange assessment

Despite soil being the major terrestrial environmental reservoir and one of the significant sinks for many hydrophobic organic compounds including organophosphate ester flame retardants (OPFRs), limited information is available about concentration and fate of OPFRs contamination in urban soil in general and especially in case of Nepal. This study investigates the environmental concentration, spatial distribution and source apportionment of eight OPFRs in surface soil (n = 28) from four major cities of Nepal with special interest on air-soil exchange. Overall, significantly high concentrations of ∑8OPFR were measured in soil ranging from 25–27,900 ng/g dw (median 248 ng/g dw). In terms of compositional pattern, tris(methyl phenyl) phosphate (TMPP) was the most abundant phosphorus chemical in soil, followed by tris(2-chloroisopropyl) phosphate (TCIPP), and accounted for 35–49% and 8–25% of ∑8OPFRs, respectively. The high level of these OPFRs was attributed to local sources as opposed to transboundary influence from remote areas. A Spearman's rank correlation analysis exhibited weak correlation of ∑8OPFRs with TOC (Rho = 0.117, p < 0.05) and BC (Rho = 0.007, p < 0.05), suggesting little or no influence of TOC and BC on the concentration of ∑8OPFRs. The fugacity fraction (ff) results indicated a strong influence of soil contamination on atmospheric level of OPFRs via volatilization.

Occurrence and air–soil exchange of organochlorine pesticides and polychlorinated biphenyls at a CAWNET background site in central China: Implications for influencing factors and fate

Ambient air and soil samples were collected between March 2012 and March 2013 at Jinsha, a regional background site in central China, to measure the concentrations of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). The average concentrations of total OCPs and total PCBs were 191 ± 107 and 39.4 ± 27.1 pg/m3 in air (gaseous and particulate phase) and 0.585 ± 0.437 and 0.083 ± 0.039 ng/g in soil, respectively. The higher concentrations of p,p′-dichlorodiphenyltrichloroethane (p,p′-DDT) and p,p′-DDT/p,p′-DDE ratios in the soil indicated recent p,p′-DDT input to the soil. A strong positive temperature dependence and average fugacity fraction value > 0.5 were observed for p,p′-DDT, suggesting that volatilization of residual DDT in the soil was the main influencing factor on atmospheric p,p′-DDT. Highly average fugacity fractions (>0.7) of trans-chlordane (TC) and cis-chlordane (CC) and high TC/CC ratios both in the soil and atmosphere suggested fresh inputs. Higher gaseous concentrations of hexachlorobenzene (HCB) were observed in winter and negative temperature dependence was directly attributed to the surrounding ongoing source (e.g. fuel consuming activities), especially in winter. Overall, most targeted OCPs and PCBs were influenced by long-range transport, and fugacity fraction values indicated highly volatile compounds (e.g. α-hexachlorocyclohexane (α-HCH) and lower chlorinated PCBs) were volatilized and low volatility compounds (e.g. p,p′-DDE and higher chlorinated PCBs) were deposited at the air–soil interface. Knowing the source and sink of OCPs and PCBs can help to control their pollution in this area and provide a reference for other studies.

Polychlorinated biphenyls in Nepalese surface soils: Spatial distribution, air-soil exchange, and soil-air partitioning

Regardless of the ban on the polychlorinated biphenyls (PCBs) decade ago, significant measures of PCBs are still transmitted from essential sources in cities and are all inclusive ecological contaminants around the world. In this study, the concentrations of PCBs in soil, the air-soil exchange of PCBs, and the soil-air partitioning coefficient (KSA) of PCBs were investigated in four noteworthy urban areas in Nepal. Overall, the concentrations of ∑30PCBs ranged from 10 to 59.4ng/g dry weight; dw (mean 12.2ng/g ±11.2ng/g dw). The hexa-CBs (22–31%) was most dominant among several PCB-homologues, followed by tetra-CBs (20–29%), hepta-CBs (12–21%), penta-CBs (15–17%) and tri-CBs (9–19%). The sources of elevated level of PCBs discharge in Nepalese soil was identified as emission from transformer oil, lubricants, breaker oil, cutting oil and paints, and cable insulation. Slightly strong correlation of PCBs with TOC than BC demonstrated that amorphous organic matter (AOM) assumes a more critical part in holding of PCBs than BC in Nepalese soil. The fugacity fraction (ff) results indicated the soil being the source of PCB in air through volatilization and net transport from soil to air. The soil-air partitioning coefficient study suggests the absorption by soil organic matter control soil-air partitioning of PCBs. Slightly weak but positive correlation of measured Log KSA with Log KOA (R2 = 0.483) and Log KBC-A (R2 = 0.438) suggests that both Log KOA and Log KBC-A can predict soil-air partitioning to lesser extent for PCBs.