Zircon Ages Research Articles

Provenance and depositional age of metasedimentary rocks in the Frontenac terrane (Grenville Province, Ontario)

The Mesoproterozoic Frontenac terrane in the southern Grenville Province of Ontario is separated by shear zones from the Composite Arc Belt to the west and the Adirondack Lowlands to the east. The majority of the terrane is made up of granulite-facies metasedimentary rocks that are the oldest lithologies recognized in the terrane. Five samples were selected for U–Pb geochronology to constrain (1) metamorphic age, (2) depositional age of sedimentary protoliths, and (3) source regions of detrital zircon. Two pelitic gneisses and a marble are dominated by metamorphic zircon, whereas two quartzites contain a diverse population of detrital zircon that are surrounded by metamorphic overgrowths. Metamorphic zircon have 206Pb/207Pb ages of 1.19–1.16 Ga, and a small population is 1.22 Ga. These ages correspond to the Shawinigan and Elzevirian orogenies and provide minimum ages for deposition. The youngest detrital grains with ages of 1.25–1.24 Ga provide maximum depositional ages. Quartzites (and pelitic gneisses) have a wide range of detrital zircon ages that reflect local Mesoproterozoic Grenville sources and Paleoproterzoic and Archean sources in the northern Grenville Province and elsewhere in Laurentia. Most notable is a large population of 1.9–1.8 Ga zircon, which points towards derivation from the Penokean orogen in the midcontinent or Makkovikian–Ketilidian orogen of Labrador and Greenland, indicating long sedimentary transport distances. The similarities in depositional ages and detrital zircon ages between Frontenac terrane and Adirondack metasedimentary rocks suggest a shared sedimentary history, which we interpret as deposition in the same Trans-Adirondack backarc basin at ca. 1.25 Ga.

Tectonic architecture of the northern Dora-Maira Massif (Western Alps, Italy): field and geochronological data

High-pressure and ultra-high-pressure metamorphic terrains display an internal architecture consisting of a pile (or stack) of several coherent tectonic thrust sheets or units. Their identification is fundamental for understanding the scale and mechanisms active during subduction and exhumation of these crustal slices. This study investigates the geometry of the northern Dora-Maira Massif and the kinematics of the major tectonic boundaries, combining field and geochronological data. The tectonic stack of the northern Dora-Maira Massif comprises the following units. The lowermost unit (the Pinerolo Unit) is mainly characterized by Upper Carboniferous fluvio-lacustrine (meta-)sediments. The Pinerolo unit is overthrust by a pre-Carboniferous basement. The latter is subdivided in two tectonic units (the Chasteiran and Muret Units) with different Alpine metamorphism (ultra-high-pressure and high-pressure, respectively). The pre-Carboniferous basement of the Muret Unit is thicker than previously thought for two main reasons. Firstly, some paragneisses, traditionally assumed to be Carboniferous and/or Permian in age, display detrital zircon ages indicating a main source at about 600 Ma. Secondly, three samples of the Granero Orthogneiss, previously assumed to be a Permian intrusive body, have provided zircon U–Pb ages of 447 ± 1 Ma, 456 ± 2 Ma and 440 ± 2 Ma, indicating a late Ordovician or early Silurian age for the protoliths. The uppermost unit (the Serre Unit) comprises porphyritic (meta-) volcanic and volcaniclastic rocks dated to the Permian (271 ± 2 Ma), on top of which remnants of the Mesozoic cover is preserved. Detailed mapping of an area about 140 km2 shows that (i) the ultra-high pressure Chasteiran Unit is localized at the boundary between the Pinerolo and Muret Units, (ii) the Granero Orthogneiss may be considered as the mylonitic sole of the Muret Unit, characterized by a top-to-W sense of shear, and (iii) the contact between the Muret and Serre Units displays ductile-to brittle structures (La Fracho Shear Zone), indicating a top-to-the-NW displacement of the hangingwall with respect to the footwall. A final episode of brittle faulting, cutting across the nappe stack (the Trossieri Fault), indicates an extensional stage in the core of the Alpine belt, as previously documented in more external zones. This work provides a necessary and robust basis before an accurate discussion of processes acting during continental subduction of the Dora-Maira Massif may be understood.

Multi-stage ultrahigh temperature metamorphism in the lower crust of the Kaapvaal craton recorded by U–Pb ages of garnet

U–Pb ages were determined by split-stream LA-SF/MC-ICPMS in garnets from UHT granulite xenoliths (Star mine, South Africa; 124 Ma). They give a considerable age range of 400 million years with well-defined maximas at 3.09, 3.01 and 2.75 Ga. The oldest peak overlaps with the changeover from tonalites to K-granites at 3.14–3.04 Ga and with zircon ages of the mid-crustal granulites of the Vredefort dome (3.1 Ga) in the wake of the 3.2 Ga collision of three terrains that compose the Witwatersrand block. Subduction (or sagduction) of the uppermost crust in an ultrahot orogen setting brought shales and greenstones to the lower crust. Ultrahigh temperature (UHT) conditions are the result of high mantle potential temperatures and self- heating by the radioactive inventory of the subducted lithologies. Metamorphism, anatexis to very high degrees and melt extraction left UHT granulites as residue. Rejuvenation of UHT conditions was brought about by Dominion Group magmatism between 3.0 and 2.95 Ga. Magmatic uprise caused intense shearing in the lower crust followed by recrystallisation of the shear zones to generate the younger garnet age group. Ventersdorp flood basalt volcanism caused similar processes at around 2.72 Ga and generated the third garnet age group. Zircon gives U–Pb ages mainly around 2.72 Ga (both literature and our own data) i.e. zircon adjusted or newly crystallized at the youngest UHT event. Only few zircon grains retained older ages up to 2.94 Ga. Still unconstrained, but very high closure temperatures (≥ 1100 °C) for the U–Pb system in garnet keep the memory of the oldest ages in UHT granulites. Such ages can only be reset by recrystallization. This way, garnet records a prolonged high-temperature history of the lower crust of the Kaapvaal craton.

BOUNDARY BETWEEN THE TIMANIAN AND URALIAN TECTONIC CYCLES: RESULTS OF DATING OF DETRITAL ZIRCONS FROM BASAL HORIZONS OF THE LOWER PALEOZOIC SYNRIFT COMPLEX OF THE POLAR URALS, AND IGNEOUS ROCK AGE DATA REPORT

The Upper Cambrian-Lower Ordovician terrigenous strata, unconformably overlying the Upper Riphean-Vendian rocks of the Timanide orogen in the north of the Urals, and contemporaneous bimodal volcanics and intrusive rocks are considered complexes marking the beginning of rifting which led to the opening of the Paleo-Ural Ocean later on. The article presents the results of U-Pb (LA-ICP-MS) dating of detrital zircons from sandstones lying at the base of the section of the rift complex in the Malaya Usa River basin in the Polar Urals. It was found that the clastic sequence (identified as the Khoydyshor formation) began to accumulate no earlier than the Cambrian–Ordovician transition. Zircon ages fall within the continuous Vendian to Early Ordovician (575–478 Ma) interval with peak at 512 Ma. This age range overlaps with the age of rhyolites interlayered conformably with sandstones and rhyolite porphyry dikes intruding the Khoydyshor formation, thus indicating a possible admixture of products of synsedimentary volcanism. A narrow zircon age pattern allows us to conclude that the main sources of detrital zircons in sandstones were the Early-Middle Cambrian igneous rocks formed at the stage of pre-rift uplift, and, to a lesser extent, the Late Cambrian-Early Ordovician riftogenic magmatic complexes, marking the beginning of the Uralian tectonic cycle, as well as the Late Vendian igneous rocks of the underlying Timanide orogen. Judging by the Th/U ratio, most of the detrital zircons within the sandstones were derived from the Early Paleozoic silicic volcanic and hypabyssal rocks and the Vendian granitoids and diorites. The almost complete absence of older grains, which are typical of coeval sandstones of the northern part of the Urals, may indicate the accumulation of the considered sandstones in a local trough with local clastic material sources. Probability density estimation of U-Pb ages for zircon from igneous and metamorphic rocks of the Polar Urals indicates that there were no gaps in the Late Riphean to Early Ordovician endogenous activity in this region. The main peaks occur at 552, 521 and 500 Ma, and an additional peak – at 665 Ma. The results of dating of detrital zircons from sandstones of the Khoydyshor formation together with the database of U-Pb isotope ages of igneous and metamorphic rocks of the Polar Urals (119 items), compiled by the authors, indicate that the change in geodynamic regime from collisional orogenesis in the Late Vendian to the Early-Middle Cambrian pre-rift uplift and following Late Cambrian rifting was not accompanied by a longterm discontinuity in magmatic activity.

Geochronology and geochemistry of zircon and columbite–tantalite group minerals from the Weilasituo Sn–polymetallic deposit, northeastern China: Implications for the relationship between mineralization and the magmatic–hydrothermal transition

The Weilasituo Sn–polymetallic deposit, located in the southern portion of the Great Xing'an Range of Inner Mongolia, China, is a super-large Sn deposit associated with abundant Li, Rb, Nb, Ta, Zn, and Cu resources. Despite that previous studies have characterized the age, hydrothermal evolution, and genetic relationship between the alkali feldspar granite porphyry and associated Sn–polymetallic mineralization, the magmatic–hydrothermal evolution and ore–forming processes remain ambiguous. To address these ambiguities and bridge this knowledge gap, this contribution characterizes the texture, geochemistry, and U–Pb isotope composition of zircon and columbite–tantalite group minerals (CGMs) from amazonitized alkali feldspar granite (AMG) and albitized alkali feldspar granite (ABG) in the Weilasituo deposit. Type-I zircon (Zr1) is inclusion-poor, translucent, and is characterized by low light rare earth element (LREE) contents, high (Sm/La)N ratios (mean = 655.7), and low Th/U (mean = 0.21 < 0.3), Zr/Hf (mean = 5.46), and Y/Ho ratios (mean = 4.42), indicating that it formed during the magmatic–hydrothermal transition. Type-II zircon (Zr2) is inclusion-rich, porous, has a low CL response, and is characterized by low Th/U ratios (0.08–0.32, mean = 0.17), high LREE contents, weakly positive Ce anomalies, and low (Sm/La)N ratios (mean = 20.7), indicating that it formed via hydrothermal alteration of Zr1 (i.e., magmatic–hydrothermal zircon). Type-I CGM (CGM1) generally lacks oscillatory zoning, and has similar and positively correlated Ta/(Nb + Ta) and Mn/(Mn + Fe) values (AMG: R2 = 0.93; ABG: R2 = 0.75), indicative of a magmatic origin. Type-II CGMs (CGM2) occur as rims on CGM1 and are characterized by higher Ta/(Nb + Ta) and lower Nb/Ta ratios than CGM1, indicative of precipitation from a hydrosilicate liquid during the magmatic–hydrothermal transition. Based on the characteristics of CGMs, two stages are evident in the evolution of the Weilasituo granite porphyry: an earlier magmatic differentiation stage and a later magmatic–hydrothermal transition stage. Furthermore, the magmatic–hydrothermal transition stage can be subdivided into the AMG and ABG substages within the porphyry system based on petrological and mineralogical characteristics. The U–Pb ages for zircons and CGMs from the alkali feldspar granite porphyry range from 137.2 ± 2.0 Ma to 129.8 ± 1.4 Ma, without a notable age gap. The similarity in U–Pb ages between CGM1–CGM2 and Zr1–Zr2 indicates that the magmatic stage and the magmatic–hydrothermal transition at Weilasituo were continuous processes that occurred during the Early Cretaceous.

EARLY NEOPROTEROZOIC GRANITOIDS IN THE RYAZANOVSKY MASSIF OF THE YENISEI RIDGE AS INDICATORS OF THE GRENVILLE OROGENY AT THE WESTERN MARGIN OF THE SIBERIAN CRATON

Studies of the geological history of the Yenisei Ridge are important not only for understanding the tectonic evolution of mobile belts at the boundaries of ancient cratons but also for problem solving whether the Siberian craton was a part of the Rodinia supercontinent. The mineralogical-petrological, geochemical and isotope-geochronological studies yielded new data on the petrogeochemical composition, petrogenesis features, U-Pb age of zircon, and Sr and 147Sm-143Nd isotopic parameters for the rocks of the Ryazanovsky granitoid massif located near the Yenisei fault zone of the Yenisei Ridge. These rocks are represented by high-ferruginous peraluminous varieties and are comparable to A-granites or highly differentiated I-granites. Their composition evolves from normal to subalkaline granites and leucogranites, characterized by increased concentrations of highly charged and radioactive elements. Isotopic (Sr, Nd) characteristics of the rocks indicate generation from an ancient crustal substrate, the average age of which corresponds to the Paleoproterozoic. The formation of these granites at the Meso-Neoproterozoic boundary (1013±9.9 Ma) corresponds to the early stage of the Grenville orogeny and the formation time of the structure of the Rodinia supercontinent. This episode of regional crustal evolution is correlated with the synchronous successions and similar style of tectonothermal events on the periphery of large Precambrian cratons (Laurentia and Baltica), thus confirming the reliability of the proposed paleocontinental reconstructions of incorporation of the Siberian craton into the Rodinia.

Moderate magnitude clockwise rotation of the Yunlong Basin: Implications for synchronous Eocene rotation of the southeastern Tibetan Plateau

The clockwise rotation and southeastward extrusion of the southeastern Tibetan Plateau have played important roles in accommodating the uplift and deformation of the plateau. Numerous paleomagnetic studies have suggested post−late Eocene clockwise rotation of the southeastern Tibetan Plateau along the eastern Himalaya syntaxis, whereas few researchers have addressed the specific Eocene deformation, leading to ambiguous interpretations of the tectonic evolution in the region. Herein, we conducted a paleomagnetic study of the Yunlong Formation in the Yunlong Basin, which is Late Cretaceous to early Paleocene in age. In total, 386 oriented samples were collected. Rock magnetic, scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS) analyses revealed detrital carriers, such as hematite and some magnetite. In thermal demagnetization processes, 332 characteristic remanent magnetizations were isolated, which yielded positive reversals and tilt tests, providing a site-mean direction of declination (Ds) = 56.0° ± 2.6°, inclination (Is) = 34.3° ± 3.8°, α95 = 2.7°, k = 91.0, and N = 31 after tilt correction. Magnetostratigraphic analysis was performed, and a depositional age of 79−61 Ma for the section was obtained, which is consistent with the previous paleontological and detrital zircon ages. Compared with the Eurasia reference pole of the period, the data revealed a 45.2° ± 5.1° clockwise rotation of the Yunlong area since 79−61 Ma. The integrated regional paleomagnetic results suggest the occurrence of ∼20° of clockwise rotation of the Lanping-Simao terrane during the Eocene, which is similar (in terms of magnitude and time of occurrence) to that of the Gonjo Basin in the eastern Qiangtang terrane. Integrated with other lines of geologic evidence, we propose a new deformation model in which the entire southeastern Tibetan Plateau experienced ∼20° of rigid clockwise rotation during the Eocene, followed by subsequent oroclinal bending.

Mineralizations of Nb-Ta-Rb-Zr and rare-earth elements in Boziguoer, South Tianshan, NW China: Geochronology and geochemistry of monazite and bastnäsite

The Boziguoer alkaline intrusion is located in the South Tianshan Orogenic Belt on the northern margin of the Tarim Craton. The intrusion is entirely mineralized and forms a super-large rare metal (RM) and rare-earth element (REE) deposit dominated by Nb-Ta-Rb, accompanied by Zr-REE. The primary RM minerals include pyrochlore, astrophyllite, and zircon, while the main REE minerals consist of fluocerite, monazite, xenotime, and bastnäsite, which are commonly present as granular aggregates or singularly filling the interstices between gangue minerals. Through a combination of geochronological and geochemical analyses of different types of monazite and bastnäsite in the mineralized alkaline rocks, this study elucidates the role of magmatic-hydrothermal evolution on the Boziguoer RM-REE mineralization and reconstructs the geochronological framework of alkalic magmatic-hydrothermal evolution and mineralization processes, as well as establishing mechanisms responsible for RM-REE enrichment. Petrographic observations and back-scattered electron (BSE) imaging revealed several types of monazite and bastnäsite with different characteristics as follows: (1) type Ia monazite (Mnz-Ia) experienced intense hydrothermal alteration, forming residual cores of monazite mantled by apatite and allanite coronas; (2) type Ib monazite (Mnz-Ib) was partially eroded, forming concentric zoning patterns with a core of monazite, a mantle of apatite, and an outer rim of allanite coronas; (3) type II monazite (Mnz-II) is slightly modified, and commonly associated with fluorite; (4) bastnäsite and fluocerite exhibit a core-rim structure, with the core of fluocerite being brighter than the rim of bastnäsite in BSE images. According to the paragenetic relationships and compositional variations, all two types of monazite are of primary magmatic origin, while bastnäsite is of hydrothermal origin. In addition, principal component analysis (PCA) and partial least squares-discriminant analysis (PLS-DA) results indicate that Mnz-Ia and Mnz-Ib belong to the same group, different from Mnz-II. The latter has higher (Ce/Gd)N and (Th/U)N ratios, indicating relatively low-temperature crystallization of Mnz-II at late stages. In-situ LA-ICP-MS U-Th-Pb dating of monazite and bastnäsite show that Mnz-Ia and Mnz-Ib have ages of ca. 290 Ma, consistent with the zircon age of the intrusion, whereas the Mnz-II and bastnäsite have younger ages of ca. 280 Ma, representing a post-magmatic hydrothermal mineralization event at Boziguoer. These new ages indicate that both magmatic and subsequent hydrothermal processes played critical roles in the RM-REE mineralization in this deposit. The latest findings also support the model that the formation of the alkaline belt where the Boziguoer ore-bearing intrusion was temporally and spatially linked to the Tarim Large Igneous Province that is genetically related to a mantle plume.

Formation of a late-orogenic conglomeratic sequence in the Neoarchean western Wabigoon terrane, Superior craton

The Neoarchean conglomeratic Timiskaming assemblage is considered to be one of the most gold-endowed rock associations in the Abitibi greenstone belt of the southern Superior craton. Identifying Timiskaming-like basins, therefore, may facilitate new discoveries of gold deposits in other Archean greenstone belts. This study focuses on the conglomeratic Ament Bay assemblage (ABA) in the Neoarchean Sturgeon Lake greenstone belt of the western Wabigoon terrane of the western Superior craton. Geologic mapping and petrographic analysis show that the ABA consists of a ≥1000 m thick conglomerate-arenite lithofacies and a conformably overlying ≥200 m thick greywacke-mudstone lithofacies, which are interpreted to indicate a sub-aerial fan delta that transitioned into subaqueous turbidites. The depositional age is constrained to be between 2697.5 ± 1.2 and 2693.2 ± 0.9 Ma by the statistically defined minimum age of the ABA detrital zircons and igneous zircons of an alkalic intrusion within the ABA, respectively. Detrital zircons from seven ABA samples are characterized by ca. 2930, 2780–2770, and 2750–2690 Ma age populations along with minor zircons of ca. 3300–3000 Ma, which are consistent with proximal sources mostly in the western Wabigoon terrane and secondarily in the adjacent Winnipeg River terrane. Petrography of conglomerate clasts and sandstone supports these provenances and reveals additional sources from proximal mafic volcanic rocks. The ABA is interpreted to result from uplift and erosion associated with the late-stage convergence between the western Wabigoon and Winnipeg River terranes and to be partially controlled by a regional fault zone and accompanied by broadly coeval alkalic magmatism. Overall, the ABA is similar to the typical Timiskaming assemblage in lithofacies, depositional environments, structural setting, and syn-depositional alkalic magmatism, but dissimilar to the latter in gold endowment. The apparent lack of gold in the ABA is likely due to assimilation of crustal components into the coeval alkalic melts and a shallow-penetrating fault zone, in contrast to the juvenile nature of alkalic magmatism and deep-penetrating fault zones associated with the Timiskaming assemblage. This study suggests that Timiskaming-like basins similar in geology are not necessarily equivalent to the typical Timiskaming assemblage in gold endowment.

Rutile and zircon U-Pb dating as a constraint on sedimentary provenance of the Jianchuan Basin: Implications for paleo-drainage evolution

The Yangtze River is the largest river in Asia, and its evolution has been a subject of debate for more than a century. The formation of the First Bend is widely recognized as a key drainage reorganization event that led to the birth of the modern Yangtze River. In this study, we use new detrital rutile UPb ages to constrain the sedimentary provenance of the Cenozoic deposits in the Jianchuan Basin. Our results show that detrital rutile UPb ages of the Eocene sandstones from the Jianchuan Basin are similar to those of the Yalong River and Jinsha River, indicating that the upper Yangtze is likely to have flowed through the Jianchuan Basin in the late Eocene. Moreover, the characteristic zircon age signature of the Yalong and Jinsha Rivers also appear in the Jianchuan Basin, which is consistent with the rutile data. Our new rutile data and previous detrital zircon data suggest that the upper Yangtze River is likely to connect the Red River via the Jianchuan Basin since the late Eocene.

Regional-Scale Paleoproterozoic Heating Event on Archean Acasta Gneisses in Slave Province, Canada: Insights from K–Ar and 40Ar/39Ar Chronology

Slave Province in Canada is an Archean granite–supracrustal terrane at the northwestern corner of the Canadian Shield. It is bordered by the Thelon–Taltson orogen (2.0 to 1.9 Ga) to the southeast and the Wopmay orogen (1.9 to 1.8 Ga) to the west. Acasta gneisses, exposed in the westernmost Slave Province, and the Wopmay rocks, located close to the gneisses, were systematically collected for K–Ar and laser step-heating 40Ar/39Ar single-crystal analyses of the biotite and amphibole. The K–Ar biotite ages of the four Wopmay samples range from 1816 ± 18 Ma to 1854 ± 26 Ma. The 40Ar/39Ar biotite analyses of the three Wopmay samples yield plateau ages of 1826 ± 21 Ma, 1886 ± 13 Ma, and 1870 ± 18 Ma. These ages fall within the reported U–Pb zircon age range of the Wopmay orogen. The K–Ar biotite ages of the fifteen Acasta gneisses range from 1779 ± 25 Ma to 1877 ± 26 Ma, except for one younger sample (1711 ± 25 Ma). The 40Ar/39Ar analyses of the biotite crystals from three samples give the plateau ages of 1877 ± 8 Ma, 1935 ± 14 Ma, and 1951 ± 11 Ma. The K–Ar amphibole ages from twelve samples range from 1949 ± 19 Ma to 1685 ± 25 Ma. Two samples of them give ages older than the zircon U-Pb age of Hepburn plutons. The 40Ar/39Ar analyses of the amphibole crystals show varied age relations. The two samples give plateau ages of 1814 ± 22 Ma and 1964 ± 12 Ma. Some samples exhibit apparent old ages of ~2000 Ma in the middle temperature fractions. These old fractions result from the amphibole crystals, originally formed in the Archean, being affected by the thermal events during the Wopmay orogeny but not fully resetting. These observations suggest that the K–Ar system ages of the biotite and amphibole in the Archean Acasta gneiss were rejuvenated during the Paleoproterozoic ages. The Discussion explores the possibility that the heat source rejuvenating the K–Ar system ages may have arisen due to asthenospheric extrusion into the wedge mantle, a process likely triggered by subduction rollback.

Middle Jurassic to Early Cretaceous orogenesis in the Klamath Mountains Province (Northern California–southern Oregon, USA) occurred by tectonic switching: Insights from detrital zircon U-Pb geochronology of the Condrey Mountain schist

The Klamath Mountains Province of Northern California and southern Oregon, USA, consists of generally east-dipping terranes assembled via Paleozoic to Mesozoic subduction along the western margin of North America. The Klamath Mountains Province more than doubled in mass from Middle Jurassic to Early Cretaceous time, due to alternating episodes of extension (e.g., rifting and formation of the Josephine ophiolite) and shortening (e.g., Siskiyou and Nevadan events). However, the tectonic mechanisms driving this profound Mesozoic growth of the Klamath Mountains Province are poorly understood. In this paper, we show that formation of the Condrey Mountain schist (CMS) of the central Klamath Mountains Province spanned this critical time period and use the archive contained within the CMS as a key to deciphering the Mesozoic tectonics of the Klamath Mountains Province. Igneous samples from the outer CMS subunit yield U-Pb zircon ages of ca. 175–170 Ma, which reflect volcanic protolith eruptive timing. One detrital sample from the same subunit contains abundant (~54% of zircon grains analyzed) Middle Jurassic ages with Paleozoic and Proterozoic grains comprising the remainder and yields a maximum depositional age (MDA) of ca. 170 Ma. These ages, in the context of lithologic and thermochronologic relations, suggest that outer CMS protoliths accumulated in an outboard rift basin and subsequently underthrust the Klamath Mountains Province during the Late Jurassic Nevadan orogeny. Five samples of the chiefly metasedimentary inner CMS yield MDAs ranging from 160 Ma to 130 Ma, with younger ages corresponding to deeper structural levels. Such inverted age zonation is common in subduction complexes and, considering existing K-Ar ages, suggests that the inner CMS was assembled by progressive underplating over a &amp;gt;10 m.y. timespan. Despite this age zonation, age spectra derived from structurally shallow and deep portions of the inner CMS closely overlap those derived from the oldest section of the Franciscan subduction complex (South Fork Mountain schist). These relations suggest that the inner CMS is a composite of South Fork Mountain schist slices that were sequentially underplated beneath the Klamath Mountains Province. The age, inboard position, and structural position (i.e., the CMS resides directly beneath Jurassic arc assemblages with no intervening mantle) of the CMS suggest that these rocks were emplaced during one or more previously unrecognized episodes of shallow-angle subduction restricted to the Klamath Mountains Province. Furthermore, emplacement of the deepest portions of the CMS corresponds with the ca. 136 Ma termination of magmatism in the Klamath Mountains Province, which we relate to the disruption of asthenospheric flow during slab shallowing. The timing of shallow-angle subduction shortly precedes that of the westward translation of the Klamath Mountains Province relative to correlative rocks in the northern Sierra Nevada Range, which suggests that subduction dynamics were responsible for relocating the Klamath Mountains Province from the arc to the forearc. In aggregate, the above relations require at least three distinct phases of extension and/or rifting, each followed by an episode of shallow-angle underthrusting. The dynamic upper-plate deformation envisioned here is best interpreted in the context of tectonic switching, whereby slab steepening and trench retreat alternate with slab shallowing due to recurrent subduction of buoyant oceanic features.

Insight into Oligocene–Early Miocene palaeogeography of the Carpathians in Poland: first cycle and recycled detrital zircon provenance in the Menilite and Krosno formations

A set of 6368 U–Pb isotope ages of detrital zircons from 53 samples of the Oligocene to Early Miocene Menilite and Krosno formations (Outer Western Carpathians) was obtained and interpreted in terms of their sources. In both units the most frequent are mid-Variscan and Cadomian zircons that were derived from the Variscan Internides underlying the studied basin, and from the Brunovistulia Terrane, respectively. The coincidence of detrital zircon ages and clast ages indicates that zircons of that age can be at least partly of first cycle. Sveconorwegian and Calymmian–Statherian recycled zircons of Baltica origin, highly frequent in the Menilite Formation, are most probably sourced from Lower Devonian sediments of the Małopolska Massif. The Oligocene basin of the Menilite Formation was supplied in detrital material largely from the north where the Meta-Carpathian Swell was elevated in the area of the Małopolska Massif and Brunovistulia Terrane. During sedimentation of the Krosno Formation this source expired. A considerable input to the Menilite Formation of Baltica derived zircons and a limited number of zircons from sources located SE of the study area suggests that they were deposited in a relatively shallow and isolated basin. Supplementary material : A list of samples collected, lithological features of sampled rocks and lithostratigraphic sub-units, methods of zircon separation and U–Pb dating, and detailed results of the dating of detrital zircons, with concordia plots and probability density diagrams are available at https://doi.org/10.6084/m9.figshare.c.7100071

Provenance Analysis of the Cenozoic Sedimentary Successions in the Ningnan Basin, NE Tibetan Plateau: Constraints on Sedimentological and Tectonomorphological Evolution

AbstractThe evolution and reforming history of the Cenozoic basins in the northeastern Tibetan Plateau (NETP) are significant for understanding the northeastward growth of the Tibetan Plateau. The sediments in these basins archived the spatial‐temporal patterns of the surface uplift and deformation processes in response to remote effects of growth of the NETP. Here, we present an integrated provenance analysis of the Ningnan basin in the NETP to provide direct insights into the basin evolution and further constraints of the Tibetan Plateau's northeastward growth. In this study, the Cenozoic strata (the Sikouzi, Qingshuiying, Zhang'enpu and Ganhegou formations) in the Ningnan basin yield complex detrital zircon age distributions featured by predominant age populations at 200–360 Ma and 360–540 Ma with minor Precambrian ages. Detrital zircon U‐Pb ages indicate that the southwestern Ordos Block, the western Qinling orogenic belt, and the eastern Qilian orogenic belt are primary source areas. Additionally, adjacent local paleo‐uplifts (e.g., Xi‐nanhuashan, Xiangshan, Liupan mountains.) also provided minor volumes of sediment. In addition, conglomerates and paleocurrent directions of the Sikouzi–Ganhegou formations exhibit an apparent change since the late Mocene, revealing an obvious provenance shift. The quantitatively determined mixing proportions of the surrounding source areas also reveals that the early source‐to‐sink system was replaced during the deposition of the Ganhegou Formation. Combined with previous studies, we suggest that the formation of the Ningnan basin was controlled by normal faults in extension setting and experienced continued sediment accumulation during the Qingshuiying–Zhang'enpu period; since the late Miocene, the significant provenance shift reflects the obvious northeastward growth of the NETP and led to the extinction of the Ningnan basin.

Magma flux variations triggering shallow-level emplacement of the Takidani pluton (Japan): Insights into the volcanic-plutonic connection

Defining the physico-chemical evolution of felsic magmatic reservoirs in the middle-upper continental crust is crucial for understanding the connection between granitic plutons and silicic volcanic rocks and for research on the trigger mechanisms of volcanic eruptions. In this study, we investigate the formation and evolution of the Hotaka-Takidani volcano-plutonic complex (Japan) using a comprehensive approach that integrates zircon petrochronology with phase-equilibria and thermal modelling. The Takidani pluton is a Pleistocene tilted zoned intrusion of granodiorite-granite composition associated with at least two large caldera-forming eruptions. We have investigated the three uppermost units of the pluton and the oldest and more voluminous Nyukawa eruption, which deposited more than 400 km3 (DRE, dense rock equivalent) of crystal-rich dacitic ignimbrite. Amphibole thermobarometry, U-Pb zircon dates and geochemical data indicate that the Takidani pluton and the Nyukawa dacite were sequentially sourced from a 10–12 km-thick long-lived magmatic reservoir in the middle crust. Thermal evolution of the reservoir led to the extraction of the Nyukawa magma, followed by brief storage in the upper crust and eruption at ca. 1.706 ± 0.091 Ma. For two of the units of the pluton, we combine high-spatial resolution zircon U-Pb geochronology with zircon chemical data. Applying the Ti-in-zircon thermometer, we observe that magma within the reservoir was stored at a relatively constant temperature of ca. 700 °C for 300 kyr and subsequently, starting from 1.4 Ma, the temperature increased progressively reaching 820–850 °C at 1.1 Ma. This temperature shift is inconsistent with a constant magma flux and suggests an increase of the magma injection rate into the reservoir. Using the distribution of zircon ages and thermal simulations, we determined that the reservoir was built by a fairly low average magma flux of ca. 6 × 10−6 km3*km−2*yr−1, shifting to a magma supply rate which is three to four times higher during the last 300 ka of zircon crystallisation. This increase in magma flux caused the final emplacement of the Takidani magma in the upper crust, where it rapidly crystallized. The integration of geochronological data with phase-equilibria and thermo-chemical modelling demonstrates that multiple melt extraction events occurred during the evolution of the Hotaka-Takidani magmatic system. Only the first one triggered a major eruption, while subsequent events resulted in the emplacement of the Takidani pluton in the shallow crust.

Magmatic, Metamorphic and Structural History of the Variscan Lizard Ophiolite and Metamorphic Sole, Cornwall, UK

AbstractThe Lizard ophiolite, Cornwall, South‐West England, is the largest and best‐preserved ophiolite within the Variscan orogenic belt. It forms part of the Rheic‐Rhenohercynian suture zone, and was obducted northwestward onto the passive continental margin of Avalonia (Laurussia) during the Middle Devonian. It comprises an almost complete thrust slice of oceanic crust with sheeted dykes, gabbros, Moho transition sequence, and upper‐mantle peridotites, underlain by a metamorphic sole. Despite the importance of the Lizard ophiolite in understanding Variscan tectonics, the origin and age of the Lizard ophiolite are debated. We present new field observations, structural maps and cross‐sections of the Lizard ophiolite from extensive re‐mapping, integrated with U–Pb geochronology, petrology, thermobarometry, and whole rock geochemistry. We report new U–Pb zircon (CA‐ID‐TIMS and LA‐ICPMS) ages of 386.80 ± 0.25/0.31/0.52 Ma (Givetian) from a plagiogranite dyke intruding the Crousa Gabbros at Porthoustock, and 395.08 ± 0.14/0.22/0.47 Ma (Emsian) from partial melts of the metamorphic sole Landewednack Amphibolites at Mullion Cove. These ages, respectively, precisely date the formation of the Lizard ophiolite oceanic crust, and the age of cooling post peak‐metamorphism of the sole. Petrological modeling on the Landewednack Amphibolites suggests peak metamorphic conditions of 10 ± 2 kbar and 600 ± 75°C. We demonstrate that the Lizard ophiolite formed as a supra‐subduction zone ophiolite overlying an inverted metamorphic sole, and we combine our observations and data into a new geodynamic model for the formation and obduction of the ophiolite. The current data supports an induced subduction initiation model.

Connection between tectonothermal events of the Yakutian kimberlite province and assembly of the Siberian craton

The tectonic framework of the Siberian craton is still under debate. It is generally assumed that the Markha and Daldyn terranes collided at 2.2–2.1 Ga and the final assembly of the Siberian craton occurred at 1.9–1.8 Ga. However, previous study on zircons from xenoliths of the Zapolyarnaya pipe, which is located in the Upper Muna kimberlite field and close to the boundary between the Markha and Daldyn terranes, do not show tectonothermal evidence younger than 2.7 Ga. To clarify the tectonothermal evolution of the Siberian craton, we present U-Pb ages and Hf isotope data of zircons from crustal xenoliths in the Novinka and Komsomolskaya Magnitnaya kimberlite pipes in the Upper Muna field. The zircon ages confirm only one major tectonothermal event at 2.7 Ga in the Upper Muna field, which doubts the existence of the collision zone between the Markha and Daldyn terranes. The middle-lower crust beneath the Upper Muna field is mainly composed of mafic and intermediate granulites and experienced long-term cooling. The negative values of εHf(2.7) suggests ignorable addition of juvenile component during partial melting of the Paleoarchean crust at 2.7 Ga. Compared with crustal xenoliths from other kimberlite pipes in the Yakutian diamondiferous province, the crust of the Anabar province shows vertical and lateral heterogeneity and the absence of a relationship between the crustal reworking degree and the main collision zones. We propose that the widespread 2.7 and 1.9 Ga tectonothermal events in the Anabar tectonic province were associated with the episodic rise of superplumes, which not only caused the crustal growth and reworking but also facilitated collision and amalgamation of terranes.

Crustal Architecture of the Paleo‐Pacific Rift Margin of East Antarctica: Evidence From U‐Pb Ages and O‐Hf Isotope Compositions of Ross Orogen Granitoids

AbstractGranitic batholiths of the ∼500 Ma Ross Orogen in Antarctica are voluminous in scale, reflecting prolific magmatism along the active early Paleozoic convergent margin of Gondwana. New age and isotopic analysis of zircons from a large suite of Ross granitoids spanning &gt;2,000 km along the orogen provide a wealth of geochronologic, tracer, and inheritance information, enabling us to investigate the pace of magmatism, along‐strike temporal and geochemical trends, magmatic sources, and tectonic modes of convergence. Because granitoids penetrate the crust of the earlier Neoproterozoic rift margin, they also provide insight into the age and composition of the largely ice‐covered East Antarctic craton. Zircon U‐Pb ages from these and other samples indicate that active Ross magmatism spanned 475–590 Ma, much longer than generally regarded. Most samples have heavy zircon δ18O values between 6.5 and 11.5‰ and initial εHf compositions between 0 and −15; their isotopic co‐variations are independent of age, as in other contemporary continental arcs, and reflect largely crustal melt sources. Samples near Shackleton Glacier have distinctly more mantle‐like isotope composition (i.e., radiogenic εHf and low δ18O) and separate two regions with distinctive isotopic properties and inheritance patterns—a more juvenile section of Mesoproterozoic crust underlying the southern TAM and an older, more evolved region of Paleoproterozoic and Archean crust in the central TAM. The isotopic discontinuity separating these regions indicates the presence of a cryptic crustal boundary of Grenvillian or younger age within the East Antarctic shield that may be traceable into the western Laurentian part of the Rodinia supercontinent.

Discriminating Superimposed Alteration Associated with Epigenetic Base and Precious Metal Vein Systems in the Rouyn-Noranda Mining District, Quebec; Implications for Exploration in Ancient Volcanic Districts

Abstract The Rouyn-Noranda mining district of Quebec contains 20 Cu-Zn (±Au ±Ag) volcanogenic massive sulfide (VMS) deposits, including the giant and gold-rich Quemont and Horne deposits. Mineralized epigenetic veins are also present, but their origin and relative timing remain enigmatic. The nature and extent of their alteration signatures and the effect of their superposition on district-scale alteration patterns is unknown. The VMS-related quartz-sulfide Cu-Zn-Ag veins have δ18Oquartz values of 8.5 ± 0.8‰, reflecting δ18Ofluid compositions of –0.4 to 3.1‰ (250°–350°C) that are typical of Archean seawater. They are associated with a proximal Fe-rich chlorite alteration and marginal spotted sericite-chlorite alteration with whole-rock δ18O values of 2.9 to 5.9‰ and are interpreted to have formed within the structurally controlled discordant upflow zones of a VMS hydrothermal system. Younger gold-bearing quartz-carbonate veins were emplaced along mechanical anisotropies created by mafic dikes during north-south compression and the formation of regional E-trending faults, folds, and cleavage. They are characterized by δ18Oquartz values of 11.3 ± 0.8‰, reflecting δ18Ofluid compositions of 2.4 to 5.9‰ (250°–350°C), typical of a metamorphic fluid, possibly mixed with a lower δ18O upper crustal fluid. They are associated with ankerite, calcite, muscovite, chlorite, albite, and quartz ± hematite alteration with whole-rock δ18O values of 5.8 to 10.3‰. Chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb zircon ages for two tonalite intrusions constrain the maximum age of the Cu-Zn-Ag veins to 2697.6 ± 0.7 Ma and the minimum age to 2695.3 ± 1.0 Ma, which is also the maximum age of the gold quartz-carbonate veins. Superposition of alteration related to the gold quartz-carbonate veins on previously chlorite- and sericite-altered rocks has resulted in mixed alteration signals with whole-rock δ18O values of ~6 to 8‰ that have perturbed and masked regional alteration patterns related to older VMS mineralization, such as those found in the Quemont and Horne deposits. These results indicate that defining alteration vectors in camps that have superimposed hydrothermal systems requires full consideration of the hydrothermal history of the camp, and if such constraints are lacking, whole-rock δ18O values should not be used as a stand-alone exploration method.

Revisiting the depositional age and provenance characteristics of metasedimentary rocks from the basement units in the Central Pontides (N Turkey): New constraints for tectonic evolution of the southern Black Sea region

The pre-Jurassic tectonic evolution of the Central Pontides in northern Turkey is still poorly understood due to the lack of detailed geochemical and geochronological data from the basement units. Therefore, this study reports for the first time combined whole rock geochemistry, trace element data and U-Pb ages for detrital zircons, and Ar-Ar geochronological data from the metasedimentary rocks of the Devrekani Massif, Geme Complex, and the Serveçay Unit to better understand their provenance, depositional age characteristics, and tectonic evolutions. The detrital zircon U-Pb data of metasedimentary units from the Devrekani Massif, Geme Complex, and the Serveçay Unit yield ca. 191, 185 and 298 Ma maximum depositional ages (youngest age peaks), respectively. The Devrekani Massif is dominated by Permo-Carboniferous-aged detrital zircons (67 %), whereas Neoproterozoic and Devonian-aged detrital zircons are more common in the Geme Complex (47 %) and the Serveçay Unit (53 %). These distinct age distributions clearly indicate that the Devrekani Massif may has been deposited in a dissimilar location compared to the Geme Complex and the Serveçay Unit. Furthermore, in contrast to the Devrekani Massif, the source area of the metasedimentary rocks from the Geme Complex is comparable with that of the Serveçay Unit. Lastly, the obtained detrital zircon U-Pb and mica Ar-Ar ages suggest that the Devrekani Massif and the Geme Complex were deposited and metamorphosed during the Early and Middle Jurassic, respectively. The Serveçay Unit was deposited and metamorphosed in the Permian.